31.

ANS :- C
HINT :-

32.

ANS :- A
HINT :-

33. Which of the following statement(s) about spectral series is/are correct ?
(a) Paschen series appears in the infrared region
(b) The lines in the Balmer series corresponds to electron transitions from
energy levels higher than n = 2 energy level
(c) Transitions from higher energy levels to 5th energy level produce pfund
series which falls in the infrared region
(d) The lines of Lyman series appear in the visible region
(A) a, b, d (B) b, d (C*) a, b, c (D) a, c, d

HINT :- The Lyman series lies in the ultraviolet

34. The radii of two of the first four Bohr's orbits of the hydrogen atom are in
the ratio 1 : 4. The energy difference between them may be :-
(A) Either 12.09 eV or 3.4 eV
(B*) Either 2.55 eV or 10.2 eV
(C) Either 13.6 eV or 3.4 eV
(D) Either 3.4 eV or 0.85 eV

HINT :-

35. Which of the following pairs of species would you expect to have largest
difference in spin only magnetic moment ?

(A) (B*)

(C) (D)

HINT :-

36. In which of the following compound all the bond angles are equal :-
(A) SF4 (B*) CCl4 (C) CHCl3 (D) XeF6
HINT :-
37. Which of the following is not correctly match between given species and
type of overlapping ?
(A) XeO3 : Three (d–p) bonds
(B) H2SO4: Two (d–p) bonds
(C*) SO3 : Three (d–p) bonds
(D) HClO4 : Three (d–p) bonds
HINT :-

38. Which of the following have highest number of 90° bond angle?
(A*) SF6 (B) IF7(C) PF5(D) ICl4–
HINT :-
39. The number of d-electrons in Mn2+ is equal to that of
(1) p-electrons in N (2*) s-electron in Na
(3) d-electrons in Fe+2 (4) p- electrons in O–2

HINT :-

40. Find the total number of element which have higher ionisation energy
than their both adjacent elements (either in a period or in a group in the
long from of periodic table).
Be, B, N, P, Ga, S, Mg
(1) 4 (2*) 5 (3) 6 (4) 7
HINT :-

41. Consider the following reaction,

5H2O2 + xClO2 + 2OH– → xCl– + yO2 + 6H2O
The reaction is balanced if -
(A) x = 5, y = 2 (B*) x = 2, y = 5
(C) x = 4, y = 10 (D) x = 5, y = 5
HINT :- As Per Theory.

42.

ANS :- B
HINT:- theoretical

43.

ANS:- B
HINT :- theoretical

44.
ANS :- B
HINT :- A,C are aromatic.

45. The least stable carbocation is

ANS :- A
HINT :- –M effect decreases stability of carbocation.
46. For which of the following molecule significant 𝜇 ≠ 0 ?
(1) Only (C ) (2) (B) and (D)
(3) Only (A) (4*) (A) and (B)

HINT :- Conceptual

47. The decreasing order of –I effect of the following is

(1*) I > II > IV > III > V

(2)

(3)
(4)

48. The Stability order of the following species is

(1) I > II > III > IV (2) III > I > II > IV
(3) IV > II > III > I (4*) IV > III > II > I

49. Which of the following is paramagnetic in nature

(1) carbocation (2) Carbanion (3*) Free radical 4) All
50. How many lone pairs are present in the given cation ?

(1) 3 (2*) 4 (3) 5 (4) 6

51. How many elements are more electropositive than Cl?

B, N, O, S, P, At, H, Li
ANS :- A
HINT :- B , S , P , At , H , Li are more are more electropositive than Cl

52. Find the total number of molecule / ions in which d–orbitals is / are not in
hybridisation

Ans :- 5

Hint :- , , , ,

53. Number of molecules or ions which has/have any bond angle of 120° is

Ans :- 4
Hint :- CH3+ , CO3–2 , BCl3 , PCl5

54. Find the total number of species have permanant dipole moment.
CH3Cl, CH2Cl2, CHCl3, CCl4,PF2Cl3, PF3Cl2,PF4Cl, SO2, SO3
Ans :- 6
HINT :- As per theory.

55. How many sp2 atom are present in aniline

ANS :- 7
HINT :-
56. How many groups show –I effect ?

ANS :- 6

57. Find out the number of compounds which are more stabilized in ionic
structure , from the following

ANS :- 2
HINT :- 1 , 4 are quasi aromatic compound which are more stabilized in ionic
structure.

58. Find the total number of the position where positive charge can be delocalized
by true resonance

ANS :- 7
HINT :-
59. A welding fuel gas contains carbon and hydrogen only. Burning a small
sample of it in oxygen gives 3.38 g carbon dioxide , 0.690 g of water and no
other products. A volume of 10.0 L (measured at STP) of this welding gas is
found to weigh 11.6 g. Calculate molar mass of the gas.(NEAREST INTEGER)
ANS :- 26
HINT :-

60. A definite amount of gaseous hydrocarbon was burnt with just sufficient
amount of O2. The volume of all reactants was 600 ml, after the explosion the
volume of the products [CO2(g) and H2O(g)] was found to be 700 ml under the
similar conditions. The molecular weight (in g/mol) of the hydrocarbon
compound is : (nearest integer)
ans :- 44
hint :-