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Issued Date: 24/04/14

TANGNAM GLASS CO., LTD


Revision No.: 0
Material Safety Data Sheet Revised Date: -

Page: 1 Of 5
Top Bond Construction Adhesive

1. Identification of the substance/preparation and of the company/undertaking

Product name : Top Bond Construction Adhesive

Company : TANGNAM GLASS CO., LTD, Telephone : (662) 416 5678


226 Rama 2 Road, Samaedam, Fax : (662) 894 0433
Bangkhuntien, Bangkok 10150, Website : http://www.tangnamglass.com
Thailand.

2. Hazard(s) identification

GHS Classification
Health Environmental Physical
Skin Irrit. 2 Aquatic Chronic 3 Flam. Liq. 2
Acute Tox. 4
STOT RE 2
Repr. 2

GHS Label:

Signal word: Danger

Hazard Statement(s):
H225 Highly flammable liquid and vapor.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H361f Suspected of damaging fertility.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statement(s):
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapor/spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection
Issued Date: 24/04/14
TANGNAM GLASS CO., LTD
Revision No.: 0
Material Safety Data Sheet Revised Date: -

Page: 2 Of 5
Top Bond Construction Adhesive

3. Composition/Information on ingredients

Chemical name CAS No. EINECS % (w/w) Toxicology Data


LD50 oral (rat): 5000 mg/kg
Hexane 110-54-3 203-777-6 < 25 LD50 dermal (rabbit): No data
LC50 inhalation: 3000 mg/kg

4. First-aid measures

• Inhalation: Remove to fresh air, keep warm and at rest. Contact physician if discomfort persists.
• Skin contact: Remove contaminated clothing. Rinse with copious amount of water. Contact physician if
discomfort persists.
• Eye contact: Contact lenses should be removed. Rinse with copious amount of water immediately, seek
medical advice if necessary.
• Ingestion: Seek medical advice immediately. DO NOT induce vomiting. Drink plenty of water followed by milk
if available. Never give anything by mouth to an unconscious person.
Avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately (show
label where possible).

5. Fire-fighting measures

• Suitable extinguishing media: Foam, CO2, dry powder.


• Special fire fighting procedures: Keep up-wind to avoid fumes. Use self-contained breathing apparatus in
confined areas.
• Unusual fire/explosion hazards: Unknown.
• Hazardous combustion products: Oxides of carbon, light flammable hydrocarbons, smoke and fumes.
• Protective measures in fire: Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.

6. Accidental release measures

• Personal precautions: Ensure adequate ventilation. Keep away from ignition sources. Wear appropriate
personal protective equipment.
• Environmental precautions: Prevent spreading of flammable vapours. Do not allow product to reach sewage
system or any water course.
• Methods for cleaning up: Pick up mechanically. Collect spill in clearly labelled container for disposal as per
statutory regulations. Wash down area where spill occurred. Do not empty into drains.

7. Handling and storage

• Handling precautions: Ensure good ventilation during processing.


• Protection against fire/explosion: General rules of fire prevention should be observed.
• Storage conditions: Keep container tightly closed and dry. Store in a well-ventilated area.
Issued Date: 24/04/14
TANGNAM GLASS CO., LTD
Revision No.: 0
Material Safety Data Sheet Revised Date: -

Page: 3 Of 5
Top Bond Construction Adhesive

8. Exposure controls/personal protection

• Ingredients with limited values to be controlled:


Ingredients CAS No. Exposure Limits
3
Hexane 110-54-3 TWA: 50ppm (176mg/m )
• Industrial hygiene: Remove immediately all contaminated clothing. Do not inhale vapor. Wash hands and
contaminated areas with water and soap before leaving the work site. Do not eat, drink or smoke while using
the product. Change clothing before leaving workplace.
• Hand protection: Suitable protective gloves like nitrile or viton is recommended. The breakthrough time of the
selected glove must be greater than the intended use period.
• Respiratory protection: An organic respirator NIOSH-approved for organic vapors is recommended where
local ventilation is not adequate.
• Eye protection: Protective goggles/safety glasses.

9. Physical and chemical properties

• Form : Paste
• Color : Brown
• Odor : Light petrol odor
• Boiling temperature : 68 - 69°C (Hexane)
• Flash point : - 18°C
• Solubility in water : Not Soluble
• Specific gravity : Approx. 1.16 ± 0.01 g/mL

10. Stability and reactivity

• Stability: Stable when stored under recommended conditions.


• Conditions to avoid: Heat, flames and sparks
• Material to avoid: Strong oxidizing agents, acids.
• Dangerous reactions: Combustion.
• Hazardous decomposition products: Oxides of carbon, light flammable hydrocarbons, smoke and fumes.

11. Toxicology information

• LD50 (Oral): >5000mg/kg (mouse).


• LD50 (Dermal): >3000mg/kg (rabbit).
• LC50 (Inhalation): No data.

12. Ecological information

• Persistence/Degradability : Not determined


• Ecology toxicity : Not determined

Individual components of this mixture have been independently tested by the raw material suppliers and any known
results have been presented above. The results for the individual components may not be representative of the
ecological toxicity of this finished product. This finished product has not been tested to determine individual
toxicological/ecological limits Great caution should be taken to prevent release to the environment. See Section 13
for further information.
Issued Date: 24/04/14
TANGNAM GLASS CO., LTD
Revision No.: 0
Material Safety Data Sheet Revised Date: -

Page: 4 Of 5
Top Bond Construction Adhesive

13. Disposal information

Preferred method of disposal includes incineration under controlled conditions in accordance with all local and
national laws and regulations. The generation of waste should be avoided or minimized wherever possible.
Untreated material is not suitable for disposal. Waste, even in small quantities, should never be poured down into
drains, sewers or watercourses. Waste must be disposed of in accordance with federal, state and local
environmental control regulations. This material, when properly mixed and cured at the proper mix ratio, may be
safely landfilled.

14. Transport information

Road transport (ADR)


• Proper shipping name : Adhesives, containing flammable liquid
• Technical name : Not Required
• UN number : UN1133
• Hazard class : 3
• Packaging group : PG II

Marine transport (IMDG)


• Proper shipping name : Adhesives, containing flammable liquid
• Technical name : Not Required
• UN number : UN1133
• Hazard class : 3
• Packaging group : PG II

Air transport (IATA)


Not regulated

15. Regulatory information

EU Classification:

• Classification and Labelling: The product is classified and labelled for supply in accordance with the Classification
of Hazardous Chemical.

F Xn

EU Risk(R) Phrases:
R11 Highly flammable.
R38 Irritating to skin.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation
R62 Possible risk of impaired fertility
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Issued Date: 24/04/14
TANGNAM GLASS CO., LTD
Revision No.: 0
Material Safety Data Sheet Revised Date: -

Page: 5 Of 5
Top Bond Construction Adhesive

EU Safety(S) Phrases:
S2 Keep out of the reach of children.
S9 Keep container in well ventilated place.
S16 Keep away from sources of ignition- No smoking.
S29 Do not empty into drains.
S33 Take precautionary measures against static discharges.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheets.
S62 If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.

16. Other information

Definitions:
• EINECS : European Inventory of Existing Commercial Chemical Substances.
• TLV : Threshold Limit Value.
• LD50 : The minimum dose required for lethal effects in 50% of a given population of test specimens.
• NIOSH : National Institute for Occupational Safety and Health.

All materials may present unknown hazards and should be used with caution. Although certain hazards are
described herein, we cannot guarantee these are the only hazards that exist. The details contained herein are
based on our present state of knowledge and experience in characterizing our product with regard to any possible
safety requirement. We do, however, pass them on without any warranty or property assurances.
Issued Date: 24/04/14
TANGNAM GLASS CO., LTD
Revision No.: 0
Technical Data Sheet Revised Date: -

Page: 1 Of 2
Top Bond Construction Adhesive

Product Specification:
Appearance: Thick Paste
Colour: Brown
Solids: 75 – 77 %
Consistency: Thixotropic
Specific Gravity: Approx. 1.16 ± 0.01 g/mL
Open Time: Max. 40 mins. at 23°C and 50% R.H.
Curing Time: 24-72 hours depending on temperature and
porosity of surface.
Water Absorption: Does absorb water to a certain extent which lowers the
mechanical properties. Not to be used for constructions
that will be exposed to severe water immersion.
Lap shear strength: 4.43 N/mm² (Wood to wood)
(Modified from ASTM D1002)
Application Temperature -20°C to 38°C
Service Temperature -30°C to 60°C
Freeze/Thraw Stability 5 Cycles
Coverage: ㎡
400–1000g/ depending on the smoothness and porosity
of the surface and desired strength of the construction to
be glued.

Product Description:
A one component, high performance, paste like construction adhesive sealant formulated to bond a variety of
common construction materials. It has strong initial grab, superior adhesion and will not slump on vertical
surfaces.

Applications:
Ideal for bonding of skirting boards of wood and PVC, particleboard, masonry, aluminum, galvanized iron, steel,
concrete, fibrous cement sheeting, wall brick, concrete and flooring paneling. It is also safe to use on foamed
polystyrene and mirror backed tiles.

Directions:
• Surfaces must be clean, dry and free of dirt, grease, oil or water.
• Cut tip off and puncture the internal foil seal with nozzle. Cut nozzle at 45° angle to desire bead-width and
apply to substrate with cartridge gun.
• For a neat finish, apply masking tape and remove it before construction adhesive sealant has skinned
over.
• Construction adhesive sealant can be applied either as a two-way contact or a one-way wet stick
adhesive (recommended for heavier panels or those that are formed to place a loading or stressed
memory on bond line).
• Two-way contact: Press firmly over entire surfaces to transfer adhesive and then pull both surfaces
apart. Allow to tack off for few minutes (3-5 minutes depending on weather conditions) and reposition and
press firmly together. Contact areas should be tapped with a hammer and padded block to ensure
intimate contact.
• One-way method: After applying adhesive and bringing substrates together, they should be sufficiently
clamped, nailed or screwed in a fashion that maintains maximum surface contact at bonded interfaces.
Mechanical fastening should be retained if highly stressed, but can be released after a minimum of 24
hours.
• Any wet or partially wet adhesive can be removed with a piece of cloth. Dried adhesive is best removed
with scraper or by sanding.
Issued Date: 24/04/14
TANGNAM GLASS CO., LTD
Revision No.: 0
Technical Data Sheet Revised Date: -

Page: 2 Of 2
Top Bond Construction Adhesive

Packaging/Coverage:

345gm per cartridge. 24 cartridges per carton. 144 cartons (18 cartons x 8 layers). A 345gm cartridge will cover
15 metres of 6mm bead.

Caution:

• Avoid contact with eyes, skin and mouth.


• In case of contact with eyes, flush with water immediately for 15 minutes. If irritation persists, seek medical
attention.

Keep out of reach of children. Use in well ventilated areas.

Storage:
• Highly inflammable, keep away from heat source or naked flames. Store in a dry and cool place with
temperature below +30°C.
• Use within 12 months from date of production.

Every endeavour has been made to ensure that the information given herein is true and reliable but it is given only for the guidance
of our customers. The company cannot accept any responsibility for the loss or damage that may result from the use of the
information, due to the possibility of various of processing or working conditions and of workmanship outside our control. Users are
advised to confirm suitability of this product by their own tests.

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