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Class 12 Chemistry MCQ - CH-2 Elctrochem
Class 12 Chemistry MCQ - CH-2 Elctrochem
Class 12 Chemistry MCQ - CH-2 Elctrochem
7. When electric current is passed through a cell having an electrolyte, the Knowledge
positive ions move towards the cathode and the negative ions towards
the anode. If the cathode is pulled out of the solution
A) The positive and negative ions will move towards the anode
B) The positive ions will start moving towards the anode, the negative
ions will stop moving
C) The negative ions will continue to move towards the anode and the
positive ions will stop moving
D) The positive and negative ions will start moving randomly
8. Molar conductivity of 0.15 M solution of KCl at 298 K, if its conductivity Application
is 0.0152 s/cm, will be
(a)124per ohm cm2 per mole
(b)204 per ohm cm2 per mole
(c) 101 per ohm cm2 per mole
(d)300 per ohm cm2 per mole
9. Kohlrausch’s law is applicable Understanding
(a)For concentrated solution
(b)At infinite dilutions
(c)For concentrated as well as dilute solutions
(d) None of the above
10. Faraday's law of electrolysis are related to the: Knowledge
(a) Atomic number of the cation
(b) atomic number of the anion
(c) equivalent weight of the electrolyte
(d) speed of the cation
11 If limiting molar conductivity of Ca2+ and Cl– are 119.0 and 76.3 S cm2 Applications
mol-1, then the value of limiting molar conductivity of CaCl2 will be:
(a)195.3 S cm2 mol-1 (b) 271.6 S cm2 mol-1
(c) 43.3 S cm2 mol-1 ( d) 314.3 S cm2 mol-1
33. If the half-cell reaction A + e−→A- has a large negative reduction potential, it Knowledge
follows that
A) A is readily reduced
B) A is readily oxidised
C) A- is readily reduced
D) A- is readily oxidized
34. The relationship between standard reduction potential of cell and equilibrium understanding
constant is shown by
A) E0 cell=n/0.059 log Kc
B) E0 cell=0.059/ n log Kc
C) E0 cell=0.059nlogKc
D) E0 cell=log Kc/ n
36 A new galvanic cell E°V of more than E°V of Daniel cell is connected to Daniel Understanding
cell in a manner that new cell gives electrons to cathode, what will happen
(a) ECell will increase
(b) ECell will decrease
(c) No change will take place
(d) Daniel cell will work as electrolytic cell where Zn will be deposit on zinc rod
and copper will dissolve from copper rod
37 The measured reduction potential for the reaction Mg2+ + 2e–⎯→Mg(s) Knowledge
depends upon
(A) Concentration of Mg2+ in solution
(B) area of Mg plate
(C) temperature
(D) both a and c
(a)
(b)
(c)
(d)
50. The conductance at infinite dilution follow the order Application
(a) Li+ > Na+ > K+
(b) Na+ > Li+ > K+
(c) K+ > Li+ > Na+
(d) K+ > Na+ > Li+
51. With increase in temperature the degree of dissociation of electrolyte: Understanding
(a) Increases
(b) Depends on the enthalpy change of dissolution
(c) Decreases
(d) Depends on the nature of salt
52 Units of the properties measured are given below. Which of the properties has Knowledge
not been matched correctly?
(a)Molar conductance = S m2mol-1
(b)Cell constant = m-1
(c)Specific conductance = S m2
(d)Equivalent conductance = S m2 eq -1
53 The quantity of charge required to obtain 1 mole of aluminum from Al2 O3 is Application
(a)3F
(b)6F
(c)1F
(d)2F
54 Which of the following statement is correct regarding variation of molar understanding
conductivity with concentration?
(a)Molar conductivity decreases with decrease in concentration.
(b)Variation in molar conductivity of weak and strong electrolytes is same.
(c)Molar conductivity increases with decreases in concentration.
(d) When concentration of the solution approaches zero, the molar
conductivity is known as conductance.
55 When water is added to an aq. Solution of an electrolyte, what is the change Application
in specific conductivity of the electrolyte?
a . conductivity decreases
b. conductivity increases
c .conductivity remain same
d.Conductivity does not depend on number of ions
67 Determine the value of E°cell for the following reaction, Cu2+ + Application
Sn+2 → Cu + Sn+4, equilibrium constant is 106.
(a) 0.1773 (b) .01773
(c) 0.2153 (d) 1.773
72 Which cell will measure standard electrode potential of copper electrode? understanding
a. Pt (s) | H2 (g, 0.1 bar) | H+ (aq. , 1 M) || Cu2+(aq.,1M) | Cu
b. Pt(s) | H2 (g, 1 bar) | H+ (aq. , 1 M) || Cu2+ (aq., 2 M) | Cu
c. Pt(s)| H2 (g, 1 bar) | H+ (aq. , 1 M) || Cu2+ (aq.,1 M) | Cu
d. Pt(s) | H2 (g, 1 bar) | H+ (aq.,0.1 M) || Cu2+ (aq.,1 M) | Cu
74 During the electrolysis of molten sodium chloride the time required to understanding
produce 0.1 mol of chlorine gas using a current of 3 A is:
(a) 55 minutes (b) 110 minutes
(c) 220 minutes (d) 330 minutes
75 What will happen during the electrolysis of aqueous solution of CuSO4 in the Application
presence of Cu electrodes?
(a) Copper will deposit at cathode.
(b) Oxygen will be released at anode.
(c) Copper will deposit at anode.(d) None of the above
78 Two different electrolytic cells are connected in series, containing aq AgNO3 Understanding
and aq CuSO4 respectively. The molar ratio of copper to silver deposited at
cathodes in the two cells will be
(a)2/1 (b)1/2 (c) 3/2 (d) 2/3
81 The standard emf of a galvanic cell involving cell reaction with n=1 is found to Application
be 0.298 Vat 250C. The equilibrium constant will be
(a) 1.1X 104 (b) 2.1X 104 (c) 2.2X 105 (d) 1.1 X 105
87 The difference between the electrode potentials of two electrodes when no Knowledge
current is drawn through the cell is called
(A) Cell potential
(B) Cell emf
(C) Potential difference
(D) Cell voltage
88 Choose the correct option : For the given cell , Analysis
Mg(s) / Mg2+(aq) // Cu 2+(aq) / Cu(s)
(A)Mg is cathode
(B)Copper is cathode
(C)Reduction takes place at Mg electrode
(D) Oxidation takes place at copper electrode.
89 An electrochemical cell can behave like electrolytic cell when Understanding
(A) Ecell =0
(B)Ecell>Eext
(C)Ecell = Eext
(D) Eext>Ecell
53 A 3F
54 c. Molar conductivity increases with decreases in concentration
55 a . conductivity decreases
56 d. 4.825*105 C
57 d. The addition of liquid bromine to iodide solution turns it violet
58 B
59 C 271.6, 91.0 and 126.4 S cm2 mol-1
60 D
61 B
62 A
63 B
64 D
65 D
66 A
67 A
68 D
69 A
70 C
71 A
72 C
73 C
74 B
75 A
76 B
77 C
78 B
79 A
80 A
81 D
82 C
83 B
84 B
85 A
86 B
87 B
88 B
89 D
90 D
91 C
92 B
93 C
94 D
95 A
96 B
Questions submitted by the PGTs (Chemistry) of Bhubaneswar, Guwahati, Kolkata, Ranchi, Silchar &
Tinsukia Regions.
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