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Evonik Tego Pep 3 Recover - SDS
Evonik Tego Pep 3 Recover - SDS
0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Product name:
TEGO PEP 3-RECOVER
Chemical name:
GHK-Cu [Gly-His-Lys)Cu
Additional identification
Chemical name: Copper, [N2-(N-glycyl-L-histidyl)-L-lysinato(2-)]-
Chemical formula: -
INDEX No. -
CAS-No. 89030-95-5
EC No. -
1.2 Relevant identified uses of the substance or mixture and uses advised against
Health Hazards
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Precautionary Statements
Prevention: P264: Wash face, hands and any exposed skin thoroughly after
handling.
P280: Wear protective gloves/protective clothing/eye protection/face
protection.
Chemical name:
GHK-Cu [Gly-His-Lys)Cu
3.1 Substances
Chemical name Copper, [N2-(N-glycyl-L-histidyl)-L-lysinato(2-)]-
INDEX No.:
CAS-No.: 89030-95-5
EC No.:
REACH Registration No.: -
2119475328- available.
30
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by
volume.
# This substance has workplace exposure limit(s).
## This substance is listed as SVHC.
Classification
Chemical name Classification Notes
Trifluoroacetic acid Classification: Acute Tox.: 4: H332; Skin Corr.: 1A: H314; Eye Note B
Dam.: 1: H318; Aquatic Chronic: 3: H412;
Skin Contact: In case of contact with skin wash off with soap and water. In case
of discomfort: Supply with medical care.
Eye contact: In case of contact with eyes rinse thoroughly with plenty of water.
If symptoms persist, seek medical advice.
Ingestion: Rinse out mouth and give plenty of water to drink. In case of
discomfort: Supply with medical care.
4.2 Most important symptoms and effects, both acute and delayed
Suitable extinguishing media: foam, carbon dioxide, dry powder, water spray.
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
5.2 Special hazards arising from the In the event of fire the following can be released: - carbon
substance or mixture: dioxide, carbon monoxide Oxides of Sulfur. Hydrogen
chloride gas.
Special fire-fighting procedures: Keep away from sources of ignition - no smoking. Take
action to prevent static discharges. Dust may form explosive
mixture with air.
Special protective equipment for fire- Do not inhale explosion and/or combusition gases. Use self-
fighters: contained breathing apparatus and wear protective suit
6.1 Personal precautions, Use personal protective equipment. Avoid dust formation.
protective equipment and
emergency procedures:
6.2 Environmental Do not allow to enter drains or waterways Prevent product from getting into
Precautions: subsoil/soil.
6.3 Methods and material for Use mechanical handling equipment. Dispose of absorbed material in
containment and cleaning accordance with the regulations.
up:
6.4 Reference to other For further information on exposure monitoring and disposal see sections 8
sections: and 13.
Safe handling advice: Avoid the formation and deposition of dust. Ensure adequate
ventilation.
Safe storage conditions: Keep container tightly closed, cool and dry Do not store with
strong oxidising agents
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Acetic acid TWA 10 ppm 25 mg/m3 EU. Indicative Occupational Exposure Limit
Values in Directives 91/322/EEC, 2000/39/EC,
2006/15/EC, 2009/161/EU, 2017/164/EU, as
amended (12 2009)
STEL 20 ppm 50 mg/m3 EU. Indicative Occupational Exposure Limit
Values in Directives 91/322/EEC, 2000/39/EC,
2006/15/EC, 2009/161/EU, 2017/164/EU, as
amended (02 2017)
TWA 10 ppm 25 mg/m3 UK. EH40 Workplace Exposure Limits (WELs),
as amended (08 2018)
STEL 20 ppm 50 mg/m3 UK. EH40 Workplace Exposure Limits (WELs),
15 minutes as amended (01 2020)
Please refer to the latest edition of the appropriate source text and consult an industrial hygienist or similar
professional, or local agencies, for further information.
Exposure guidelines
Chemical name Type Source
DNEL-Values
Remarks: DNEL-Values
Acetic acid General population Inhalation Local, long-term; 25 irritation respiratory tract
mg/m3
Workers Eyes Local effects; Medium hazard (no
threshold derived).
Workers Inhalation Local, long-term; 25 irritation respiratory tract
mg/m3
General population Eyes Local effects; Medium hazard (no
threshold derived).
General population Inhalation Local, short-term; 25 irritation respiratory tract
mg/m3
Workers Inhalation Local, short-term; 25 irritation respiratory tract
mg/m3
PNEC-Values
Remarks: PNEC-Values
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Hygiene measures: When using do not eat, drink or smoke. Wash hands before
breaks and immediately after handling the product. Remove
soiled or soaked clothing immediately.
Skin Contact: Relevant route of exposure. Information on effects are given below.
Eye contact: Relevant route of exposure. Information on effects are given below.
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Oral
Product: Not classified for acute toxicity based on available data.
Components:
Trifluoroacetic acid No data due to skin-corrosive action
Dermal
Product: Not classified for acute toxicity based on available data.
Components:
Trifluoroacetic acid No data due to skin-corrosive action
Inhalation
Product: Not classified for acute toxicity based on available data.
Components:
Trifluoroacetic acid NOAEL (Rat, Female, Male, 4 h): 0.3 mg/l Literature
moderately toxic after single exposure, Vapour, EU. GHS Classification.
CLP Regulation (EC) No 1272/2008, Annex VI, Table 3, List of harmonized
classification and labeling of hazardous substances
Not applicable, Dusts, mists and fumes
Skin Corrosion/Irritation
Product: No data available.
Components:
Trifluoroacetic acid Corrosive. , Literature
Acetic acid Corrosive.
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
No data available.
In vitro
Product: No data available.
Components:
Trifluoroacetic acid No data available.
Acetic acid Ames test (OECD 471): negative Literature
Chromosomal aberration (OECD 473): negative Literature
Genetic mutation in mammal cells (OECD 476): negative Literature
In vivo
Product: No data available.
Components:
Trifluoroacetic acid No data available.
Acetic acid Micronucleus test Inhalation - vapor (Rat, Female, Male): negative Literature
Reproductive toxicity
Product: No data available.
Components:
Trifluoroacetic acid Not classified
Acetic acid Not classified
Aspiration Hazard
Product: Not classified
Components:
Trifluoroacetic acid Not classified
Acetic acid Not classified
Other hazards
Product: Causes skin irritation. Causes serious eye damage.;
12.1 Toxicity:
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Fish
Product: No data available.
Components:
Trifluoroacetic acid LC 50 (Brachydanio rerio (zebrafish), 96 h): > 1,200 mg/l Literature
Aquatic Invertebrates
Product: No data available.
Components:
Trifluoroacetic acid EC 50 (Daphnia magna, 48 h): > 1,200 mg/l Literature
Acetic acid EC 50 (Daphnia magna, 48 h): > 300.82 mg/l Literature
Toxicity to microorganisms
Product: No data available.
Components:
Trifluoroacetic acid (activated sludge, 3 h): > 1,000 mg/l Literature
Acetic acid NOEC (Pseudomonas putida, 16 h): 1,150 mg/l Literature
Fish
Product: No data available.
Components:
Trifluoroacetic acid No data available.
Acetic acid LC 50 (Oncorhynchus mykiss, 21 d): 52.2 mg/l (OECD 204) Literature
NOEC (Oncorhynchus mykiss, 21 d): 34.3 mg/l (OECD 204) Literature
Aquatic Invertebrates
Product: No data available.
Components:
Trifluoroacetic acid NOEC (21 d): >= 100 mg/l (OECD 211) Literature
Acetic acid NOEC (Daphnia magna, 21 d): 31.4 mg/l (OECD 202) Literature
Toxicity to microorganisms
Product: No data available.
Components:
Trifluoroacetic acid (activated sludge, 3 h): > 1,000 mg/l Literature
Acetic acid NOEC (Pseudomonas putida, 16 h): 1,150 mg/l Literature
Biodegradation
Product: No data available.
Components:
Trifluoroacetic acid No data available.
BOD/COD Ratio
Product: No data available.
Components:
Trifluoroacetic acid No data available.
Acetic acid No data available.
Other hazards
Product: The product is classified as highly hazardous to waters (according to the
German Regulation on the Classification of Substances Hazardous to
Waters (WwSV). Do not allow to enter soil, waterways or waste water
canal.
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
EU. Directive 2012/18/EU (SEVESO III) on major accident hazards involving dangerous substances,
Annex I: Not applicable
15.2 Chemical safety assessment: No chemical safety assessment was carried out for this product.
Notes:
Trifluoroacetic acid Note B Some substances (acids, bases, etc.) are placed on
the market in aqueous solutions at various
concentrations and, therefore, these solutions require
different classification and labelling since the hazards
vary at different concentrations. In Part 3 entries with
Note B have a general designation of the following
type: 'nitric acid...%'. In this case the supplier must
state the percentage concentration of the solution on
the label. Unless otherwise stated, it is assumed that
the percentage concentration is calculated on a
weight/weight basis.
Acetic acid Note B Some substances (acids, bases, etc.) are placed on
the market in aqueous solutions at various
concentrations and, therefore, these solutions require
different classification and labelling since the hazards
vary at different concentrations. In Part 3 entries with
Note B have a general designation of the following
type: 'nitric acid...%'. In this case the supplier must
state the percentage concentration of the solution on
the label. Unless otherwise stated, it is assumed that
the percentage concentration is calculated on a
weight/weight basis.
Revision Information Changes since the last version are highlighted in the margin. This version
replaces all previous versions.
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GB 2022-05-25
Version: 3.0
Issue Date: 17.07.2020
Last revised date: 24.05.2022
Supersedes Date: 17.02.2022
Disclaimer: This information and all further technical advice is based on our present
knowledge and experience. However, it implies no liability or other legal
responsibility on our part, including with regard to existing third party
intellectual property rights, especially patent rights. In particular, no
warranty, whether express or implied, or guarantee of product properties in
the legal sense is intended or implied. We reserve the right to make any
changes according to technological progress or further developments. The
customer is not released from the obligation to conduct careful inspection
and testing of incoming goods. Performance of the product described
herein should be verified by testing, which should be carried out only by
qualified experts in the sole responsibility of a customer. Reference to trade
names used by other companies is neither a recommendation, nor does it
imply that similar products could not be used.
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GB 2022-05-25