23-07-23 - JR - Iit - Star Co-Sc (Model-A) - Jee Adv - 2020 (P-I) - Wat-12 - QP - Final@

Sec: JR.
*CO SC(MODE-A) Date: 23-07-2023

Time: 3HRS WAT-12 Max. Marks: 198
23-07-23_JR.IIT_STAR CO-SC(MODEL-A)_JEE ADV_2020(P-I)_WAT-12_QP _FINAL

MATHS:
TRIGINOMETRIC EQUATIONS:
General Solution, Solution of Trigonometric equation using graph or otherwise, Equations
based on extreme values using graph or otherwise, Trigonometric inequalities using graph or otherwise
DETERMINANTS: Introduction of Determinants & its Properties, Properties of Determinants
PHYSICS
Work ,Power, Energy: Work, Kinetic energy, work – energy theorem, conservative and non
conservative forces, potential energy, conservation of energy (EXCLUDE: Problems related to
power, Problems related to types of equilibria, vertical circular motion, Spring problems)
Elastic Potential energy of Spring, Spring Block Problems, Stable and unstable equilibrium
CHEMISTRY
Ionic Equilibrium: Theories of acid & bases – Arhenius, Bronsted-Lowry and Lewis theory
(Exclude: Comparison of Acidic & Basic strength), Ionic product of water and pH scalep H calculation
involving strong acid, Strong base and their mixtures, pH of weak acids and bases, Mixture of weak
acids, Levelling effect, Common ion effect, Dissociation of polyprotic acids, Salts and their
Hydrolysis, Buffer solution & Buffer capacity, Solubility of sparingly soluble salts and solubility product,
Indicator, Acid base titration curves
Narayana IIT Academy 23-07-23_JR.IIT_STAR CO-SC(MODEL-A)_JEE ADV_2020(P-I)_WAT-12_QP
2020-P1 MODEL
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198
MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single Correct Options +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -1 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66
PHYSICS
Sec – II (Q.N : 25 – 30) +4 -1 6 24
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
CHEMISTRY
Sec – II (Q.N : 43 – 48) +4 -1 6 24
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐ +4 0 6 24
127.30)
Total 18 66
Please mark/bubble/bolden your answer against the corresponding question

No.(ignore the subjects mentioned on OMR sheet, if found any difference).
JR .IIT_*CO-SC Page. No. 2

MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. For n  Z, the general solution of the trigonometric equation
sin x  3 cos x  4sin 2x  4 3 cos 2x  sin 3x  3 cos3x  0 is

n  n  n  
A)  B)  C)  D) 2n 
2 8 2 6 2 6 6
2. The number of positive integral triplets (x,y,z) satisfying the equation
x3  1 x2y x 2z
xy 2 y 3  1 y 2 z  11 is
xz 2 yz 2 z 3  1
A) 0 B) 6 C) 3 D) 12
a b ax  by
3. If x  0, y  0 , b 2  a 2 , satisfies the equation b c bx  cy  0, then
ax  by bx  ay 0
which of the following is correct for non-zero a,b,c?
A) form an A.P. B) form a G.P.
C) form a H.P. D) satisfy the relation a 2  b 2  c 2
a1 b1 c1
4. The maximum value of a b c is ______  where a1 ,a 2 ,a 3 ,b1 ,b 2 ,b3 ,c1 ,c 2 ,c3  1,1 
2 2 2
a3 b3 c3
A) 0 B) –4 C) 4 D) 6
5. Let , ,  be the roots of the cubic x 3  ax 2  bx  c  0, which (taken in given order) are
2 1 2
   r  a r 
100
in G.P. If  and  are such that 1      0. If S          , then S

r 1     b  
4  3   1 
equals:

1 1  4 1  8 1  2 1 
A) 1  100  B) 1  100  C) 1  100  D) 1  100 
3 2  3 2  3 2  3 2 
6. x sin a  ysin 2a  z sin3a  sin 4a,
x sin b  ysin 2b  zsin 3b  sin 4b,
x sin c  ysin 2c  zsin 3c  sin 4c , then the roots of the equation:
z  y  2 z  x 
t3    t2   t     0, a,b,c  n, are
2  4   8 
A) sin a, sin b, sin c B) sin 2a, sin 2b, sin 2c
C) cos a, cos b, cos c D) cos 2a, cos 2b, cos 2c
SECTION - 2 (Maximum Marks : 24)

Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
1 
7. If  2sec x  1 3   sec x  1 3  1, then x can be present in the interval
       3 5 
A)   ,  B)   ,  C)  ,  D) none of these
 3 3  6 12   4 4 
8. Let f :  0,4  R be the function defined by
   
f  x    3  sin  2 x   sin  x    sin  3 x   , which of the following is/are correct?
 4  4
A) If x   0, 2 : f  x   0  ,  , then     1
B) If x   0,2  : f  x   0   , , then     2
C) If x   2, 4 : f  x   0  ,  , then     1
D) If x   2,4  : f  x   0   ,  , then     2

2 cos A  cos B  cos3 B

9.  Then possible values of sin  A  B  is /are
2 sin A  sin B  sin 3 B 
1 1 1 1
A) B) C)  D) 
2 3 2 3
a1 a2 a3
10. Let a i ,i  1,2,3,.......,9 be perfect square of odd integers, then a 4 a5 a 6 is always a
a7 a8 a9
multiple of
A) 4 B) 7 C) 16 D) 5
1  sin 2 x cos 2 x sin 2x
11. If maximum and minimum values of sin 2 x 1  cos 2 x sin 2x are , 
sin 2 x 2
cos x 1  sin 2x
respectively, then which of the following is/are true?
A)   99  4
B) 3  17  26
C)  2n  2n is always an even integers for n  N
D) A triangle can be constructed having its sides as , ,   
1 1

 x  y
z z z2
 y  z  1 1
12. If   then
x2 x x
y y  z  x  2y  z  y x  y 
x2z xz xz 2
A)  is independent of z B)  is independent of x
C)  depends on z D)  is independent of y

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
8sin 2 x cos x  3sin x  cos x

13. The number of solutions of  0 in the interval 0,4 is
 7   3 
sin  x    3 cos  x  
 2   2 
2y 2y
14.

If the ordered pair  x, y  ,0  x  satisfies
 sin x 

 cos x 
 sin 2x , then the value
y2 y2
2
 cos x  2  sin x  2
of y is equal to_____
15. Let a, b, c be three non-zero real numbers such that the equation
   
3 a cos x  2bsin x  c, x    ,  has two distinct real root  and  with     ,
 2 2 3
b
then the value of is____
a
16. Number of real values of ‘  ’ satisfy the equation
2 2 2
1    1  2  1  3 
2 2 2
 2     2  2   2  3   648 is______
2 2 2
 3     3  2   3  3 
17. Let a third order determinant 1  a ij  ;i, j  1, 2,3 and the determinant  2 is constructed
by multiplying the element a ij of 1 by 2i  j ,i.e.,  2  2i  j a ij  ;i, j  1,2,3 , then
5 2  4 1
is equal to____
5 2  41
18. If a,b,c,d  0; x  R and  a 2  b 2  c 2  x 2  2  ab  bc  cd  x  b 2  c 2  d 2  0, then
33 14 ln a
65 27 ln b is equal to____
97 40 ln c

PHYSICS MAX.MARKS: 66
19. A block is tied within two springs, each having spring constant equal to k. Initially the
springs are in their natural length and horizontal as shown in the figure, the block is
released from rest. The springs are ideal, acceleration due to gravity is g downwards. Air
resistance is to be neglected. The natural length of spring is l0 .
If the decrease in height of the block till it reaches equilibrium is 3 l0 , then the mass of
the block is:
2kl0 2kl0
A) B)
g g
3kl0
C) D) data insufficient to determine mass of block
g
20. A body of mass 'm' is hauled from the earth's surface by applying a variable force F
 
varying with height y as F  2  ay  1 mg , where a is a positive constant. For first half of
the height ascended, choose the correct statement: (Neglect variations of g with height)
5mg
A) Work done by F is
2a
mg
B) Increase in gravitational potential energy is
2a
3mg
C) Increase in gravitational potential energy is
2a
3 mg
D) Kinetic energy of the body is
4a

21. A block of mass 250g is kept on a vertical mass less spring of spring constant 100N/m
fixed from below. The spring is now compressed to have a length 10cm shorter than its
natural length and the system is released from this position. How high does the block
rise above its relaxed length position? (g = 10m/s2)
A) 10cm B) 20cm C) 30cm D) 40cm
22. A block of mass 2 kg is free to move along the x-axis. It is at rest and from t=0 s on
wards it is subjected to a time dependent force F(t) in x- direction. The force F(t)varies
with t(in sec) as shown in fig. The kinetic energy of the block after 4.5 sec is (nearly)
A) 4.50 J B) 7.50 J C) 5.06 J D) 14.06 J

23. A light spring of spring constant k has its one end fixed to wall. A block moving on the
smooth floor with velocity v0 starts compressing the spring. The maximum spring force
v0
during the subsequent motion of the block is F0 . The spring force when velocity is is
2
3 F0 F0 3F0 F0
A) B) C) D)
4 2 2 2

24. A block of mass 'm' is released on a smooth fixed incline plane at t = 0. The spring
shown is ideal. The block touches the spring for the first time at t  t1 , with speed v0 . The
block returns to initial position of the release for the first time at t  t2 . Then the number
of times speed of the block becomes v0 , in t  0 to t  t2 is
A) 1 B) 2 C) 3 D) 4
correct options.
option.
25) Identify correct statement(s) from the following
A) total mechanical energy is not constant if non conservative forces such as friction acts
between the parts of the system
B) work energy theorem is valid in the presence of non-conservative forces
C) work energy theorem can be applied if the observer is in a moving frame
D) if Non conservative internal forces operate within the system, or external force do
work on the system, the mechanical energy changes as the configuration of system
changes

26. The figure shows system consisting of a block at rest on a long smooth horizontal
surface with a light relaxed spring attached to it. Free end of the spring is now pulled by
an external agent rightwards such that its velocity as a function of time is given as v  ct ,
here c is a constant. (m=mass of block, k=spring constant) Choose the correct
alternative (s)
2mc
A) maximum elongation in the spring is equal to
k
B) magnitude of maximum acceleration of the block is c
C) magnitude of velocity of the block is zero at the instant, spring is in maximum
elongation
D) magnitude of velocity of block relative to free end of the spring is zero at the instant
of maximum elongation in spring.
27. A rod is fixed between a vertical wall and a horizontal surface. A smooth ring of mas
1kg is released from rest which can move along the rod as shown. At the release point
spring is vertical and relaxed. The natural length of the spring is 3  1 m . Rod makes an
angle of 300 with the horizontal. Ring again comes to rest when spring makes an angle of
300 with the vertical, (g=10 m/s2)
5
A) Force constant of the spring is
2
 
3 1 N / m
2
B) Maximum displacement of ring is m
3 1
C) Maximum extension in the spring is  
3 1 m
D) Normal reaction on ring due to rod when it again comes to rest is  5 3  1 N

28. Potential energy of a particle of mass m  2 kg varies with its x co-ordinate as shown in
the figure below.
Which of the following statement (s) are correct?

A) If the particle is released at origin, it will move in negative x - direction
B) The maximum speed of the particle if it is released from a position just to the right of
x  2.0 m is 5 m / s
C) x  10, x  2 and x  10 (all in metres) are positions of unstable equilibrium
D) The minimum velocity that should be imparted to the particle in positive x- direction
at x  5 m , so that it may eventually cross to left of x  10m is 30 m / s
29. The spring block system is as shown in the figure. The block rests on a rough surface
with coefficient of friction  . The spring is ideal and has a spring constant k.
The spring is compressed by a length a and released. The block again comes to rest
when the spring is elongated by a length b. During this: Which of the following
statement (s) is / are correct?
1
A) Work done by the spring on the block  k  a  b 2
2
1
B) Work done by the spring on the block  k  a 2  b 2 
2
k a  b
C) Coefficient of friction 
2mg

k a  b
D) Coefficient of friction 
2mg
a b
30. The potential energy of a particle in a certain field has the form U   , where ‘a’ and
r2 r
‘b’ are positive constant, ‘r’ is the distance from center of the field. Then:
2a
A) At r  particle is in stable equilibrium
b
2a
B) At r  particle is in unstable equilibrium
b
b3
C) Maximum magnitude of force of attraction towards the centre of the field is
27a 2
27a 2
D) Maximum magnitude of force of attraction towards the centre of the field is
b3

31. A ring of mass m  0.2kg is attached to one end of a spring of force constant
k  100 N / m and natural length l  10 cm . The ring is constrained to move on a rough
vertical wire in shape of an ellipse of major axis 24 cm and minor axis 16 cm with its
centre at origin  O  . Initially the ring is at rest, top point A with other end of the spring
being fixed to the origin. Normal reaction of the wire on the ring is zero at A . Now, the
ring is given a horizontal velocity v  10 ms 1 towards right so that it just reaches point
B.

Calculate the modulus of work done (in Joules) by friction on the ring as it moves from
A to B. (Take g  10 m / s 2 )
32. A block of mass m=1.0kg placed on a horizontal floor is connected at one end of a long
spring of stiffness K=100N/m. coefficient of kinetic friction between the floor and the
block is k  0.47 . The free end of the spring is pulled gradually away from the block
until the block begins to slide. If the block stops after sliding a distance s = 0.6cm. Find
the coefficient of static friction between the block and the floor. (g = 10 m/s2)
33. The set up shown in vertical plane has ideal spring and ideal pulley. The spring (spring
constant k) is initially at its natural length. Block of mass 4m is resting on floor. Block
of mass ‘m’ is given a downward initially velocity v0 . The value of v0 required to lift
xm
block of mass 4m off the floor was found to be just more than g where x is a
k
natural number. Then x  ____
34. A block of mass 0.18 kg is attached to a spring of force constant 2 N/m. the coefficient
of friction between the block and the floor is 0.1. Initially the block is at rest and the
spring is unstretched. A sudden rightward velocity vo is given to the block by giving a
sudden Blow as shown in the figure. The block slides a distance of 0.06 m and comes to
rest for the first time. Find magnitude of vo in m/s

35. A particle is moved along a path AB  BC  CD  DE  EF  FA, as shown in figure, in

 
presence of a force F   yiˆ  2 xjˆ N , where x and y are in meter and

  1 N / m 1. The work done on the particle by this force F will be _____ Joule.
36. A light inextensible string that goes over a smooth fixed pulley as shown in the figure
connects two blocks of masses 0.36 kg and 0.72 kg. Taking g  10 m / s 2 , find the work
done (in joules) by the string on the block of mass 0.36 kg during the first second after
the system is released from rest.

CHEMISTRY MAX.MARKS: 66
37. Match the percentage of ionization given in column-II with the weak acid along with
condition given in column-I (Given log 5=0.7, 1.4  1.183 )
Column-I Column-II
A) At TK 0.1 M aqueous solution of weak acid p) 50
HA  K a  1103  is on dilution by 1000 times the
percentage of ionization of HA becomes

B) At TK 1 litre of aqueous solution of weak acid HA of q) 20
0.01 M is on mixing with 1 litre of 0.01 M of solution
of NaA the pH has become 3.3. The percentage of
ionization of HA before the addition of NaA is
C) At TK the pH of aqueous solution of weak acid HA r) 91.5
 Ka  110 3  is 3. The percentage of ionization of weak
acid HA in the solution is
A) A  r; B  q; C  p B) A  q; B  p; C  r
C) A  r; B  q; C  p D) A  q; B  p; C  r

38. We represent various reagents pictorially such that,
 0.1M Strong acid  0.1M Strong base
 0.1M Weak base  K b  10 5 

 0.1M Weak acid  K a  10 5 
The relative area of the squares represents the relative volume of the reagents used and
the overlapping region represents the relative amount of mixing of the reagents.
Consider the temperature to be 298 K. Which of the following does not leads to buffer
formation?
39. A small amount of solid lead iodide was added to a beaker of water, which was stirred.
Most of the solid settled on the bottom of the beaker, but a little dissolved, establishing
the equilibrium. The rates of the forward and reverse reactions were monitored over
time, producing the graph shown below:
 Pb 2   aq   2 I   aq 
PbI 2  s  

Which can be the reason for the change at time t?
A) The beaker was cooled in an ice-bath.
B) A small amount of solid Pb  NO3 2 was added to the beaker.
C) A small amount of solid KI was added to the beaker.

D) A small amount of water was added to the beaker.
40. Among the following buffer solutions, buffer capacity is highest for
K a of CH 3COOH is 1.8 10 5 
A) 0.02 M CH 3COOH  0.8M CH 3COONa B) 0.1M CH 3COOH  0.1M CH 3COONa

C) 0.3M CH 3COOH  0.7 M CH 3COONa D) 1M CH 3COOH  1M CH 3COONa
41. A divalent metal hydroxide M  OH 2 is partly soluble in water. When the solid is shaken
with water, most of it remains undissolved. However, the saturated solution obtained,
was found to be basic and had a pH  10 . In another experiment a soluble salt of M 2 was
taken in a test tube and NH 4OH was added to it. Precipitate of M  OH 2 was
instantaneously formed. Under the circumstances, the precipitate was shaken with
solid NH 4Cl . The precipitate dissolved. What should be the minimum concentration of
NH 4 Cl that must be present to prevent precipitation, when 0.01M NH 4OH is added to
0.01M M 2  solution? (near value)
 K of NH OH  1.8 10
b 4
5
, 50  7.07 
A) 0.025 M B) 0.01 M C) 0.25 M D) 0.005 M
42. Select the correct stoichiometry and its K sp value of salt, according to given graphs.
A) XY , K sp  2 10 6 B) XY2 , K sp  4 109 C) X 2Y , K sp  9 109 D) XY2 , K sp  1109


correct options.
option.
43. Select the correct statement(s) regarding phosphoric acid. Given that
 f H 0  H 3 PO4  aq  1290 kJ mol 1 ,  f H 0  H 2 PO4   1302 kJ mol 1 ,
aq
S 0  H 3 PO4  aq  176 J mol 1 K 1 , S 0  H 2 PO4   89 J mol 1 K 1 .Assume

aq
 f H 0  H    0 and S 0  H    0
aq aq
consider standard temperature as 298K.R=8.314 and ln x=2.303 log x.

A) pK a1 of  H 3 PO4 aq is 2.44 (nearly)
B) pK a 2 of phosphoric acid is less than pK a1 .

C) First dissociation of phosphoric acid is exothermic.
D) First dissociation of phosphoric acid is entropy driven.
44. Among the following which of the correct options
A) HCl is a potential electrolyte and a strong electrolyte.
B) On dilution, change in pH of weak acid is less than the change in pH of strong acid at
moderate concentration.
C) A weak polyprotic acid can form n number of buffers with maximum capacity, where
n is basicity of polyprotic acid.
D) If pH of a buffer is less than 7, then it must be an acidic buffer.

45. Which of the following are correct options among the following?
A) Neutralization of all bases need not to be have pH = 7 at equivalent point.
B) To prepare a buffer of pH = 5, the weak acid HA  Ka  5.8  is preferred then weak
acid HB  K a  4.8 
C) Heat of neutralization of weak acid and strong base and heat of ionization of weak
acid data can be used to calculate Ka of weak acid at given temperature and at given
concentration.
D) Magnitude of Heat of neutralization of 0.1M weak acid HA with 1M NaOH is less
than heat of neutralization of 0.01M weak acid HA with 1M NaOH.
46. A salt AB dissolves in H 2O and causes increase in temperature of solution and another
salt CD dissolves in H 2O and causes decrease in temperature of solution. At a particular
temperature T1 , K sp of AB = K sp of CD, then
A) At T2 , K sp of AB  K sp of CD if T2  T1
B) Lattice energy of AB  hydration energy of AB.

C) If hydration energy of AB and CD is same lattice energy of AB  lattice energy of CD
D) The dissolution of CD is entropy driven process.
47. Among the following, the correct statements are..
A) Ionic product can be defined for any amphiprotic solvent
B) Degree of hydrolysis of a salt of weak acid and weak base is independent of
concentration of the salt solution at appropriate concentration.
C) pH of 0.1M HCl and 0.2M CH 3COOH both are same if dilution tend to infinity.
D) H 3 BO3 is an Arrhenius acid
48. Which of the following are correct regarding the hydrolysis of salt of weak acid and
weak base …
A) To derive an expression for pH of a salt of weak acid and weak base, we must assume
that, degree of hydrolysis of anion and cations are same
B) If degree of hydrolysis is negligible or considerable, expression for pH of salt
remains same.

C) If pH of salt of a weak acid and a weak base is 7, then in solutions of 0.1 molar that
weak acid and 0.1M that weak base, degree of ionization is same.
D) pH of solution of a salt of weak acid and weak base is independent of concentration.

49. 
 Zn  OH 
Given: Zn  OH 2 s  
 ; K1  106
2  aq 
 Zn  OH    OH  aq

Zn  OH 2  aq  
 ; K 2  107
 aq   

Zn  OH  
 Zn 2  aq  OH  aq

 ; K 3  104
 aq     


  Zn  OH  
Zn  OH 2  aq   OH  aq  
 ; K 4  103
 3  aq 
 2
 Zn  OH 3  
  Zn  OH  
 OH  aq  
 ; K 5  10 13
 aq   4  aq 
Find out negative log of the solubility of solid zinc hydroxide at 250 C and pH = 6.
Consider zinc hydroxide makes saturated solution.
50 The solubility of a salt of weak acid (AB) at pH =3 is Y 10 3 mol L1 . The value of
Y is____
(Given that the value of solubility product of AB  K sp   2 1010 and the value of ionization
constant of HB  K a   110 8 )
51. The molar solubility of Cr  OH 3 in a solution where  H   is 100 times OH   is
x 10 y mole/lit is scientific notation at 250 C . Find the value of  y  x  if K sp of Cr  OH 3 is
6 10 32 (ionic product of water =10-14

52. A schematic graph of the first derivative of the pH curve is plotted for the titration of
10ml of unknown HCl solution by using 0.2M Ca  OH 2 , as shown
The concentration of HCl solution will be____M

53.
NH 4 HS  s  , NH 3  g  ,
H 2 S  g  , He  g  He  g 
at equilibrium
Fixed SPM, which allows only He (g) to cross it.

The entire system is at equilibrium at 300 K. The volume of each chamber is 82.1 L. The
total pressure in left chamber is 4 atm and in right chamber, 2 atm. NH 3  g  and
H 2 S  g  are obtained only from the dissociation of NH 4 HS  s  . The value of K p (in atm 2 )
 NH 3  g   H 2 S  g  is
for the reaction NH 4 HS  s  
54.  HB  aq   A  aq  has K eq  10 x , how many of

If an acid-base reaction HA  aq   B   aq  
the following statements are true?(x is a positive integer)
(i) HB is stronger acid than HA
(ii) HA is stronger acid than HB
(iii) HA and HB have the same acidic strength
(iv) B  is stronger base than A
(v) A is stronger base than B 
(vi) B  and HB are conjugate acid-base pair
(vii) A is the conjugate base of acid HA.
(viii) HA can be HSO4 and HB can be HCOOH
(ix) A can be F  and B  can be CN 

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Sec: JR.

*CO SC(MODE-A) Date: 23-07-2023

23-07-23_JR.IIT_STAR CO-SC(MODEL-A)_JEE ADV_2020(P-I)_WAT-12_QP _FINAL

Please mark/bubble/bolden your answer against the corresponding question

JR .IIT_*CO-SC Page. No. 2

1. For n  Z, the general solution of the trigonometric equation

sin x  3 cos x  4sin 2x  4 3 cos 2x  sin 3x  3 cos3x  0 is

JR .IIT_*CO-SC Page. No. 3

SECTION - 2 (Maximum Marks : 24)

B) If x   0,2  : f  x   0   , , then     2

JR .IIT_*CO-SC Page. No. 4

2 cos A  cos B  cos3 B

JR .IIT_*CO-SC Page. No. 5

8sin 2 x cos x  3sin x  cos x

JR .IIT_*CO-SC Page. No. 6

JR .IIT_*CO-SC Page. No. 7

A) 4.50 J B) 7.50 J C) 5.06 J D) 14.06 J

JR .IIT_*CO-SC Page. No. 8

JR .IIT_*CO-SC Page. No. 9

D) Normal reaction on ring due to rod when it again comes to rest is  5 3  1 N

JR .IIT_*CO-SC Page. No. 10

Which of the following statement (s) are correct?

JR .IIT_*CO-SC Page. No. 11

SECTION - 3 (Maximum Marks : 24)

JR .IIT_*CO-SC Page. No. 12

JR .IIT_*CO-SC Page. No. 13

JR .IIT_*CO-SC Page. No. 14

percentage of ionization of HA becomes

acid HA in the solution is

JR .IIT_*CO-SC Page. No. 15

 0.1M Strong acid  0.1M Strong base

 0.1M Weak base  K b  10 5 

JR .IIT_*CO-SC Page. No. 16

C) A small amount of solid KI was added to the beaker.

A) 0.02 M CH 3COOH  0.8M CH 3COONa B) 0.1M CH 3COOH  0.1M CH 3COONa

0.01M M 2  solution? (near value)

A) XY , K sp  2 10 6 B) XY2 , K sp  4 109 C) X 2Y , K sp  9 109 D) XY2 , K sp  1109

JR .IIT_*CO-SC Page. No. 17

SECTION - 2 (Maximum Marks : 24)

S 0  H 3 PO4  aq  176 J mol 1 K 1 , S 0  H 2 PO4   89 J mol 1 K 1 .Assume

consider standard temperature as 298K.R=8.314 and ln x=2.303 log x.

B) pK a 2 of phosphoric acid is less than pK a1 .

JR .IIT_*CO-SC Page. No. 18

B) Lattice energy of AB  hydration energy of AB.

JR .IIT_*CO-SC Page. No. 19

SECTION - 3 (Maximum Marks : 24)

51. The molar solubility of Cr  OH 3 in a solution where  H   is 100 times OH   is

x 10 y mole/lit is scientific notation at 250 C . Find the value of  y  x  if K sp of Cr  OH 3 is

6 10 32 (ionic product of water =10-14

JR .IIT_*CO-SC Page. No. 20

The concentration of HCl solution will be____M

Fixed SPM, which allows only He (g) to cross it.

54.  HB  aq   A  aq  has K eq  10 x , how many of

JR .IIT_*CO-SC Page. No. 21

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