NEET (UG)

MOCK TEST - 8

CHEMISTRY

(c) C2H5OH, C2H6, C2H5Cl

SECTION A
(d) C2H5OH, C2H5ONa, C2H5Cl
Q. 51. The correct bond order in the following Q. 57. Equal moles of hydrogen and oxygen gases
species is: are placed in a container with a pin-hole
(a) O+ – 2+ through which both can escape. What fraction
2 < O 2 < O2
of the oxygen escapes in the time required for
(b) O2– < O+ 2+
2 < O2 one-half of the hydrogen to escape?
(c) O22+ < O+ –
2 < O2 (a) 3/8 (b) 1/2
(d) O22+ < O2– < O+
2
(c) 1/8 (d) 1/4
Q. 52. Which oxide of nitrogen is not a common Q. 58. The pair of electrons in the given carbanion,
–
pollutant introduced into the atmosphere CH3C≡≡C is present in which of the
both due to natural and human activity? following orbitals?
(a) N2O (b) NO2 (a) sp2 (b) sp
3
(c) N2O5 (d) NO (c) 2p (d) sp
Q. 53. Iron carbonyl, Fe(CO)5 is: Q. 59. The compound C7H8 undergoes the follow­
(a) Trinuclear (b) Mononuclear ing reactions:
(c) Tetranuclear (d) Dinuclear 3Cl / ∆ Br /Fe Zn/HCl
C7 H8 
2
→ A 
2
→ B → C
Q. 54. A gas is allowed to expand in a well-
The product ‘C’ is
insulated container against a constant
external pressure of 2.5 atm from an initial (a) m–bromotoluene
volume of 2.50 L to a final volume of 4.50 L. (b) o–bromotoluene
The change in internal energy DU of the gas (c) 3–bromo–2,4,6–trichlorotoluene
in joules will be: (d) p–bromotoluene
Q. 60. How many grams of concentrated nitric
(a) 1136.25 J (b) – 500 J
acid solution should be used to prepare
(c) – 505 J (d) 505 J
250 mL of 2.0 M HNO3? The concentrated
Q. 55. The van’t Hoff factor (i) for a dilute aqueous acid is 70% HNO3.
solution of the strong electrolyte barium (a) 45.0 g conc. HNO3
hydroxide is:
(b) 90.0 g conc. HNO3
(a) 0 (b) 1 (c) 70.0 g conc. HNO3
(c) 2 (d) 3 (d) 540 g conc. HNO3
Q. 56. The compound A on treatment with Na Q. 61. Consider the reaction,
gives B, and with PCl5 gives C. B and C react CH3CH2CH2Br + NaCN → CH3CH2CH2CN
together to give diethyl ether. A, B and C are  + NaBr
in the order:
This reaction will be the fastest in:
(a) C2H5Cl, C2H6, C2H5OH (a) ethanol
(b) C2H5OH, C2H5Cl, C2H5ONa (b) methanol
 (c) N, N’-dimethylformamide (DMF) of nitrogen collected at 300 K temperature
(d) water and 715   mm pressure. The percentage
Q. 62. A gaseous mixture was prepared by taking composition of nitrogen in the compound
equal moles of CO and N2. If the total would be (Aqueous tension at 300 K = 15
pressure of the mixture was found 1 atm, mm)
the partial pressure of the nitrogen (N2) in (a) 16.45 (b) 17.45
the mixture is: (c) 14.45 (d) 15.45
(a) 0.8 atm (b) 0.9 atm Q. 70. Given are cyclohexanol (I), acetic acid (II),
(c) 1 atm (d) 0.5 atm 2, 4, 6-trinitrophenol (III) and phenol (IV).
Q. 63. The number of carbon atoms per unit cell of In these the order of decreasing acidic
diamond unit cell is: character will be:
(a) 6 (b) 1 (a) III > II > IV > I
(c) 4 (d) 8 (b) II > III > I > IV
Q. 64. Jahn-Teller effect is not observed in high (c) II > III > IV > I
spin complexes of: (d) III > IV > II > I
(a) d7 (b) d8 Q. 71. Magnetic moment 2.84 B.M. is given by:
4 9
(c) d (d) d
Atomic number Ni = 28, Ti = 22, Cr = 24,
Q. 65. Which one of the following is correct option Co = 27)
for free expansion of an ideal gas under
(a) Ni+2 (b) Ti+3
adiabatic condition? 3+ +2
(c) Cr (d) Co
(a) q ≠ 0, DT = 0, W = 0
Q. 72. 2, 3-dimethyl-2-butene can be prepared by
(b) q = 0, DT = 0, W = 0
heating which of the following compounds
(c) q = 0, DT < 0, W ≠ 0
with a strong acid?
(d) q = 0, DT ≠ 0, W = 0
Q. 66. The number of octahedral void(s) per atom (a) (CH3)3CCH=CH2
present in a cubic close-packed structure is: (b) (CH3)2C=C(CH3)2
(a) 1 (b) 3 (c) (CH3)2CHCH2CH=CH2
(c) 2 (d) 4 (d) (CH3)2CH  CHCH=CH2
Q. 67. The given below reaction is an example of 
CH3
NaH – +
—OH —O Na Q. 73. Given that bond energies of H–H and
–1 –1
Cl–Cl are 430 kJ mol and 240 kJ mol
Me-I respectively and ∆Hf for HCl is –90 kJ mol–1.
Bond enthalpy of HCl is:
Me (a) 290 kJ mol–1 (b) 380 kJ mol–1
—O (c) 425 kJ mol–1 (d) 245 kJ mol–1
Q. 74. The formation of the oxide ion, O2–(g) from
(a) Riemann Tiemann reaction
oxygen atom requires first an exothermic
(b) Kolbe’s reaction and then an endothermic step as shown
(c) Williamson ether synthesis reaction below:
(d) Williamson alcohol synthesis reaction
O(g) + e– → O–(g) ∆f ; H° = –141 kJ mol–1
Q. 68. Given, the mass of electron is 9.11 × 10–31 kg,
Planck’s constant is 6.626 × 10–34 Js, the O–(g) + e– → O2–(g); ∆f, H° = + 780 kJ mol–1
uncertainty involved in the measurement Thus, process of formation of O2– in gas
of velocity within a distance of 0.1Å is: phase is unfavourable even though O2– is
(a) 5.79 × 106 ms–1 (b) 5.79 × 107 ms–1 isoelectronic with neon. It is due to the fact
(c) 5.79 × 108 ms–1 (d) 5.79 × 105 ms–1 that:
Q. 69. In Duma’s method of estimation of nitrogen (a) O ion has comparatively smaller size
0.35 g of an organic compound gave 55 mL than oxygen atom.
 (b) Oxygen is more electronegative. (c) They have large excess of H+ or OH–
(c) Addition of electron in oxygen results in ions.
larger size of the ion. (d) They have fixed value of pH.
(d) Electron repulsion outweighs the stabil- Q. 80. Which one of the alkali metals, forms only
ity gained by achieving noble gas con- the normal oxide, M2O on heating in air?
figuration.
(a) Rb (b) K
Q. 75. Which one of the following statements is (c) Li (d) Na
not true regarding (+) lactose?
Q. 81. The Langmuir adsorption isotherm is
(a) On hydrolysis (+) lactose gives equal deduced by using the assumption that:
amount of D-(+) glucose and D-(+)
(a) the adsorption takes place in multi-­
galactose.
layers.
(b) (+) Lactose is a b-glucoside formed by
(b) the adsorption sites are equivalent in
the union of a molecule of D(+) glucose
their ability to adsorb the particles.
and a molecule of D(+) galactose.
(c) the heat of adsorption varies with cov-
(c) (+) Lactose is a reducing sugar and
erage.
does not exhibit mutarotation.
(d) the adsorbed molecules interact with
(d) (+) Lactose, C12H22O11 contains 8-OH
each other.
groups.
Q. 82. Which of the following compounds will not
Q. 76. The relative reactivity of acyl compounds
undergo Friedel-Craft’s reaction easily?
towards nucleophilic substitution are in the
order of: (a) Cumene (b) Xylene
(c) Nitrobenzene (d) Toluene
(a) acyl chloride > acid anhydride > ester
> amide Q. 83. The correct sequence of increasing covalent
(b) ester > acyl chloride > amide > acid character is represented by:
anhydride (a) LiCl < NaCl < BeCl2
(c) acid anhydride > amide > ester > acyl (b) BeCl2 < NaCl < LiCl
chloride (c) NaCl < LiCl < BeCl2
(d) acyl chloride > ester > acid anhydride (d) BeCl2 < LiCl < NaCl
> amide Q. 84. If the concentration of OH– ions in the
Q. 77. Activation energy of a chemical reaction can reaction, Fe(OH)3(s)  Fe3+(aq) + 3OH–(aq)
be determined by: is decreased by ¼ times, then equilibrium
3+
(a) evaluating rate constant at standard concentration of Fe will increase by:
temperature. (a) 8 times (b) 16 times
(b) evaluating velocities of reaction at two (c) 64 times (d) 4 times
different temperatures. Q. 85. Which of the following is redox reaction?
(c) evaluating rate constants at two differ-
(a) Evaporation of H2O.
ent temperatures.
(d) changing concentration of reactants. (b) Both oxidation and reduction.
Q. 78. Which of the following compounds has a (c) H2SO4 and NaOH.
3-centre-2-electron bond? (d) In atmosphere O3 from O2 by lightning.
(a) Diborane
(b) CO2 SECTION B
(c) Boron trifluoride
(d) Ammonia Q. 86. Which one of the following statements
regarding photochemical smog is not
Q. 79. Buffer solutions have constant acidity and
correct?
alkalinity because:
(a) Carbon monoxide does not play any
(a) These give unionized acid or base on
role in photochemical smog formation.
reaction with added acid or alkali.
(b) Acids and alkalies in these solutions are (b) Photochemical smog is an oxidizing
shielded from attack by other ions. agent in character.
 (c) Photochemical smog is formed through COO–
photochemical reaction involving solar (c)
energy.
(d) Photochemical smog does not cause
irritation in eyes and throat.
Q. 87. The straight chain polymer is formed by:
(d)
(a) Hydrolysis of (CH3)3SiCl followed by
condensation polymerisation.
(b) Hydrolysis of CH3SiCl3 followed by
condensation polymerisation. Q. 92. Aniline in a set of the following reactions
(c) Hydrolysis of (CH3)4Si by addition pol- yields a coloured product Y.
ymerisation. NH2
(d) Hydrolysis of (CH3)2SiCl2 followed by
condensation polymerisation. NaNO2/HCl N, N-dimethylaniline
X Y
Q. 88. Which of the following statements, about (273–278 K)
the advantage of roasting of sulphide ore
before reduction is not true? The structure of Y would be:
(a) Carbon and hydrogen are suitable
reducing agents for metal sulphides. (a)
(b) The Df G° of the sulphide is greater than
those for CS2 and H2S.
(c) The Df G° is negative for roasting of sul-
phide ore to oxide. (b)
(d) Roasting of the sulphide to the oxide is
thermodynamically feasible.
Q. 89. Acidity of diprotic acids in aqueous solutions (c)
increases in the order.
(a) H2S < H2Se < H2Te
(b) H2Se < H2S < H2Te
(d)
(c) H2Te < H2S < H2Se
(d) H2Se < H2Te < H2S
Q. 93. The relative lowering of vapour pressure
Q. 90. Solution of 0.1N NH4OH and 0.1N NH4Cl
of an aqueous solution containing a non
has pH 9.25, then find out pKb of NH4OH.
volatile solute is 0.0125. The molality of
(a) 9.25 (b) 4.75
solution is:
(c) 3.75 (d) 8.25
(a) 0.40 (b) 0.50
Q. 91. What will the product formed in the given
(c) 0.70 (d) 0.80
reaction?
Q. 94. E°cell for the given reaction is 1.10 V at 25°C.
CHO
Calculate the equilibrium constant for the
50% KOH reaction.
Zn + Cu 2 + ( aq )  Zn 2 + ( aq ) + Cu
Cl
–28 37
(a) 10 (b) 10
19 17
(a) (c) 10 (d) 10
Q. 95. Which of the following is the correct order
OH OH of E°M2+/M values for Cr, Mn, Fe and Co?
CH2COO– (a) Fe > Mn > Cr > Co
(b) Cr > Mn > Fe > Co
(b)
(c) Mn > Cr > Fe > Co
(d) Cr > Fe > Mn > Co
Cl Cl
Q. 96. Match List I with List II. (d) Statement 1 is correct but statement 2 is
incorrect.
List I List II
Q. 98. Calculate the time required to produce
(a) Iproniazid (i) analgesic
0.10 mol of chlorine gas using a current of
(b) Aspirin (ii) anti-fertility drug 3 amperes during the electrolysis of molten
(c) Novestrol (iii) antibiotics sodium chloride.
(d) Ofloxacin (iv) Antidepressant drug (a) 55.67 mins (b) 219.9 mins
Choose the correct answer from given (c) 330 mins (d) 107.22 mins
options. Q. 99. Given two statements
(a) (a) - (i), (b) - (ii), (c) - (iii), (d) - (iv) Statement 1: ∆H is not always equal to cp∆T.
(b) (a) - (iii), (b) - (ii), (c) - (iv), (d) - (i)
Statement 2: cp is a polynomial function of
(c) (a) - (iv), (b) - (i), (c) - (ii), (d) - (iii)
temperature.
(d) (a) - (i), (b) - (iv), (c) - (iii), (d) - (ii)
Q. 97. Given two statements (a) Statement 1 is incorrect but statement 2
is correct.
Statement 1: Permanent hardness can be
(b) Both statement 1 and statement 2 are
removed by process of boiling.
correct.
Statement 2: During boiling the soluble (c) Both statement 1 and statement 2 are
bicarbonates are converted into insoluble incorrect.
carbonates, which can be precipitated easily.
(d) Statement 1 is correct but statement 2 is
(a) Statement 1 is incorrect but statement 2 incorrect.
is correct. Q. 100. In which of the following the central metal
(b) Both statement 1 and statement 2 are atom doesn’t exhibit an oxidation state of +2.
correct. (a) K2[Ni(CN)4] (b) K4[Fe(CN)6]
(c) Both statement 1 and statement 2 are 3–
(c) [Fe(C2O4)3] (d) [Cu(NH3)4]2+
incorrect.
 ANSWER KEY (SQP-8)

Chemistry
51. (b) 64. (b) 77. (c) 90. (b)
52. (c) 65. (b) 78. (a) 91. (c)
53. (b) 66. (a) 79. (a) 92. (a)
54. (c) 67. (c) 80. (c) 93. (c)
55. (d) 68. (a) 81. (b) 94. (b)
56. (d) 69. (a) 82. (c) 95. (c)
57. (c) 70. (a) 83. (c) 96. (c)
58. (b) 71. (a) 84. (c) 97. (a)
59. (a) 72. (b) 85. (b) 98. (d)
60. (a) 73. (c) 86. (d) 99. (b)
61. (c) 74. (d) 87. (d) 100. (c)
62. (d) 75. (c) 88. (a)
63. (d) 76. (a) 89. (a)

mmm
 NEET (UG)
MOCK TEST - 8

ANSWERS WITH EXPLANATION

CHEMISTRY

SECTION A
51. Option (b) is correct.
+
Electronic configuration of O2 = σ1s2 < σ*1s2 < σ2 s2 < σ* 2 s2 < σ2 pz2 < π 2 px2 = π 2 py2 < π* 2 p1x = π* 2 p0y
10 − 5 5
Bond order = = = 2.5
2 2
–
Electronic configuration of O2 = σ1s2 < σ* 1s2 < σ2s2 < σ* 2s2 < σ2 pz2 < π2 px2 = π2 py2 < π* 2 px2 = π* 2 p1y
10 − 7 3
Bond order = = = 1.5
2 2
2+
Electronic configuration of O2 = σ1s2 < σ*1s2 < σ2 s2 < σ* 2 s2 < σ2 pz2 < π 2 px2 = π 2 py2 < π* 2 px0 = π* 2 p0y
10 − 4
Bond order = =3
2
2– + 2+
Thus, the correct bond order for given species is: O < O2 < O2 .

52. Option (c) is correct. S 2

C2 H5O− Na+ + C2 H5Cl 
N
→ C2 H5OC2 H5
Nitrogen pentaoxide (N2O5) is an oxide of (B) (C)
nitrogen that is not a common pollutant.
Nitrous oxide (N2O) occurs naturally in the 57. Option (c) is correct.
environment. In an automobile engine, when Let the number of moles of each gas be x moles.
fuel is burnt dinitrogen and dioxygen combine Then, the fraction of hydrogen gas escaped
to yield NO and NO2. x
= moles
 53. Option (b) is correct. 2
Based on the number of metal atoms present in Then, according to the following relation
a complex, they are classified into mononuclear, nO2 MH2 2
dinuclear, trinuclear and so on. E.g.: = =
nH 2 M O2 32

Fe(CO)5 : Mononuclear
Co2(CO)8 : Dinuclear nO2 1
=
Fe3(CO)12: Trinuclear nH 2 4

Fe(CO)5 is mononuclear because, nO2 1
=
EAN = Z – O.N. + 2(C.N) x/2 4

Here, Z = Atomic no., O.N.= Oxidation no., x
C.N=Coordination no. ⇒ nO2 =
8
So, EAN = 26 – 0 + 2(5) = 36
Thus, a fraction of moles of oxygen gas escaped
Only one central atom is present and it follows 1
is .
EAN rules, so it is mononuclear. 8
54. Option (c) is correct. 58. Option (b) is correct.
Work done against constant external pressure sp sp
(irreversible process). CH3  C ≡≡ C −
W = –Pext DV. Thus, pair of electrons is present in
Work done in irreversible process: sp-hybridized orbital.
W = – Pext DV = – Pext (V2 – V1) 59. Option (a) is correct.
= –2.5 atm (4.5 L – 2.5 L) CH3 CCl3 CCl3

= 2.5 atm × 2 L 3Cl2 Br2

= –5 L atm = –5 × 101.3 J = –505 J ∆ Fe
Br
Now, according to first law of thermodynamics, (C7H8) (A) (B)
DU = q + w
Zn HCl

Since, the system is well insulated, q = 0
\ DU = w = –505 J CH3

55. Option (d) is correct.

Ba(OH)2 is a strong electrolyte and undergoes
cent percent dissociation in a dilute aqueous Br
(C)
solution.
m-bromotoluene
2+ –
Ba(OH)2(aq) → Ba (aq) + 2OH (aq)
60. Option (a) is correct.
Thus, van’t Hoff factor, i = 1 + 2 = 3.
Molarity of solution
56. Option (d) is correct.
Mass of solute
Na
→ C 2 H 5O− Na+
C 2 H 5OH  =
The molecular weight of solute × Volume (in L))

(A) (B)
…(i)
PCl 5
Let the mass of HNO3 in solution be m.
C 2 H 5 Cl
(C)
 Molarity of HNO3 solution = 2 M (given)
Molecular weight of HNO3 = 1 + 14 +3(16)
–1
= 63 g mol
Volume of solution = 250 mL = 0.25 L
Thus, putting these values in eq. (i),
63. Option (d) is correct.
Diamond is like ZnS (Zinc blende). Carbon
forming ccp ( fcc) and also occupying half of
tetrahedral voids.
Total number of carbon atoms per unit cell

m 1 1
2= = 8× + 6 × + 1× 4 =8
63 × 0.25 8 2 (tetrahedral

(corners) (face void)
centered)
⇒ m = 2 × 63 × 0.25
m = 31.5 g 64. Option (b) is correct.

Now, if concentrated HNO3 is 100% then it Jahn-Teller distortion is generally significant
requires 31.5 g. for asymmetrically occupied eg orbitals as they
But the original solution of HNO3 is 70% are directed toward the ligands and the energy
concentrated. Hence, the mass of HNO3 gain is more.
required to produce a 2.0 M solution On the other hand in unevenly occupied t2g
100 orbitals, the John-Teller distortion is very weak.
= × 31.5 g Since the t2g orbitals do not point directly at
70

the ligand and thus energy gain is less.
= 45.0 g of conc. HNO3
eg
61. Option (c) is correct.
For the reaction, t2g

CH3CH2CH2Br + NaCN → CH3CH2CH2CN d4 d7 d8 d9

Unsymmetrical Unsymmetrical Symmetrical Unsymmetrical
 + NaBr
This follows SN2 mechanism which is 65. Option (b) is correct.
favoured by polar aprotic solvent, i.e., N, For adiabatic conditions, change in heat does
N′-dimethylformamide (DMF). not take place thus, q = 0. If q = 0, then a
O change in temperature does not take place
 CH 3 thus, DT = 0. Also for a free expansion of ideal

HC N gas, work done, W = 0 as there is no external

CH 3 pressure on it.

62. Option (d) is correct. 66. Option (a) is correct.

Number of moles ⇒ nCO = nN2 The number of octahedral voids is the same as
the number of atoms.
The volume of the container is the same. So,
VCO = VN2. Also, the temperature is the same 67. Option (c) is correct.
for both the gases thus, The treatment of sodium alkoxide with a
TCO = TN2 suitable alkyl halide to form an ether is called
as Williamson ether synthesis reaction.
According to the ideal gas equation,
68. Option (a) is correct.
PV = nRT
According to Heisenberg’s uncertainty
Now, V, n, R, and T for both the gases are the
principle,
same. So,
h
PCO = PN2 Dx.Dp =
4π

Now, the total pressure is 1 atm, and according
to Dalton’s sum of partial pressure, h
Dx.D(m.v) =
4π

PCO + PN2 = 1 atm
2PN2 = 1 atm [∵ PCO = PN2] h
⇒ Dx.mDv = ...(i)
PN2 = 0.5 atm 4π
 Now, Dx = 0.1 Å withdrawing NO2 groups on the benzene
= 0.1 × 10–10 m ring which makes the OH bond extremely
= 1.0 × 10–11 m polarized. This facilitates the release of H+.
m = 9.11 × 10–31 kg In acetic acid, the electron-withdrawing  C 
||

h = 6.626 × 10–34 Js O

Put the values in equation (i) group polarizes the OH bond and increases
–11 –31 the acid strength.
Thus, 1.0 × 10 × 9.11 × 10 × Dv
6.626 × 10 −34 Thus, acetic acid is more acidic than phenol or
= cyclohexanol.
4 × 3.14
Thus, the order of acidic strength will be
6.626 × 10 −34
9.11 × 10–42 × Dv = III > II > IV > I
12.56
71. Option (a) is correct.
⇒ Dv = 5.79 × 106 ms–1
Magnetic moment,
= µ n( n + 2) B.M.
69. Option (a) is correct.
Pressure of nitrogen For = 2.84

m
= Measured pressure – aqueous tension 2.84 = n ( n + 2 )
= 715 mm – 15 mm ⇒ n=2
+2
= 700 mm For Ni = [Ar] 3d84s0
Room Temperature = 300 K  (two unpaired electrons)
Volume of nitrogen = 55 mL 3d 4s 4p
Now, at standard temperature-pressure (STP)
the volume of nitrogen can be calculated by
Thus, Ni+2 will give = 2.84 B.M.
combined gas equation.

m
72. Option (b) is correct.
 PV   PV 
  = 
 T given  T at STP CH3


H+
CH 3  C  CH= = CH 2  →
700 mm × 55 mL 760 mm × VSTP
= 

300 K 273 K CH3

VSTP = 46.098 mL CH3

 ⊕
Now, 22400 mL of nitrogen = 1 mole Alkyl shift
H 3C  C  CH  CH 3  →
1 × 46.098 
  
46.098 mL of nitrogen = mol CH3
22400 (2° Carbocation)

1 × 46.098 ⊕
Weight of nitrogen = mol × 28 g/mol H
H 3C  C  CH  CH 3 → H 3C  C =
=
+
C  CH 3
22400
   
= 0.057 g CH3 CH3 CH CH3 3
(3° Carbocation)
2, 3-dimethyl-but-2-ene
Percentage composition of nitrogen in 0.35 g of
compound 73. Option (c) is correct.
0.0576 1 1
= × 100% H 2 + Cl 2 → HCl
0.35 2 2


= 16.45% ∆Hf = –90 kJ mol–1
70. Option (a) is correct. 1 1 
=
∆H f  (B.E.)H2 + (B.E.)Cl 2  − (B.E.)HCl
As we know that phenols and carboxylic acids 2 2 

are more acidic than aliphatic alcohols thus
1 1 
cyclohexanol is the least acidic. –90 =  ( 430 ) + ( 240 ) – (B.E.)HCl
2 2 
On the other hand, III is more acidic than IV
because of the presence of three highly electron –90 = [215 + 120] – (B.E.)HCl
 (B.E.)HCl = 335 + 90 When acid is added
–1
= 425 kJ mol A– + H3O+  H2O + HA
74. Option (d) is correct.
Ion in buffer solution added undissociated
The process of formation of O2– in gas phase is acid.
unfavorable even though O2– is isoelectronic
When alkali is added,
with neon because electron repulsion out­
weigh the stability gained by achieving noble HA + OH –  H2O + A–
gas configuration. Undissociated acid and added alkali ion
75. Option (c) is correct. transform the base (OH –) into water (H2O)
(+)-Lactose is a reducing sugar and all and the conjugate base.
reducing sugar shows mutarotation. 80. Option (c) is correct.
76. Option (a) is correct. When alkali metals are heated in the
In acyl compounds the reactivity depends atmosphere of oxygen, the alkali metals ignite
upon the nature of group Z (i.e., Cl–, RCOO–, and form oxides. On combustion, Li forms
R’O–, NH2–, etc.) Li2O, sodium gives the peroxide Na2O2 while
RC Z K and Rb give superoxides (MO2).
 81. Option (b) is correct.
O
The main assumption of Langmuir adsorption
If group Z is a weak base, then it is a strong isotherm are:
leaving agent and its reactivity towards (i) Adsorption takes place on the surface of
nucleophilic substitution is high. the solid only till the whole of the surface
The order of basic nature of Z group is is completely covered with a unimolecu-
– –
Cl < RCOO < R′O < NH2
– – lar layer of the adsorbed gas.
(ii) Adsorption consists of two opposing pro-
Thus, the reactivity order is: cesses condensation and evaporation.
RCOCl > ( RCO)2 O > RCOOR ′ > RCONH 2 (iii) The rate of condensation depends upon
Acyl Acid Ester Amide the uncovered surface of the adsorbent
Chloride anhydride available for condensation.
77. Option (c) is correct. 82. Option (c) is correct.
Activation energy can be calculated by using Nitro group being electron withdrawing,
Arrhenius equation. deactivates the benzene nucleus due to which
k2 Ea  T1 − T2  electrophile cannot attack on benzene ring
log = −   easily and it becomes incapable to give Friedal-
k1 2.303 R  T1T2 
Craft’s reaction easily.
where, k1, k2 are two different rate constants at 83. Option (c) is correct.
temperature T1 and T2 respectively.
Among the given compounds the anion is
78. Option (a) is correct. same i.e., chloride ion however the difference
In diborane 3-centred-2-electron bonds are is in the cations.
present. Now, according to Fajans’ rule,
H H H
B B 1
H H H Covalent character ∝ .
size of cation
79. Option (a) is correct. The size of cations varies as Be2+ < Li+ < Na+.
When acid or alkali is added to a buffer Hence, the covalent character of compounds is
solution then this added amount of acid or in the order is as follows:
alkali is consumed by the solution according to
NaCl < LiCl < BeCl2
following equations.
 84. Option (c) is correct. 88. Option (a) is correct.
3+ – Carbon and hydrogen are not suitable for
Fe(OH)3(s)  Fe (aq) + 3OH (aq)
reducing agents for metal sulfides.
[Fe3 + ][OH − ]3 89. Option (a) is correct.
Kc
Equilibrium constant, K =
c=
1 As the atomic size increases down the group,
Equilibrium constant remains same at constant the bond length increases and the bond
temperature. strength decreases and the cleavage of EH
Thus, let the increase in the concentration of bond become easier thus, more will be the
Fe3+ be x times. acidity. Thus, order of acidity will be
3
1  H2S < H2Se < H2Te
[ x × Fe3 + ]  × OH − 
K
Kcc =
= 4  90. Option (b) is correct.
1
NH4OH and NH4Cl constitute to form a basic
x [Fe3 + ][OH − ]3 buffer.
==
64 [ Salt ]
pOH = pKb + log
x [ base]

Kcc==
K Kc
64
Now, pOH = 14 – pH = 14 – 9.25 = 4.75
x ⇒ pKb = 4.75
⇒ =
11=
64
91. Option (c) is correct.
⇒ x = 64 times
85. Option (b) is correct.
Redox reactions are those chemical reactions
which involves the transfer of electrons from
one chemical species to another.

This reaction is called Cannizzaro’s reaction.

SECTION B
92. Option (a) is correct.
86. Option (d) is correct. NH2 N==NCl
Photochemical smog cause eye and throat
NaNO2/HCl
irritation.
(273–278 K)
87. Option (d) is correct.
(X)
Hydrolysis of (CH3)2SiCl2 followed by conden­ CH3
sation polymerization. —N
CH3
CH3
CH3 CH3 —N==N— —N
| Hydrolysis | CH3
Cl  Si  Cl → HO  Si  OH Coupling product
| − HCl | (Y)
CH3 CH3
dimethyl
dichlorosilane 93. Option (c) is correct.
CH3 Relative lowering of vapor pressure can be
| expressed as:
nHO  Si  OH →
− HO
| p° − p
condensation = x1

polymerization
CH3 p°

 CH 3  CH 3 p° − p
   
Where is the relative lowering of vapor
p°
O  Si  O   Si  O
  pressure, x1 is the mole fraction of solvent.
 

 CH 3  n − 1 CH 3 0.0125 = x1
straight-chain polymer
(silicone)
 Relation between the mole fraction and be removed by Calgon’s method or the ion
molality is exchange method.
 1  1000 98. Option (d) is correct.
 − 1 = 1 mole of chlorine gas produces charge = nF
x
 1  m × m1

= 2 × 96500 C.
 1  1000
 − 1 = 0.10 mole of chlorine gas produces
 0.0125  m × 18

∴
= 2 × 96500 × 0.10
⇒ m = 0.70 = 19300 C.
94. Option (b) is correct. Also Q = It.
From the Nernst equation, 19300 = 3 × t.
t = 6433.33 s
0.0591 [ 2n2 + ]

Ecell = E°cell − log =107.22 min
n [Cu 2 + ]
99. Option (b) is correct.
At equilibrium, Ecell = 0
∆H= cp ∆T (only at constant pressure).
0.059 At any other condition
0 = 1.1 - log Keq
2
∆H = ∆U + P∆V
37
Keq = 1.94 × 10 100. Option (c) is correct.
95. Option (c) is correct. The oxidation states of central metal atoms in
The correct order of E°M2+/M values of given given compounds are as follows:
element is In K2[Ni(CN)4], the oxidation of Ni is
Mn > Cr > Fe > Co x + (-4) = -2

Mn have high negative E° values because of x = +2

half-filled stable electronic configuration. For In K4[Fe(CN)6], the oxidation state of Fe is
other transition elements, the value decreases x + (-6) = -4
across the series.

x = +2
96. Option (c) is correct.

3-
In [Fe(C2O4)3] , the oxidation state of Fe.
Iproniazid is an antidepressant drug. Aspirin
x + (-6) = -3
is analgesic. Novestrol is an antifertility drug.

Ofloxacin is antibiotics. x = +3

2+
97. Option (a) is correct. In [Cu(NH3)4] , the oxidation state of Cu is
Temporary hardness can be removed by the x + 0 = +2

process of boiling. Permanent hardness can x = +2
∴