30. 29. 28. For the reaction: 280,(g) + 2802(e) + Ox(2) which of the following defines the rate of reaction? ‘What is the unit for the rate constant, k, of a reaction that is second order overall?” (A) mol L's (B) Khas no unit (©) Lmot's! @) st A first order reaction has a half-life of 55 s. What is the rate constant for this reaction? (A) (B) () (D) bes 1.26x10? st Sst 719s! 38.15 ‘The reaction 2NO + 2H2 — No + 2H20 is thought to occur by the following three step mechanism 2NO 5 N202 fast, equilibrium N:02 + Hz > N20 + 20 slow N20 + Hp > No + HO fast What is the rate law for the overall reaction that would be predicted on the basis of this mechanism? (A) rate= A[NOPTH:? (B) rate= A{NOP[H:] (C) rate = A{NO][H2] (D) _rate= {NOP33. 34, Questions 32-34 refer to the aqueous phase reaction SBr + BrOy + 6H" + 3Br.+3H:0 for which the following mechanism has been proposed. 22 BrOy + 2H" 2 HaBrOs" fast equilibrium HaBrOs" + Br > B02 + H0 slow BO: +41" + 4Br > 3Br + 20 fast Which of the following species is a reaction intermediate? a) (B) © ©) Bro: Bros Br 120 ‘The most likely rate law predicted by this mechanism is (A) (B) © (D) rate = k [BrOs ][H*]*[Br}* rate = k[Br-][H2BrOs*] rate = k[Br ][BrOs][H"}? rate = k[Br.02|[Br }[H"}* An appropriate energy profile diagram for this reaction is w © energy > energy > t o 3 i veadion covey readin wordincey t ” 2 3 : § Cpa cada reaction coordinated