Definition Systematic classification of all elements
Arranged in order of increasing atomic number (Z)
Elements are arranged so that elements with similar
properties are in one group
Divided into 3 main groups – metals, non-metals and
metalloids Arrangement Groups – vertical columns where elements have the same number of valence electrons
Valence electrons – electrons in outer energy level
Number at top are group numbers (1 – 18)
Position of elements Groups 1 & 2 have 1 and 2 valence e- respectively
Groups 13 – 18 have valence e- same as 2nd digit of
group number
Periods – rows across periodic table
Period number – indicates number of energy level
where valence e- appear Metals 70 Metals in nature
Found on left hand side of periodic table
Have similar physical properties
Shiny lustre Relatively high density Good electrical conductors Good conductor of heat Relatively high melting & boiling point Few have magnetic properties eg. Iron, cobalt & nickel Metals React in characteristic way
Most metals solids at room temperature
Have high melting and boiling points
Metalloids Have properties of both metals and non-metals
Solids at room temp but is not malleable nor ductile
At room temp offer great resistance when conducting
electric current
When reacting in chemical reactions with metals
behave like non-metals and vice versa Non-metals Physical properties opposite to metals
Dull and good insulators
Do not conduct electric current or heat (exception is
graphite)
Many are gases at room temp
Very low melting and boiling points
Periodicity and Trends in PT Periodicity – repetition of similar properties eg. Number of valence electrons
Other trends include:
Atomic Radius Melting & Boiling Points Ionisation Energy Electron Affinity Electronegativity Atomic Radius Mean distance from the nucleus of atom to border of outermost energy level
Increases from top to bottom within group
Decreases from left to right – number of protons
increase making attraction between nucleus & electrons stronger Melting & Boiling points Increase across a period up to group 14
From group 15 it drops and decrease to end of period
Decrease going from top to bottom down a group
Some elements are exceptions to this trend eg Mg in
Group 2 Ionisation Energy Energy needed per mole to remove electrons from atoms in the gaseous phase
Measured in kJ.mol-1
First ionisation energy increases from left to right
across the period
Related to atomic radius
Ionisation Enegy Decreases from top to bottom within a group
Element First Ionisation Energy
(kJ.mol-1) Li 520 Na 496 K 419 Rb 408 Cs 376 Electron Affinity Amount of energy released when electron is attached to an atom or molecule to form a negative ion
High electron affinity – more likely atoms of element
will attract electrons
Electron affinity increases from left to right across a
period
Noble gases do not fit trend
Electronegativity Tendency of an atom in a molecule to attract bonding electrons
Linus Pauling drew up scale
Generally increases from left to right across a period