The Heat energy REQUIRED to Heat of Combustion (∆𝐻 − 𝑣𝑒) The heat energy REQUIRED to remove the outermost electron from Heat Energy Produced when ONE form ONE mole of free gaseous free gaseous atoms to form ONE mole of a substance completely burns atoms of an element. 1 mole of free gaseous ions. in air/O2(g). Cl2 (g) Cl (g) ∆𝐻 = +122𝑘𝐽/𝑀𝑜𝑙 9 2 Na (g) Na+(g) ∆𝐻 = +496𝑘𝐽/𝑚𝑜𝑙 C(s) + O2(g) CO2(g) ∆𝐻 = −393𝑘𝐽/𝑀𝑜𝑙 Na(s) Na (g) ∆𝐻 = +107𝑘𝐽/𝑀𝑜𝑙 H2(g) + 𝟏 O2(g) H2O(l) ∆𝐻 = −286𝑘𝐽/𝑀𝑜𝑙 2 𝟐 1 Electron Affinity (∆𝐻 +/−𝑣𝑒) The Heat Energy REQUIRED or PRODUCED, when free gaseous atoms Enthalpy of formation (∆𝐻 −/+𝑣𝑒) gain electron to form ONE mole of free Energy EVOLVED/ABSORBED when gaseous IONS. ONE mole of a substance is formed from its constituent ELEMENTS ∆𝑯 Cl (g) + 1e O-(g) + 1e Cl- (g)∆𝐻 = −349𝑘𝐽/𝑚𝑜𝑙 O2-(g) ∆𝐻 = +844𝑘𝐽/𝑚𝑜𝑙 8 C(s) + O2(g) CO2 (g)∆H=-393k J/mol H2(g) + O2 (g) 1 2 H2O(l)∆𝑯 = −𝟐𝟖𝟔kJ/mol 3
Lattice Energy (∆𝐻 − 𝑣𝑒)
The Heat Energy PRODUCED when Hydration Energy (∆𝐻 − 𝑣𝑒) Heat of Solution (∆𝐻 +/−𝑣𝑒) free gaseous IONS (cations and anions) Heat Energy PRODUCED when Heat Energy EVOLVED/ABSORBED combine to form ONE mole of a solid ONE mole of free gaseous ions are When ONE mole of a substance is substance. completely surrounded by water 6 dissolved in excess water. Na+(g) + Cl-(g) NaCl(s)∆𝐻 = −787𝑘𝐽/𝑚𝑜𝑙 molecules. Na+(g) Excess water Na+(aq)∆𝐻 = −405𝑘𝐽/𝑚𝑜𝑙 water NaCl(s) Na+(aq) + Cl-(aq)∆𝐻 = +4𝑘𝐽/𝑀𝑜𝑙 4 5