NEET

Lakshya NEET (2025)

Physical Chemistry DPP: 3
Electrochemistry

Q1 For the cell Zn| Zn2+||Cu2+|Cu, if the

+
Cr(s) + 3Ag (aq, 0.10 M) → 3Ag(s)

2+ 2+
concentration of both, Zn and Cu ions are + Cr
3+
(aq, 0.30 M)

doubled, the EMF of the cell (A) 1.35 (B) 1.40

(A) Doubles (C) 1.65 (D) 1.55
(B) Reduces to half
(C) Remains same Q6 For a cell reaction involving a two-electron

(D) Becomes zero change, the standard EMF of the cell is found to
be 0.295 V at 25 C
∘
. The equilibrium constant
Q2 Assuming that hydrogen behaves as an ideal of the reaction at 25 ∘
C will be
gas, what is the EMF of the cell at 25 C
∘
if (A) 1 × 10 10

P 1 = 600 mm and P 2 = 420 mm : (B) 1 × 10−10

Pt |H2 (P 1 )| HCl||H2 (P 2 ) ∣ Pt ? [Given: (C) 29.5 × 10−2
2.303RT/F = 0.06, log 7 = 0.85 ] (D) 2 × 1010
(A) −0.0045 V
Q7 The EMF of the cell:
2+ 2+
Zn ∣ Zn (0.01M)∥Fe
(B) −0.0 V
(C) +0.0045 V (0.001M) ∣ Fe at 298 K is 0.2905 V , then the

(D) +0.0015 V value of equilibrium constant for the cell

reaction is
Q3 For the cell: .
2+ 2+ ∘
Ni ∣ ∣ Cu; E
(A) e
0.32

∣Ni ∥Cu ∣ = 0.77 V

0.0295

By which of the following activity, E cell will (B) 10

0.32

0.0295

increase?
(C) 10
0.26

0.0295

(A) On decreasing [Ni

+2
]
(D) 10
0.32

(B) On decreasing [Cu

+2 0.0591
]

(C) On increasing mass of Ni electrode

Q8 For the cell reaction:
(D) On increasing mass of Cu electrode
4Br
−
+ O2 + 4H
+
⇌ 2Br2 + 2H2 O ;
Q4 For a reaction A(s) + 2 B
+
⇌ A
2+
+ 2 B( s) ; E
∘
= 0.18 V . The value of (log KC ) at 298 K

has been found to be 12

. The standard is [2.303 RT/F = 0.06]
KC 10

EMF of the cell is (A) 12 (B) 6

(A) 0.354 V (C) 18 (D) 3

(B) 0.708 V Q9 The value of equilibrium constant for feasible

(C) 0.534 V cell reaction is
(D) 0.453 V
(A) < 1 (B) Zero

Q5 The measured voltage for the reaction with the (C) = 1 (D) > 1

indicated concentration is 1.50 V .

Q10 Determine the equilibrium constant of the
Calculate E∘ .
following reaction at 298 K
3+ 2+ 2+ 4+
2Fe + Sn → 2Fe + Sn

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(Given: E
∘
4+ 2+
= 0.15 volt, (B) −0.295 V
sn /Sin

E
∘
Fe
2+
= 0.771 volt) (C) 0.13 V
3+/
Fe
(D) −0.13 V
(A) 1.0 × 1010
(B) 1.0 × 1021 Q15 The standard EMF of a galvanic cell involving
(C) 2.0 × 1021 two moles of electrons in its redox reaction is
(D) 2.0 × 1011 0.59 V . The equilibrium constant for a redox
reaction of the cell is
Q11 The equilibrium constant of the following redox
(A) 1020 (B) 105
reaction at 298 K is 1 × 108
(C) 10 (D) 1010
3+ − 2+
2Fe (aq.) + 2I (aq.) ⇌ 2Fe (aq.)
Q16 The oxidation potential of hydrogen electrode
+ I 2 (s)
at pH = 10 and PH 2
= 1 atm is
If the standard reduction potential of iodine (A) 0.51 V
becoming iodide is +0.54 V . What is the (B) 0.00 V
standard reduction potential of Fe 3+
/Fe
2+
? (C) +0.59 V
(A) +1.006 V (D) 0.059 V
(B) −1.006 V
Q17 If the E
∘
cell for a given reaction has a
(C) +0.77 V
negative value, then which of the following
(D) −0.77 V
gives the correct relationships for the values of
Q12 The E
∘
at 25 C
∘
for the following reaction is ΔG
∘
and Keq ?
0.22 V . Calculate the equilibrium constant at (A) ΔG∘ > 0; Keq > 1

25 C
∘
. (B) ΔG 0
< 0; Keq > 1

H2 ( g) + 2AgCl(s) → 2Ag(s) + 2HCl(aq) (C) ΔG ∘

< 0; Keq < 1

(A) 2.8 × 10 7
(D) ΔG ∘
> 0; Keq < 1

(B) 5.2 × 10 8

Q18 At equilibrium:
(C) 5.2 × 10
6

(A) E∘ cell = 0, ΔG
∘
= 0
(D) 5.2 × 103
(B) Ecell = 0, ΔG = 0

Q13 The equilibrium constant for the following (C) Both are correct
general reaction is 10
30
. Calculate E
∘
for the (D) None is correct
cell at 298 K .
2+ 3+ Q19 Free energy change (ΔG) is related to the EMF
2X2 ( s) + 3Y (aq) ⇌ 2X (aq) + 3Y(s)
2
of the cell (E)
(A) +0.105 V
(A) E = −nFΔG
(B) +0.2955 V
(B) ΔG = −nFE
(C) 0.0985 V
(C) ΔG = −
RT
F log E
(D) −0.2955 V n

(D) ΔG = −
nF

RT
log E

Q14 The potential of the cell containing two

hydrogen electrodes as represented below Q20 Consider the following equations for a cell
1 + −8 + reaction
Pt; H2 (g) ∣
∣ H (10 M)∣∣
∣∣ H (0. 001 M )
2
A + B ⇌ C + D
1
∣ H2 (g) ; Pt
∣ ∘
2 E = x volt , Keq = K1

is 2 A + 2 B ⇌ 2C + 2D
(A) 0.296 V
E
∘
= y volt, Keq = K2

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then
(A) x = y, K1 = K2

(B) x = 2y, K1 = 2 K2

(C) x = y, K
2
1
= K2

(D) x 2
= y, K
2
1
= K2

Q21 The standard free energy change for the

following reaction is −210 kJ . What is the
standard cell potential?

2H2 O2 (aq) → 2H2 O(l) + O2 ( g)

(A) +0.752 (B) +1.09

(C) +0.420 (D) +0.640

Q22 Given:(i) Cu2+ + 2e

−
→ Cu; E
∘
= 0.337 V

(ii) Cu 2+ −
+ e → Cu
+
;E
∘
= 0.153 V

Standard electrode potential (E )

∘
for the
reaction, Cu +
+ e
−
→ Cu , will be:
(A) 0.52 V
(B) 0.90 V
(C) 0.30 V

(D) 0.38 V

Q23 The Gibb's energy of the decomposition of

Al2 O3 at 500 C
ο
is as follows

2 4
Al2 O3 → Al + O2 , Δr G =
3 3
−1
+966 kJ mol

The potential difference needed for electrolytic

reduction of Al2 O3 at 500 C
ο
is at least
(A) 5.0 V

(B) 4.5 V
(C) 3.0 V
(D) 2.5 V

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Answer Key
Q1 (C) Q13 (B)

Q2 (C) Q14 (A)

Q3 (A) Q15 (A)

Q4 (A) Q16 (C)

Q5 (D) Q17 (D)

Q6 (A) Q18 (B)

Q7 (B) Q19 (B)

Q8 (A) Q20 (C)

Q9 (D) Q21 (B)

Q10 (B) Q22 (A)

Q11 (C) Q23 (D)

Q12 (A)

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