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Tribology International
journal homepage: www.elsevier.com/locate/triboint
A R T I C L E I N F O A B S T R A C T
Keywords: The friction behaviors of elastomer, polyacetal, and hard-felt writing tips sliding on various textured glass sur
Texture faces prepared via micro-slurry-jet technology were investigated via reciprocating friction tests. The friction
Adhesive coefficients of each writing tip could be varied using textured glass surfaces. Adhesive, abrasive, and deformation
Abrasive
frictions were observed owing to two types of surface roughness (sub-millimeter-millimeter sized texture and
Ploughing
nanometer sized fine roughness). By inducing a surface texture with a smaller pitch (sub-millimeter-millimeter
sized texture) than the contact area of the writing tip, the largest changes of friction coefficients were observed
for the elastomer. These reductions occurred due to reduced adhesive friction by decreasing real contact areas.
1. Introduction Generally, a pen tip on a glass surface is slippery due to which, the user
experiences a “poor” writing feeling. This can be improved by adjusting
Adhesive and abrasive frictions are the representative frictional the elastic modulus or changing the material of the pen tip. However, it
mechanisms considered to underlie frictional contact at the asperity is difficult to achieve “good” writing feeling by improving only the pen
level of surface roughness [1–3]. The friction behavior of an elastic tip. In this study, we measured the friction behaviors of three types of
material depends on its material properties, which are derived from the commercially available pen tips on textured glass that represents the
structures of its main and sub-molecular chains, molecular weight, and surface of tablet computers. This was realized to achieve better friction
crystal structure [4–6]. Furthermore, the effects of chemical and phys control to provide an improved writing feeling. We observed the
ical interactions on the elastic material influence the real contact area of changes in the friction behaviors via reciprocating friction tests in
the material sliding on a hard surface. relation to the textured glass surfaces having two types of roughness.
In this context, several studies have reported on the influence of One is the fine roughness in nanometer sized asperities, which can in
textured surfaces on the tribological characteristics under both lubri fluence adhesive and abrasive frictions. The other is due to the surface
cated and unlubricated conditions [7]. Under the lubricated condition, texture of sub-millimeter-millimeter sized pitches, which can influence
the textured surface is generally expected to afford enhanced hydrody deformation friction generated by the pen tip entering concave parts
namic lubrication [8,9]. Under the unlubricated condition, the textured with elastic deformation. Thus, the frictional mechanisms based on
surface “adjusts” to the apparent contact areas, which also influences the adhesive, abrasive, and deformation frictions were analyzed by
adhesive friction and abrasive friction against a counterface [10–12]. considering these two types of surface roughness.
Furthermore, in the sliding pair comprising an elastic material surface
and a textured hard surface, deformation friction cannot be neglected 2. Material and methods
[13–17]. Moreover, the elastic deformation and migration of the elastic
material into the concave structure in the textured hard counterface may 2.1. Writing tip
increase the friction and induce fatigue wear of the elastic material.
Recently, the frictional behaviors of pen tips on the glass surfaces of In this study, the writing-tip specimens included an elastomer tip
tablet computers have attracted considerable attention because the (ACK-20004, Pen Nibs, Wacom Co., Ltd.), a polyacetal tip (ACK-20001,
friction behavior influences the “writing feeling” of the pen [18,19]. Pen Nibs, Wacom Co., Ltd.), and a hard-felt tip (ACK-20003, Pen Nibs,
* Corresponding author at: Research and Development Group., Nippon Electric Glass Co., Ltd., 2–7-1 Seiran, Otsu, Shiga 520–8639, Japan.
E-mail address: nfujita@neg.co.jp (N. Fujita).
https://doi.org/10.1016/j.triboint.2022.107539
Received 28 February 2022; Received in revised form 16 March 2022; Accepted 18 March 2022
Available online 23 March 2022
0301-679X/© 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-
nc-nd/4.0/).
N. Fujita et al. Tribology International 171 (2022) 107539
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Fig. 6. Schematic of contact area observation between the writing tips and the glass surfaces.
75 µm × 55 µm area of the convex section that contained a section of the writing tip after each test.
apparent contact area between the elastic material and the glass surface.
Since the measured values of Sa in the micro region have variations 2.4. Contact area observations between glass surface and writing tip
depending on measurement points, the average of measurement results
at any 10 points was calculated. Fig. 6 shows the procedure employed to observe the contact area
Fig. 4 shows an illustration of the boundary between the writing tip between the writing tips and a glass surface. During the observations,
and textured glass surface. To change the contact conditions of the real the writing tips were fixed at an orientation angle of 45◦ and pressed
contact and apparent contact areas and amount of the elastic deforma onto the glass plate under a load of 1.96 N. The contact area between the
tion, we prepared nine types of textured surfaces (three heights and writing tips and the glass surface was observed from the back side of the
three pitches). glass with a laser microscope (LEXT OLS5000-SAT, Olympus Corpora
tion, Japan). First, the contact areas between the three types of writing
2.3. Compression test tips and the flat glass were observed. Then, the contact areas between
these writing tips and glass specimens with and without a texture near
Fig. 5 is a schematic of the compression test process (EZ-LX, Shi the stroke-end part in the reciprocating motion were observed. The
madzu Corporation, Japan). A compression test was performed to reciprocating motion in the right and left direction was performed by
investigate the difference in the amount of elastic deformation of each operating an x-stage micrometer; the glass specimens on the x-stage
pen tip and effect of bending of the writing tip. During the test, the were moved against fixed writing tips. The movement interval in the
writing tip was fixed at orientation angles of 90◦ and 45◦ and pressed right and left directions was approximately 250 µm.
onto the writing surface (flat glass plate; OA-10 G, Nippon Electric Glass
Co. Ltd., Japan) at a speed of 0.05 mm/s. The compression in the writing 2.5. Reciprocating friction tests
tips was measured thrice (in each writing tip) by gradually increasing
the pushing load up to 5 N. The writing tip was replaced with a new Fig. 7 shows a schematic of the reciprocating friction test. During the
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Table 1
Surface profile observations of the writing-tip specimens.
Height image and Sa[mm] Radius of curvature of the tip [mm]
Elastomer tip
10.54 687
Polyacetal tip
0.71 665
Hard-felt tip
689
4.49
test, the writing tip was fixed at an orientation angle of 45◦ and pressed calculated from the frictional force measured by a load cell. The writing
onto the glass plate under a load of 1.96 N. Reciprocating motions with a tip was replaced after each test, and the glass writing specimen was
stroke of 40 mm and a period of 14 s were applied for 100 cycles at room cleaned with ethyl alcohol before testing with the next tip.
temperature (approximately 23 ◦ C). The coefficient of friction was
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Fig. 8. Glass surfaces considered as writing-surface specimens in the study. SD is the standard deviation of surface roughness (Sa).
3. Results and discussion of the textured surface was higher than that of the non-processed glass
plate (flat glass plate), the transparency of the processed glass was
3.1. Writing-tips observations maintained [23]. Based on these observations, we estimated that Sa
increases with height between the convex and concave sections (Fig. 8),
Table 1 shows enlarged views and the surface profiles of the writing possibly resulting from the increased collision rate of the alumina par
tips (elastomer tip, polyacetal tip, and hard-felt tip). The elastomer tip ticles at these points. We also determined that in the micro-slurry-jet
consists of thermoplastic polyester elastomer, which has a structure with processing, a lower feeding speed of the injection nozzle yields a
slits. The surface roughness (Sa) and radius of curvature of the tip were greater height (Fig. 2).
approximately 10.5 µm and 687 µm, respectively, and those of the pol
yacetal tip were approximately 0.7 µm and 665 µm, respectively. The 3.3. Compression differences among the three types of writing tips
hard-felt tip has a hardened filamentous structure. The Sa and radius of
curvature of the tip were approximately 4.5 µm and 689 µm, Fig. 9 shows the experimental results of the compression tests for
respectively. each writing tip at angles of 90◦ and 45◦ . At 90◦ , large changes in
compression in each writing tip were observed in low-load regions from
3.2. Surface properties of textured glass the contact point. These changes were primarily attributed to the elastic
deformation in the curved part of each writing tip. After the bending
Fig. 8 shows the glass surfaces used as the writing-surface specimens, point for low loads, the compression changed linearly with elastic
wherein we can clearly observe the formation of continuous and smooth deformation. The elastic deformations increased in the following order:
concave–convex sections on the textured glass surface. Although the Sa elastomer > hard felt > polyacetal. The changes in the compression for
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Fig. 9. Experimental results of compression tests for each writing tip on flat glass at angles of 90◦ and 45◦ .
Fig. 10. Contact area observations between the writing tips and glass surface.
low loads were greater at 45◦ than at 90◦ , indicating that these changes The upper right views (E) are the observations of the contact areas in the
involved the bending of writing tips in addition to dents. As the test load stroke-end part. The lower views (F–J) are the observations when the
of “1.96 N” for the reciprocating friction test is larger than the folding writing tips were moved to the left from the stroke-end part.
points in the compression changes, the effect of bending of the writing From the sliding pair of the elastomer and the flat glass plate (Fig. 11
tips is considered to be small. (a): (a-1)), a transferred elastomer onto the glass surface during sliding
motion and considerable change in the shape of the contact part near the
stroke-end part were observed, which is due to high adhesion of the
3.4. Comparison of contact area between the writing tips and glass surface elastomer. On the contrary, for the sliding pair of the elastomer and the
textured glass (Fig. 11 (a): (a-2)), no transferred material was observed,
Fig. 10 shows views of the contact area between the writing tip and and the change in the shape of the contact part on the textured glass
the flat glass surface for the three writing tips. The diameters of the surface was reduced. There was no change in the contact part for the
contact area of the elastomer tip, polyacetal tip, and hard-felt tip were polyacetal with and without the texture on the glass surfaces (Fig. 11 (b):
approximately 850 µm, 180 µm, and 480 µm, respectively. The diameter (b-1) and (b-2)). For the hard felt (Fig. 11 (c): (c-1) and (c-2)), although
of the elastomer tip contact area was the largest because of its low elastic there was almost no change in the shape of the contact part with and
modulus and deformable slits structure. Conversely, that for the poly without the texture on the glass surfaces, the contact area on the
acetal tip was the smallest because deforming the polyacetal tip is textured glass surface was observed to have slightly decreased. In the
difficult. The order of the contact area diameter was the same as that in future, for further detailed analysis of the contact part, methods such as
the compression test results (Fig. 9). SEM and RAMAN spectroscopy will be used [24].
Fig. 11 (a)-(c) show enlarged views of the contact areas between the
writing tips and glass surfaces (flat glass and textured glass of Type 5)
near the stroke-end part during reciprocating motion. The upper left 3.5. Friction behaviors of three types of writing tips against textured glass
views (A) in each specimen are the observations before a load is applied. surfaces
The second set of views (B) are observations after applying 1.96 N of the
load. After applying the load, the writing tips were moved to the right. In this study, the following three friction components were defined to
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Fig. 11. (a). Contact area between the elastomer tip and glass surfaces near the stroke-end parts (where the directions of relative motions of writing tips changed) in
reciprocating motion. (b). Contact area between the polyacetal tip and glass surfaces near the stroke-end parts (where the directions of relative motions of writing
tips changed) in reciprocating motion. (c). Contact area between the hard-felt tip and glass surfaces near the stroke-end parts (where the directions of relative
motions of writing tips changed) in reciprocating motion.
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Fig. 14. Experimental results for the case of elastomer tip sliding on glass surfaces.
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Fig. 15. Experimental results for the case of polyacetal tip sliding on glass surfaces.
than that on the flat glass surface; moreover, the change in the shape of Flat glass surface), we observed a slight increase in the friction coeffi
the contact part on the textured glass became smaller (Fig. 11 (a): (a-1) cient with the number of reciprocation cycles. However, the maximum
and (a-2)). This suggests that the textured glass surface can reduce the friction coefficient was still lower than that obtained with the elastomer
damage of the elastomer tip. (Fig. 17, flat glass surface). Although some damage of the polyacetal
For the textured glass surface with small and medium pitches may have occurred at the real contact area during the reciprocating
(Fig. 17, Types 1–6), both pitch sizes are smaller than the diameter of the motions, we speculate that an increase in the adhesion between the two
contact area between the elastomer tip and the glass surface (Fig. 10). surfaces due to the exposure of the chemically active parts is not pre
Therefore, the adhesive friction was reduced because of the apparent- dominant. The amount of polyacetal transferred was small (Fig. 11 (b):
contact-area and the real-contact-area reduction. In Type 5 (after 80 (b-1)). A slightly increased friction coefficient is observed when using a
cycles), the coefficient of friction was reduced by up to 27% compared to textured surface (Fig. 18, Types 1–9) than when using a flat glass sur
that for flat glass surface. The effect of differences in height on these face; further, no significant increase is observed in the friction with the
pitch sizes is not considered to be large. In contrast, for the case of the increasing number of reciprocating motions. Even with the texture of the
textured glass surface with large pitches (Fig. 16, Types 7–9), a pitch size glass surface, the damage of the polyacetal tip did not increase (Fig. 11
of 1 mm is larger than the diameter of the contact area between the (b): (b-2)). In this case, we confirmed that the elastic deformation and
elastomer tip and the glass surface (Fig. 10). That is, the apparent- migration of the polyacetal on the textured glass surface were smaller
contact-area reduction is small and, therefore, the reduction in friction than those for the elastomer (Fig. 9, 11 (a): (a-2) and 11 (b): (b-2)); thus,
is not effectively large because the elastomer contacts the concave sec deformation friction is not considered a predominant factor here. The
tion because of elastic deformation. Since no difference was observed in increase in the friction coefficient with the textured glass surface may
the amount of transferred materials among the textured surfaces and the thus be due to abrasive friction (Fig. 12). In the textured surfaces, the
increasing tendency of coefficient of friction for the textured glass sur diameter of the contact area between the polyacetal tip and the glass
face with large pitches, it is suggested that it could be due to deformation surface was smaller than the three types of pitch sizes. Therefore, the
friction causing by the writing tip entering the concave sections difference in the apparent contact areas is not significant, and the
(Fig. 13). change in friction depends on the contact frequency with asperity level.
Fig. 20 shows an enlarged view of the friction-coefficient waveforms Because the contact area between the polyacetal tip and the glass surface
after 80 cycles in Type 7 of Fig. 17. Obviously, there are increases in is not much smaller than the pitch sizes, a larger pitch size corresponds
friction when the writing tip moves to the convex sections and decreases to easier contact along the concave parts. Thus, larger pitch sizes tended
in friction when the writing tip moves to the concave sections. Thus, to increase the friction coefficient.
large pitches (Fig. 17, Types 7–9) can induce the elastic deformation of For the hard-felt tip sliding on glass surfaces (Fig. 19), we observed
the elastomer across the concave section, which can lead to enhanced an increase in friction with the number of reciprocation cycles. In this
deformation friction. The contribution of the height difference for the case, the damaged and chemically active real contact area can afford
textured glass surface with large pitches to friction appears to be small. increased friction. We noted that the textured surfaces (Fig. 19, Types
Regarding the polyacetal tip sliding on the flat glass surface (Fig. 18, 1–9) afford increased friction possibly because the filamentous structure
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Fig. 16. Experimental results for the case of hard-felt tip sliding on glass surfaces.
of the hard felt promotes abrasive friction at the asperity level (Fig. 12). millimeter sized texture difference is considered small (Figs. 17–19).
This can be supported by changes in the contact condition between the Meanwhile, studies on textured surfaces based on bio-inspired
hard felt and the textured glass surface (Fig. 11 (c): (c-1) and (c-2)); that structures have reported that the surface hydro
is, we can confirm that the amount of contact area on the textured glass philicity–hydrophobicity can be suitably modified by structural changes
surface was reduced owing to the existence of the asperity compared [37–39]. Such a change can influence the adhesion force between two
with the flat glass surface (the size of the non-contact part in the contact surfaces and thereby influence the friction characteristics. Texture
area was increased). For the textured surface, frictions of types 1–3 were changes on the glass surface can influence the adhesion force resulting
smaller than those of types 4–9 owing to relation between the diameter from contact between two surfaces and, thus, such changes can be
of the contact area and the pitch size (Figs. 8 and 10). Each friction applied to control the frictional characteristics. These topics will form
coefficient for the medium and large pitches (Fig. 19, Types 4–9) is the crux of our future investigations.
higher than those of the small pitches owing to an increase in the
apparent contact area (the diameter of contact area < the pitch sizes CRediT authorship contribution statement
(750 µm and 1000 µm)). For these pitches, we speculate that the effect
of the “height difference” is not significant because the hard felt may Naoki Fujita: Conceptualization; Formal analysis; Validation;
undergo deformation with a small force corresponding to the textured Roles/Writing – original draft, Hajime Yamaguchi: Investigation;
surfaces with the medium and large pitches [36]. Software, Takumi Kinoshita: Data curation; Visualization, Masaru
Last of all, the influence of the size for nanometer sized asperity on Iwao: Resources; Project administration, Yoshitaka Nakanishi: Fund
the friction coefficient was investigated. The results of the elastomer, ing acquisition; Methodology; Supervision; Writing – review & editing,
which has largest changes, and those of the polyacetal, which has Statement of originality, This manuscript has not been published or
smallest changes for the friction coefficient, are shown in Fig. 21. These presented elsewhere in part or in entirety and is not under consideration
samples were prepared via micro-slurry-jet processing to eliminate by another journal. We have read and understood your journal’s pol
millimeter sized textures. Thus, these samples have only nanometer icies, and we believe that neither the manuscript nor the study violates
sized asperities (approximately 2–4 nm). For the elastomer, by intro any of these.
ducing these asperities for the flat glass surface, the friction coefficient
decreased. This is because of reduction of real contact area due to
4. Conclusions
nanometer sized asperities (reduction of adhesion between the elas
tomer and glass surfaces). For the polyacetal, in contrast, the friction
In this study, we conducted reciprocating friction tests with elastic
coefficient increased due to the abrasive friction at asperity level
materials sliding on textured glass surfaces. We found that the friction
(Fig. 12). However, for both writing tips, there was no difference in the
coefficients of three types of writing tips (elastomer, polyacetal, and
friction coefficient against asperity size in the range of Ra of approxi
hard felt) could be varied with the use of textured glass surfaces pre
mately 2–4 nm. Therefore, the effect of differences in size of nanometer
pared via micro-slurry-jet technology. The textured glass surfaces of sub-
asperities on the results of the friction behaviors for submillimeter-
millimeter-millimeter sized pitches with fine roughness in nanometer
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Fig. 17. Summary of experimental results (writing tip: elastomer). Each value is the average of three trials.
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Fig. 18. Summary of experimental results (writing tip: polyacetal). Each value is the average of three trials.
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Fig. 19. Summary of experimental results (writing tip: hard felt). Each value is the average of three trials.
Fig. 20. Enlarged view of the friction-coefficient waveforms after 80 cycles in Type 7 of Fig. 17.
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