Date Printed: 12/22/2022 Product: 0533S1NL

Safety Data Sheet

Prepared in Accordance with HCS 29
C.F.R. 1910.1200

1. Identification of the Substance/Mixture and the Company/Undertaking

1.1 Product Identifier 0533S1NL Revision Date: 12/05/2022

Product Name: THINNER 33 Supercedes Date: 07/27/2022

Thinner for industrial

1.2 Relevant identified uses of the coatings - Industrial use.
substance or mixture and uses
advised against

1.3 Details of the supplier of the safety data sheet

Manufacturer: Carboline Global Inc.

2150 Schuetz Road
St. Louis, MO USA 63146

Regulatory / Technical Information:

Contact Carboline Technical Services at
1-800-848-4645

Schlereth, Ken - regulatory@carboline.com

Datasheet Produced by:

1.4 CHEMTREC 1-800-424-9300 (Inside US)

Emergency telephone number:
CHEMTREC +1 703 5273887 (Outside US)
HEALTH - Pittsburgh Poison Control 1-412-681-6669

2. Hazard Identification

2.1 Classification of the substance or mixture

Acute Toxicity, Inhalation, category 4

Hazardous to the aquatic environment, Chronic, category 3
Eye Irritation, category 2
Flammable Liquid, category 3
Reproductive Toxicity, category 1A
STOT, repeated exposure, category 2
STOT, single exposure, category 3, NE
STOT, single exposure, category 3, RTI
Skin Irritation, category 2

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Date Printed: 12/22/2022 Product: 0533S1NL

2.2 Label elements

Symbol(s) of Product

Signal Word
Danger

Named Chemicals on Label

1,2,4 TRIMETHYLBENZENE, ETHYL BENZENE, PROPYLENE GLYCOL MONOMETHYL ETHER, 2-BUTOXYETHANOL,
TRIMETHYLBENZENE
HAZARD STATEMENTS

Flammable Liquid, category 3 H226 Flammable liquid and vapour.

Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Reproductive Toxicity, category 1A H360-1A May damage fertility or the unborn child.
STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated
exposure.
Hazardous to the aquatic environment, H412 Harmful to aquatic life with long lasting effects.
Chronic, category 3
PRECAUTION PHRASES
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/
face protection.
P284 Wear respiratory protection.
P304+340 IF INHALED: Remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do so.
Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention
P314 Get medical advice/attention if you feel unwell.
P332+313 If skin irritation occurs: Get medical advice/attention.
P403+233 Store in a well-ventilated place. Keep container tightly
closed.
ADDITIONAL INFORMATION
Note_P Note P : The classification as a carcinogen or mutagen need
64742-95-6 not apply; the substance, CAS 64742-95-6, contains less
than 0,1 % w/w benzene

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2.3 Other hazards

No Information

Results of PBT and vPvB assessment:

The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.

3. Composition/Information On Ingredients
3.2 Mixtures
Hazardous ingredients
Name According to EEC EINEC No. CAS-No. % Classifications
AROMATIC 265-199-0 64742-95-6 25 - <50 H226-315-319-332-335-336-373
HYDROCARBON -411

PROPYLENE GLYCOL 203-539-1 107-98-2 25 - <50 H226-319-332-336 Acute Tox. 4 Inhalation, Eye
MONOMETHYL Irrit. 2, Flam. Liq. 3, STOT SE
ETHER 3 NE

2-BUTOXYETHANOL 203-905-0 111-76-2 25 - <50 H302-312-315-319-332 Acute Tox. 4 Dermal, Acute

Tox. 4 Inhalation, Acute Tox. 4
Oral, Eye Irrit. 2, Skin Irrit. 2

1,2,4 202-436-9 95-63-6 10 - <25 H226-315-319-332-335-411

TRIMETHYLBENZENE

TRIMETHYLBENZENE 247-099-9 25551-13-7 2.5 - <10 H226-304-315-319-332-335-336

-411

2-METHOXY-1- 216-455-5 1589-47-5 0.1 - <1.0 H226-315-318-335-360 Eye Dam. 1, Flam. Liq. 3,
PROPANOL Repr. 1A, Skin Irrit. 2, STOT
SE 3 RTI

CUMENE 202-704-5 98-82-8 0.1 - <1.0 H226-304-335-411 Aquatic Chronic 2, Asp. Tox.
1, Flam. Liq. 3, STOT SE 3
RTI

ETHYL BENZENE 202-849-4 100-41-4 0.1 - <1.0 H225-304-332-373-412

CAS-No. M-Factors
64742-95-6 0
107-98-2 0
111-76-2 0
95-63-6 0
25551-13-7 0
1589-47-5 0
98-82-8 0
100-41-4 0

Additional Information: The text for GHS Hazard Statements shown above (if any) is given in Section 16.

4. First-aid Measures
4.1 Description of First Aid Measures
AFTER INHALATION: Give oxygen or artificial respiration if needed. Remove person to fresh air. If signs/symptoms
continue, get medical attention.
AFTER SKIN CONTACT: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. If skin irritation persists, call a physician.
AFTER EYE CONTACT: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
AFTER INGESTION: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If swallowed, call
a poison control centre or doctor immediately.

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Date Printed: 12/22/2022 Product: 0533S1NL

4.2 Most important symptoms and effects, both acute and delayed
Harmful if swallowed. Irritating to eyes and skin. Risk of serious damage to the lungs (by aspiration). Vapours may cause
drowsiness and dizziness.
4.3 Indication of any immediate medical attention and special treatment needed

No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if
available, can be found in section 11.
When symptoms persist or in all cases of doubt seek medical advice.

5. Fire-fighting Measures
5.1 Extinguishing Media:
Carbon Dioxide, Dry Chemical, Foam, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable liquid. Vapours are heavier than air and may spread along
floors. Vapours may form explosive mixtures with air. Vapors may travel to areas away from work site before igniting/flashing
back to vapor source. Provide adequate ventilation. Prevent the creation of flammable or explosive concentrations of vapour
in air and avoid vapour concentration higher than the occupational exposure limits. Keep away from heat/sparks/open
flames/hot surfaces. - No smoking. Electrical installations / working materials must comply with the technological safety
standards. Wear shoes with conductive soles.
FOR SAFETY REASONS NOT TO BE USED: No Information

5.2 Special hazards arising from the substance or mixture

No Information

5.3 Advice for firefighters

SPECIAL FIREFIGHTING PROCEDURES: In the event of fire, wear self-contained breathing apparatus. Cool containers /
tanks with water spray. Flammable.
SPECIAL FIREFIGHTING PROTECTION EQUIPMENT: No Information

6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures

Ensure adequate ventilation. Evacuate personnel to safe areas. Remove all sources of ignition. To avoid ignition of vapours
by static electricity discharge, all metal parts of the equipment must be grounded. Wear personal protective equipment. For
personal protection see section 8.
6.2 Environmental precautions

Do not allow material to contaminate ground water system. Prevent product from entering drains.
6.3 Methods and material for containment and cleaning up
Prevent further leakage or spillage if safe to do so. Contain spillage, soak up with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations
(see section 13).
6.4 Reference to other sections

No Information

7. Handling and Storage

7.1 Precautions for safe handling

INSTRUCTIONS FOR SAFE HANDLING : Keep containers dry and tightly closed to avoid moisture absorption and
contamination. Prepare the working solution as given on the label(s) and/or the user instructions. Do not breathe vapours or
spray mist. Ensure all equipment is electrically grounded before beginning transfer operations. Do not use sparking tools. Do
not get in eyes, on skin, or on clothing. Use only with adequate ventilation/personal protection. Wash thoroughly after
handling.
PROTECTION AND HYGIENE MEASURES : Handle in accordance with good industrial hygiene and safety practice. Wash
hands before breaks and at the end of workday. When using, do not eat, drink or smoke.
7.2 Conditions for safe storage, including any incompatibilities

CONDITIONS TO AVOID: Heat, flames and sparks.

STORAGE CONDITIONS: Keep container closed when not in use. Store in a dry, well ventilated place away from sources of

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Date Printed: 12/22/2022 Product: 0533S1NL

heat, ignition and direct sunlight.

7.3 Specific end use(s)

No specific advice for end use available.

8. Exposure Controls/Personal Protection

8.1 Control parameters
Ingredients with Occupational Exposure Limits
(US)

Name CAS-No. ACGIH TWA ACGIH STEL ACGIH Ceiling

AROMATIC HYDROCARBON 64742-95-6 300.0 PPM N/E
PROPYLENE GLYCOL MONOMETHYL 107-98-2 50 PPM 100 PPM N/E
ETHER
2-BUTOXYETHANOL 111-76-2 20 PPM 50 PPM N/E
1,2,4 TRIMETHYLBENZENE 95-63-6 25.0 PPM N/E N/E
TRIMETHYLBENZENE 25551-13-7 25 PPM NE N/E
2-METHOXY-1-PROPANOL 1589-47-5 N/E N/E N/E
CUMENE 98-82-8 50 PPM N/E N/E
ETHYL BENZENE 100-41-4 100.0 ppm 125 ppm

Name CAS-No. OSHA PEL OSHA STEL

AROMATIC HYDROCARBON 64742-95-6 500.0 PPM

PROPYLENE GLYCOL MONOMETHYL 107-98-2 360 MGM3, 100 PPM

540 MGM3, 150
ETHER PPM

2-BUTOXYETHANOL 111-76-2 120 MGM3, 25 PPM

N/E

1,2,4 TRIMETHYLBENZENE 95-63-6

TRIMETHYLBENZENE 25551-13-7 25 PPM

2-METHOXY-1-PROPANOL 1589-47-5 N/E

N/E

CUMENE 98-82-8 245 MGM3, 50 PPM

N/E

ETHYL BENZENE 100-41-4 100.0 PPM

FURTHER ADVICE: Refer to the regulatory exposure limits for the workforce enforced in each country. Some components may
not have been classified under the EU CLP Regulation.

8.2 Exposure controls

Personal Protection
RESPIRATORY PROTECTION: In order to avoid inhalation of spray-mist and sanding dust, all spraying and sanding must be
done wearing adequate respirator. Use only with ventilation to keep levels below exposure guidelines reported in this
document. User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not able
to monitor, use State or federally approved supplied air respirator. For silica containing coatings in a liquid state, and/or if no
exposure limits are established above, air-supplied respirators are generally not required.
EYE PROTECTION: Safety glasses with side-shields.
HAND PROTECTION: Gloves should be discarded and replaced if there is any indication of degradation or chemical
breakthrough. Impervious gloves. Request information on glove permeation properties from the glove supplier. Lightweight

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Date Printed: 12/22/2022 Product: 0533S1NL

protective clothing
OTHER PROTECTIVE EQUIPMENT: Ensure that eyewash stations and safety showers are close to the workstation location.
ENGINEERING CONTROLS: Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined
areas.

9. Physical and Chemical Properties

9.1 Information on basic physical and chemical properties
Appearance: Clear Liquid
Physical State Liquid
Odor Solvent
Odor threshold N/D
pH N/D
Melting point / freezing point (°C) N/D
Boiling point/range (°C) 265 F (129C) - 387 F (197 C)
Flash Point (°C) 90F (32C)
Evaporation rate Slower Than Ether
Flammability (solid, gas) Not determined

Upper/lower flammability or explosive 1.3 - 15.3

limits
Vapour Pressure, mmHg 4.2 mmHg @ 20C
Vapour density Heavier than Air
Relative density Not determined
Solubility in / Miscibility with water N/D
Partition coefficient: n-octanol/water Not determined
Auto-ignition temperature (°C) Not determined
Decomposition temperature (°C) Not determined
Viscosity Unknown
Explosive properties Not determined
Oxidising properties Not determined

9.2 Other information

VOC Content g/l: 888
Specific Gravity (g/cm3) 0.89

10. Stability and Reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous polymerisation does not occur.
10.4 Conditions to avoid
Heat, flames and sparks.

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10.5 Incompatible materials

Strong oxidizing agents.

10.6 Hazardous decomposition products

Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke.

11. Toxicological Information

11.1 Information on toxicological effects
Acute Toxicity:
Oral LD50: N/D
Inhalation LC50: N/D

Irritation: Eye Irritation and Skin Irritation, category 2

Corrosivity: Unknown

Sensitization: Unknown

Repeated dose toxicity: Unknown

Carcinogenicity: Unknown

Mutagenicity: Unknown

Toxicity for reproduction: Reproductive Toxicity, category 1A

STOT-single exposure: STOT, single exposure, category 3, NE & RTI

STOT-repeated exposure: STOT, repeated exposure, category 2

Aspiration hazard: Unknown

If no information is available above under Acute Toxicity then the acute effects of this product have not been tested.
Data on individual components are tabulated below:

Chemical Name Oral LD50 Dermal LD50 Vapor LC50 Gas LC50 Dust/Mist
CAS-No.
LC50
3670 ppm/8
4700 mg/kg,
64742-95-6 AROMATIC HYDROCARBON oral, rat
hours, rat, 0.000 0.000
inhalation
10000
PROPYLENE GLYCOL 4016 mg/kg, 13536 mg/kg,
107-98-2 ppm/4hrs rat, 0.000 0.000
MONOMETHYL ETHER oral, rat dermal, rabbit
inhalation
450 ppm/l /
1300 mg/kg, 2000 mg/kg,
111-76-2 2-BUTOXYETHANOL oral, rat dermal, rat
4H, rat, 0.000 0.000
Inhalation
6000 mg/kg, 18000 mg /
95-63-6 1,2,4 TRIMETHYLBENZENE oral, rat
0.000 0.000
m3 / 4 hours

25551-13-7 TRIMETHYLBENZENE NE NE 0.000 0.000

5710 mg/kg, 5660 mg/kg, 1600 ppm /

1589-47-5 2-METHOXY-1-PROPANOL oral, rat dermal, rabbit
0.000 0.000
4h, inh, rat
2910 mg/kg, 12300 MG/ 8000 ppm / 4
98-82-8 CUMENE oral, rat KG (RABBIT)
0.000 0.000
hours

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3500 mg/kg >5000 mg/l, 17.2 mg/L
100-41-4 ETHYL BENZENE rat, oral dermal rabbit
0.000 0.000
Inh, Rat, 4Hr

Additional Information:
No Information

12. Ecological Information

12.1 Toxicity:
EC50 48hr (Daphnia): Unknown
IC50 72hr (Algae): Unknown
LC50 96hr (fish): Unknown

12.2 Persistence and degradability: Unknown

12.3 Bioaccumulative potential: Unknown

12.4 Mobility in soil: Unknown

12.5 Results of PBT and vPvB The product does not meet the criteria for PBT/VPvB in accordance with Annex XIII.
assessment:

12.6 Other adverse effects: Unknown

CAS-No. Chemical Name EC50 48hr IC50 72hr LC50 96hr

64742-95-6 AROMATIC HYDROCARBON No information No information No information

PROPYLENE GLYCOL MONOMETHYL
107-98-2 23300 mg/l (Water flea) No information 20800 mg/l (Fish)
ETHER
111-76-2 2-BUTOXYETHANOL 1800 mg/l (Water flea) 911 mg/l (Algae) 1474 mg/kg (Fish)
95-63-6 1,2,4 TRIMETHYLBENZENE No information No information No information
25551-13-7 TRIMETHYLBENZENE No information No information No information
19000 mg/l (Daphnia
1589-47-5 2-METHOXY-1-PROPANOL magna)
No Information 4998 mg/l (Fish)

98-82-8 CUMENE No information No information 6/32 mg/l (Fish)

100-41-4 ETHYL BENZENE No information No information No information

13. Disposal Considerations

13.1 WASTE TREATMENT METHODS: Do not burn, or use a cutting torch on, the empty drum. If recycling is not practicable,
dispose of in compliance with local regulations. Dispose of in accordance with local regulations. Empty containers should be
taken to an approved waste handling site for recycling or disposal.

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14. Transport Information

14.1 UN number UN 1263
14.2 UN proper shipping name Paint Related Material
Technical name N/A
14.3 Transport hazard class(es) 3
Subsidiary shipping hazard N/A
14.4 Packing group III
14.5 Environmental hazards No Information
14.6 Special precautions for user Unknown
EmS-No.: F-E, S-E

14.7 Transport in bulk according to Annex II Unknown

of MARPOL 73/78 and the IBC code

15. Regulatory Information

15.1 Safety, health and environmental regulations/legislation for the substance or mixture:

U.S. Federal Regulations: As follows -

CERCLA - Sara Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Flammable (gases, aerosols, liquids, or solids), Acute Toxicity (any route of exposure), Reproductive toxicity, Skin Corrosion
or Irritation, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated exposure)
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No. %

1,2,4 TRIMETHYLBENZENE 95-63-6 10.7

CUMENE 98-82-8 0.49
ETHYL BENZENE 100-41-4 0.49
Toxic Substances Control Act:
All components of this product are either listed on the TSCA Inventory or are exempt.

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:

No TSCA 12(b) components exist in this product.

U.S. State Regulations: As follows -
New Jersey Right-to-Know:

The following materials are non-hazardous, but are among the top five components in this product.

No NJ Right-To-Know components exist in this

product.
Pennsylvania Right-To-Know

The following non-hazardous ingredients are present in the product at greater than 3%.

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No PA Right-To-Know components exist in this product.

CALIFORNIA PROPOSITION 65

WARNING: Cancer and Reproductive Harm -- www.P65Warnings.ca.gov

International Regulations: As follows -

* Canadian DSL:

All chemical ingredients included on inventory (DSL)

15.2 Chemical Safety Assessment:

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other Information

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Reasons for revision

No Information

The information contained herein is, to the best of our knowledge and belief accurate. However,
since the conditions of handling and use are beyond our control, we make no guarantee of results,
and assume no liability for damages incurred by use of this material. It is the responsibility of
the user to comply with all applicable federal, state, and local laws and regulations.

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