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P 144000 q00032362 Neom Care Water Clo2 Ksa Rev 0
P 144000 q00032362 Neom Care Water Clo2 Ksa Rev 0
P 144000 q00032362 Neom Care Water Clo2 Ksa Rev 0
Alessandro Meneghini
COMPANY De Nora Water Technologies
Care Water Company Phone: 0039 342 6726786
email: alessandro.meneghini@denora.com
Date: May 17, 2024
Proposal Manager: Paolo Ferrari
Proposal Writer: Niji Roy Thomas
© Present document is property of De Nora Water Technologies. Any unauthorized use or copy is not allowed
GENERAL IND EX
1 INTRODUCTION ........................................................................................................................................ 4
1.1 SUMMARY FOR THE MOBILE CLO2 SYSTEM .......................................................................................... 6
1.2 IMPORTANT NOTICE REGARDING THE SAFETY OF THE OPERATIONS AND PURITY OF THE PRODUCED
CHLORINE DIOXIDE ........................................................................................................................................... 7
2 PROCESS DESCRIPTION........................................................................................................................... 10
3 SCOPE OF SUPPLY................................................................................................................................... 11
3.1 MATERIAL .......................................................................................................................................... 11
3.2 ACTIVITIES.......................................................................................................................................... 12
3.3 ENGINEERING..................................................................................................................................... 13
4 CHLORINE DIOXIDE SYSTEMS DESCRIPTION FOR TYPICAL MOBILE CLO2 UNIT ........................................ 15
4.1 CHLORINE DIOXIDE COMPACT PACKAGES WITH U-TYPE REACTION CHAMBER .................................. 15
4.1.1 REAGENT DOSING SECTION............................................................................................................ 16
4.1.2 REACTION AND INJECTION SECTION .............................................................................................. 17
4.2 CLO2 INJECTION PUMP SKID ............................................................................................................... 17
4.3 CONTROL SYSTEM .............................................................................................................................. 17
4.4 STORAGE AREA .................................................................................................................................. 19
4.5 CONTAINER DESCRIPTION .................................................................................................................. 19
4.6 ANALYSERS ........................................................................................................................................ 20
5 TESTING AND SITE ACTIVITIES ................................................................................................................ 21
5.1 SITE COMMISSIONING ....................................................................................................................... 21
5.2 REMOTE COMMISSIONING ................................................................................................................ 21
6 INCLUSIONS / EXCLUSIONS..................................................................................................................... 23
7 ASSUMPTIONS AND DEVIATIONS ........................................................................................................... 25
8 COMMERCIAL QUOTATION .................................................................................................................... 26
8.1 CHLORINE DIOXIDE SYSTEMS ............................................................................................................. 26
8.2 DAILY RATES ...................................................................................................................................... 26
9 COMMERCIAL CONDITION ..................................................................................................................... 27
9.1 INVOICING AND PAYMENTS TERMS ................................................................................................... 27
9.2 DELIVERY TERMS ................................................................................................................................ 27
9.3 DELIVERY DATE .................................................................................................................................. 27
9.4 BID VALIDITY ...................................................................................................................................... 27
9.5 TERMS AND CONDITIONS................................................................................................................... 27
10 GUARANTEES ..................................................................................................................................... 28
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FIGURES INDEX
TABLES INDEX
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1 INTRODUCTION
The present is a techno-commercial proposal for the design, engineering, supply,
commissioning, and start-up of a chlorine dioxide disinfection system for the NEOM
Magna project, Saudi Arabia.
In this proposal, the following disinfection systems will be proposed as per below:
Mobile ClO2 generating system: Supply of 2 set of 2 x 1 kg/hr (1D & 1SB) ClO 2
generating system which is installed in a customized 40 feet container suitable for
mounting on a trailer (trailer to be supplied by client).
Our company has acquired a broad experience in engineering, supplying, installation and
commissioning of chlorine dioxide plants worldwide and particularly in the Gulf region.
Each chlorine dioxide production system here described will consist of a storage and a
dosage section of sodium chlorite 31% and hydrochloric acid 31-33%, while the chlorine
dioxide is produced from these two reagents into submerged type reaction chambers
and injected in line by using injection pumps.
The two reagents are dosed in the reactors, using diaphragm electronic diaphragm
pumps, along with the electrical panel, the control system, and the injection skids.
The dilution water lines will be equipped with monitoring instruments required for the
safety of the system. The plant has been designed considering a mechanical redundant
configuration to allow a quick restart in case of failure.
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The following scheme is self-explanatory regarding the process and the underwater
chlorine dioxide formation.
•
The present proposal includes the complete engineering and factory test of the system
at DNWT’s workshop in Italy, commissioning and start up.
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Some deviations have been considered due to space constraints but guaranteeing a 2
x 100% redundancy of generators. This container shall be put on a trailer (supplied by
client).
o 1 x 100% dosing skids (one for each reagent with dosing pump, piping, fitting,
and instrumentation).
✓ 1 x 100% injection pump skid (with the related piping, fitting, and
instrumentation installed on a base frame).
o No.2 x 50% storage tank for hydrochloric acid and sodium chlorite. The total
tank capacity for each reagent has been designed to guarantee 30 days of
storage at maximum capacity.
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We would like to underline that our generating systems have been specifically studied
for potable water disinfection by paying strong interest in two paramount points:
Safety aspect related to all parts of the system, from the storage of reagents, by
installing different sizes loading connections for sodium chlorite and hydrochloric acid
to avoid any mistake during the reagents loading operation, up to the reaction
chambers, which are very small and placed inside a GRP pipe where the dilution water
flows continuously preventing any kind of chlorine dioxide spilling in case of an unlikely
event of leakage from the reaction chamber. This reaction chamber is named
“Submerged reactor” because is located “underwater” and it is not in direct contact with
the area of operation.
Reaction chamber
NaClO2 HCl
The reaction between sodium chlorite and hydrochloric acid takes place in a small
reaction chamber. The formed chlorine dioxide is immediately dissolved in the dilution
water flowing right outside the reactor, forming a solution of only 1000 mg/l, with no
ClO2 accumulation in any part of the system. The classic chlorine dioxide generation of
our competitors needs a much bigger reaction chamber, where the concentration is
maintained around 20,000 mg/l, placed in direct contact with the operation place. In an
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event of breakage, chlorine dioxide immediately spills all over the surrounding area with
serious risks for operators.
The safety limit of exposure in the workplace (TLV-TWA) for chlorine dioxide is 0.1 ppm.
For a 10 kg/h classic generator, the reaction chamber would have a chlorine dioxide
hold-up of 70 litres that (with a concentration of 20 g/l) means 1400 g of ClO 2
accumulation. For instance, in a container of 20 feet (40 m 3 the most conservative
assumption), the concentration of the chlorine dioxide in the air would be 35 g/m 3, more
than 100 times over the TLV limit.
The Chlorine dioxide formed in the process will therefore reach these elevated
temperatures and being in a concentration of 20 g/l decomposes.
It should be considered that often in the year the ClO 2 concentration in the reaction
chamber would exceed the explosion/safety threshold. This is a serious issue for the
conventional chlorine dioxide generators.
The submerged reactors can provide the required safety. This technology does not have
any storage of ClO2 except in the reaction chamber surrounded by water.
Purity of the produced chlorine dioxide solution is another important aspect in case of
potable water. In fact, to comply with the international regulation (WHO, EPA), residual
chlorate and chlorite must be kept below 0.7 mg/l. The formation of chlorate takes place
in the generators during the reaction and chlorite formation, in case of desalinated
water, is mainly linked to the yield of the reaction, in addition to the one formed by the
reaction of chlorine dioxide during the disinfection. According to many years of
experience in desalinated water disinfection all over the Middle East, with our
submerged generators a negligible formation of chlorate and the highest possible yield
of conversion of chlorite into chlorine dioxide are guaranteed. Therefore, our technology
allows the end user plant to comply with the international regulation.
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Volume of reaction
chamber for 10 Less ClO2 quantity means,
Up to 70 litre 0.1 litre
kg/h ClO2 in general, less risk
production
Quantity of
Since the normal Only one generating Less equipment, less
required chlorine
production is 10 kg/h for system is required. One space required, less
dioxide for large
each generator, it is single reaction chamber maintenance and less
plant (example
required to install can generate up to 100 spare parts in the
200,000 m3/h
several generators kg/h of chlorine dioxide warehouse
water)
Location of high concentration ClO2 is
reaction chamber Under water, inside the surrounded by water,
In the atmosphere main water line or into a with no chance to release
by-pass into the atmosphere high
concentration ClO2
Chlorine dioxide In the classic reactors,
solution there is normally a
accumulation concentrated solution No accumulation of
Very small reactors and
accumulation in the chlorine dioxide solution
surrounded by water
reactors where a 20,000 except underwater
mg/l of ClO2 solution is
stored
Yield of reaction Less chemicals, less by-
products such as chlorite
90-95% 95-98%
and chlorate ions into the
water to be treated
Constancy of Feedback from The yield is constant in
Reagents constant and
performance over customers report a time and is not
low consumption
time decrease of efficiency in dependent on climatic
guarantee over time
time conditions
Concentration of About 18% Less cost in
Most of the case only 7.5 It is possible to feed the
sodium chlorite reagent transportation,
or 25% sodium chlorite generator with 31%
water solution less cost in storage
concentration is allowed concentrated sodium
capacity, more time
to feed to the generator chlorite solution
autonomy
Spare parts and Often, specific Free market availability
Low cost and less
maintenance mechanical spare parts of mechanical spare
repairing time
are required parts
Table 1 – Comparison between DNWT system and traditional system
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2 PROCESS DESCRIPTION
In the chlorine dioxide generators, the formation of the ClO2 takes place only in the
water (submerged- type reactor) and it is not present in any other part of the plant.
The reactors have an expected yield higher than 95%, obtained using a strong
hydrochloric acid excess.
The above indicated water flow rate is not a consumption, because the same amount
of water (containing chlorine dioxide) is sent back to the client system.
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3 SCOPE OF SUPPLY
3.1 MATERIAL
SL. NO. DESCRIPTION QTY UOM
MOBILE CHLORINATION – 1
1 ClO2 generator skid, 1 kg/hr 2 SET
2 Injection pump skid (having 2 pumps mounted on base 1 SET
frame)
3 Residual analyzer 1 NO.
4 Redundant PLC control panel 1 NO.
5 Electric drum pumps 4 NO.
6 Storage tanks with related piping, valves and 1 SET
instrumentation
7 Customized 40 feet container for housing the tanks, 1 SET
generators, and control panel
8 Gas detector 2 NO.
9 Injection lance 1 NO.
MOBILE CHLORINATION – 2
1 ClO2 generator skid, 1 kg/hr 2 SET
2 Injection pump skid (having 2 pumps mounted on base 1 SET
frame)
3 Residual analyzer 1 NO.
4 Redundant PLC control panel 1 NO.
5 Electric drum pumps 4 NO.
6 Storage tanks with related piping, valves and 1 SET
instrumentation
7 Customized 40 feet container for housing the tanks, 1 SET
generators, and control panel
8 Gas detector 2 NO.
9 Injection lance 1 NO.
Table 2 – Equipment summary
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3.2 ACTIVITIES
The activities included in the scope of the work are:
• Project management.
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3.3 ENGINEERING
The Engineering activities will include the development of the documents (1)(2)
listed here below:
2. P&ID
o Injection pumps.
o Instruments.
o Motors.
4. System Description
7. Instrumentation List
8. I/O List
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Notes:
Technical, job quality and test documents shall be as per DNWT’s standards.
(1): All engineering documents will be sent in digital format (e-mail). Final documentation
will be sent in 1 soft and 1 hard copy.
(2): A maximum of 3 revisions (for approval/information, for construction, as built) have
been included for each document and a period of two (2) weeks after receipt has been
considered for the approval of the documentation by Client.
(3): the following documents shall be provided from sub-vendors.
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The below description illustrates a typical unit of 1 mobile chlorination system. Same will
be considered for the other mobile chlorination system as they will be identical to each
other.
Two separate Compact packages will be supplied to reach the 2 x 100% configuration.
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The correct dosing of the chemicals into the reaction chamber is guaranteed by dosing
pumps. Pumps will be electronic diaphragm type (PVC headed with PTFE diaphragm)
with the maximum range-ability available on the market (also 1/800 of maximum flow
rate is assured).
Each pump will have a separated basin for possible leakages, provided with high level
switch for leakages detection. The section frame will be in Polypropylene and a
removable Plexiglas panel will be provided, in front of each section, to protect the
operators. The piping material will be U-PVC PN16.
The dosing section configuration will be 1 x 100%.
All the draining will be separated and separately collectable in bottles, to always avoid
the direct contact between sodium chlorite and hydrochloric acid.
The dosing section will have all the required devices for a safe functionality; the following
items will be supplied:
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A double flow check by means of a flow switch and a variable area flow meter equipped
with a minimum switch is foreseen to assure that the dilution water is flowing prior to
dose the reagents.
A continue water source shall be made available by the customer (1 x 1 m3/h of flow rate
guaranteed at 1 bar) to the chlorine dioxide generator.
The chlorine dioxide solution, generated in the U-Type reactor and always submerged
by dilution water, is delivered at the injection point by means of an injection pump.
From the HMI the operators will be able to check and control the whole package,
adjusting the dosage according to the process requirement.
A power supply will be made available by the client for the electrical panel feeding, 3 X
380-415 Vac 3ph+N+E, 60 Hz ± 10%.
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The software will be programmed with three different running modes that can be set by
the operator:
• Maintenance mode
• Shot mode
1 - Maintenance mode
This mode is configured for the plant maintenance and testing. The operator can
manually start/stop any dosing pump and set its speed percentage for operating the
plant on a manual intervention mode.
2 - Shot mode
In this mode, 9 programs are provided; the parameters that must be set in each program
are start and stop times. After selecting the program, the operator can choose between
manual or automatic running mode.
2.1 manual shot mode: the operator manually selects the pump speed percentage and
the theoretical water flow rate. To check the plant functioning the operator can read the
ppm value theoretically present in the treated water (ppm will be calculated with the
water flow rate value and the quantity of sodium chlorite used).
2.2 automatic shot mode: the operator can set the ppm value in the treated water and
the dosing pumps, which are automatically adjusted by the PLC. The water basin
flowrate will be manual inserted by the operators.
3 - Continuous modes
In this mode, the operator can set the plant in manual or in automatic mode (as before),
but there is no need of start/stop programs: once start is given, the plant runs
continuously 24h a day.
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• No.4 (2 x 50% for each reagent) horizontal tanks, 2 m3 capacity, Vinyl Ester GRP
with UV Protection according to BS4994.
• Level transmitter with local display for local indication and alarm thresholds.
The container is a 40 feet ISO Marine, with dimension 12.192 x 2.438 x 2.591H mm.
Provision for wall mounted A/C system, electrical service sockets, internal and external
lights.
The container will be provided with lugs for lifting with the equipment installed inside
(approx. 150 kg/m2).
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The walls will be realized with sandwich panels, thickness at least 40 mm, insulating from
heating, composed of mineral wool or polyurethane inside and two external pre-painted
metal sheets. The door structure will be in anodized aluminium.
1. Cost saving
2. Pre-mounted and pre-installed items are completely tested in Italy. The plant
inside the container will be completely hydraulically tested during F.I.T., and only
connections with the external are needed on site. Moreover, since the Control
System will be installed inside the container, the dosing strategy will be fully
tested and tuned at DNWT workshop in Italy, saving costs and time site
commissioning and start up.
4. Maintenance and operation facilities and space are assured in the container.
4.6 ANALYSERS
1 no. of residual analyzer is included in scope of supply as loose material. Installation
shall be under client’s scope.
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A FAT (Factory Acceptance Test) will be performed at workshop, and the client will have
the option to be present for testing of all pre-installed components.
On Customer’s request, our Engineers will be available, at a daily rate mentioned in the
commercial offer, for any additional activity required at site.
In the last months Authorities like DEWA, SEWA and Major EPCs like SAIPEM, Okamura,
Tecton have favourably evaluated our new service, as efficient, resilient, reliable, and
up to the safest and high-quality standard as per our market requirements.
This quote does include all the tools, procedures, and training to perform the
commissioning in a package of 10 man-days (8 hours/day) of a DNWT senior engineer.
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- Performance check
- the price is built up on service only (no board and lodging, travel costs).
- avoids sanitary restrictions (no need for quarantine, no limitations to reach the
site)
- A DNWT specialist will be always available to the client in case of need during
the commissioning.
To perform the remote commissioning our client shall provide us a technician to operate
manual devices when it is required and an internet connection.
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6 INCLUSIONS / EXCLUSIONS
This proposal includes the following activities for each mobile unit:
- Mechanical, Electrical and Instrumental Engineering.
- Power & Control panels test (including devices installed inside the container, as
per DNWT test procedure).
- Dosing, reaction, and injection skids factory tests (as per DNWT test procedure).
- Injection lance
- No.2 flexible pipes 50m (±10%) flanged to connect container inlet and outlet.
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- Installation activities.
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8 COMMERCIAL QUOTATION
8.1 CHLORINE DIOXIDE SYSTEMS
The price for the scope of work as detailed in the technical offer are as below:
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9 COMMERCIAL CONDITION
9.1 INVOICING AND PAYMENTS TERMS
Invoicing will be as follows:
- 60% at delivery.
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10 GUARANTEES
ClO2 system warranty:
DNWT reserves the right to determine damage that might be caused by external non-
manufacturing defects and reject the warranty under conditions of miss-use, power
conditions or use not for the stated purpose of the products or equipment.
This warranty supersedes and replaces any warranty statements orally made by the
Salesperson, Distributor, or Dealer or contained in written instructions or other
Brochures or informational documents in relation to this product.
Owner shall provide all necessary labour to install and test the replacement
components. Equipment sent back pre-paid (including custom duties) to the factory for
repair shall have all labour charges waived if the warranty claim is deemed valid. All
incoming and outgoing freight during the warranty period is the responsibility of the
system owner if the warranty claim is not valid. All incoming and outgoing ground freight
within Italy during the warranty period is the responsibility of the Manufacturer if the
warranty claim is valid.
The Manufacturer's obligations under this warranty is being limited to repairing or
replacing any part found to its satisfaction to be so defective, provided that such part is,
upon request, returned to the Manufacturer, with freight prepaid.
This warranty does not cover parts damaged by decomposition from chemical action or
wear caused by abrasive materials, nor does it cover damage resulting from misuse,
abuse, or any other than its intended use, accident, neglect, or from improper operation,
maintenance, installation, modification, or adjustments.
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