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Sustainable Development Goals Series Connecting the Goals
Green Human
Resource
Management Research
Issues, Trends, and Challenges
Editor
Pascal Paillé
Rouen campus
NEOMA Business School
Rouen, France
© The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer
Nature Switzerland AG 2022
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Contents
v
vi CONTENTS
Index 227
Notes on Contributors
vii
viii NOTES ON CONTRIBUTORS
Journal of retailing and consumer services and Business Ethics, the Envi-
ronment and Responsibility. She has also participated in various national
and international conferences on business strategy.
Carballo-Penela Adolfo, Ph.D. is Associate professor in human resource
management at the University of Santiago de Compostela, where he
received his Ph.D. after obtaining a B.A. in Business Administration.
His current research interests include corporate sustainability issues, with
emphasis in sustainable and green human resource management. He
has published on these topics in journals such as Business Strategy and
the Environment, Journal of Cleaner Production, Business Strategy and
Development, The International Journal of Life Cycle Assessment, Sustain-
able Development, Journal of Environmental Planning and Management,
Canadian Journal of Administrative Sciences, Sustainability, Journal of
Sustainability Research and Social Sciences. This research includes some
recent articles about the role of Green HRM in influencing employee
pro-environmental behavior at work (Journal of Sustainability Research),
green recruitment and selection (Sustainability) and antecedents of
workplace environmentally friendly behavior of employees (Sustainable
Development ).
Chaudhary Richa is Associate Professor of Organizational Behaviour
in the Department of Humanities and Social Sciences at IIT Patna.
She obtained her Ph.D. from Department of Management Studies, IIT
Roorkee and holds an M.B.A. with specialization in human resource
management. She is a prolific researcher and has published a number of
research papers in international journals of repute like Journal of Busi-
ness Ethics, Personality and Individual Differences, International Journal
of Hospitality Management, International Journal of Human Resource
Management, Personnel Review, Journal of Cleaner Production, etc.
She was awarded with the best young women management research
award by AIMS International for the year 2018. Her current research
interests include green human resource management, corporate social
responsibility, authentic leadership, and sustainability.
Farooq Kahlid received the M.B.A degree in human resource manage-
ment from the COMSATS Institute of Information Technology, Pakistan,
in 2008, the M.S. degree in human resource management from the
University of Central Punjab, Lahore, Pakistan, in 2012. He is currently
NOTES ON CONTRIBUTORS ix
has been published in journals such as Business & Society, Journal of Busi-
ness Ethics, Ecological Economics, and International Journal of Produc-
tion Economics. In 2019 he received a British Academy of Management
Best-Paper Award in Sustainable and Responsible Management. He serves
as Associate Editor of Journal of Cleaner Production.
Jackson Susan E., Ph.D. is Distinguished Professor of human resource
management in the School of Management and Labor Relations at
Rutgers, The State University of New Jersey. She received her B.A. in
psychology and sociology from the University of Minnesota, master’s
and doctoral degrees in organizational and social psychology from the
University of California at Berkeley, as well as an honorary doctorate (Dr.
h.c.) from the University of Zürich. Prior to joining Rutgers, she was a
member of the faculties at New York University, University of Michigan,
and University of Maryland.
Joshi Gunjan did her Ph.D. in Management at the Indian Institute
of Technology, Roorkee. Her research area is Industrial Relations and
human resources management, specifically: skill development, compe-
tency development, employability, green training, GHRM, and career
success.
Mardani Abbas, Ph.D. is graduated in the field of operation manage-
ment; his master’s and bachelor’s degrees were in industrial management
(operation and production management), and he has been Postdoc,
Researcher, and Senior Lecturer at the USF and UTM. His main inter-
ests are SCM, sustainable development, fuzzy decision making, operation
management, HRM, industry 4.0, circular economy, and big data.
Müller-Camen Michael is Full Professor and Head of the Institute of
Human Resource Management at WU Vienna. His research interests
include Sustainable HRM, Green HRM, and Common Good HRM.
Obereder Lisa is Post Doc Researcher at the Institute of Human
Resource Management at WU Vienna with psychological background and
a doctoral degree in social and economic sciences. Her research interests
are green behavior at the workplace and Green HRM.
Paillé Pascal is Full Professor in People & Organisations department
at NEOMA Business School. Before joining NEOMA Business School,
Pascal was Full professor at Laval University (Canada), where he acted as
NOTES ON CONTRIBUTORS xi
xiii
List of Tables
xv
xvi LIST OF TABLES
Table 6.4 Title of the article, authors and year of publication 128
Table 6.5 International Standard Serial Number (ISSN), impact
factor and number of papers published by the journal 129
Table 6.6 Classification and coding of the analyzed studies 131
Table 7.1 Coding scheme for the content analysis of sustainability
reports 149
Table 7.2 Reporting rates on the dimensions of the AMO
framework 151
Table 7.3 Reporting rates on GHRM practices according
to the AMO framework 152
CHAPTER 1
Pascal Paillé
P. Paillé (B)
NEOMA Business School, Rouen, France
e-mail: pascal.paille@neoma-bs.fr
(Ahmad, 2015; Bratton & Bratton, 2015; Ciocirlan, 2018; Ren et al.,
2018). Other publications have focused on specific practices, such as
employee recruitment and selection (Pham & Paillé, 2020), employee
empowerment (Tariq et al., 2016) and environmental training (Jabbour,
2013; Stefanelli et al., 2020). The topic has also been the subject of
three collective volumes (Jackson et al., 2012; Renwick, 2018; Shen et al.,
2019).
In short, huge advances have been made since the Wehrmeyer volume.
However, a closer examination of the development of the new field
shows that while some areas are reaching a degree of conceptual matu-
rity (thus paving the way for a new phase of development focused on
the consolidation of existing knowledge), others have yet to realize their
full heuristic potential. Through the range of topics considered in the
following chapters, this book aims to add substantially to the vast existing
literature.
of the fight against climate change, with the traditional focus being the
acquisition of technical competencies, tacit knowledge and the develop-
ment of environmental skills. In that sense, GHRM directly meets SDG
4 (i.e., Ensure inclusive and equitable quality education and promote
lifelong learning opportunities for all). In nurturing and broadening envi-
ronmental awareness, GHRM also partly meets SDG 12 (i.e., Ensure
sustainable consumption and production patterns) by enabling people
to adopt more environmentally responsible behaviors not only in the
course of their day-to-day work but also in non-work settings. GHRM
also provides a basis for meeting SDG 8 (i.e., Promote sustained, inclu-
sive and sustainable economic growth, full and productive employment
and decent work for all).
One of the functions of GHRM is to enable employees to integrate
environmental matters into their work practices, from the most basic
to the most complex. In other words, by meeting SDG 9 (i.e., Build
resilient infrastructure, promote inclusive and sustainable industrializa-
tion and foster innovation), GHRM may also be thought of as a means
to an end. Put differently, GHRM can be seen as an instrument in the
fight against climate change in that it enables organizations to put in
place measures designed to repair the environmental damage caused by
industrial activities and prevent environmental degradation.
Overview
In this book, leading researchers in the field consider a wide range
of issues, examining GHRM from a variety of perspectives. The issues
investigated are addressed in standalone chapters. Although the various
contributions are linked by the same overarching theme, and while refer-
ences to issues discussed in other chapters will be made throughout the
book, each chapter can be read independently of the others.
The book is divided into three parts. The common denominator of
the two chapters in Part I is that they address the process of human
resource acquisition. In Chapter 2, Joshi introduces the concept of green
employability and explores various links with organizational productivity
and individual careers. In Chapter 3, Chaudhary examines organizational
attractiveness from the perspective of predictors of job pursuit intentions.
Part II includes three chapters devoted to examining the effects
induced by green HRM practices. In Chapter 4, Yong, Yusliza and Ahmad
provide a theoretical analysis of the links between GHRM and a set of
1 GREEN HUMAN RESOURCE MANAGEMENT … 5
References
Ahmad, S. (2015). Green human resource management: Policies and practices.
Cogent Business & Management, 2(1), 1030817.
Amrutha, V., & Geetha, S. (2020). A systematic review on green human
resource management: Implications for social sustainability. Journal of Cleaner
Production, 247 , 119131.
Bratton, A., & Bratton, J. (2015). Human resource management approaches. In
J. L. Robertson & J. Barling (Eds.), The Psychology of Green Organizations
(pp. 275–295). Oxford University Press.
Ciocirlan, C. E. (2018). Green human resources management. In V. Wells,
D. Gregory-Smith, & D. Manika (Eds.), Research handbook on employee
pro-environmental behaviour (pp. 39–60). Edward Elgar Publishing Limited.
de Freitas Netto, S. V., Sobral, M. F. F., Ribeiro, A. R. B., & da Luz Soares,
G. R. (2020). Concepts and forms of greenwashing: A systematic review.
Environmental Sciences Europe, 32(1), 1–12.
Jabbour, C. J. C. (2013). Environmental training in organisations: From a liter-
ature review to a framework for future research. Resources, Conservation and
Recycling, 74, 144–155.
6 P. PAILLÉ
Jackson, S. E., Ones, D. S., & Dilchert, S. (2012). Managing human resources
for environmental sustainability (Vol. 32). John Wiley & Sons.
McCormick, et al. (2012). Climate change during and after the Roman Empire:
Reconstructing the past from scientific and historical evidence. Journal of
Interdisciplinary History, 43(2), 169–220.
Neukom, R., Steiger, N., Gómez-Navarro, J. J., Wang, J., & Werner, J. P.
(2019). No evidence for globally coherent warm and cold periods over the
preindustrial common era. Nature, 571(7766), 550–554.
Paulet, R., Holland, P., & Morgan, D. (2021). A meta-review of 10 years of
green human resource management: Is Green HRM headed towards a road-
block or a revitalisation? Asia Pacific Journal of Human Resources, 59(2),
159–183.
Pham, D. D. T., & Paillé, P. (2020). Green recruitment and selection: An insight
into green patterns. International Journal of Manpower, 41(3), 258–272.
Ren, S., Tang, G., & E Jackson, S. (2018). Green human resource management
research in emergence: A review and future directions. Asia Pacific Journal of
Management, 35(3), 769–803.
Renwick, D. W. (Ed.). (2018). Contemporary developments in green human
resource management research: Towards sustainability in action? Routledge.
Renwick, D. W., Redman, T., & Maguire, S. (2013). Green human resource
management: A review and research agenda. International Journal of Manage-
ment Reviews, 15(1), 1–14.
Shen, J., Dumont, J., & Deng, X. (2019). Green human resource management
in Chinese enterprises. Routledge.
Stefanelli, N. O., Teixeira, A. A., Caldeira De Oliveira, J. H., Antonio Ferreira,
M., & Sehnem, S. (2020). Environmental training: A systematic review of the
state of the art of the theme. Benchmarking: An International Journal, 27 (7)
2048–2076.
Tariq, S., Jan, F. A., & Ahmad, M. S. (2016). Green employee empower-
ment: A systematic literature review on state-of-art in green human resource
management. Quality & Quantity, 50(1), 237–269.
Wehrmeyer, W. (Ed.). (1996). Greening people. Greenleaf Publishing.
CHAPTER 2
Gunjan Joshi
Introduction
The worldwide transition toward a ‘green economy’ has disrupted the
labor market affecting individual careers directly or indirectly. In response
to this ‘green’ transition, both developed and developing nations have
shown severe concerns regarding individual and businesses’ impact on the
environment and the collective responsibility toward the planet and future
generations (Jabbour, 2015; Joshi & Dhar, 2020). A report published
by the International Labor Organization in 2019 stated that reskilling
and upskilling of occupational skills is of utmost importance to develop
the right skills for the green transition. Following these academic and
institutional dialogues, it is evident that generating green employment
G. Joshi (B)
Entrepreneurship Government Stewardship Center, Nyenrode Universiteit,
Breukelen, The Netherlands
e-mail: g.joshi@nyenrode.nl
and facilitating green market growth is one goal that economies want to
achieve globally.
How the changes in employment conditions and transition in the labor
market influence individual employability has been an essential theme of
discussion in the economic and career literature. Researchers like Gazier
(1998) and McQuaid and Lindsay (2005) have discussed in detail the
evolution of employability in the economic literature and explained how
labor market transition influenced employment outcomes. Researchers
like Delva et al. (2021) and Fugate et al. (2004) have extended employ-
ability dialogues in the career literature and explained the importance of
employability for individual and organizational productivity. Therefore, in
light of the green transformation, it is time to progress the employability
dialogue and understand how economic and labor market transitions
influence employability.
First, the dialogue toward environment sustainability and green
approaches toward organization moves progressively across disciplines
like HRM, marketing, supply chain management. The concept of ‘green’
gained so much popularity that fields like green marketing, GHRM, and
green supply chain management emerged. Researchers explored new
dimensions, and contemporary theories were developed and redesigned,
focusing specifically on environmental sustainability. For example, a
significant number of studies on green HRM concentrate on developing
and measuring constructs like green training (Paillé & Valéau, 2020;
Teixeira et al., 2016), green competencies (Cabral & Dhar, 2019), green
employment, and green skills (Bowen et al., 2018; Brown, 2013). These
studies suggest that human resource plays a significant role in the success
of sustainable enterprises and one must not ignore how these green
variables influence individual employability.
Second, according to the resource-based view, corporate-level compe-
tencies support organizations to achieve sustainable competitive advan-
tage. These competencies are described as exceptional, non-substitutable,
and rare (Barney, 1991). An essential element that helps build corporate-
level competencies is the worker’s skill and knowledge, i.e., human assets.
Thereby, when we talk about environmentally sustainable businesses, we
cannot ignore the dialogue on how the workers who are an integral
part of the sustainable enterprises perceive their performance, skill, and
competencies under the green continuum. Research suggests that workers
associate work outcomes with career success and employability is essential
in assessing career success (De Vos et al., 2011). It is necessary to analyze
2 GREEN EMPLOYABILITY … 9
Employability
Studies have stated that individual employees tend to choose work that
helps them express and develop their self-concepts . Self-concept is
defined as an individual’s perception of themselves, influencing their
career development and career choices. According to Super (1990), an
individual’s career options can be explained by understanding the self-
concept implementation in that person’s work. In this regard, Super
(1990) suggested that career maturity derived from one’s self-concept
is the central aspect common to career development stages. Fugate et al.
(2004) addressed both career maturity and career adaptability in terms
of employability, describing employability “as a psycho-social construct
that embodies individual characteristics that foster adaptive cognition,
behavior, and effect and enhance the individual-work interface” (pp. 14–
38). The employability construct has gained significant importance in
the individual career literature, and researchers explain employability both
from an individual (agentic perspective) and contextual approach.
10 G. JOSHI
Dichotomic
approach
Economic
Literature
Holistic approach
Approaches to Perceived
Employability employability
approach
Psychological and
Competence based
Managemet
approach
literature
Dispositional
approach
Green approach
Green Approach
to Employability---Trends and Research
The transition from ‘economy’ to ‘green economy’ has impacted poli-
cymakers’ decision-making globally to understand how organizations
promote economic growth characterized as ‘green’. One of the essen-
tial characteristics of an organization oriented toward environmental
sustainability is to create green jobs. Defining the nature of green jobs,
researchers state that the degree of ‘greenness’ may vary from one
position to the other, suggesting that rather than representing it as a
binary characteristic, the ‘greenness’ aspect of a job should be seen in
a continuum (Bowen et al., 2018). The individuals working in an orga-
nization driven toward environment management must know how their
skills, attitudes, and competencies contribute to the green goals. It is also
crucial to analyze the gaps in the skill set which should be met to move
toward environmental sustainability. The gap in the skill set can be met by
providing training to the workers directed toward meeting organizational
sustainability.
Organizations driven toward ecological management at the proactive
level provide green training to human resources to maintain a competitive
edge (Jabbour, 2015). Green training is considered “a type of training
related to relevant environmental topics, enabling all staff to integrate
the firm’s performance with environmental issues” (Teixeira et al., 2016,
p. 171). Thus, it can be said that individuals who undergo green training
become more aware of how their efforts to complete the job will impact
the environment. Such individuals are part of an organization that focuses
on providing green employment. Depending on the training content, an
occupation can be defined as green or non-green (Bowen et al., 2018).
Significantly, the increasing scholarly dialogue on green jobs has raised
concern regarding the fragmented literature on green skills and green
competencies required to perform green jobs. Thus, it can be seen that
green transition in employment influences the skill set to perform the
occupation, which eventually impacts individual employability. It is the
right time for scholars to look at employability from a green perspective
via the integrative approach. In this section, I will offer some prac-
tical examples of handicraft organizations driven toward environmental
sustainability. Firstly, there is an urgent need for businesses dependent on
natural resources for their production to contribute to managing envi-
ronmental issues through creative means (Sánchez-Medina et al., 2011).
14 G. JOSHI
Green Competencies
The second dimension of green employability is green competencies.
Green competencies consist of green skills, green attitudes, green knowl-
edge, and green behavior (Cabral & Dhar, 2019; Pedersen, 1999). An
individual’s ability to benefit from the opportunities in the labor market
is prominently influenced by their knowledge, skills, and abilities. Orga-
nizations and individuals invest in developing their skills and expertise
to build their green competencies. This helps them build resilience and
see through the changes required. More specifically, an individual’s ability
to identify and benefit from career opportunities is influenced by green
competencies. According to Fugate et al. (2004), skills, knowledge, and
attitudes form individuals’ career identity; thereby, it can be said that
green competencies help individuals to identify their careers along the
green continuum, and as a result of this embedding green competen-
cies in green employability . Green competencies help organizations to
achieve sustainable goals by enhancing workers’ green creativity. There-
fore, organizations facilitate training and development activities so that
the workers improve their green skills and abilities. Research in the past
18 G. JOSHI
Ethics
The popularity of green jobs has influenced individuals to seek a
career path that leads to meaningful employment. An ethically driven
worker requires some degree of passion for sustainable living. National
Geographic published an article on the fastest-growing green jobs naming
urban growers, recyclers, clean car engineers, solar technicians, and green
buildings for sustainable living to name a few (National Geographic,
2021). These examples show that personal drive and love for work are
crucial factors when individuals focus on green careers. For instance, few
handicraft owners in Uttarakhand, India, manufactured organic prod-
ucts and used environmentally friendly processes to manufacture goods
and services from the very first day of their operations. The owners
focused on making the local people employable without causing any
harm to their natural surroundings and cultural values. This example
also explains that the philosophy of the organizations is also an impor-
tant aspect when workers are looking for ethical or green jobs. Thereby
suggesting that green organizations are oriented toward enhancing green
employability(Fig. 2.2).
Environmental
Ethics
awareness
Green
employability
2 GREEN EMPLOYABILITY … 19
created, and technical skills and knowledge are imparted. For example,
training is being provided to workers to learn computers for stock
entry and making designs and patterns to reduce paperwork. There-
fore, it is essential to understand that the content of green training may
differ based on different contexts. Therefore, green employability can be
perceived differently by workers across diverse cultures. In big organiza-
tions, workers perform jobs ranging from low-skilled to high-skilled jobs.
The nature of training differs depending on the skill set and level of occu-
pation. However, some basic knowledge and skills are essential across the
labor force when performing green jobs. For example, every employee
must be aware of how their actions are impacting the environment; the
employees should adapt and transfer skills when new technologies and
techniques are introduced to perform green jobs
philosophy and ethical system. Scholars must study how such organiza-
tions integrate various profitability, ecological conservation, and ethics to
succeed in the market.
Thirdly, government policy, training, and regulations directed toward
environmental sustainability pave the way for green transformation and
green job creation in the developed economies. The development of
proper skills catalyzes these transitory disruptions. Researchers can study
this aspect of employability from a sustainable perspective and measure the
influence of factors that help individuals move toward a higher degree of
the green continuum to perform green jobs.
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2 GREEN EMPLOYABILITY … 23
Introduction
Environmental degradation is one of the largest threats facing the world
today. World Economic Forum in its global risk report 2021 positioned
environmental degradation as one of the top risks for the mankind.1
The awareness of the damaging consequences of environmental deteri-
oration has led to a magnified interest in environmental sustainability
among the leaders across the globe. The governments, non-governmental
1 https://www.weforum.org/reports/the-global-risks-report-2021.
We see that the total energy of the new configuration is greater than
in the original. According to the condition of stability in §1 the system
is consequently stable for the displacement considered. In this
connexion, it may be remarked that in Part I. we have assumed that
the frequency of radiation emitted or absorbed by the systems cannot
be determined from the frequencies of vibration of the electrons, in
the plane of the orbits, calculated by help of the ordinary mechanics.
We have, on the contrary, assumed that the frequency of the radiation
is determined by the condition , where is the frequency,
Planck’s constant, and the difference in energy corresponding to
two different “stationary” states of the system.
In considering the stability of a ring of electrons rotating round a
nucleus for displacements of the electrons perpendicular to the plane
of the ring, imagine a configuration of the system in which the
electrons are displaced by , ,.... , respectively, and
suppose that the electrons, under influence of extraneous forces,
rotate in circular orbits parallel to the original plane with the same
radii and the same angular momentum round the axis of the system
as before. The kinetic energy is unaltered by the displacement, and
neglecting powers of the quantities , .... , higher than the
second, the increase of the potential energy of the system is given by
where is the radius of the ring, the charge on the nucleus, and
the number of electrons. According to the condition of stability in §1
the system is stable for the displacements considered, if the above
expression is positive for arbitrary values of ,.... . By a simple
calculation it can be shown that the latter condition is equivalent to
the condition
has its smallest value. This condition is identical with the condition of
stability for displacements of the electrons perpendicular to the plane
of the ring, deduced by help of ordinary mechanical
considerations[28].
A suggestive illustration is obtained by imagining that the
displacements considered are produced by the effect of extraneous
forces acting on the electrons in a direction parallel to the axis of the
ring. If the displacements are produced infinitely slowly the motion of
the electrons will at any moment be parallel to the original plane of
the ring, and the angular momentum of each of the electrons round
the centre of its orbit will obviously be equal to its original value; the
increase in the potential energy of the system will be equal to the
work done by the extraneous forces during the displacements. From
such considerations we are led to assume that the ordinary
mechanics can be used in calculating the vibrations of the electrons
perpendicular to the plane of the ring—contrary to the case of
vibrations in the plane of the ring. This assumption is supported by
the apparent agreement with observations obtained by Nicholson in
his theory of the origin of lines in the spectra of the solar corona and
stellar nebulæ (see Part I. pp. 6 & 23). In addition it will be shown
later that the assumption seems to be in agreement with experiments
on dispersion.
The following table gives the values of and from
to .
, , ; , ,
1 0 0 9 3.328 13.14
2 0.25 0.25 10 3.863 18.13
3 0.577 0.58 11 4.416 23.60
4 0.957 1.41 12 4.984 30.82
5 1.377 2.43 13 5.565 38.57
6 1.828 4.25 14 6.159 48.38
7 2.305 6.35 15 6.764 58.83
8 2.805 9.56 16 7.379 71.85
We see from the table that the number of electrons which can
rotate in a single ring round a nucleus of charge increases only
very slowly for increasing ; for the maximum value is
; for , ; for , . We see, further,
that a ring of electrons cannot rotate in a single ring round a
nucleus of charge ne unless .
In the above we have supposed that the electrons move under the
influence of a stationary radial force and that their orbits are exactly
circular. The first condition will not be satisfied if we consider a
system containing several rings of electrons which rotate with
different frequencies. If, however, the distance between the rings is
not small in comparison with their radii, and if the ratio between their
frequencies is not near to unity, the deviation from circular orbits may
be very small and the motion of the electrons to a close
approximation may be identical with that obtained on the assumption
that the charge on the electrons is uniformly distributed along the
circumference of the rings. If the ratio between the radii of the rings is
not near to unity, the conditions of stability obtained on this
assumption may also be considered as sufficient.
We have assumed in §1 that the electrons in the atoms rotate in
coaxial rings. The calculation indicates that only in the case of
systems containing a great number of electrons will the planes of the
rings separate; in the case of systems containing a moderate number
of electrons, all the rings will be situated in a single plane through the
nucleus. For the sake of brevity, we shall therefore here only consider
the latter case.
Let us consider an electric charge uniformly distributed along
the circumference of a circle of radius .
At a point distant from the plane of the ring, and at a distance
from the axis of the ring, the electrostatic potential is given by
where
The corresponding force perpendicular to the plane of the ring at a
distance from the centre of the ring and at a small distance from
its plane is given by
where
the summation is to be taken over all the rings except the one
considered.
If we know the distribution of the electrons in the different rings,
from the relation (1) on p. 28, we can, by help of the above,
determine , , .... The calculation can be made by successive
approximations, starting from a set of values for the ’s, and from
them calculating the ’s, and then redetermining the ’s by the
relation (1) which gives , and so on.
If all the electrons in one of the rings are displaced in the same
direction by help of extraneous forces, the displacement will produce
corresponding displacements of the electrons in the other rings; and
this interaction will be of influence on the stability. For example,
consider a system of concentric rings rotating in a plane round a
nucleus of charge , and let us assume that the electrons in the
different rings are displaced perpendicular to the plane by , ,....
respectively. With the above notation the increase in the
potential energy of the system is given by
The condition of stability is that this expression is positive for arbitrary
values of ,.... . This condition can be worked out simply in the
usual way. It is not of sensible influence compared with the condition
of stability for the displacements considered above, except in cases
where the system contains several rings of few electrons.
The following Table, containing the values of and for
every fifth degree from to , gives an estimate of
the order of magnitude of these functions:—
N=1. Hydrogen.
In Part I. we have considered the binding of an electron by a
positive nucleus of charge , and have shown that it is possible to
account for the Balmer spectrum of hydrogen on the assumption of
the existence of a series of stationary states in which the angular
momentum of the electron round the nucleus is equal to entire
multiples of the value , where is Planck’s constant. The formula
found for the frequencies of the spectrum was
N=2. Helium.
As shown in Part I., using the same assumptions as for hydrogen,
we must expect that during the binding of an electron by a nucleus of
charge a spectrum is emitted, expressed by
This spectrum includes the spectrum observed by Pickering in the
star Puppis and the spectra recently observed by Fowler in
experiments with vacuum tubes filled with a mixture of hydrogen and
helium. These spectra are generally ascribed to hydrogen.
For the permanent state of a positively charged helium atom, we
get
Since
we see that both electrons in a neutral helium atom are more firmly
bound than the electron in a hydrogen atom. Using the values on p.
38, we get
these values are of the same order of magnitude as the value
observed for the ionization potential in helium, assume[31],
and the value for the frequency of the ultra-violet absorption in helium
determined by experiments on dispersion [32].
N=3. Lithium.
In analogy with the cases of hydrogen and helium we must expect
that during the binding of an electron by a nucleus of charge ,a
spectrum is emitted, given by
N=4. Beryllium.
For reasons analogous to those considered for helium and lithium
we may for the formation of a neutral beryllium atom assume the
following stages:
although the configurations:
correspond to less values for the total energy than the configurations
and .
From analogy we get further for the configuration of a possible
negatively charged atom,
Comparing the outer ring of the atom considered with the ring of a
helium atom, we see that the presence of the inner ring of two
electrons in the beryllium atom markedly changes the properties of
the outer ring; partly because the outer electrons in the configuration
adopted for a neutral beryllium atom are more lightly bound than the
electrons in a helium atom, and partly because the quantity , which
for helium is equal to , for the outer ring in the configuration is
only equal to .
Since , the beryllium atom will
further have a definite, although very small affinity for free electrons.
§4. Atoms containing greater numbers of electrons.