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Chemistry Paper 2 TZ2 HL Markscheme
Chemistry Paper 2 TZ2 HL Markscheme
Markscheme
May 2019
Chemistry
Higher level
Paper 2
18 pages
–2– M19/4/CHEMI/HP2/ENG/TZ2/XX/M
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–3– M19/4/CHEMI/HP2/ENG/TZ2/XX/M
1. b iii London/dispersion/instantaneous dipole-induced dipole forces ✔ Do not accept just “intermolecular forces” or
1
“van der Waals’ forces”.
1. c i ethanal ✔ 1
1. c ii «sum of bond enthalpies of reactants » 2(CH) C~C 2(OH) Award [3] for correct final answer.
OR
2 414 «kJ mol1» 839 «kJ mol1» 2 463 «kJ mol1»
OR
2593 «kJ» ✔
(continued…)
–4– M19/4/CHEMI/HP2/ENG/TZ2/XX/M
(Question 1c continued)
1H NMR spectrum:
2
«only» two signals AND A would have three Accept “two signals with
OR areas 1:3”.
(Question 1c continued)
1. d ii 1 ✔ 1
2. c i half «of the initial rate» ✔ Accept “lower/slower «than initial rate»”.
1
2. c ii 1 slower than 2
OR
1 rate determinant step/RDS ✔
initial pressure is lower AND final pressure of gas lower «by similar factor» ✔
catalysed and uncatalysed Ea marked on graph AND with the catalysed being at
lower energy ✔
«for catalysed reaction» greater proportion of/more molecules have E Ea / E Ea Accept “more molecules have the
OR activation energy”.
«for catalysed reaction» greater area under curve to the right of the Ea ✔
2. g i SÖ 2(SÖ(N2)) SÖ(O2) 2(SÖ(N2O)) Award [2] for correct final answer.
OR
SÖ 2 193 «J mol1 K1» 205 «J mol1 K1» 2 220 «J mol1 K1» ✔ 2
(continued…)
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(Question 2g continued)
3. b i mass spectrometry/MS ✔
1
3. d ii linear AND 2 electron domains Accept “two bonds AND no lone pairs” for
reason.
OR
1
linear AND 2 regions of electron density ✔
3. d iii sp ✔ 1
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4. b ii electrolyze «a solution of /molten» rhenium salt/Ren ✔ Accept “using rhenium anode” for M1.
4. b iii Any two of: Accept other valid responses related to its
variable oxidation states ✔ chemical metallic properties.
Do not accept “catalytic properties”.
forms complex ions/compounds ✔
2 max
coloured compounds/ions ✔
«para»magnetic compounds/ions ✔
4. c place «pieces of» Re into each solution ✔ Accept other valid observations such as “colour
of solution fades” or “solid/metal appears” for
if Re reacts/is coated with metal, that metal is less reactive «than Re» ✔ “reacts”.
2
– 13 – M19/4/CHEMI/HP2/ENG/TZ2/XX/M
186.21 2
«100 » 63.648 «%» ✔
292.56
5. a ii CO32 ✔ 1
5. b shifts to left/reactants AND to increase amount/number of moles/molecules of Accept “shifts to left/reactants AND
gas/CO2 (g) ✔ to increase pressure”.
1
«pH » 3.53 ✔
– 15 – M19/4/CHEMI/HP2/ENG/TZ2/XX/M
2
Between hydrogen and oxygen in hydrogencarbonate:
«polar» covalent ✔
5. d ii «additional HCO3» shifts position of equilibrium to left ✔ Do not award M2 without any justification in
terms of equilibrium shift in M1. 2
pH increases ✔
5. d iii «molar mass of NaHCO3 » 84.01 «g mol1» ✔ Award [2] for correct final answer.
3.0 10 –2 g 1 2
«concentration –1
» 3.6 10–3 «mol dm3» ✔
84.01 g mol 0.100 dm 3
5. e Equation (3):
OH donates an electron pair AND acts as a Lewis base ✔
2
Equation (4):
OH accepts a proton/H/hydrogen ion AND acts as a Brønsted–Lowry base ✔
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6. c Similarity:
«both» involve an electrophile
OR
«both» electrophilic ✔
2
Difference:
first/reaction of ring/with NO2 is substitution/S«E» AND second/reaction of Answer must state which is substitution and
C=C/with HBr is addition/A«E» ✔ which is addition for M2.
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OR
carbon atom attached to 4 different groups ✔
2
Relationship:
mirror images
OR
enantiomers/optical isomers ✔
6. d ii benzene ring «of the C6H5CH2» and the bromine «on the CH2Br» can take up Accept “different parts of the molecule
different relative positions by rotating about the «CC, »bond ✔ can rotate relative to each other”.
1
Accept “rotation around bond”.
6. e C6H5CH2CH2OH ✔ 1