¸YMZ imvqb  EngineringPractieSh 1

wØZxq Aa¨vq ¸YMZ imvqb

Qualitative Chemistry
ACS Chemistry Department Gi g‡bvbxZ wjwLZ cÖkœmg~n Type: Av‡cwÿK cvigvbweK fi:
16 17 18
 nh 11| Aw·‡Rb cigvYy‡Z wZbwU AvB‡mv‡Uvc 8 O, 8 O, 8 O h_vµ‡g
Type: †K․wYK fi‡eM: mvr =  99.76%, 0.04% Ges 0.2% wn‡m‡e cvIqv hvq| Aw·‡R‡bi mwVK
 2 
1| †Kv‡bv cigvYyi M Kÿc‡_ AveZ©biZ GKwU e Gi †K․wYK cvigvYweK fi = ?
–

fi‡eM = ? H Kÿc‡_i e¨vmva© 3.6 × 10–8 cm n‡j MwZ‡eM KZ? DËi: 16

–34 5
DËi: .13 624 ×10 Js ; 96. 4 ×10 m/s
1 2
12| H Gi `ywU AvB‡mv‡Uvc 1H I 1H; mvaviY H Gi cvigvYweK fi
Type: e– Gi e¨vmva©, MwZ‡eM, kw³: 1 2
1.008 n‡j †g․jwU‡Z 1H I 1H AvB‡mv‡Uv‡ci kZKvi cwigvY = ?
1
H cigvYyi e– wUi †eM hw` Av‡jvi †e‡Mi
1
2| 275
Ask n‡q _v‡K, DËi: 9.2%  1 H
2
Z‡e e– wU †Kvb Kÿc‡_i? 0.8%  1 H
DËi: n=2
Type: cvigvYweK msL¨v fi msL¨v AYyi msL¨v:
3| H cvigvYyi 3q Kÿc‡_ AveZ©bkxj e– Gi †eM wbY©q K‡iv|
wbDwK¬qvm‡K wN‡i GB e– cÖwZ †m‡K‡Û KZevi AveZ©b K‡i? 13| 54 AvYweK fi Ges 26 cvigvYweK msL¨vwewkó X †g․j Y
DËi: 7.28×10 7
cms –1 ; 2.43 ×10 14
evi †g․‡ji mv‡_ AvB‡mvUwbK| Y Gi cvigvYweK fi 56 n‡j Y Gi
cvigvYweK msL¨v KZ?
4| H cigvYyi 1g Kÿc‡_i e¨vmva© 0.53Å n‡j 3Li2+ Gi e¨vmva© DËi: 28
KZ?
DËi: 0.177 Å hc c 1
Type:†dvU‡bi kw³: E = , E = h,  = , V– =
–
5| H cigvYyi 1g I 3q K‡ÿ AveZ©bkxj e Gi †eM wbY©q Ki|   
†Kvb K‡ÿi MwZ‡eM †ewk? –
14| H cigvYyi e Gi `ywU wfbœ kw³¯Í‡ii kw³i cv_©K¨ 245.9
DËi: V1 =3V 3 ; 1g K‡ÿi †eM †ewk| KJ/mol| D”PZi kw³¯Íi †_‡K wb¤œZi kw³¯Í‡i e– jvwd‡q co‡j
wewKwiZ Av‡jvK iwk¥i Zi½‣`N©¨ I K¤úv¼ = ?
6| Na cigvYyi 3q kw³¯Í‡i N~Y©vqgvb 11 Zg e– Gi MwZ‡eM wbY©q DËi: 6.1616×10 14
H z; 48. 67×10 2
nm
K‡iv|
5
DËi: 80.169×10 m/s 15| GKwU wewKwiZ iwk¥i Zi½‣`N©¨ 530 nm| G iwk¥i K¤úv¼ I
Zi½ msL¨v = ? wewKwiZ iwk¥i eY© = ?
7| m¦vfvweK Ae¯vq H cigvYyi N~Y©vqgvb e– wbDwK¬qvm n‡Z KZ DËi: 5.66×10 14
Hz ; 1.8868×10 4
cm –1
nm `~iZ¡ cwiågb K‡i MYbv K‡iv| Zi½‰`N©¨ 530nm nIqvq GwU meyR eY©|
DËi: 0.5292 Å
16| H cigvYyi e– wU 3q †evi Kÿc_ n‡Z 1g Kÿc‡_ jvwd‡q
8| †evib Gi 3q †evi K‡ÿi e¨vmva© = ? co‡j weKxY© kw³i Zi½‣`N©¨ Å GK‡K †ei Ki|
–
2
DËi: .962×10 nm DËi: 1025.8 Å

9| H cvigvYyi e– hLb K †k‡j Ae¯vb K‡i, ZLb Zvi kw³i gvb = ? 17| Zi‡½i K¤úv¼ 3.35 × 108 Hz; Ryj GK‡K kw³ KZ?
–11
DËi: –2.176×10 erg wK‡jvRyj/†gvj GK‡K kw³i cwigvY KZ?
–
4
DËi: 1.34×10 KJ/mol
Type: B‡jKUªb †cÖvUb, wbDUªb, AvB‡mv‡Uvc, AvB‡mvevi
18| He cigvYy e– hLb PZz_© kw³¯Íi n‡Z wØZxq kw³¯Í‡i hvq, ZLb
10| 0.8 g CH4 M¨vm e– KZwU?
DËi: .03 115×10 23
wU m„ó eY©vjx †iLvi Zi½‣`N©¨ I wewKi‡Yi eY© = ?
DËi:  =121.56nm `„k¨gvb bq|
 st
2  Chemistry1 Paper Chapter -2
19| `ywU Av‡jvi K¤úv¼ 5.46 × 1014 Hz I 4.4117 × 108 MHz 29| Li2+ Avq‡bi e– hLb 4_© kw³¯Íi n‡Z 2q kw³¯Í‡i cwZZ nq,
Av‡jv `ywUi eY© wbaviY K‡iv Ges Zv‡`i Zi½‣`N©¨i cv_©K¨ wbY©q Ki| ZLb eY©vjx †iLvi Zi½‣`N©¨ I eY©vjxi eY© wbY©q Ki|
DËi: 1g Av‡jv  meyR ; cv_©K¨ =1305. 5nm DËi: 54.03nm ; eY©vjx `„k¨gvb bq|
2q Av‡jv  jvj
30| H Gi eY©vjxi eªv‡KU wmwi‡Ri Z…Zxq jvBb Gi Zi½‣`N©¨ wbY©q Ki|
3
20| H cigvYy (fi 1.66 × 10 Kg) 5.1625 × 10 J MZxq DËi: 2.1656×10
–27 –27 nm
kw³‡Z Nyi‡Q| H cigvYyi wW-eªMjx Zi½‣`N©¨ wbY©q Ki|
DËi: 1.6×10 –7
m. 31| H Gi AvqbxKiY wefe = ?
DËi: 13.6eV
21| 4.8 MeV MwZkw³m¤úbœ GKwU -KYvi wW-eªMwj Zi½‣`N©¨i
32| evgvi wmwi‡Ri H Ges H †iLv `ywUi Zi½‣`N©¨ KZ?
gvb wbY©q Ki| –5
–
15
DËi: 4.863×10 cm
DËi: 6.55×10 g

33| Li2+ Avq‡bi e– 7g kw³¯Íi †_‡K 2q kw³¯Í‡i avcvšÍ‡ii d‡j

22| mÄq`v`v 150 g f‡ii GKwU wµ‡KU ej‡K 80 km/h †e‡M Qz‡o
wewKwiZ eY©vwj‡Z cÖvß †gvU †iLvi msL¨v wbY©q Ki|
w`‡qwQj| wµ‡KU e‡ji wW-eªMwj Zi½‣`N©¨ wbY©q Ki| GwU
DËi: 15
cwigvc‡hvM¨ wKbv = ?
–25
DËi:  = 1.987 × 10 nm ; GB gvb A‡bK ÿz`ª ZvB cwigvc‡hvM¨
bq| Type: `ª‡e¨i `ªve¨Zv wbY©q:
34| 30C ZvcgvÎvq 110 ml m¤ú„³ Rjxq `ªe‡Y 1.15 Av‡cwÿK
23| GKwU KYvi fi‡e‡Mi AwbðqZv 1.15 × 10 kgm/s KYvwUi ¸iæ‡Z¡i †Kv‡bv c`v‡_©i 20.7 g `ªexf~Z Av‡Q| 30C G `ª‡e¨i `ªve¨Zv
–8

Ae¯v‡bi AwbðqZv KZ? wbY©q Ki|

DËi: x  45. 87×10 –27
m DËi: 22.5

24| †gvU B‡jKUªb msL¨v MYbv K‡iv| 35| 30C ZvcgvÎvq †Kv‡bv je‡Yi `ªve¨Zv 80g/100g H2O| G
(i) F
–
(ii)S 2–
(ii)Mg 2+
(i)v PH 4 + ZvcgvÎvq 80g `ªe‡Yi g‡a¨ 30g jeY `ªexf~Z Av‡Q| G Ae¯vq
DËi: (i)10 ; (ii)18 ; (ii)10 ; (i)v 18 `ªeYwU‡K m¤ú„³ Ki‡Z cÖ‡qvRbxq je‡Yi cwigvY wbY©q Ki|
DËi: 10g
1 1 1 
Type: wiWevM© aªæeK:  = RH 2 – 2 × Z2 36| 30C I 50C ZvcgvÎvq †Kv‡bv `ª‡e¨i `ªe¨Zv h_vµ‡g 60 I
 n 1 n 2  
80| 50C ZvcgvÎvq 50g m¤ú„³ `ªeY‡K 30C ZvcgvÎvq kxZj
25| H cigvYyi e– Amxg n‡Z me©wb¤œ kw³¯Í‡i avcvšÍi n‡j †h kw³
Ki‡j Kx cwigvY `ªe `ªeY n‡Z †ewi‡q Avm‡e?
wewKwiZ nq, Zvi Zi½‣`N©¨ wbY©q Ki|
DËi: 5.552g
DËi: 19 .175nm
37| 95% weky× Lv`¨ jeY w`‡q 80C ZvcgvÎvq cvwb‡Z 600 ml
26| H cigvYyi jvB‡gb wmwi‡Ri n«vmZg/ÿz`ªZg Zi½‣`N©¨
b¨v‡bvwgUv‡i KZ n‡e? wK‡jvRyj/ †gvj †dvU‡bi kw³ ZLb KZ? m¤ú„³ `ªeY cÖ¯‧Z Ki‡Z 195g Lv`¨ jeY cÖ‡qvRb nq| 80C G
DËi: 19 .175nm;1312.85KJ/mol NaCl Gi `ªve¨Zv = ? H `ªeY‡K 25C G kxZj Ki‡j KZ MÖvg
weï× NaCl †KjvwmZ n‡e? 25C G NaCl Gi `ªve¨Zv 240 g/L
27| He+ Avq‡bi D‡ËwRZ e– 4_© kw³¯Íi †_‡K ¯vbvšÍwiZ n‡j DËi: 41.25g †KjvwmZ; 80 C G `ªve¨Zv =308.75g/L
jvB‡gb wmwi‡R †iLv eY©vjx •Zwi Ki‡j wewKwiZ iwk¥i Zi½msL¨v I
Zi½‣`N©¨ = ? 38| 750 mL m¤ú„³ `ªe‡Y 200g NaCl `ªexf~Z Av‡Q| MÖvg I †gvj
DËi: Zi½msL¨v =4.112×10 5 –
cm ;  =24.3163 nm
1 GK‡K cÖwZ wjUvi m¤ú„³ `ªe‡Y NaCl Gi `ªve¨Zv MYbv Ki|
DËi: 266.67g/Land4.558mol/L
Type: eY©vjx msµvšÍ MvwYwZK mgm¨v 39| cvwb‡Z 15C I 75C ZvcgvÎvq CuSO4 Gi `ªve¨Zv 19 I 55
28| H cigvYyi e Z…Zxq Kÿ †_‡K cÖ_g K‡ÿ jvwd‡q co‡j m„ó n‡j 77.5g m¤ú„³ Kcvi mvj‡dU `ªeY‡K 75 n‡Z 15C ch©šÍ VvÛv
–

eY©vjxi Av‡jvK‡iLvi K¤úv¼ Ges Zi½‣`N©¨ nm GK‡K †ei K‡iv| Ki‡j Kx cwigvY CuSO4 Rgv co‡e?
DËi: 2.92×10 15
Hz DËi: 18g
¸YMZ imvqb  EngineringPractieSh 3
–8
40| 25C ZvcgvÎvq 100g f‡ii GKwU `ªe‡K 300 ml dzUšÍ cvwb‡Z 49| 35C ZvcgvÎvq PbI2 Gi `ªve¨Zvi ¸Ydj 1.55 × 10
`ªexf~Z K‡i m¤ú„³ `ªeY •Zwi Kiv nj| G `ªeY‡K 50C G kxZj mol3/L3 n‡j G ZvcgvÎvq `ªe‡Y PbI2 Gi 80% we‡qvwRZ n‡j PbI2
Ki‡j KZ MÖv‡g `ªe `ªeY n‡Z †ewi‡q Avb‡e? 50C ZvcgvÎvq `ªewUi Gi `ªve¨Zv = ?
–3
`ªve¨Zv 54.4 DËi: =1.963×10 mol/L
DËi: 25g
50| BaSO4 Gi `ªve¨Zv ¸Ydj 1.1 × 10–10 mol2/L2 n‡j
Type: †nbixi m~Î e¨envi K‡i `ªve¨Zv wbY©q: (i) weï× cvwb‡Z Gi `ªve¨Zv = ?
(ii) 0.1 M BaCl2 `ªe‡Y Gi `ªve¨Zv = ?
S = KH × P; S  `ªve¨Zv –5
DËi: (i)1.048×10 mol/L
KH  †nbixi aªæeK –19
(ii) 1.1 ×10 mol/L
P  Pvc|

51| 25C ZvcgvÎvq K¨vjwmqvg A·v‡j‡Ui (CaC2O4) `ªve¨Zv

41| 20C ZvcgvÎvq cvwb‡Z CO2 M¨vm `ªexf~Z nIqvi †ÿ‡Î
¸Ydj 2.34 × 10–9 mol2/L2 n‡j, cÖwZ 100 ml m¤ú„³ `ªe‡Y KZ
†nbixi aªæeK 0.8725 g/100g H2O/atm| 20C ZvcgvÎv I 15.5 MÖvg CaC O `ªexf~Z Av‡Q = ?
2 4
atm Pv‡c CO2 M¨v‡mi `ªve¨Zv = ? DËi: 6.1824×10 –4
g
DËi: 13.524g/100gH 2O

52| 25C G Fe(OH)3 Gi m¤ú„³ `ªe‡Y OH– Avq‡bi MvpZ¡

42| †Kvgj cvbxq Gi g‡a¨ 25C ZvcgvÎvq I 2.65 atm Pv‡c 9.843 × 10–9 g/L; g/L; Fe(OH) Gi `ªve¨Zv Gi ¸Ydj wbY©q Ki|
3
CO2 M¨vm `ªexf~Z Av‡Q| †evZ‡ji wQwc Lyj‡j Pvc 1.05 atm n‡j DËi: .73 4 ×10 –
38

250 ml `ªeY n‡Z KZ †gvj CO2 †ewi‡q Avm‡e? 25C G †nbixi

aªæeK 1.75 × 10–2 m/atm. 53| 25C ZvcgvÎvq AgCl I PbCl2 Gi `ªve¨Zv ¸Ydj h_vµ‡g
DËi: 7×10 –3 mol 1.6 × 10–10 mol2/L2 I 1.6 × 10–5 mol3/L3 n‡j †Kvb jeYwUi
m¤ú„³ `ªe‡Y Cl– Gi NbgvÎv AwaK?
43| 25C ZvcgvÎvq CO2 M¨v‡mi †ÿ‡Î †nbixi mgvbycvwZK DËi: .13 748×10 2
mol/L
8
aªæe‡Ki gvb 1.67 × 10 Pa n‡j H ZvcgvÎvq 2.5 atm Pv‡c 2.25 L
†mvWv IqvUv‡ii g‡a¨ KZ MÖvg CO2 `ªexf~Z Av‡Q wbY©q| 54| 25C G, Fe(OH)3 `ªve¨Zv ¸Ydj 3.98 × 10–38| G m¤ú„³
DËi: 8.615gCO 2 `ªe‡Y 0.1 mol NaOH †hvM Ki‡j Fe3+ Avq‡bi NbgvÎvi Kxiƒc
cwieZ©b n‡e?
Type: `ªve¨Zv I `ªve¨Zv ¸Ydj wbY©q I mgAvqb cÖfve DËi: cÖv_wgK `ªve¨Zv =1.59 94×10 –10
M
–12
44| 25C ZvcgvÎvq Rjxq `ªe‡Y PbS Gi `ªve¨Zv 4.40964 × 10 g/L wgkÖ `ªe‡Y `ªve¨Zv =3.89 ×10 – 35
M
n‡j PbS Gi `ªve¨Zv ¸Ydj = ? [Pb = 207, S = 32]
–28
DËi: .43 ×10 mol 2/L 2 55| 25C ZvcgvÎvq GK wjUvi `ªe‡Y m‡e©v”P 1 × 10–3 mol PbI2
45| 25C ZvcgvÎvq CaF2 Gi `ªve¨Zv 0.002 mol/L n‡j Gi `ªexf~Z Av‡Q| (i) PbI2 Gi Ksp = ? (ii) I(aq) Avq‡bi NbgvÎv wظY
`ªve¨Zv ¸Ydj wbY©q Ki| Ki‡j PbI2(s) Gi mv‡_ mvg¨ve¯vq _vKv Pb2+(aq) Gi NbgvÎvq
DËi: .23 ×10 –11 mol 3 /L 3 Kxi~c cÖfve co‡e?
–9
DËi: (i)K sp =4×10
46| Fe(OH)3 Gi Ksp = 4.5 × 10–22 mol4/L4; g/L GK‡K Gi (ii) `ªve¨Zv, S 1 =
1
×1 ×10 –3
4
`ªve¨Zv = ?
1
DËi: 2.158×10 –
4
g/L  Pb 2+ Avq‡bi †gvjvwiwU n‡e|
4

47| 25C ZvcgvÎvq Cu(II) mvjdvBW Gi `ªve¨Zv ¸Ydj 56| AgCl Gi Ksp = 1.8 × 10–10 n‡j H ZvcgvÎvq 0.1M
6.3 × 10–36 mol2/L2 n‡j Gi `ªve¨Zv = ? AgNO3 `ªe‡Y AgCl Gi `ªve¨Zv = ?
–18 –
DËi: 2.5×10 mol/L DËi: 1.8×10 9
mol/L

48| 25C ZvcgvÎvq Al(OH)3 Gi `ªve¨Zv ¸Ydj 3.7 × 10–15 57| 25C ZvcgvÎvq weï× cvwb‡Z Ni(OH)2 Gi AvqwbK ¸Ydj
mol4/L4 Al(OH)3 Gi m¤ú„³ `ªe‡Y Al3+ Avqb I OH– Avq‡bi 1.75 × 10–15; 14 pH Gi gv‡bi NaOH `ªe‡Y Ni(OH)2 Gi
NbgvÎv Ges Al(OH)3 Gi `ªve¨Zv = ? `ªve¨Zv mol/L GK‡K KZ?
–15
DËi: 1.08×10 –4
mol/L DËi: S=1.75×10 mol/L
 st
4  Chemistry1 Paper Chapter -2
58| 25C ZvcgvÎvq weï× cvwb‡Z AgCN Gi `ªve¨Zv I 2M 68| 25C ZvcgvÎvq Ca(OH)2 Gi Ksp = 4.42 × 10–5| G
NaCN Gi Rjxq `ªe‡Y Ag+ Avq‡bi NbgvÎv mol/L GK‡K wbY©q Ca(OH)2 Gi 500 ml m¤ú„³ `ªe‡Y mgAvqZb 0.4M NaOH †hvM
Ki| Ksp = 6 × 10–17 Ges Kf = 5.6 × 1018 Kiv n‡jv| G‡Z Ca(OH)2 Gi nªvmK…Z `ªve¨Zv KZ Ges KZ wgwj MÖvg
–28
DËi: .436×10 mol/L Ca(OH)2 Aatwÿß n‡e?
–5
DËi: S 1 =110.5×10 mol/L
59| wbw`©ó ZvcgvÎvq `ywU ¯^í `ªve¨ jeY XY I X 2Y Gi `ªve¨Zv Aat‡ÿc 7832. 3 mg
¸Yd‡ji gvb h_vµ‡g 10–10 I 10–13; m¤ú„³ Rjxq `ªeY †KvbwUi
`ªve¨Zv †ewk? 69| AgNO3 Gi 0.1M Rjxq `ªe‡Y PO43– Avq‡bi NbgvÎv KZ n‡j
–
DËi: XY  S=10 5
;X 2Y Gi `ªve¨Zv †ewk| Ag3PO4 Gi Aat‡ÿcb ïiæ n‡e| [Ksp(Ag3PO4) = 1.3 × 10–20]
–5
X 2Y  S=2.92×10 DËi: [PO 4 3 –]=1.3×10 –17
M

60| 25C ZvcgvÎvq CaF2 Gi `ªve¨Zv ¸Yd‡ji gvb 4 × 10–11; H 70| mgAvqZ‡bi 0.002M NbgvÎvi NaIO3 I Cu(CIO3)2 `ªeY‡K
ZvcgvÎvq CaF2 Gi m¤ú„³ `ªe‡Y Gi `ªve¨Zv Ges †h․MwU †_‡K Drcbœ wgwkÖZ Kiv n‡jv| Gi d‡j Cu(IO3)2 Gi Aat‡ÿc co‡e wK?
Avqb¸‡jvi †gvjvi NbgvÎv wbY©q Ki| [Cu(IO3)2 Gi Ksp = 7.4 × 10–7]
–4
DËi: CaF 2 Gi `ªve¨Zv =2.15×10 mol/L DËi: Kpi =1×10 –
9
; co‡e bv|
–4
[Ca 2+ ]=2.15 ×10 M
[F –]=4.3 ×10 –4
M 71| mg‡gvjvi NbgvÎvwewkó FeSO4 I Na2S `ªeY‡K mgAvqZ‡b wgwkÖZ
Kiv n‡q‡Q| D³ `ªeY؇qi cÖwZwUi m‡e©v”P NbgvÎv KZ n‡j Avqib
61| 30C ZvcgvÎvq CaCl2 Gi `ªve¨Zv ¸Ydj 1.55 × 10–8
mvjdvB‡Wi Aat‡ÿc co‡e? [Ksp(FeS) = 6.3 × 10–18]
mol3/L3, H ZvcgvÎvq CaCl2 Gi 80% we‡qvwRZ n‡jv CaCl2 Gi
DËi: Aat‡ÿc co‡e bv|
`ªve¨Zv wbY©q Ki|
–
3
DËi: 1.963×10 mol/L
72| †Kv‡bv `ªeY †hLv‡b Pb2+ I Zn2+ Dfq Avq‡bi NbgvÎv
62| weï× cvwb I 0.025 NaCl `ªe‡Y c„_Kfv‡e AgCl `ªexf~Z Kiv 0.01M; H2S m¤ú„ ³ `ªe‡Y [H+] Gi NbgvÎv Kx cwigvb n‡j †Kej
2+ 2+
n‡jv| weï× cvwb I D³ NaCl `ªe‡Y Ag+ Avq‡bi NbgvÎvi Abycv‡Z gvÎ `ªe‡Yi Pb Aatwÿß n‡e wKš‧ Zn Aatwÿß n‡e bv?
wbY©q Ki| AgCl Gi Ksp = 1.75 × 10–10 [Ksp(H2S) = 1.1 × 10–22, Ksp(ZnS) = 1 × 10–21]
–2
3 DËi: 1.65×10 M
DËi: 1.88×10

63| 25C G cvwb‡Z Al(OH)3 Gi Ksp = 2 × 10–33 pH = 13 73| i³ cøvRgvq Ca2+ Gi NbgvÎv 0.0025M| hw` C2O42– Gi
Giƒc GKwU Rjxq `ªe‡Y Al(OH)3 Gi `ªve¨Zv 2 × 10–x mol/L n‡j NbgvÎv 1 × 10–7 M nq, Z‡e CaC2O4 Gi Aat‡ÿc Drcbœ n‡e Kx?
x Gi gvb KZ? CaC2O4 Gi Ksp = 2.3 × 10–3
DËi: x=30 DËi: Kpi = 2.5× 10 –10 ; Aat‡ÿc co‡e bv|

64| 25C ZvcgvÎvq AgCl Gi Ksp = 1.8 × 10–10 mol2/L2;
AgCl Gi 1L m¤ú„³ `ªe‡Yi g‡a¨ 1 mol NH3 †hvM Kiv n‡j `ªe‡Y
Ag+ Avq‡bi †gvjvi NbgvÎv wbY©q Ki| [Kf = 1.7 × 107]
DËi: 7.88×10 –13
mol/L
74| `ªe‡Yi pH gvb KZ n‡j 1.5 × 10–15 M CdCl2 Gi Rjxq `ªe‡Y
H2S M¨vm Pvjbv Ki‡j CdS Aatwÿß n‡e? Ksp(CdS) = 10–28;
Ksp(H2S) = 10–22
DËi: 4.

Type: Aat‡ÿc Type: †Kjvmb: C2 = bZzb `ªve‡K `ª‡e¨i NbgvÎv

65| 10 mol 0.25 M FeCl3 `ªe‡Y 1 ml 0.5M NH4OH `ªeY †hvM C1 = Av‡Mi/cÖ_g `ªve‡K `ª‡e¨i NbgvÎv
Kiv n‡jv| 25C ZvcgvÎvq Fe(OH)3 Gi `ªve¨Zv ¸Ydj 3.74 × 10–38 C2
n‡j †Kv‡bv Aat‡ÿc co‡e wKbv? * KD =
C1
DËi: co‡e  V n
* Wn = W
KDS + V
66| 0.02 M CaCl2 Gi `ªe‡Y 0.0003M Na2SO4 `ªeY mgAvqZ‡b KD  e›UY ¸bv¼ [KD Gi gvb 1 Gi †P‡q eo n‡e|]
wgwkÖZ Kiv n‡jv| Gi d‡j wgkÖ‡Y CaSO4 Gi Aat‡ÿc co‡e wKbv? V  ïiæi `ªe‡Yi AvqZb; W  ïiæi `ª‡e¨i fi
CaSO4 Gi Ksp = 2.4 × 10–5 S  bZzb `ªve‡Ki AvqZb
DËi: Aat‡ÿc co‡e bv| Wn  Awb®‥vwkZ `ª‡e¨i fi; n  wb®‥vlb msL¨v
67| 25C ZvcgvÎvq 2 × 10–3 M CaCl2 `ªe‡Yi 500 ml Gi mv‡_ 75| 100 ml Rjxq `ªe‡Y wKQz cwigvY I `ªexf~Z Av‡Q| 50 ml
2
1.5 × 10–2 M Na2CO3 `ªe‡Yi 1L †K wgwkÖZ Ki‡j CaCO3 Gi CCl †hvM Ki‡j 50% I wb®‥vwkZ nq| K = ?
4 2 D
Aa©t‡ÿc co‡e wKbv? [Ksp (CaCO3) = 9 × 10–9 mol2/L2] DËi: KD =2
DËi: Aat‡ÿc co‡e (Kpi >K sp )
¸YMZ imvqb  EngineringPractieSh 5
76| CCl4 I H2O †Z I2 Gi e›Ub ¸Yv¼ 80 †Kv‡bv ZvcgvÎvq cÖwZ 84| Calculate the energy required to excite one liter of
wjUv‡i cvwb‡Z 0.35g Av‡qvwWb m¤ú„³ `ªeY •Zwi K‡i| H ZvcgvÎvq H2 at 1atm and 298 K to the first excited state of atomic
Kve©b †UUªv‡K¬vivB‡W (CCl4) G I2 Gi `ªve¨Zv = ? H. The energy for dissociation of H-H bond is 436 J/mol.
DËi: 28g/L DËi: 10.93×10 14
sec –1 or Hz

77| GK wjUvi Rjxq `ªe‡Y 1g Av‡qvwWb `ªexf~Z Av‡Q| 85| The ionization energy of He+ is 19.6 × 10–18 J/atom
(i) H `ªeY‡K 50 ml CCl4 mn SuvKv‡j Rjxq `ªe‡Y Avi KZ Av‡qvwWb  Calculate the first stationary state of Li2+
Aewkó _vK‡e? (ii) 50 ml CCl4 †K 10 ml K‡i cuvPevi e¨envi DËi: 4.1 ×10 –17 J
Ki‡j Rjxq `ªe‡Y Avi KZ I2 _vK‡e? [CCl4 I cvwbi g‡a¨ I2 Gi
e›Ub ¸Yv¼ 80|] 86| D”PZi kw³¯Íi †_‡K e– kw³ Z¨vM K‡i wb‡P Avmvi mgq 6wU
DËi: (i)0.2g ; (ii)0.053g 64
†iLv cvIqv hvq| D”PZi Ges wb¤œZi kw³¯Í‡ii kw³i AbycvZ 100.
kw³¯Íi Øq Kx Kx?
78| H cigvYyi Rb¨ weve function 2s =
1
.  1  DËi: n =12;
1
2
a0 L nH =15
4 (2)
–r/a0
2 – r  87| In an atom, the total electrons having quantum
2s AiweUv‡ji †iwWqvj †bv‡Wi e¨vmva© av Gi gva¨‡g
 a0e 1
numbers n = 4, |mL| = – 1 and ms = – =?
cÖKvk Ki| 2
DËi: r=2a 0
DËi: 6

th +
79| The max and min for certain radiation are 121.65 nm 88| In 4 shell of He find the wavelength of electron.
–
10
and 91.24 nm. Find the color of the radiation =? DËi: 6.66×10 m
DËi: n2  2
89| In one liter saturated solution of AgCl [Ksp = 1.6 × 10–10]
= 1.0 × 10–10) is added. The resultant
80| -particles of 6 MeV energy is scattetced back from 0.1 mol of CuCl (Ksp
+ –x
concentration of Ag in solution = 1.6 × 10 ; x = ?
a silver toil calculate maximum volume in which the
entire positive charge of the atom is supposed to be DËi: x =7
concentrated. Z = 47
DËi: 48×10 –
42
m3 90| The solubility of CdSO4 in water is 8 × 10–4 molL–1.
It’s solubility in 0.01M H2SO4 = ?
–6
81| The dissociation energy of H2 is 430.53 kJmol–1. If H2 DËi: 64×10
is exposed to radiation of wavelength 253.7 nm what % of
radiant energy will be converted to kinetic energy? saL tofall:
–
19
DËi: 0.68×10 J ; 8.68% (i) †Kvqv›Uvg msL¨v
(ii) MRI I IR G‡`i g~j bxwZ I e¨envi
82| A bulb emits light of  = 4500Å The bulb is rated as (ii) Avqb kbv³ KiY|
150W and 8% of the energy is emitted as light. How many (i)v e –web¨vm|
photons are emitted by bulb per second?
18 GB UwcK¸‡jv n‡Z gyL¯Í Quseoit n Av‡m, GKUz fv‡jv K‡i †`Lv iv‡Lv|
DËi: 27.2×10 photons.

Ze2
83| prove that Un = mrn
where u is the velocity of
electron in a one electron atom at no. Z at distance rn
from nucleus, m and are mass and charge of electron.
2
Ze
DËi: mr n
 st
6  Chemistry1 Paper Chapter -2
4
ACS Chemistry Department Gi g‡bvbxZ eûwbe©vPwb cÖkm
œ g~n 11. 2He Gi GKwU cigvYyi cÖK…Z fi 4.003 a.m.u; 1wU proton
Gi fi 1.0075 a. m. u Ges 1wU wbDUª‡bi fi 1.0089 a. m.
Type: B‡j±ªb I †cÖvUb msL¨v u n‡j He cigvYy‡Z wbDwK¬qvi kw³i cwigvY KZ?
–8 –
10
5.62 ×10 J 3.59 ×10 J
18 2– –12 –10
1. 8
O Gi KqwU B‡jKUªb Av‡Q? 4.5 ×10 J 4.22 ×10 J
4 wU 6wU
10 wU 12 wU Type: cigvYyi g‡Wj:
12. †KvbwUi eY©vjx †evi ZË¡vbyhvqx e¨vL¨v Kiv m¤¢e bq?
2. †Kvb cigvYyi †Kv‡bv wbDUªb †bB? He + iL 2+
H wWD‡Uwiqvg 2 2+
H Be
wUªwUqvg meKwU 1

13. mvaviYZ †evi B‡jKUªb Kÿc‡_ AveZ©bKv‡j KqwU mgmsL¨K

3. B‡jKUªb Nb‡Z¡i w`K †_‡K mwVK µg †KvbwU?
c~Y©Zi½ m„wó K‡i?
1s>2s>3s>4s 1s<2s<3s<4s
n n2
1s=2s=3s=4s †KvbwUB bq
n+ 1 2l
4. wb‡Pi †Kvb †mUwU K‡¤úvwRU KwYKv? 14. †Kv‡bv ¯v‡b B‡jKUªb cvIqvi m¤¢vebv eySvq Kx Øviv?
Electron,proton,neutron
 Øviv 2 Øviv
- particle,dutron
x Øviv dx Øviv
positron,mes on
photon 15. û‡Ûi wbq‡g f¨vbvwWqvg (V) †g․‡j KqwU we‡Rvo electron
_v‡K?
5. cigvYyi 5th kw³¯Í‡i m‡ev©”P electron aviYÿgZvÑ 1 wU 3 wU
28 32
5 wU 0 wU
50 82
16. GKwU cigvYy‡Z GKwU B‡jKUªb 4_© kw³¯Í‡i GKwU c~Y© AveZ©b
6. fvix cvwb †KvbwU?
Ki‡Z KqwU c~Y© Zi½ m„wó Ki‡e?
H 2O D 2O
2 3
H 2O 2 D”P Nb‡Z¡i LwbR cvwb
4 5

7. wb‡Pi †Kvb cigvby¸”Q AvB‡mv‡UvwbK? 17. Zeeman effecr Gi †ÿ‡Î f~wgKv iv‡LÑ
40 40 40 39 40 17
18
Ar, 19
K, 20
Ca 19
K, 20
Ca, 37
Cl evwn¨K Pz¤^K‡ÿÎ evwn¨K Zwor †ÿÎ
16 17 18 30 31 32
O, O, O Si, P, S a+b None
8 8 8 14 15 16

79 81 18. †KvbwU mwVK mgxKiY?

8. 35
Br Ges 35 Br Gi Av‡cwÿK AvB‡mv‡UvwcK fi h_vµv‡g  
78.919 Ges 80.917 Ges G‡`i kZKiv cwigvY h_vµ‡g  0 2 d v = 0  0  dv = 0
0
50.52% Ges 49.48| Br Gi cvigvYweK fi KZ? – 2 dv=1 None
799.869 79.91 0
DËi: – 2 dv=1
79 80

9.
54 56
X Ges a Y AvB‡mv‡UvwbK n‡j a=? Type: †Kvqv›Uvg msL¨v
26
26 27 19. wb‡Pi †Kvqv›Uvg b¤^‡ii †Kvb †mUwU Aev¯Íe?
28 None 1
(n=2, l =0,m=0 ,s=  )
2
Type: †ZRw¯…qZv: (n=2, l =1,m=+1,s=
1
 )
228 212 2
10. 90 Th  83 Bi GB †ZRw¯…q wewµqvq wbM©Z  I  KYvi msL¨v 1
KZ? (n=2, l =1,m=0,s=  )
2
1 wU, 4 wU 4 wU, 1 wU 1
(n=2, l =0,m=+1,s=  )
7wU, 4 wU None 2
¸YMZ imvqb  EngineringPractieSh 7
20. wb‡Pi †KvbwU n Zg kw³¯Í‡i †gvU AiweUv‡ji msL¨v cÖKvk K‡i?
n n
{1 +(2n –2)} {1 +(2n –1 )}
2 2
n n
{2 +(2n+1)} {2 +(2n –1)}
2 2

21. hw` †P․¤^Kxq †Kvqv›Uvg msL¨v m Ges mnKvix †Kvqv›Uvg msL¨v

nq, Z‡eÑ
m{23m[()]TJETBT1001199.256TJET424ETo17810017657.46Tm[()]10010R[(n)tTJET4630vTf1001TJ8TBTTBT/F13110.00125-0.12134595.56841.8reW*nET6.7630vTf1L30500051>4<002E>-4/F39.6Tf100176.7