)Dat:

Page

eenyaton
Che te
metala
Comaunds etal atens ahe brund to aa numpes
anions Oh neuthal mele culea
blechona
Coohdination Ciuptunda
Mg conplex

MoLECULAR OR
ADDITION COMPOUNDS
hen Aelutitna Containing 2 oth mobe.
Aimplestable ebmpaunda Ahe ales in moleclas
are allAusedto erapbhote
Aubstances btainod. hese
ttaned as mblecule addition Conpounda.
KCl t+ 6 Ha0 Kl.Maly.6H,0
(lekaite)
+
+ 24 H,0
h2KAL(S0.)2H,ó
4 NHa
4KCN+ Fe(ca) ’ Fe (cN),. 4 KCN
+ KCN KCN. AgCN
 Catc

MoLCCULAR OR ADDITION CoPOUND S

CoORDINATIONCOMPOUNs
DouBLE SALT
t existsinAelid sbt
as well as 9ater
sate
ether cent
pesent
the constitents ahe the consttuento are
tbtaine d sken disted mat dasered in ater
en ater.
Fe So,.NH4), SQ,. GH,0’
3 K*+eCN.
2so} lay) 6h,0 CNitis not ebained

"ft Centains ienic tonda.t Cantains itnic

well aA Condinate bends
Motol iÝns ahe Aubunded

nentral maeoulesmohe

C&hdination
ahe the Aane
Compunda
the
conaltatnt conpouida
otaalt the
CNH, Qnd |does net
So aqueeus selutin CN ns tot qivestest
Fe SO, (NH)S0 6H,0 ned itn
NH, +
 Lonsund
Coehdnation Campaund may
meleulan Compaund that esuls
the combination slable
milecalea Cempenda luid sctain iita identty
in th selid

hadical wthich consibts a cential meaL attn

swreundad
heutad meecules h
AA Coordination Compoundthus, comsists f ester 8

) a Aimple caton and e cenplex Rnion

Oe Complen caton ande sinple

Aimple Qnion

(i) d Compex cation and 'a Compler Qnitn

neutal
Ni (co)

aERNER'S
h Coondination conptunh, metala she)
Qnd
 Date

PRIMARY VALENGIES
anitns hich ane
Wahe ioniaable nohmally
ahis is alae called prinlijpal , wionisakl
ibnic alency
SECONDARY VLENCIESahe
hagativeJens
Aatistied
hich
by
hehalmolecades
non-i¡nisable
CAGhdinaton number
otem

*
Ligande
dinked it tiecenhal metal atomm ion
called igands
Ligenta be
1, Aeathaldike. NH3
lgatisely chengd ike
B. Pobibvel,chaned ike. NO
he ligand aheattached te thecenthal metal.
bendsth
dative
ilecton
Leusisbaahen
Central metal atoms oh ions
Leutis acids
he cenlaal netal aton o ion Ahuld
have Vacamt
the
his Cendtinis eletonsdenated
atoms tamition metals
 tensysica bidendate
2
hey
2 at metal
2donsatnys.
LiGANDs BiDENTATE
neS CyaneSCN < M 3.
NC MO CN M 2.
Mituto
NO NO, M<
1.
AMBIDENTATE. caled aediganda
anylaas,
y ion metal t
osmig atached isatom dono 1
but atoms dna
moh 2.hee dhat diganda ceriain ae hey
ete, Coo CH,
NH, -H,N
H,o, H,O CA, NO.
NHa,OH
CN
etaltem cental
the topain 1e inly
atom. donoh have
LIGANDSMÌNODENTATE
Page
Dat:
2. 1. 3. 2.
Rdentate
lagmtical
bilayiandsate agnsebhicnl
phiendinalinefohem)10- 1,
xalateim etiylendinnine
CHa (aeAamehiganda
en) Bidetate
CHa are

H
Ldentate
N H
N

in
n
aohich
coehdnatng
1hickthe Date
Pege.

the
coh
dinatng
 Date

Page

it OTRbENTATE LIGANDS
hey hare 3dnhatoms
3de
H

1. Ho CH Jekylene tiamine (eni)

CH

2.

HEXADENTATEMLIGANDS
hey hane 6denshatoms
lnylinediamminetlebaacetate ion
jcH CHyn
(ERTA)

CHa

Chelatid
he
coGhdinetion
aclased oh

hus frmed ae cald chelats.

 Date

Paçe

Polydentant ligemda AhaeFLEXIDENTATE

charactes.i met necenahy hat al the
donehatoms present n
should fehencoehdimotebond tsi
solydentate ponca.
centaal
netaliatem
EDTA a henadentate daand but
can
tethadentat 4tk certain tmetals
can ot mpmtalenlate yand.

Charecteristies
mohe atakle Compleres
than monolentate
Ki) Cheletes contaiingUthe metalatomare

simgsnheatable
notable
due
ingestenic hindance Amaller

* le-hdination nmber

ttat are bound_to thecental

ametal atm eion by coohdinate bends
knautn cohdination nmber the
metalatem

wdads hasting salency 3 hane CN. 6

2 have CNi 4,5 h 6
1 have C-N =2.
 Dat:

Page

C-N.

Coordination ne.
o cental metal
Ky fe (C)e 6
2
4
aledtas]
Fe (cos 5
5

* Co-ohdinationsphere
he centalmetalatomoh on
en and
the digenda that ahl dhectyatached to
it enclased Ibyacketiocalled
ceGhdinatioy sphere h csehdinatiom lntiy
bingle tunit.
ion plaent tulaidk tis sphese
Aeparetec
h ater
medim n Ysittn utside tte
aecalld Counter ions.
CoGhdnaton Conpeund omplex in t Center ien +
+ 4K
Co( NH+3C
-tenthat metat
6 Cothdinaton no.

sphere
 Date

lo- danaton ayhedhn

atbched o
atomsi 2hich are
called
the Central atom oh on
Coordination polyhedron
Coahdinalón palghedsadauere planeh
"tetiadhal
totakadhel

uaken (EAN)
heesullant numbe ot elechors witl
the metal atn ohon electhons
the don bh atoms
VcalledEfectie Atomic Nunber (EAN)
EAN = Atomic ne. tiemetal
+ no. oe gained fhomth conon

EAN a metal na
sonplen Cmpeund caincides ahitk the attmic
yet inent

CoMPLEX OxIb. STATE Z CooRDINATION EAN

OF ME TAL At.No) NuMBER
+2 26 6 26-2 +6 x2 =36
+2 80 4 30-2 + 4x2 = 86
+1 47 2 447-1+2x2 =50