Answer: (c) [Pt(NH3)4 (NO2) Cl]SO4

Q.10 Which of the following isomers will give white precipitate with
BaCl2 solution?
REVISION TEST CLASS – XII [CHEMISTRY] CHAPTER –COORDINATION COMPOUNDS
(a) [CO(NH3)5SO4]Br (b) [CO(NH3)5Br]SO4
(c) [CO(NH3)4(SO4)2]Br (d) [CO(NH3)4(SO4)]
VINAY GUPTA –B1 JANAKPURI SHAHGANJ AGRA - 7302699469, 9412161447
Answer :- (b) [CO(NH3)5Br]SO4
Q.11 |Pt(NH3)4| |CuCl4| and |Cu(NH3)4||PtCl4| are known as
Q.1 Which of the following compounds has tetrahedral geometry?
(a) ionisation isomers. (b) coordination isomers
(a) [Ni(CN)4]2- (b) [Pd(CN)4]2- (c) [PdCl4]2- (d) [NiCl4]2-
(c) linkage isomers (d) polymerisation isomers
Answer: (d) [NiCl4]2-
Answer: (b) coordination isomers
Q.2 The number of possible isomers for the complex [Co(C2O4)2 (NH3)2|
Q.12 The name of the linkage isomer of |Co(NH3)5NO2|Cl2 will be
(a) 1 (b) 2 (c) 3 (d) 4
(a) pentaammonotrocobalt (II) chloride
Answer: (c) 3
(b) pentaaminenitrochloridecobaltate (III)
Q.3 According to Werner’s theory of coordination compounds
(c) pentaamminenitritocobalt (III) chloride
(a) Primary valency is ionisable (b) Secondary valency is ionisable
(d) pentanitrosoamminechlorocobaltate(III)
(c) Primary and secondary valencies are lonisable
Answer: (c) pentaamminenitritocobalt (III) chloride
(d) Neither primary nor secondary valency’s ionisable
Q.13 Which of the following complex species is not expected to exhibit optical
Answer:- (a) Primary valency is ionisable
isomerism?
Q.4 Among the following which arc ambidentate ligands?
(a) [Co(en) (NH3)2Cl2]+ (b) [Co(en)3]3+ (c)[Co(en)2Cl2] (d) [Co(NH3)3Cl3]
(i) SCN– (ii) NO3− (iii) NO2− (iv) C2O42−
Answer: (d) [Co(NH3)3Cl3]
(a) (i) and (iii) (b) (i) and (iv) (c) (i) and (ii) (d) (ii) and (iv)
Q.14 Which of the following will not show geometrical isomerism?
Answer: (a) (i) and (iii)
(a) [Cr(NH3)4Cl2]Cl (b) [Co(en)2Cl2]Cl
Q.5 Which of the following ligands form a chelate?
(c) [(Co(NH3)5NO2]Cl2 (d) [Pt(NH3)2Cl2]
(a) Acetate (b) Oxalate (c) Cyanide (d) Ammonia
Answer: (c) (Co(NH3)5NO2]Cl2
Answer: (b) Oxalate
Q.15 For the square planar complex |Mabcd| where M is the central atom and a,
Q.6 The complex ion which has no d-electrons in the central metal atom is
b. c, d are monodentate ligands, the number of possible geometrical
(a) [MnO4]– (b) [Co(NH3)6]3- (c) [Fe(CN)6]3- (d) [Cr(H2O)6]3+
– isomers are
Answer: (a) [MnO4]
(a) 1 (b) 2 (c) 3 (d) 4
Q.7 The correct IUPAC name of the coordination compound K3[Fe(CN)5NO] is
Answer: (c) 3
(a) Potassium pentacyanonitrosylferrate (II)
Q.16 The hybridisation involved in [Co(C2O4)3]3- is
(b) Potassium pentacyanonitroferrate (II)
(a) sp3d2 (b) sp3d3 (c) dsp3 (d) d2sp3
(c) Potassium nitritopentacyanoferrate (IV) 2 3
Answer: (d) d sp
(d) Potassium nitritepentacynanoiron (II)
Q.17 Determine which of the following statements about VBT is inaccurate.
Answer: (a) Potassium pentacyanonitrosylferrate (II)
a) It does not explain the colour of coordination compounds
Q.8 The correct IUPAC name of the following compound is
b) It can distinguish between strong and weak ligands
[Cr(NH3)5(NCS)][ZnCl4]
c) It does not explain the kinetic stabilities of coordination compounds
(a) Penta amine isothiocyanato chromium (III) tetrachlorozincate (II)
d) It is unreliable in the prediction of geometries of 4-coordinate complexes
(b) Penta amine isothicocyanatezinc chloridechromate (III)
Answer: b
(c) Penta amine isothicoyanato chromate (II)
Q.18 Which of the following determines the position of ligands in a mononuclear
(d) isothiocyanatopenta amine chromium (II) zinc chloride (IV)
coordination entity’s formula?
Answer: (a) Penta amine isothiocyanato chromium (III) tetrachlorozincate (II)
a) Atomicity of the ligand b) Charge on the ligand
Q.9 Correct formulae of tetraaminechloronitroplatinum (IV) sulphate can be
c) The first letter in the name of the ligand d) Denticity of the ligand
written as
Answer: c
(a) [Pt(NH3)4 (ONO) Cl]SO4 (b) [Pt(NH3)4Cl2NO2]2
(c) [Pt(NH3)4 (NO2) Cl]SO4 (d) [PtCl(ONO)NH3(SO4)]
Q.19 Which of the following statements about a charged coordinating entity is Q.29 Which one of the following is an inner orbital complex as well as
correct? diamagnetic in behaviour?
a) The sign of the charge is written after the number (a) [Zn(NH3)6]3+ (b) [NI(NH3)2]2+
3+
b) The charge of the complex ion is written in parenthesis while naming (c) [Cr(NH3)6] (d) [Co(NH3)6]3+
3+
the entity Answer: (d) [Co(NH3)6]
c) The charge is indicated as a subscript outside the square bracket on the Q.30 Which type of isomerism is shown by, the octahedral complex
right [CO(NH3)4 Br2] Cl?
d) The charge on the complex ion is depicted along with the counter ion (a) Geometrical and ionization (b) Geometrical and optical
Answer: a (c) Optical and ionization (d) Geometrical only
Q.20 The core atom of which of the following biologically significant Answer: (a) Geometrical and ionisation
coordination molecules is magnesium? Q.31 In the spectrochemical series, the magnitude of the crystal field splitting
a) Vitamin B12 b) Haemoglobin c) Chlorophyll d) Carboxypeptidase-A is maximum for which ion?
Answer: c (a) Cl– (b) F– (c) NO2 (d) CN–
Q.21 The oxidation number of Cr in a [Cr(NH3)2F4]– complex is Answer: (d) CN –

(a) II (b) III (c) IV (d) VI. Q.32 The complex used as an anticancer agent is
Answer : (b) III (a) mer-[Co(NH3)2 Cl3] (b) cis-[PtCl2 (NH3)2]
Q.22 The formula of potassium dicyanobis (oxalato) nickelate (II) is (c) cis-K2[PtCl2Br2] (d) Na2CoCl4
(a) K4[Ni(CN)(Ox)2] (b) K3[Ni2 (CN)2 (Ox)2] Answer: (b) cis-[PtCl2 (NH3)2]
(c) K4[Ni(CN)2(Ox)2] (d) K2[Ni(CN)2(Ox)2] Q.33 One mole of complex compound Co (NH3)5Cl3 gives 3 moles of ions on
Answer: (c) K4[Ni(CN)2(Ox)2] dissolution in water. One mole of the same complex reacts with two moles
Q.23 The co-ordination number of cobalt in the complex [Co(en)2Br2]Cl2 is of AgNO3 solution to yield two moles of AgCl (s). The structure of the
(a) 4 (b) 6 (c) 5 (d) 2. complex is
Answer : (b) 6 (a) [Co(NH3)3Cl3] 2NH3 (b) [CO(NH3)4Cl2] Cl NH3
Q.24 The number of ions in [Pt(NH3)3Cl3Br]Cl will be (c) [CO(NH3)4Cl]Cl2.NH3 (d) [CO(NH3)5Cl]Cl2
(a) 4 (b) 3 (c) 2 (d) 1. Answer:- (d) [CO(NH3)5Cl]Cl2
Answer:- (c) 2 Q.34 The correct order for the wavelength of absorption in the visible regionis
Q.25 K3[Al(C2O4)3] is called (a) [Ni(NO2)6]4- < [Ni (NH3)6]2+ < [Ni (H2O)6]2+
(a) Potassium alumino oxalate (b) [Ni(NO2)6]4- < [Ni (H2O)6]2+ < [Ni (H3)6]2+
(b) Potassium aluminium (III) trioxalate (c) [Ni(H2O)6]2+ < [Ni (NH3)6]2+ < [Ni (NO2)6]4+
(c) Potassium trioxalato aluminate (III) (d) [Ni(H3)6]2+ < [Ni (H2O)6]2+ < [Ni (NO2)6]4-
(d) Potassium tris (oxalato) aluminium. Answer: (a) [Ni(NO2)6]4- < [Ni (NH3)6]2+ < [Ni (H2O)6]2+
Answer: (c) Potassium trioxalato aluminate (III) Q.35 Which of the following statements is incorrect?
Q.26 Amongst Ni (CO)4, [Ni(CN)4]2- and NiCl42- (a) in K3[Fe(CN)6], the ligand has satisfied only the secondary valency of
(a) Ni(CO)4 and NiCl42- are diamagnetic and [Ni(CN)4]2- is paramagnetic ferric ion.
(b) NiCl42- arrd [Ni(CN)4]2- are diamagnetic and Ni(CO)4 is paramagnetic. (b) In K3[Fe(CN)6], the ligand has satisfied both the primary and
(c) Ni(CO)4 and [Ni(CN)4]2- are diamagnetic & [NiCl4]2- is paramagnetic. secondary valence of ferric ion.
(d) Ni(CO)4 is diamagnetic & [NiCl4]2- and [Ni(CN)4]2- are paramagnetic. (c) In K4 [Fe(CN)6] the ligand has satisfied both the primary and
Answer: (c) Ni(CO)4 and [Ni(CN)4]2- are diamagnetic & [NiCl4]2- is paramagnetic. secondary valencies of ferrous ion.
Q.27 In Ni (CO)4, the nickel atom is ……… hybridised (d) In [Cu(NH3)4]SO4, the ligand has satisfied only the secondary valency
(a) sp² (b) sp³ (c) dsp² (d) sp³d. of copper.
Answer :- (b) sp³ Answer: (a) in K3[Fe(CN)6], the ligand has satisfied only the secondary valency of
Q.28 Which of the following compounds can show optical isomerism? ferric ion.
(a) trans-[Co(en)2Cl2]Br (b) [Co(en)3]Cl3
(c) trans-[Co(NH3)4Cl2]Cl (d) [Co(NH3)5Cl]Cl2.
Answer: (b) [Co(en)3]Cl3