Nitides and s class ificatíon

Nitides N)

Metal
Metal
nitides
haing } i g h LE and al

hat hove YeYy nigh

eySensiti awards aCid /aenerali

itis txposed wit acd, i+ Canaod e

ammowia gos
undexgoaydra lysis to pom

o Canet Moleculay Nireqen

si s eey Ra
atouicnitagtn ancd altr hatahnaic dik
eact wi meku a metul
Aady o
niidu_

*dhen an elechicglo dischae isa s e a

undoh
uduuCed pmmuY eYuund

0-DL 00 Pa),
N 2N firsh obServed Jo
Wham Shrutt

Ha,Zn Cd Na,Mg
SMg2N MgsNa
AHs
-
395 K mola
Li tN L2 N
a t I 0 _Rmp eNen_at reo
Seddun nihide
NaNH
Seda awde Socliummile
 Zbinel shucas Mm M-1ad, m'Oh ati
anim Date

Pege No.

classificahon
O Tonic nitide s
3
2
3

AteN AIN

Censi.deralka amount Coualent cherachrsaL

bxent in such kind itides
Sensitive tosarda add athieh give N
Covalet tids
Si N, SnN 2N8(N)

N
SaNy aad Sng Ny
Spinel hiides

CeP
AO,O+
oh ho

nides
4Nitides git 4 Oh_hele
8 Tcl hale
2 oh hole oCCubied
S i atom -Sigay-
Td hole o
ccupied y Si at0m
Oh
2 hale dsoceuprd ay Si7Sn
ostyosHy Siad_and S3 ly uud a

efracorx vhtral
Boro xich Nitmide BayN).

Ba

Tehagsat u t CeLt

Lcosa hedyo
aeln N -atom Bondad t
4 -

Bi2 aton

Nitragw r i w n i ide

&er vapu)t3Ag Ng ts

Boron hinitride isStable at gaseous Shsefor 6o

Min Jiberat
sih N 9a to faim GNz
C sslicd sate (-35°'c)_itwl shows hehberatn
Nas because it s notStab le h Se d form.

-H-
N
 Dare

Page Ne

Metulle Nirides
metal i sbacked in_ecp form

Clastdpacked lathce

MN M2
wdr)
TN ,ZrN HEN NbN
ard, hesistunt to e and Chemical attack
neluding oxidation
* high mp.
used inprotechin high shred Cuthng taals.
Per Per nitides
LN)
1P 2-etauzot
Ba Na Md SY N2
920 K
a
5600ba
StN S6 o b Sr N
 Date
Pege o
Boxon Nitides GN)

3t exist in hree diftenent farms

O - BN Chexagonal N )

analLagauo qoaphie
0) B-BN (Cubic N)
orazonon zinc blende N
analagos o dianmoud
Cit) Y-N (WuTtzite ovon nitide)
ltnh îs hexagtOma,
tnS

Zincbtude wurter-

CCp lathice hep ype lattiec

N
Syuthesis
Ca Poy)4
_ 8,0a t NH
200-1200
Na

Ammouo lysis boron haud

borm
B + NH3
Aed
Cecess) 750
- BN
 Date

ago No.

-360-190e-
d-N

Probernes
CYySulline
Colawles extreely ther moS fable hexagona

-BN m.p. -3270°C d2 25glom

* uik unvealhive
e
-BN+O, BorOn OXIde

- BN_ HOeg- Y B(oH) t

hear NH
Naou

-N+3F BF+N
gly veachye
X N
+4H E CNH UBFyJ
gh veachviy AmmoMum feha Pleura Bnate.
-GN+ LigN
onic niide
i[6N,J

GN = Co, lineav Shuetve

#Stuctw
Sinilar
Siulla as a gashte
BNS2e
ESOelechenua
 11 f lae
N

B
- N- 158A
N 2
N
=N1324
20

N N
N
3-35A
2D

2DayY Sebarated 3:35 A and in q re hit is

3-33A hiehis uery cinailar to iaphit

Sn gaabhit Second loyer is not eclibsed but

-8N the huo layer a eclibed
in_Casi

3n qrabhik shuchu isMaclu by burly

C-atomL no intaction b
C-C atem.

n N B-behaa as lesis aud andN5ahav

aleois Base
Reloa lay)Corou is ecliksed by N (aba laurr m e a
and Nito-
here is weakinttraction beturten Breu

detscaticed, so it behave
n 14bki*, e® a hghly
good CosbuCtos elechriut
N rgen aton
Jn BN, he ee y me locolse d tosases
b e cause eechonegehv diftoA A , ConuauetiviA
 Dat

/P»

d-8Nclaes o t Comduct_elechidh

mea eguyhonta
abyasieh
# Applicathou
kmberatuve
as ig met al
eahra
I tis used Cast
metalsland

m o l d s for
Line chambe YS,
chamhers
Coneiun4 rocket Combushion
Sheatiný
Shatn
for
eactosS
nuclea
and
buvnevs
blasma

2B-8N
Cubie Bovon Niride
s i
Peparation
15e0-2
15o0-2200C
-BN (highly skblu)
d-BN
5-4tP-

KI50
Y- 8N
(meta stalyle Conpoun

Nhe
lalhenhle add AiN to0N it will giue
o1leadato p-6N whieu is guble .
8-N)= 56A
3

N
=N- N
56A

N -
 Datn

In B-O t h e boron nirideisStable_in

ichair
2D-sbuehure

N
N

N
p-B ccp)

In BN Csaueture)

N
- N Chep)

n - Ntwo choirs de in Same (onormatio

L l ein X-N tuo chars hot in_Same
Conarmatiu_ie a oppaait to eacl oty

4Properhies-
After diqmond -LN is_next hqrd he tals.
9+is au extemely ad,
sed as
abasivead Cdthig
disks fr i
hasauaA tool aud nickel-chyomium Skl
eurviw aph 300 C,
kSh 300 Curviw

uTvie uto 6 coC, Tungsten Carbide

 Dat
Pag N

-6N
explaiud sth B-8N
Reterence Holleman
berg

Pablem luthH0
Palo_Combouwol aly solueinpur
Snuhne_ CAmbound

A 3%0
Allo 3e

AlL is ued o pmceed_ fdel

ALl
Lewis acobehanebecam 6-(odrik
A
protonNMR dffeanhlala N e--
0at
ma

Preparatim ef Diboraue
Non -metal KeH4+l2-
n g o velslng
,t_k
A
Cduci +H

TAJ hez
nanatube
fn_fehmao
nca utd Catenstion(h

Carenhane bopev y
maien

AlKane

CH
Gorane
Ha
mono mty-
due to edeiuent.
Neen Raist ag

Ha
Grouwd stt
1S 2P-

2s
2P

H1 25
8
Bnd
1 2S-2s
P - LS A
-bmd
 Ha mna e e m dA y o n d s N-ah
CH4
foudands H
rdnsi
ty
Cem
m e rneo
/per

Tattain snbilty Csmble+éng etet

3- cte m bH3is olimer is e inps m

Diborane , H Ke1o
Dimer

Sen9 3eouing. agentbuut ot acebt oltc ron

e d u i n g agent did accept eec
a nom
9 i e1 H t ) _

e
Diborane alisays i e HT, do not atept
cusbohng i o aCcetins
Reduion potenha do nst

SruchuL anal Bonding

1 3 7 P m

122

Sp3
H

*Non-plamay (sp hybridised)

D,h Cym mety

M H
H
oCb) - 1
BO(a)=0-5

qz Bond lernghs
Bo 1
 i s less

80 fon 8-H) bond bcz denaii

hisJLn
so
Aad Gmong to Br
a true Sing/e bond 312 6 e s
Fz
-

to -w-B
2hei a
Bend
anale
2 - 2 e b n d

sC-2ebond

H
H

Boron atom hat 3 e So 2- Bxn hav

6 e from wuch u ye ae occuprrd in

bending with 4-trminal ydrogenOnly 2 -
tmaining foY bmolin wih bridging hyd

But 1 Bovon hqne Onl ee mA

eJtmuns to Bovm and 2c H

-H-B (bndqed) Calleo as 3C- 2ond

6 :1
(L
 Hhae
moreAlectaneqaivi t han Deran. So
haae LA drid and foming 2-bonhd
e
with Baron aama

rMoT, L Cant tell Bond

lihoLut-

ee-
directy
MO
3 Ao
Ya
bais 2-7aae
y 3c-2

ABMD
hb

1L

H-

n n a d e s i n c r e a s e s t h e n _ R n e h gL -
an
INhen Moaleculax
orhiak
a l o incveass ecaing aa

n
B-H-6 b.and hase 2e So fisH e ffu
in
nh - h
2 o L3--6)
Bo
2 2 BCutle h a e Snd
eReh
means

Orole 1
Brn ham o
2
ond so electronit u
H

2 e