POLYVEST - 2017 - Overview

POLYVEST® - 2017
Liquid polybutadienes
1
POLYVEST®
Product Portfolio
Liquid polybutadienes are highly suitable for a broad field of
applications.
The functional POLYVEST® grades and their tailor-made
post-modified grades offer new opportunities for the
application of polybutadienes.
Synthesis via POLYVEST® 110/130 POLYVEST® HT

polymerization Non-functionalized Hydroxyl-terminated
of butadiene
Synthesis via
POLYVEST® MA 75 Epoxy- Silane- Further end-
post-modification
Maleinized grade terminated terminated group mod.*
of polybutadienes
*Experimental products
2 | POLYVEST 2017 | Liquid polybutadienes
Benefits of
POLYVEST®
Production Processing Logistics (UTM) Application Technology
• Multi kt production sites in • Unique polymers due to • Highly efficient logistics hub • Two Application Technology
central location of Europ tailormade catalyst systems next to POLYVEST® groups & Butadiene
• Integrated in & processing parameters production plants Competence Center for
Verbundstandort Marl with • Well defined microstructure • Short lead times within research in Marl
backward integrated raw • Competencies to make Europe (warehousing • Intensive formulation support
material supply (butadiene, polymer post-modification concepts outside Europe) • On site support at customers
catalysts, peroxides) (derivatives) • Various types of packaging

POLYVEST®
Synthesis and product features of liquid polybutadienes
Ene-Reaction
POLYVEST® 110 & 130 with low vinyl-content exhibit:

Low viscosity
Unpolar und hydrophobic polymer backbone
Efficient curing with atmospheric oxygen and vulcanization
POLYVEST ® MA 75 & 120 with anhydride functionalities:

Promote adhesion on polar substrates
Label-free hardener compound for two-part formulations
POLYVEST ® HT with hydroxyl functionalities:

Promotes adhesion on polar substrates
Polyol with hydrophobic backbone

POLYVEST®
Markets and Applications
POLYVEST® grades are used in adhesives and sealants for…
POLYVEST® POLYVEST® POLYVEST®
HT
110 & 130 MA HT
Automotive Applications (e.g. sealants and adhesives, sound
dampener, anti-flutter, seam sealer)
Coatings (e.g. Air Drying Improver of vegetable oils, Defoamers,
Impregnations, Modifier in resin systems)
Construction (e.g. Binder for dusty and dry Quartz Sand, Binder for
soil stabilization, Modifier of Silicone Sealants, Insulated Glass
Sealants)
Electronics (e.g. Electronical insulations and potting compounds)
Plastics (e.g. Cell opener for PU-Foam, Release Agents for PUR-Foam)
Polymer Modification (e.g. Chlorinated Rubbers, Electrocoatings)
Printing & Inks (e.g. Offset Printing Inks, Polymer Printing Plates)
Rubber (e.g. Binder for recycled Rubber Compounds, Modifier in
Carbon-Black filled EPDM Compounds, Reactive Plasticizer in Rubber
and Tire Compounds
POLYVEST® –
Extended Versatility of Curing and Chemical modifications
I) Curing or modification via II) Curing or modification via
unsaturated polymer backbone terminal functionalities
• Vulcanization with sulphur • Curing with hardener

compounds (e.g. isocyanates
and anhydrides (for R= OH);
amines (R: epoxy)
• Curing with peroxides • Moisture-initiated curing

(for R: -Si(OAlkyl)3; R: NCO-
terminated
POLYVEST®
• Curing with atmospheric Non-functionalized: • Precise end-group
oxygen R=H modification
Functionalized:
R (terminal) = hydroxyl, silane, epoxy
R (backbone) = anhydride
POLYVEST®
POLYVEST® HT - Functional liquid polybutadiene with terminal
hydroxyl functionalities
vinyl: 22% trans: 57% cis: 21%
Typical properties: Product features:

Viscosity 4-5.5 Pas (@30°C) Low temperature flexibility
~ 48 mg KOH/g Excellent hydrophobicity

OH value
~ 0.85 meq/g Very good hydrolytic stability
Mean molecular 2900 g/mol (Mn) Excellent chemical resistance to acids
weight 6200 g/mol (Mw) and alkali
OH functionality 2.3 - 2.6 Good adhesion on metal substrates
Tg - 80°C Tolerates high filler loads
POLYVEST® HT
Features & Benefits
Production with high reproducibility and constant product quality
• Constant OH value, OH functionality and microstucture
• Low viscosity
• Constant reactivity
High technical standards for purification of POLYVEST HT
• Low odor by highly efficient removal of by-products
• Low concentration of residual water
• High transparency and low color

POLYVEST® HT –
Versatile Building Block for Various Applications
Automotive:
(e.g. PUR sealants,
rubber-based sealants,
additive for epoxy-based adhesives)
Construction:
(e.g. PUR sealants for insulation
window glazing, waterproofing
coatings, sealants for crack filling,
expansion joints, water-borne
dispersions)
Electrical insulation:
(PUR sealants for underground
couples, encapsulation of circuit
POLYVEST® HT boards)

POLYVEST®
POLYVEST® HT
Two-part polyurethanes One-part polyurethanes Isocyanate-free two-part Waterborne polyurethane

(2C PUR) (1C PUR) sealants dispersions (PUD)
POLYVEST Isocyanate/ POLYVEST HT-based POLYVEST POLYVEST POLYVEST HT-based

HT Prepolymers prepolymers HT MA 75 aqueous dispersions
• Fast curing at ambient • Moisture-initiated curing • Isocyanate- and label-free • Low viscous water-borne
conditions with aliphatic via pre-conversion of system in combination polyurethane dispersions
or armomatic isocyanates POLYVEST HT with with maleic-modified for coating applications
isocyanates POLYVEST MA75

POLYVEST®
POLYVEST® HT -
An excellent polyol resin for tailor-made two-part polyurethane sealants
Formulation flexibility facilitates Excellent properties for Applications:
tailormade mechanical properties: electrical insulation
Hardness: < 0.5 wt% water uptake
after 4h High hydrophobicity
80
after 24h
(after water storage at 120°C)
60
Shore A
82
Excellent electrical Volume resistivity
40
62 55 54 52
insulation properties Up to 1015 Ω cm
20 31 34
17
0 Low water vapour
2-3 g/m²/d
6
Tensile strength: transmission rate
4
MPa
6,2
2 3,5 4,0
2,3
0 Polyether-based two part PUR
Elongation at break: 30
WVTP [g/(m²/d]
200 POLYVEST HT-based PURs

150 20 POLYVEST HT & MA75
100
%
168 177 159

50
10
64
0
0
Chalk Quartz China Wollastonite
Clay
POLYVEST HT offers a broad formulation flexibility and exhibits sealants with tailormade mechanical properties and excellent
electrical insulation properties.
POLYVEST® HT
for 2C PUR adhesive on polymer substrates
Starting formulation:
A-Component
Properties
POLYVEST HT (Main binder) 30
ShoreA after 3 d 67
Sovermol 860 (Co-Binder) 6
Tensile Strength after 3 d [MPa] 2.3
Irgafos 168 (Antioxidant) 0,2
Elongation at Break after 3 d [%] 323
Vestinol DINP (Plasticizer) 7
Tensile Shear Strength [MPa] after 3 d
Aerosil 202 (Filler) 0,7
on PMMA 1.7
Winnofill SPM (Filler) 44,5
on Polycarbonate 1.6
Omyacarb 2AL (Filler) 10
on PET 1.7
Tego Dispers 650 (Dispersing agent) 0,5
on PVC 1.5
Tego Airex 900 (Defoamer) 0,1
on PA6 1.6
Borchi Kat 315 (10 % in PV HT) 1
B-Component Flexible PUR based sealant with excellent
Suprasec 2020 (Hadener) 100 adhesion on various polymer substrate
Ratio A:B (wt:wt) 13:1
Seite 4
POLYVEST®
POLYVEST® HT



POLYVEST® HT based NCO-terminated prepolymers:
Features and applications
Modification of POLYVEST HT with isocyanates via conversion with diisocyanates (e.g. IPDI, MDI,TDI):
Stochiometric excess of isocycanate is needed for the fabrication of prepolymers with moderate viscosity
Excess of isocyanate
Product features: Potential Applications:
NCO-modified liquid polybutadiene Hardener compound for two-component PURs sealants
Polymeric isocyantes with reduced Two-component polyurea coatings and sealants (via conversion of
amount of free NCO prepolymer with amine)
Good compatibilty with hydrophobic polyols One-component PUR and bituminous PUR
Low glass transition temperature (~ -80°C) Flexible and elastomeric PURs and polyureas
Versatile toolbox for fabrication of NCO- PUR sealants for electrical insulation and waterproofing
prepolymers with varying NCO-content applications

Page | 14
POLYVEST® HT based NCO-terminated prepolymers:
Properties
Library of POLYVEST HT-based Prepolymers: POLYVEST HT vs.

250
80
prepolymers reference HTPB
70
Viscosity (20°C) / Pas
200 MDI prepolymers

IPDI prepolymers 60
Viscosity (20°C) / Pas

Polyvest HT based
150 TDI prepolymers 50
reference HTPB
40
100
30
50 20
10
0 0
0 5 10 15 MDI-Prepolymer IPDI-Prepolmer TDI-Prepolymer
NCO-content / wt%
- POLYVEST HT-based prepolymers show beneficial lower viscosity compared to other HTPB grades

POLYVEST® HT
for PUR-based Waterproofing
Benefits of two-pack PUR based on POLYVEST® HT:

• Very hydrophob PUR with low water & moisture uptake and low water vapor
permeability
• POLYVEST HT is highly compatible with bitumen and mineral oil for cost
efficient systems and higher elongations
• Good resistance to acids and bases
• Liquid-appliable, self-leveling
Applications:
Waterproofing coatings
Sealing for water reservoirs
Crack Fillers
Joint Fillers / Expansion Joints
Repair systems for roofing, road surface and building facade or sealant damages
Guided formulations for one- & two-part bitumen-based systems are available
POLYVEST® HT– Bitumen modified
two part PUR formulations
Two-part PUR Application form: Two-part liquid form, self-leveling
Curing temperature: Ambient conditions

Broad formulation flexibility:
A-Component Properties: Thermoset (not thermoplastic

POLYVEST HT (reactive binder) anymore) with highly
flexible and hydrophobic properties
Bitumen/Asphalt
Filler (e.g. calcium carbonate)
Mineral oil / Plasticizers

B-Component
Isocyanate-based hardener
POLYVEST HT is an efficient reactive resin for self-leveling bitumen-modified PURs for waterproofing and
17
flexible sealants.
| POLYVEST 2017 | Liquid polybutadienes
Guided formulations:
Bitumen modified two-part PUR - Formulations
Liquid-applicable bitumen-based formulations:
A-Component A1 A2 A3 A4
Bitumen Nybit E190 (160/220) 33 28 28 28
Mineral Oil 0 10 5 10
POLYVEST HT (main binder) 34 29 24 29
2-Ethylhexandiol (co-binder) 0 0 10 1
Omyacarb 2AL (calcium carbonate) 32.95 32.95 32.95 32
Tego Kat 218 (1% in POLYVEST HT) 0.05 0.05 0.05 0
100 100 100 100
B-Component B1 B1 B1 B1
Suprasec 2020 100 100 100 100
Mixing ratio A:B (wt/wt) 20:1 16:1 3.5:1 16:1

Bitumen modified two-part PUR - Properties
Viscosity of A-component/ Pas A1 A2 A3 A4

D= 5 [1/s] 166 31 31 31
D= 50 [1/s] 54 22 22 18
D= 100 [1/s] 45 18 18 16
Properties A1:B1 A2:B1 A3:B1 A4:B1

Shore A after 24h 49 30 66 <10
Shore A after 1 w 50 52 73 33
Tensile strength after 1w / Mpa 1.5 1.6 4.2 0.9
Elongation at break after 1w / % 643 310 87 775
The combination of POLYVEST HT with bitumen, mineral oil and filler

provides highly flexible elastomeric sealants
The mechanical properties could be easily modified and tailored to specific
technical requirements.
Bitumen modified two-part PUR -Formulation
A-Component A1 A2
Bitumen Nybit E190 33
Bitumen 70/110 33
Infrasolv LC 5 15
Polyvest HT 29 19
2-Ethylhexandiol 1 1
Omyacarb 2 AL 32 32
B-Component B1 B1
Suprasec 2020 100 100
A:B 16:1 20:1

OH:NCO-Verh. 1: 1,2 1: 1,17

Bitumen modified two-part PUR -Properties
A1:B1 A2:B1
Potlife in min 16 20
shore A after 24h 37 17
shore A after 96h 40 22
shore A after 7d 41 22
Tensile strength after 7d 0.7 0.7
Elongation at break after 7d 1690 554

Bitumen modified two-part PUR –Storage stability
2.05
Tensile strength / MPa:
1.3
1.09
0.9 0.81 0.87 0.85
0.67 0.73 0.75 0.67
0.31
after 7 d after 8 weeks at 60°C after 8 weeks in water at after 8 weeks in 0,5N after 8 weeks in 0,5N after 500 h UV-B
60°C NaOH at 40°C HCl at 40°C irradiation
Elongation at break/ %: A1B1 A2B1
2055 1892 1884

1690
1352 1362 1266
554 566 520 667 589
after 7 d after 8 weeks at 60°C after 8 weeks in water at after 8 weeks in 0,5N after 8 weeks in 0,5N after 500 h UV-B
60°C NaOH at 40°C HCl at 40°C irradiation

A1B1 A2B1
22
Bitumen modified two-part PUR – Water uptake
Water uptake (wt%) after water immersion test:

a) at 40°C b) at 60°C
0.3 0.7
0.25 0.6
0.5
0.2
0.4
0.15
0.3
0.1
0.2
0.05 0.1
0 0
n. 1 Wo n. 2 Wo n. 3 Wo n. 4 Wo n. 5 Wo n. 6 Wo n. 7 Wo n. 8 Wo n. 1 Wo n. 2 Wo n. 3 Wo n. 4 Wo n. 5 Wo n. 6 Wo n. 7 Wo n. 8 Wo
A1B1 A2B2 A1B1 A2B2

23
POLYVEST® HT– Bitumen modified
one-part PUR formulations
One-part PUR: One component, liquid form,

Application form:
self-leveling
Curing temperature: Ambient conditions,

moisture-initiated curing
Broad formulation flexibility:
Properties: Thermoset (not thermoplastic
anymore) with highly
One Component
flexible and hydrophobic properties
POLYVEST HT-based prepolymer (reactive binder)
Bitumen/Asphalt
Fillers (e.g. calcium carbonate)
Mineral oil / Plasticizer

Bitumen modified one-part PUR - Formulations
Liquid-applicable bitumen-based formulations:
A-Component A5 A6 A7 A8 A10
Bitumen Nybit E190 (160/220) 40 40 40 40 0
Bitumen (70/100) 0 0 0 0 40
Mineral Oil 10 15 20 15 10
Prepolymer (PVHT-MDI;
50 45 40 20 50
NCO: OH = 3.5/1; NCO content = 6.5 wt%)
Winnofill SPM (filler) 0 0 0 25 0
100 100 100 100 100

Bitumen modified one-part PUR - Properties
Viscosity of A-component/ Pas A5 A6 A7 A8 A10

D= 5 [1/s] 165 150 66 31 151
D= 50.. 111 96 54 22 103
D= 100.. 89 76 45 18 88
Properties after curing at rt A5 A6 A7 A8 A10

Shore A after 7d 37 34 33 42 41
Tensile strength after 7d / MPa 2.9 2.3 1.9 0.8 3.3
Elongation at break after 7d / % 155 126 154 51 342
POLYVEST HT-based prepolymers in combination with bitumen, mineral oil and

inorganic filllers result in highly flexible moisture-curing elastomeric sealants

POLYVEST®
POLYVEST® HT



POLYVEST® MA 75 & POLYVEST® HT
Two-part label-free formulations
LA_33_15 A6 A7 A8 LA_33_15 A/B A A A
POLYVEST HT 44.3 30 83.2 6/B 7/B 8/B
Wingstay L 0.5 0.5 1
1 1 1
Irganox 1520 L 1 1 1 Pot life [min] 15 7 9
Tego Dispers 650 0.5 - -
Shore hardness A
Mikrosöhl 52.9 - -
After 1 day 12 25 11
Dorkafill 600 - 47.3 -
After 3 days 14 26 12
Tremin 939-100 - 10 -
After 7 days 16 27 13
Aerosil 200 - - 10
DYNASYLAN AMEO - 1 1
Tensile strength [MPa]
POLYVEST HT - 9 -
Tego Dispers 650 - 0.5 0.5 After 3 days 0.49 0.81 0.56
Tetramethylethylen-diamine 0.7 0.6 1
After 7 days 0.55 1.05 0.59
Tego Airex 900 0.1 0.1 0.1 Elongation at break [%]
100 100 100
After 3 days 431 185 333
LA_33_15 B1 B1 B1
POLYVEST MA 75 100 100 100 After 7 days 423 175 318
28Mixing rate A:B 2:1 2:1 1:1

POLYVEST®
POLYVEST® HT



POLYVEST® HT
in water-borne polyurethane dispersions (PUD)
Prepolymer A B Reference
POYVEST HT / POLYVEST HT / Oxoester T
VESTANAT IPDI VESTANAT H12MDI 1136/VESTANAT IPDI
Mol wt% Mol wt% Mol wt%
15.6 mol 15.6 mol
Diisocyanate 23.73% 27.19% 15.6 IPDI 40.16
IPDI H12MDI
POLYVEST HT 2.13 mol 39.90% 2.00 mol 36.47% - -
OE T1136 - - - - 2.5 mol 29.81
1,4-Butanediol 2.50 mol 1.54% 2.50 mol 1.50% 2.5 mol 2.61
DMPS 5.25 mol 4.80% 5.40 mol 4.80% 3.75 mol 5.82
TMP - - - - 1.0 mol 1.55
DBTL 0.05% 0.05% 0.05%
Proglyde DMM 30.0% 30.0%
Aceton 20.0%
NCO/OH ratio 1.52 / 1.0 1.52 / 1.0 1.52/1.0
NCO content/ wt% 3.1 3.2 5.2

POLYVEST® HT
in Polyurethane Dispersions (PUD)
Polyurethane Dispersion
POYVEST HT / POLYVEST HT / OE T1146/ VESTANAT
Prepolymer
VESTANAT IPDI (A) VESTANAT H12MDI (B) IPDI (Ref)
Prepolymer in water
Method Prepolymer in water Prepolymer in water
with Triethylamine with Triethylamine
Neutralization Triethylamine (TEA)
(TEA) (TEA)
Chain extender Ethylenediamine (EDA) Ethylenediamine (EDA) Ethylenediamine (EDA)
Solid / wt% 33.0 33.0 32.7
pH value 7.6 7.6 7.8
Viscosity/ mPas
204 3950 36
(23°C)

POLYVEST® HT
Film tests
POYVEST HT / VESTANAT IPDI POLYVEST HT / VESTANAT OE T1146/ VESTANAT IPDI (Ref)
(A) H12MDI (B)
Curing conditions [°C] RT 30min.80°C RT 30min.80°C RT 30min.80°C
Dry film thickness [µm] 38-40 37-41 37-46 41-46 29-35 26-29
Hardness Buchholz 59 56 50 63 100 100
Pendulum hardness 1d 66 70 73 73 50 158
Pendulum hardness 7d 66 67 77 74 144 158
Tropic resitance after 14d
after 14d: 40°C, 100%

14d ok 14d ok 14d ok 14d ok 1dE 1dE
moisture

POLYVEST® HT
Film tests
POYVEST HT / VESTANAT POLYVEST HT / VESTANAT OE T1146/ VESTANAT IPDI
IPDI (A) H12MDI (B) (Ref)
Substrat glass glass glass
Curing conditions 1d RT, 30min. 80°C, 6d RT 1d RT, 30min. 80°C, 6d RT 1d RT, 30min. 80°C, 6d RT
Film forming agent 0,05% Byk 346 0,05% Byk 346 Byk 348 0,05%, 5,0% Bdg.
Dry film thickness [µm] 120 117 156
Tensile strength [MPA] 26,0 25,1 17,6
Elongation [%] 324 243 193
Tension at 100 % Elongation MPa 15,86 19,39 13,7
Tension at 200 % Elongation MPa 20,08 23,22 -
Hydrolysis 70°C, 90%LF 2Wo 70°C / 90% LF 2Wo 70°C / 90% LF

Dry film thickness [µm] 154 138 -
Tensile strength [MPA] 27,5 25,0 -
Elongation [%] 346 160 -
Tension at 200 % Elongation MPa 20,46 - -
Tension at 300 % Elongation MPa 25,18 - -
POLYVEST® HT for
Automotive Applications
Potential Applications:
• Adhesives & Sealants (PUR- & rubber-based)
• Sound dampener
• Structural adhesives (Toughening agent in Epoxy Resins)
Key Features and Benefits:

• Compatible with fillers, tackifiers and multi-functional additives
• Excellent oil absorption properties
• Efficient curing via sulphur vulcanization
• Extraordinary low temperature properties, and tolerance of
thermal cycling to < -40 °C
• Formulating flexibility
• Low water uptake and excellent hydrolytic stability

POLYVEST® HT
Guided formulations for low viscous body shop adhesives (I)
One-part rubber-based formulation
POLYVEST® 110 20,5
POLYVEST® HT 4 Liquid Rubber
Polyisoprene LiR 50 9
Ionol LC 1 Antioxidant
Irgafos 168 0.2 Antioxidant
Lamp Black 101 1 Carbon Black
Sulphur 4.1
Vulcanization
ZnO 3.2
agents
Stearic acid 0.3
CaO 1.5 Filler
Alpha Talc CT+P 6 Filler
Omyacarb 2 AL 45.6 Filler
Vulkacit DM/C 3.5
Vulcanization accelerator
Vulkacit ZBEC 0.1
100

POLYVEST® HT
Guided formulations for low viscous body shop adhesives (I)
Properties
No adhesion failure
Viscosity at 23 °C, [Pa s] 233
After curing 30 minutes 170°C
Shore hardness A 50
Tensile strength [MPa] 1.66
Elongation [%] 155
Lap shear strength
On steel [MPa] 1.65
On galv. steel [MPa] 1.43
On aluminum[MPa] 1.40
POLYVEST HT acts as reactive plasticizer and increases adhesion on oily and

polar substrates.

POLYVEST® HT
High viscous, Expandable Body Shop Adhesive (I)
One-part rubber-based formulation

POLYVEST® 110 12 Liquid rubber
POLYVEST® HT 7 Liquid rubber
BUNA CB 24 6 Solid rubber
IONOL LC 1 Antioxidant
Irgafos 168 0.2 Antioxidant
ZnO 3.5 Vulcanization
Stearic Acid 0.4 agents
CaO 3 Filler
Lamp Black 101 0.5 Carbon Black
Alpha Talk CT + P 6 Filler
Omyacarb 2 AL 46.6 Filler
Sulphur 2.5 Vulcanization agent
POLYVEST 110 7.5 Liqud rubber
Expancel 009 DU 80 0.8 Blowing agent
Vulkacit DM/C 3.0 Accelerator
100
POLYVEST® HT
High viscous, Expandable Body Shop Adhesive
Properties
Viscosity at 23 °C [Pa s] 6970
Properties
after curing 30 min. 180 °C
Shore hardness A 30
Tensile strength [MPa] 0.68
Elongation [%] 73
Volume expansion [%] 90
Tensile shear strength
On steel [MPa] 0.58
On galvanized steel [MPa] 0.54
On aluminium [MPa] 0.54
POLYVEST® HT acts as reactive plasticizer

(no migration after cross-linking)
POLYVEST® HT increases adhesion on substrates.

POLYVEST®
POLYVEST® ST
Silane-terminated liquid polybutadienes
Features of Silane-Modification:
POLYVEST® EP ST-M (R‘‘ = Methyl)
POLYVEST ® EP ST-E (R‘‘ = Ethyl)
*Experimental product
Silane functionality
Grades Silane Type
(Silane/chain)
POLYVEST® EP ST-E 100 Triethoxy (R‘‘= Ethyl) Approx. 2.5
POLYVEST® EP ST-E 80 Triethoxy (R‘‘= Ethyl) Approx. 2.0 Modification Adhesion on polar Moisture
of inorganic Substrates Curing
POLYVEST® EP ST-E 60 Triethoxy (R‘‘= Ethyl) Approx. 1.5
fillers
POLYVEST® EP ST-M Trimethoxy (R‘‘= Methyl) Approx 2.5

POLYVEST®
POLYVEST® ST
improves adhesion on polar substrates in one-part rubber-based formulations
Test formulations 1 2 3 4 5 6 Mechanical properties after curing at 170 °C for 30 min

wt % With PVHT With PVST
POLYVEST 110 30 30 22 22 22 22 a) Hardness b) Tensile strength

80 2,0
POLYVEST HT 10 - 10 - 10 - 60 64 1,7
60 51 1,5
Shore A
POLYVEST EP ST - 10 - 10 - 10 40 1,1
1,0
MPa
40 30 1,0
0,6
Silica 1.5 1.5 - - - - 20
0,5
0,5
5 0,2
0
China Clay - - 25 25 - - 0,0
Silica China Clay Wollastonite
Silica China Clay Wollastonite
Wollastonite - - - - 25 25
c) Shear strength on aluminum d) Shear strength on steel
Others 58.5 58.5 43 43 43 43 2,0
2,0
1,5 1,4
∑ 100 100 100 100 100 100 1,1 1,1 1,5 1,3
MPa
MPa
1,0 0,8 0,8 1,0 0,9 0,9
0,5 0,3 0,5 0,4

Sulphur curing 30 min at 170 °C 0,1 0,1
0,0 0,0
Silica China Clay Wollastonite Silica China Clay Wollastonite
POLYVEST EP ST optimizes dispersability of various inorganic fillers and therefore improves mechanical
properties of rubber compounds.
POLYVEST® EP ET
Properties & Features
vinyl (x): 22% trans (y): 57% cis (z) : 21%

POLYVEST® EP* ET
Typical properties: Product features:

Viscosity at 20 °C ~ 10 Pa s Low temperature flexibility
Epoxy equivalent ~ 1400 g/eq. Terminal epoxy-functionalities

Mean molecular ~ 3200 g/mol (Mn)
Conversion with amines and carbon acids
weight ~ 8300 g/mol (Mw)
Functionality ~ 2.3 Low viscosity
Tg - 80°C Good compatibility in rubbers

Epoxy-modified polybutadienes in 2C Epoxy-resins
Formulation
POLYVEST® EP ET has been tested as toughening agents in two-component epoxy formulations.
Reference Formulation
parts wt%
Component A
Epikote 828 (bisphenol A epoxy resin) 279 69.8
DER 734 (1,6-hexanediol diglycidylether) 31 7.7
Toughening agent
Component B
Jeffamin D230 (polyetheramine) 63 15.8
Vestamin IPD (Isophorondiamine) 27 6.8
Curing parameters: 24h @ rt and 5h @ 71°C

Performance
Reference POLYVEST EP ET
Rubber content 0 wt% 2.4 wt% 9.1 wt%
Tensile strength / MPa 69 60 48
Elongation at break / % 6 6 8
Tensile modulus / MPa 3254 3007 2604
Flexural strength / MPa 115 107 88
K1C / MN/m3/2 0.73 1.45 2.7
G1C / J/m2 170 420 1600
Youngs modulus / MPa 2800 2800 2300
The application of POLYVEST® EP ET in 2C epoxy formulations results in improved toughening

properties (K1C is significantly improved).
Formulation
Reference A9 A8 A10
Epikote 828 (epoxy resin) 66,8 62,1 58,4 48,4
POLYVEST® EP ET (toughener) 0 2,5 2,8 3,5
Dyhard 100S (hardener) 4,0 4,3 4,7 5,8
Dyhard UR 500 0,2 0,2 0,2 0,2
Omyacarb 5GU (filler) 26,7 28,4 31,2 38,7
Aerosil 202 (silica) 2,3 2,5 2,7 3,4

Properties (I)
A11 A9 A8 A10
Curing for 30 min at 170 °C
Elongation at break [%] 9,2 7,2 7,9 5,8
Tensile strength [MPa] 51 31 35 24
Curing for 30 min at 200 °C
Elongation at break [%] 7,3 10,3 9,0 7,2
Tensile strength [MPa] 39 56 49 37

Properties (II)
Lab shear strengths Reference A9 A8 A10
after 30át 170°C on Aluminium [MPa] 6,1 7,0 7,8 5,5
after 30át 200°C on Aluminium [MPa] 5,9 8,1 7,1 5,1
after 30´ at 170°C on Steel [MPa] 6,7 5,8 7,8 7,9
after 30át 200°C on Steel [MPa] 6,1 7,4 6,9 5,7
after 30át 200°C galv. Steel [MPa] 6,4 6,5 6,9 4,9
after 30át 200°C galv. Steel [N/mm²] 5,4 7,1 3,1 5,0

Properties (III)
Impact resistance
A11 A9 A8 A10
Charpy-toughening DIN EN ISO 179-1/1 eU
after 30´ 170°C Ø [KJ/m²] 23 17 23 15
after 30´ 200°C Ø [KJ/m²] 23 24 23 11
Due to limited compatibility with epoxy resins POLYVEST® EP ET is recommended to be used in low
concentrations (< 2.5 wt%) as flexibilizing agent in 1C epoxy formulations .

Epoxy-modified polybutadienes in rubber-epoxy hybrid formulations
Formulation
LA-TS2_45_15_ Reference 1 Reference 2 47
POLYVEST® 110 22
POLYVEST® HT 22
POLYVEST® EP ET 22
Epikote 828 (epoxy resin) 10 10 10
Polyisoprene LiR 50 2 2 2
Irgafos 168 0,2 0,2 0,2
Lamp Black 101 1,0 1,0 1,0
Sulphur 4,1 4,1 4,1
ZnO 3,2 3,2 3,2
Stearic acid 0,3 0,3 0,3
CaO 1,5 1,5 1,5
Alpha Talc CT+P 6,0 6,0 6,0
Omyacarb 2 AL 45,0 45 45
Vulkacit DM/C 3,5 3,5 3,5
Dyhard 100S 1,0 1,0 1,0
Dyhard UR 500 0,2 0,2 0,2
100 100 100
Epoxy-modified polybutadienes in rubber-epoxy hybrid formulations
Properties
LA-TS2_45_15_ Reference 1 Reference 2 47

POLYVEST® 110 22
POLYVEST® HT 22
POLYVEST® EP ET 22
Epikote 828 10 10 10
Mechanical properties after curing for 30 min at 170°C
8 steel
6 galv. Steel
6
4
4
6,5
2 4,5
2 3,4
1,5 2,5 1,8 1,9
0 0 0,4 0,5
without funct. with HTPB with ETPB
without funct. with HTPB with ETPB
Polybutadiene
Polybutadiene
POLYVEST® EP ET as dual-curing agent (epoxy + sulphur) increases

49
mechanical properties of rubber compounds
50

POLYVEST - 2017 - Overview

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POLYVEST® - 2017

Synthesis via POLYVEST® 110/130 POLYVEST® HT

Production Processing Logistics (UTM) Application Technology

3 | POLYVEST 2017 | Liquid polybutadienes

POLYVEST® 110 & 130 with low vinyl-content exhibit:

POLYVEST ® MA 75 & 120 with anhydride functionalities:

POLYVEST ® HT with hydroxyl functionalities:

4 | POLYVEST 2017 | Liquid polybutadienes

Electronics (e.g. Electronical insulations and potting compounds)

Polymer Modification (e.g. Chlorinated Rubbers, Electrocoatings)

• Vulcanization with sulphur • Curing with hardener

• Curing with peroxides • Moisture-initiated curing

vinyl: 22% trans: 57% cis: 21%

Typical properties: Product features:

~ 48 mg KOH/g Excellent hydrophobicity

8 | POLYVEST 2017 | Liquid polybutadienes

9 | POLYVEST 2017 | Liquid polybutadienes

Two-part polyurethanes One-part polyurethanes Isocyanate-free two-part Waterborne polyurethane

POLYVEST Isocyanate/ POLYVEST HT-based POLYVEST POLYVEST POLYVEST HT-based

10 | POLYVEST 2017 | Liquid polybutadienes

200 POLYVEST HT-based PURs

168 177 159

Two-part polyurethanes One-part polyurethanes Isocyanate-free two-part Waterborne polyurethane

POLYVEST Isocyanate/ POLYVEST HT-based POLYVEST POLYVEST POLYVEST HT-based

13 | POLYVEST 2017 | Liquid polybutadienes

Product features: Potential Applications:

NCO-modified liquid polybutadiene Hardener compound for two-component PURs sealants

14 | POLYVEST 2017 | Liquid polybutadienes

Library of POLYVEST HT-based Prepolymers: POLYVEST HT vs.

200 MDI prepolymers

Viscosity (20°C) / Pas

15 | POLYVEST 2017 | Liquid polybutadienes

Benefits of two-pack PUR based on POLYVEST® HT:

Two-part PUR Application form: Two-part liquid form, self-leveling

Curing temperature: Ambient conditions

A-Component Properties: Thermoset (not thermoplastic

Filler (e.g. calcium carbonate)

Mineral oil / Plasticizers

Liquid-applicable bitumen-based formulations:

18 | POLYVEST 2017 | Liquid polybutadienes

Viscosity of A-component/ Pas A1 A2 A3 A4

Properties A1:B1 A2:B1 A3:B1 A4:B1

The combination of POLYVEST HT with bitumen, mineral oil and filler

A:B 16:1 20:1

20 | POLYVEST 2017 | Liquid polybutadienes

shore A after 24h 37 17

shore A after 96h 40 22

Tensile strength after 7d 0.7 0.7

Elongation at break after 7d 1690 554

21 | POLYVEST 2017 | Liquid polybutadienes

Elongation at break/ %: A1B1 A2B1

2055 1892 1884

| POLYVEST 2017 | Liquid polybutadienes

Water uptake (wt%) after water immersion test:

| POLYVEST 2017 | Liquid polybutadienes

One-part PUR: One component, liquid form,

Curing temperature: Ambient conditions,

Fillers (e.g. calcium carbonate)