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IOP Conference Series: Earth and

Environmental Science

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ICCAPC 2021 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 760 (2021) 012034 doi:10.1088/1755-1315/760/1/012034

Current status of hazardous waste disposal technology

Wu Maowei1, Liu Jiahao2, Li Qifen3*, Yang Yongwen4


1
College of Energy and Mechanical Engineering, Shanghai University of Electric
Power, China
2
College of Energy and Mechanical Engineering, Shanghai University of Electric
Power, China
first author’s e-mail: 18201034@mail.shiep.edu.cn

Abstract. Hazardous wastes refer to wastes with hazardous characteristics that are included in
the national hazardous waste list or identified in accordance with the hazardous waste
identification standards and identification methods prescribed by the state. Hazardous waste
disposal methods are relatively mature including incineration treatment technology, plasma
treatment technology, microwave treatment technology, pyrolysis vaporization, high
temperature cooking, chemical method and landfill, etc. The final disposal achieves the effects
of detoxification, reduction and stabilization.

1. Introduction.
With the acceleration of the modernization process, China's economy is also developing at a high
speed, but with it, China's resource consumption has increased, and more and more hazardous wastes
have been brought. Hazardous wastes may not only destroy the beautiful living environment on which
humans depend, but also have an adverse effect on human health and even endanger lives and restrict
healthy and sustainable development. There are many types of hazardous wastes, complex components,
toxic, corrosive, flammable and explosive, and their pollution is latent and lagging. It is one of the key
and difficult problems of global environmental protection. Precisely because of the various types of
hazardous waste and the complex composition, it is difficult to handle and can easily cause secondary
pollution. Therefore, there must be a standardized disposal system.

2. Collection and transportation of hazardous waste


Due to the inherent properties of hazardous waste, including chemical reactivity, toxicity, flammability,
corrosiveness or other characteristics, it can cause harm to human health or the environment[1].
Therefore, there are strict requirements on the reception, storage, transfer, and addition of hazardous
waste. Prior to the disposal of hazardous wastes, processes such as incoming identification,
classification, storage, and pretreatment must be carried out.

2.1 Temporary storage


In order to prevent hazardous waste from contacting with the outside world or being exposed to
outside life during the entire process, there should be a fixed parking location provided by the
production unit of the hazardous waste and a container for the storage of hazardous waste should be
provided by the collection and transportation unit to make the hazardous waste generated. The waste is
produced and processed in accordance with the standardized process. According to the time specified
by each unit that produces hazardous wastes, and according to the chemical compatibility of the

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ICCAPC 2021 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 760 (2021) 012034 doi:10.1088/1755-1315/760/1/012034

hazardous wastes, the hazardous wastes classified by professionals are placed in the prescribed
temporary storage sites for hazardous wastes. The hazardous wastes are then collected and transported
regularly by enterprises that handle hazardous wastes for centralized processing[2].
Before analysis and identification, the hazardous wastes entering the plant are temporarily stored in
the temporary dumping area of the plant, and the storage time of the wastes stored in the dumping area
shall not exceed one day. The temporary storage area adopts corrosion-resistant hardened ground, set
up light steel rainproof shed, and set up collection ditch and collection pool around. The temporary
storage place of hazardous waste must be provided with reliable rain proof, moth proof, ventilation
and other means, with eye-catching hazard warning signs, and more importantly, it needs to be
managed by special personnel to avoid the accidental entry of irrelevant personnel; it is also necessary
to facilitate the retrieval of hazardous waste collection containers and the traffic of transport vehicles.

2.2 Transportation system


According to the current relevant regulations, hazardous wastes are collected separately by various
hazardous waste producing units and centralized harmless treatment at specialized treatment plants.
Therefore, there is a link in the transfer of hazardous wastes from producing units to centralized
harmless treatment plants. The transshipment of hazardous waste belongs to a special industry, and a
professional transportation fleet needs to be set up to be transported in accordance with national and
local regulations on hazardous waste transshipment[3].

2.3 Collection container


Hazardous waste contains a lot of toxic and harmful substances and is highly harmful. Therefore, it is
required to place these hazardous wastes in special containers from the source of production to ensure
the safety of storage, handling and transfer. With reference to relevant regulations, this project uses
specially customized containers for hazardous waste collection. The special container and its mark
shall meet the requirements of the "Hazardous Waste Storage Pollution Control Standard". According
to the nature and form of hazardous waste, containers of different sizes and materials can be used for
storage.[4] The hazardous waste containers can be steel drums, steel tanks or plastic products.
According to the characteristics of hazardous wastes, the collected hazardous wastes shall be designed
in accordance with relevant standards and regulations in special containers, packaging and packaging
behavior.
(1) Liquid and semi-solid hazardous waste must be packed in packaging containers. Solid
hazardous waste can be packed in packaging containers or bags and stored in temporary storage
facilities that comply with this specification.
(2) The packaging container must be intact and free from corrosion, pollution, damage or other
defects that can reduce its packaging efficiency. The packaging container that contains waste should be
properly covered or sealed. The surface of the container should be kept clean and no hazardous waste
should be attached.
(3) The same packaging container or packaging bag cannot contain more than two types of
hazardous wastes of different properties or categories at the same time. The packaging container and
packaging bag should be made of materials compatible with the contents. The packaging container
must be strong, not easily broken, and have good impermeability.
(4) The hazardous waste packaging containers used in this project will not be cleaned in our factory,
but will be sent to a unit with processing qualification and processing capacity for disposal.

3. Hazardous waste treatment process


The more mature disposal methods of hazardous waste include incineration treatment technology,
plasma treatment technology, microwave treatment technology, pyrolysis vaporization, high
temperature cooking, chemical method and landfill, etc., so that the final disposal can achieve
detoxification, reduction, and stability[5].

2
ICCAPC 2021 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 760 (2021) 012034 doi:10.1088/1755-1315/760/1/012034

3.1 Physical and chemical method


This method is to treat various liquid materials such as waste acid, waste alkali and waste liquid
containing heavy metals. According to the treatment plan proposed by the laboratory according to the
properties of different materials, the harmful substances in the solution can be decomposed or formed
into precipitates and insoluble substances through neutralization, oxidation, reduction and other
reactions. The precipitates are dehydrated by pressure filtration. The recovered filter cake is
transported to the curing workshop for curing[6].

3.2 Biological treatment


Biological treatment mainly uses microorganisms to decompose the biodegradable organic matter of
solid waste to achieve harmlessness or resource utilization. Treatment methods include biological
treatment, anaerobic facultative anaerobic and aerobic treatment processes. Compared with chemical
treatment, biological treatment is more economical and widely used, but this process takes a long time
and the treatment efficiency is not stable enough.

3.3 Stabilization/curing method


Stabilization/solidification technology is an important means to deal with heavy metal waste and other
non-metal hazardous waste[7]. The treatment objects in the solidification workshop are heavy metal
sludge, industrial dust, asbestos, incineration ash, soot, cake filter, etc. After the hazardous waste is
solidified, a barrier is established between the waste particles and the environment, so that the
permeability and dissolution of the final product can be greatly reduced, can be safely transported, and
can be conveniently finalized.

3.4 Incineration method


Disposal of hazardous waste by incineration has the advantages of high harmlessness, good volume
reduction effect, high resource utilization rate, and small area[8]. It can completely kill harmful
microorganisms and viruses in the waste. Most of the harmful compounds are It is decomposed into
simple harmless substances (mainly CO2 and H2O), so that flammable substances are completely
oxidized and reach a stable state. The most important and critical equipment in the incineration system
is the incinerator. The design and selection of the incinerator should be comprehensively considered
based on the type, quantity and investment of waste in the area. The one-time investment and
operating costs of the incineration method are relatively high.
Its main advantages:
(1) After the waste is incinerated, the pathogens in it are completely eliminated. The harmful gases
and smoke generated during the combustion process will meet the emission requirements and be
harmless after treatment;
(2) After incineration, after the combustible components in the waste are decomposed by high
temperature, it can generally be reduced by 80% and volume reduction by more than 90%. The
reduction effect is good, which can save a lot of landfill area, and the incineration residue is a dense,
Non-corrupted and sterile substances;
(3) The land occupation of the incineration plant is small;
(4) Conditional incineration equipment can also recover part of the energy.
(5) The incineration treatment can be operated around the clock and is not easily affected by the
weather.
Its problems:
The incineration method requires well-trained technicians for operation and management: the
incineration treatment also requires supporting safe landfills.

3.5 Plasma treatment technology


Plasma furnace is the core of plasma treatment technology. As the equipment of waste gasification, the
waste in the plasma furnace goes through three stages of preheating, gasification and burning out in

3
ICCAPC 2021 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 760 (2021) 012034 doi:10.1088/1755-1315/760/1/012034

turn to decompose the waste, which is the main place to realize waste reduction and harmless
treatment[9].
Plasma technology, which is completely different from ordinary rotary kiln incineration equipment,
is a high-temperature gasification technology. The plasma torch not only has the advantage of
generating a high-intensity heat source, but also the plasma in the gasification furnace is a highly
ionized or charged gas. Due to its high temperature and high thermal density, the plasma furnace can
convert almost all the organic matter in the carbon-based waste into synthesis gas (mainly CO and H2),
while the inorganic matter can be turned into harmless ash (glass body). Due to the high temperature
in the furnace, the formation of dioxins was avoided at the source. And a lot of research and
engineering practice have proved that the leaching toxicity concentration of slag (glass body)
generated by plasma is lower than the national standard, and it can be treated as general waste or
developed and utilized.

3.6 Safe landfill


Safe landfill is the ultimate disposal method of hazardous waste[10]. Various countries have
formulated design standards for safe landfill and technical requirements for landfill operations. The
United States has required that all hazardous waste landfills must be equipped with double-layer liner
system and leachate collection, drainage and treatment system. For new landfills, in addition to the
above-mentioned systems, groundwater monitoring system and surface stabilization system must also
be set up. The pollution control standard for hazardous waste landfill safety promulgated by China
stipulates the requirements for site entry, site selection, design, construction, operation, site closure
and environmental protection.

4. Summary and outlook


With the increase of hazardous waste, the disposal of hazardous waste has become a problem that
people must pay attention to. Nowadays, the disposal of hazardous waste is mostly carried out by
landfill and incineration, which has initially realized the reduction and harmlessness of hazardous
waste. However, the incineration flue gas caused by the treatment of hazardous wastes by the
incineration method requires a flue gas purification system to process. In recent years, plasma
treatment technology has gradually matured and has been applied to practice. The application of
plasma treatment technology has greatly reduced the pollutants in incineration flue gas. And with the
continuous development of science and technology, the continuous improvement of hazardous waste
treatment technology, reducing waste incineration, landfill disposal, and paving the way for the
creation of a "waste-free city", so as to achieve effective protection of the ecological environment.

References
[1] Yu Ruijun. Resource and Harmless Treatment of Hazardous Waste.[J].Energy Conservation &
Environmental Protection.2020(11):34-35.
[2] Lin yi, Zhang rong, Lai Guangpin. Storage and treatment of waste liquid in chemical
laboratory.[J].Information of China Construction. Water-Industry Market.2012(08):77-80.
[3] Pourhejazy Pourya, Zhang Dali, Zhu Qinghua, et al. Integrated E-waste transportation using
capacitated general routing problem with time-window. 2021, 145
[4] GB 18597-2001.Standard for pollution control on hazardous waste storage[S].
[5] Zheng Yingying Jiang Qiaowen Liu Xiaolai. Discussion on chemical treatment process of waste
water in hazardous waste disposal center.[J].Environment and Development.
2020,32(12):95-96.
[6] Gu bi Song Tiancheng Fu Keping. Engineering analysis of chemical treatment of industrial solid
waste leachate[J].Environment and Development.2020,32(05):68-69.
[7] Song Fanshui. Study on remediation of heavy metal contaminated soil by acid enhanced
solidification/stabilization technology. Institute of New Materials, Shandong Academy of
Sciences, Shandong Province.2018-11-27.

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ICCAPC 2021 IOP Publishing
IOP Conf. Series: Earth and Environmental Science 760 (2021) 012034 doi:10.1088/1755-1315/760/1/012034

[8] DENG Jie.Key Points in the EIA of Hazardous Waste Centralized Incineration Disposal
Projects[J].Guangzhou Chemical Industry.2020,48(23):116-117+180
[9] QIU Jing-xian HE Xi PENG Fen DAI Xin QIAO Rui-ping. QIU Jing-xian HE Xi PENG Fen DAI
Xin QIAO Rui-ping.[J].China Environmental Protection Industry.2020(10):63-67.
[10] SHEN Chen. Hazardous Waste Treatment and Disposal Technology.[J].Energy and Energy
Conservation.2019(04):88-89.

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