Integrated Rate Expression (DPP 3)

Subjective Type
1. Compounds A and B react with a common reagent with first order kinetics in both cases. If 99% of A must
react before 1% of B has reacted. What is the minimum ratio for their respective rate constants?
2
(Given = 458 )
2 − log99
2. The decomposition of Cl2 O7 at 400 K in the gas phase to Cl2 and O2 of I order. After 55 sec at 400 K, the
pressure of Cl2 O7 falls from 0.062 to 0.044 atm, calculate:
(A) The rate constant (B) Pressure of Cl2 O7 after 100 sec.
3. The reaction SO2Cl2 ( g ) → SO2 ( g ) + Cl2 ( g ) is a first order gas reaction with k = 2.22  10−5 sec-1 at
320°C. What % of SO2Cl2 is decompose on heating this gas for 90 min?
4. 1
The half-life of the reaction N 2O5 ( g ) → 2 NO2 ( g ) + O2 ( g ) is 2.4 h at 30°C.
2
(A) Starting with 10 g, what is the mass of N 2O5 left after 9.6 h?
(B) How much time is required to reduce 5.0  1010 molecules of N 2O5 to 1.0  108 molecules?
Single Correct Answer Type
5. Which of the following is/are correct for the first order reaction?

(A) I, II (B) II, III (C) I, II, III (D) I, III

6. 1
For a second order reaction, A → Product, the graph is plotted against and time ‘t’.
 A

tan  = 0.6 and OC = 2L , mol-1. The rate of reaction at beginning is:

(A) 1.25 mol L-1 min-1 (B) 0.150 mol L-1 min-1
-1 -1
(C) 0.5 mol L min (D) 1.50 mol L-1min-1
7. For a first order reaction, the plot of ‘t’ against log C gives a straight line with slope equal to
k k In k
(A) (B) − (C) (D) −k
2.303 2.303 2.303

8. In a first order reaction, the reactant substance has half – life period of ten minutes. What fraction of the
substance will be left after an hour of the reaction has occurred?
(A) 1/6 of the initial the concentration (B) 1/64 of the initial the concentration
(C) 1/12 of the initial the concentration (D) 1/32 of the initial the concentration
9. Two substance A ( t1/ 2 = 5 min) and (t1/ 2 = 15 min) are taken in such a way that initial  A = 4 B . The time
after which both the concentration will be equal is (assuming reactions are of 1st order):
(A) 5 min (B) 15 min
(C) 20 min (D) Concentration can never be equal

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 Integrated Rate Expression (DPP 3)

10. The rate constant for the reaction A → B is 2 10−4 It. mol-1. The concentration of A at which rate of the
reaction is (1/ 12 ) 10−5 M sec-1 is:
(A) 0.25 M (B) (1/ 20 ) 5 / 3 M (C) 0.5 M (D) None of these
11. The presence of HCl, sucrose gets hydrolysed into glucose and fructose. The concentration of sucrose was
found to reduce from 0.4 M to 0.2 M in 1 hour and to 0.1 M in total of 2 hours. The order of the reaction is
(A) zero (B) one (C) two (D) None of these
Multiple Correct Answer Type
12. The specific rate constant of a first order reaction is independent of the:
(A) Concentration of the reactants (B) time
(C) temperature (D) activation energy
13. For a I-order reaction
2 N2O5 ( g ) → 4 NO2 ( g ) + O2 ( g )
(A) The concentration of the reactant decreases exponentially with time
(B) the half-life of the reaction decreases with increasing temperature
(C) the half-life of the reaction depends on the initial concentration of the reactant
(D) the reaction proceeds to 99.6% completion in eight half-life duration.
14. Which of the following relationship(s) are correct for 1st order reaction?
(A) t75% = 2t1/ 2 (B) t87.5% = 3t1/ 2 (C) t99.9% = 9t1/ 2 (D) t96.87% = 4t1/ 2
15. In a 1 order reaction, amount of the substance left after n half lives and average life of a 1st order reaction
st

respectively are
A  1
(A) n0 ,
A  1
(B) 20 ,
A 
(C) 0n ,1.44  t1/2
A 
(D) 20 1.44t1/2
2 k n k n2 n
16. If the reactant ‘A’ is gaseous and pressures are measured instead of molar concentrations, then for reactions
of zero order,
1 p
(A) k =  p0 − p A ; t1/2 = 0
t 2k
1 p
(B) k =  p A − po ; t1/2 = o
t k
1
(C) k =  po − p A ; decrease in pressure of the gaseous reactant A  time
t
1
(D) k =  p A − po ; decrease in pressure of the gaseous reactant = kt
t
Matching Column Type
17. Only one match is possible:
Column I Column II

A. 1 O.R. = ½

(B) 2 O.R. = zero

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 Integrated Rate Expression (DPP 3)

(C) 3 O. R. = 2

(D) 4 O. R. = 3

Integer Type
18. dx  dx 
vs. log10 ( a − x ) with an intercept on log   axis to
n
A straight line was obtained on plotting log10
dt  dt 
0.6021. The rate constant for the reaction is …… litre mol t .
n-1 1 -1

19. The half – life period of a reaction, becomes 16 times when reactant concentration is solved. The order of
reaction is ……
Comprehension Type
Dinitrogen pentoxide decomposes to NO2 and O2 following first order kinetics.
N2O5 ( g ) → 2 NO2 + O2 ( g )
0.2 mole of N 2O5 was taken in 2L vessel and ,heated at 200 K. The concentration of N 2O5 is measured at different
intervals. Following graphs, A and B were obtained from the data.

20. Slope of straight line in graph ‘A’ is −1.2  102 sec-1. What is half life of the reaction?
(A) 2.5 10−2 s (B) 2.5 10−3 s (C) 12.5  10−4 (D) 2.5  10−3 m w
21. Calculate the rate of reaction after 5 10−3 s.
(A) 6.84 mol L-1 s-1 (B) 3.42 mol L-1 s-1 (C) 6.84 mol L-1 (D) 6.84 mol s-1

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 Integrated Rate Expression (DPP 3)

Answer Key
1. 458
(A) 6.23 10−3 sec−1
2.
(B) 0.033 atm
3. 11.2%
(A) 0.625 g
4.
(B) 21.52 h
5. C
6. B
7. B
8. B
9. B
10. B
11. B
12. AB
13. ABD
14. AB
15. AC
16. AC
17. (A→2), (B→3), (C→1), (D→4)
18. 4
19. 5
20. B
21. A

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National Admission Office: FIITJEE Ltd. FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi-110016, Ph-46106000
4