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Thermalphysics (3403)
Thermalphysics (3403)
Thermalphysics (3403)
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12.2.a
Internal energy
All substances contain moving particles. In the context of this chapter, the word
‘particle’ is a general term that might apply to a molecule, an atom or an ion. Although
different substances may contain any or all of these, most substances are molecular and
in the rest of this chapter the term ‘molecule’ will be used to describe the particles in
any substance.
Moving molecules have kinetic energy. The molecules might be moving in different
ways, which gives rise to three different forms of random molecular kinetic energy:
■ Molecules might be vibrating about fixed positions (as in a solid) − this gives the
molecules
vibrational kinetic energy.
■ Molecules might be moving from place to place (translational motion) − this gives
the molecules translational kinetic energy.
■ Molecules might also be spinning (rotating) − this gives the molecules rotational
kinetic energy.
Molecules can have potential energy as well as kinetic energy. In solids and liquids, it
is the electrical forces (between charged particles) that keep the molecules from
moving apart or moving closer together. Wherever there are electrical forces there will
be electrical potential energy in a system, in much the same way as gravitational
potential energy is associated with gravitational force.
In gases, however, the forces between molecules are usually negligible because of the
larger separation between molecules. This is why gas molecules can move freely and
randomly. The molecules in a gas, therefore, usually have negligible electrical
potential energy – all the energy is in the form of kinetic energy.
So to describe the total energy of the molecules in a substance, we need to take account
of both the kinetic energies and the potential energies. This is called the internal
energy of the substance and is defined as follows:
12.2.b
It is important not to call internal energy ‘heat’. That is, we should not refer to the
thermal energy (or heat) in anything.
In the definition of internal energy given above, the word ‘random’ means that the
molecular movements are disordered and unpredictable. That is, they are not linked in
any way to each other, or ordered – as their motions would be if they were all moving
together, such as the molecules in a macroscopic motion of a moving car. The
molecules in a moving car have both the ordered kinetic energy of macroscopic
movement together and the random kinetic energy of internal energy.
Summarizing the differences between temperature, internal energy
and thermal energy
Temperature, internal energy and thermal energy are widely used and are very
important concepts throughout all of science, but they are commonly misunderstood
and misused terms.
To stress their importance, the meanings of these concepts are summarized below.
■ Internal energy is the total energy (random kinetic and potential) of all the molecules
inside a substance.
■ If energy is transferred to a substance it gains internal energy and its molecules move
faster.
We say that it has become hotter and this is measured as an increased temperature. A
more precise meaning of temperature is given on page 127.
■ Thermal energy (heat) is energy flowing from a higher temperature to a lower
temperature.
In any particular example, the object or substance we are considering is often called
the system, and thermal energy flows between the system and the surroundings.
Students may know that thermal energy is transferred by conduction, convection and
radiation.
12.2.c
Teaching activity 1
Worksheet (and mark scheme) prepared by you to practice this idea and its
applications.
Teacher guidance notes 1
It is important that learners appreciate that the internal energy of a system can
be increased by two means:
o Heat transfer to the object
o Work done on the object by an external agency (e.g. electrically)
Often, an increase in internal energy is due to a combination of these two
causes. Both constitute an energy transfer to the object.
Learners should also note that, if work is done by the system (e.g. a gas
expands against the pressure of the atmosphere), the internal energy will
decrease, meaning the temperature will be lowered.
Past papers
Paper 41, Nov 2010, Q2 (b)
Paper 43, Nov 2013, Q2 (b)(ii)
Apart from supplying thermal energy to a system (‘heating’ it), there is another, very
common and fundamentally different way to make something hotter: we can do
mechanical work on it.
A simple example would be the force of friction causing a temperature rise when
surfaces rub together. Heating is a non-mechanical transfer of energy.
Energy must be supplied to melt or boil a substance in this case there is no temperature
rise to consider since the temperature stays constant during a change of state. This
energy is called latent heat.
When a substance melts this quantity is called specific latent heat of fusion; for
boiling it is the specific latent heat of vaporization. To calculate the amount of energy
required to melt or vaporize and mass of a substance, we simply need to know its
specific latent heat.