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Vidyamandir Classes

Solutions to JEE MAIN HOME PRACTICE TEST -5 | JEE - 2022


PART-A PHYSICS
2 d
d
d1 d 2 3 4d d 25d
1.(C) Apparent depth     3   
1 2 3 4 9 4 36
2 3
21 52
2.(D) Req  1  
31 31
20  31
i A
52
1 1 1
i1 : i2 : i3  : :  7 : 21: 3
3 1 7
21 20  31 21 20 105
i2      8A
31 52 52 13
3.(B) For the system Pi  2muiˆ  mujˆ

As all the impulses are internal, Pi  Pf

Pf  3mu f , where u f is the velocity of the combined mass after inelastic collision

2u ˆ 1 ˆ 5
Thus 3mu f  2muiˆ  mujˆ ; uf  i  j  uf  u
3 3 9

1 2 1 5 5mu 2
Thus final energy of the system   3m  u f   3m  u 2 
2 2 9 6

m1v12 m2v22 1 1 3
Initial energy of the system    mu 2   2m  u 2  mu 2
2 2 2 2 2
Loss in K.E. = [(Initial K.E.) – (Final K.E.)]
3 5 2
Loss  mu 2  mu 2  mu 2
2 6 3
4.(A) The intensity of the wave remain unchanged

B2 B2 B1 B 1
So, c 1    n  
0  B B1 n
E E E B1 c E n
Also,  c and 1  v   n    n
B B1 E1 B v E1 n
5.(D) Unites of the given
Constants

R   JK 1mol 1  ; K   JK 1  ; N A   mol 1 

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Thus, For X  (Thus X is dimensionless)

2 d 
2  2  d 2   2  d 2 2  22
6.(A) I A  m    2   m    md 2    m    m   2d    md 2
5 2 5  2   5  2   5
12
 2  d 2  d   12
2
I0 6
I0  4   m    m     md 2 ;  5 
 5  2   2   5 IA 22 11
5

h p2 h2 h2 9h2 8h2
7.(C) p1   E1  1  E1   E2    E2  E1   8E1
1 2m 2m12 2m 22 2m12 2m12

0 Jr1 0i
8.(A) B1  ; B2 
2 2r2

B1 Jr1 2r2 i r r rr 5  15 3
   2  1 2  1 22  
B2 2 i R i R 10 10 4

9.(B) By Bernoullis theorem & equation of continuity


We get,
1 1
P1  V12  P2  V22 …(i)
2 2

1 1  A2V2  Q
AV …(ii)

Substituting the values, we get Q  1600 2 cm3 / s

10.(A) As (2,4) lies on axis of dipole

2  9  109   iˆ  2 ˆj   1028
E ||  iˆ  2 ˆj 
2 KP
 E  
r3  22  42 3 / 2
11.(D) y1  A sin(t  )  I0  A2 
y2  A sin t ; y3  A sin(t  ) ; y  y1  y2  y3
y  A sin t cos   A cos t sin   A sin t cos   A cos t sin   A sin t
y  2 A sin t cos   A sin t

1
If cos  
2

They y  2 A sin t I  (2 A)2  I  4 A2  I  4I 0


Here I  4 I 0
12.(D) E is parallel to B & V is perpendicular to both. Therefore to path of the particle is a helix with
increasing pitch. Speed of particle of at any time t is
V  Vx2  Vy2  Vz2 ; Here Vz2  V y2  V02

Vx 3 V0 3mV0
V  2V0  Vx  3 V0  t   t
ax qE / m qE

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0 1 0 1
 x4 y3 1 1 7
13.(C) dr  dxiˆ  dy ˆj ;   
F  dr   x  dx  y dy      J
3 2
4 1 3 0 4 3 12
1 0


14.(B)   1.22
D
x 1.22  5500  1010
 ; x  26.84m
4  105  103 10
15.(C) Torque  p  E
fR
16.(A) Cv  (where the degree of freedom and R is the universal gas constant)
2
For A, diatomic molecules, f = 5
For B, diatomic molecule, with vibration, f = 7
5  R 5R 7  R 7R CA 5
CvA   ; CvB    vB 
2 2 2 2 Cv 7

17.(A)  K .E max 
hc
;  K .E.max   1240  1 eV  3eV
  310 

3 1.6 1019  mV 2  m  9.11031 kg  ;


1
V  106 m / s
2
18.(B) Let the velocity of first particle be x
on conserving momentum
m  m  5V  mx 5m 5V
 mV  x   m     mV   
4  4  8  4 4 8
mx 25mV mx 7mV 7V
   mV    x
4 32 4 32 8
19.(A) 25VSD  20MSD
20
1VSD  MSD
25
Least count  1MSD  1VSD
20
 1MSD 
MSD
25
5 1
 MSD  1mm = 0.2 mm = 0.02 cm
25 5
20.(A) Process 1  2  Adiabatic
Process 2  3  Isobaric
Process 3  1  Isochoric
Hence, option A is correct

NUMERICAL VALUE TYPE


21.(15) Loss of gravitational potential energy = Gain in kinetic energy
l 1 l  1  1  ml 2  2
 mg sin30  I 2  mg     
2 2 2 2 2 3 
mgl ml 2 2 6g
    
4 6 4l
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6 gl 60
Velocity of end point  l    15m / s  n  15
4 4

22.(8) V  3x2  2 x (Given)


dV dV dx d (3x 2  2 x )
 a    (V )  (6x  2)(3x2  2x )
dt dx dt dx
Now, put x = 2
We have a  (6  2  2)(3  22  2  2)  80 m / s 2
23.(1)

The tension is the wire will be same in both the cases. Hence elongation will be same i.e., 1mm.
24.(400) Flux ()  NBA
Change in flux = 2NBA
 2 100 105 104
 2 10 7
EMF induced  
t t
1ms
t  0.5ms
2
2  107
EMF   4  104V
0.5  103
 400  106V  400V

25.(15)

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d d
26.(250) We know, induced emf (ε) is |  |  ; iR 
dt dt
Now, d   R idt or  d   R  idt
 Change in magnetic flux = R  area under the current time graph
1 1
  R  10  0.5  100   10  0.5  250 Wb
2 2
l
27.(3) Torque of weight about hinge P is mg  I p  …….(i)
2
  5l  
2
ml 2  ml 2
Now, I p    m   
3  12  2  
5ml 2 3g
Ip  ……….(ii) Solving (i) and (ii) we get   x  3
3 10l
n T
28.(5) f 
2L 
n 0.5
100 
2 L 0.5  102
n4
20
Distance between two successive nodes   5cm
4
hc
29.(5.20)  0   KE max ………(i)

hc 12400
E   6.2eV
 2000
From equation (i)
 KE max  6.2  1  5.2eV

30.(8) Ceq  C so n  8

PART-B CHEMISTRY

1.(B) k uncatalysed  k catalysed


Ea1 Ea 2
AeEa1 / RT1  AeEa 2 / RT2    Ea1  Ea 2  20
T1 T2
Ea 2  20 Ea 2
   2Ea 2  Ea 2  20  Ea 2  20
400 200
Activation energy of the catalysed reaction = 20 kJ/mol
2.(C) (3) is least basic due to both –M and –I effect of NO2 group.
1
pK b  , (3) has highest pK b .
Kb
3.(D) (i) A  BO2 
 AO2  B, rxnG

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(ii) A  CO2   C  AO2 , rxnG


Below 600°C,  rxn G  for both the reaction (i) and (ii) is negative.
4.(B) (I) Electron from 3p can be removed more easily than from 3s, as nucleus shows less
attraction towards 3p electrons than 3s electron. Hence Al has smaller first Ionization enthalpy.
(II) Shielding of 3p is more than 3s
(III) Order of penetration power: s > p > d > f
(IV) Atomic Radius of Al is less than Mg
Hence, It is an incorrect option.
Correct option is (B); (I), (II) and (III)

5.(D)

6.(D) 2rn  n : n is number of waves made by electron.


7.(B) Co(NH3 )5 Cl Cl2
The above complex reacts with 2 equivalents of AgNO3 and doesn’t show geometrical isomerism.
IUPAC = Pentaamminechlorocobalt(III) chloride

8.(C)

  Cl is o/p directing but deactivating group


  CH 3 is activating group and o/p directing
 Activating group will decide the product towards EAS reaction
 Para position is blocked, so only ortho product will be formed.
9.(D) (i) CH4 (g)  2O2 (g) 
 CO2 (g)  2H2O( ), combH  x
3
(ii) CH3OH( )  O2 (g)   CO2 (g)  2H2O( ), combH  y
2
Reversing reaction (ii) and adding it in (i),
1
Hreaction  x  y for CH4  O2 
 CH3OH
2
For x  y  0, y  x
10.(D) A compound which gives a negative test with ninhydrin, it cannot be a protein or amino acid. As it gives
a positive test with benedicts solution. So must be a monosaccharide but not a lipid.

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11.(C)

12.(D)  Pb2 Cl 2  Q


2
350  0.225  200  0.6 
 0.1432   0.22  0.0069
2
  
550  550 
Q  K sp
1
13.(D) Heat of combustion 
stability of alkene
Conjugated diene is more stable than isolated diene
Trans alkene is more stable than cis alkene.
14.(A) KO 2 can act as both oxidizing as well as reducing agent since it has – 0.5 O.S which is between its
highest 0 and lowest O.S  2 ; Thus it can increase as well as decrease its oxidation number.
15.(C) CO 2  Acidic oxide
MgO  Basic oxide
N 2O, NO  Neutral oxide
16.(B) Because of inert pair effect.

17.(D)

18.(D) O 2 (x) has 2 unpaired electrons and O2  2(2  2)  8 B.M.

O2 & O2 , both has 1 unpaired electron.


19.(B) (i) Tb   Xe 6s2 4f 9 ; Tb4   Xe 4f 7
(ii) Yb   Xe6s2 4f 14 ; Yb2  [Xe]4f 14

20.(D) (i) Co(H 2O)6 2 : number of unpaired e  3,   15 B.M.


n  6  2
n  8
(ii)  PtCl2 BrF2
dsp3 hybridization square planar, total three isomers
8 + 3 = 11
NUMERICAL VALUE TYPE
21.(100) Hardness due to CaCO3  103 103  100  100 ppm

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22.(27.10) Molecular formula of histidine is C6 H9 N3O 2


molecular mass = 155
42
% nitrogen by mass  100  27.1
155
10dx
23.(15) Molarity  ( d = density in gm/mL, x = mass% of solute, M0 = molar mass of solute)
M0
10 1.5  49
  7.5M  Normality  Molarity n  factor  7.5  2  15N
98
24.(193) 2H  2e 
 H2  1 mole H2  2mole eΘ
0.01 mole of H2  0.02 mole eΘ
Q I t 0.02  96500
0.02   ; t  193sec
F F 10
25.(2.63) Tf  0.3C ; Tf  i K f m
w 1000 0.3  58.5 900 157.95
 0.3  2  3    w   2.63g
58.5 900 6  1000 60
26. (10) 2  k   NO   O 2   3.2  10 5 ; k  10sec 1 M 2
2

27.(7)

28.(3) HgCl2 ,C 2 H 2 and CO 2 are linear without any lone pair.



Whereas ICl2 ,XeF2 ,I3 , I  CN 2  are linear but all have lone pair on central atom.

29.(–3.47) f G  RT ln K eq

16.628  2  1000  2.303  8.314  500 log K P

16.628  2 1000
log K P    3.47
2.303  8.314  500

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30.(2)

No. of stereoisomer for P will be 2.

PART-C MATHEMATICS
3
3 (ax  bx3  cx  k ) dx
5
1.(D)
3
 ax6 bx 4 cx 2 
    kx 
 6 4 2  3
a  36 b  34 c  32 a  36 b  34 c  32
    k (3)     k (3)
6 4 3 6 4 3
=6k
i.e., Integral depends upon k.
1  2 sin x
2.(D) lim f ( x)  lim
x

x
   4x
4 4

 2 cos x 1
 lim  (by L’ Hospital’s rule)
x
 4 4
4

  1
Since f (x) is continuous at x  .  lim f ( x)  f     a
4  4 4
x
4
3.(C) Let z  x  i y
z  25 ( x  25)  iy
 5  5  ( x  25)  iy  5 ( x  1)  iy
z 1 ( x  1)  iy

 ( x  25)2  y 2  5 ( x  1)2  y 2
On squaring both sides, we get


( x  25) 2  y 2  25  x  1  y 2
2
  x2  50x  625  y 2  25x2  50x  25  25 y 2

 24x2  24 y 2  600  x2  y 2  25

 x2  y 2  5 [ | z | ( x2  y 2 )]  | z | 5
1 1 1  1 1 
 3  9  27  ....    
3  11/ 3 
4.(B) 91/ 3
9 1/ 9
9 1/ 27
 ....   (9) 9  91/ 2 = 3
1
5.(C) f '( x) 
(1  x 2 )3 / 2

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dx
On integrating both sides, f ( x)   (1  x2 )3 / 2  c
sec2 
Put x  tan   dx  sec2  d   f ( x)   sec3  d   c   cos  d   c
x
 f ( x)  sin   c  f ( x)  c  f (0)  0  c  c  0
1  x2
x 1
 f ( x)   f (1) 
1 x 2 2

x(4 x3  2 x)
 x4  x2  1
x 1
4
2 x  x  ( x  x  1)
4 2 4 2
2 x  x 1 4 2
6.(D)  dx   dx   dx
  x2
1/ 2
x2 x4  x2  1 x 2
x  x 1
4 2

d  x4  x2  1  x4  x2  1
 

dx  x
 dx 
 x
c
 
7.(B) Let the equations of the required tangent be x  y  a, then length of the perpendicular from centre
= radius
2  2  a
  2  a  2 2, ( , a  0) . Hence, the equation of tangent is x  y  2 2
2
8.(B) Let p : It rains, q : I shall go to school
Thus, we have p  q
Its negation is ~ ( p  q) ie, p  ~ q
ie, It rains and I shall not go to school.
9.(D) Standard deviation
2
18  18 
 ( x j  8) 

2
 ( x j  8) 
 45  9 
2
45 1 81 9 3
j 1 j 1
          
n  n  18  18  18 4 36 6 2
 
 
10.(C) sin 12 sin 48 sin 54

1 1  5  1 1   5  1 1
 cos36  cos60 cos36     
2 2 4 2  4  8

11.(A) Let f ( x)  ax2  bx  c


f (1)  f (1)  a bc  a bc  b  0

f ( x)  ax2  c  f '( x)  2ax f '(a1 )  2aa1 , f '(a2 )  2aa2 ,


f '(a3 )  2aa3
Now assume
2 f '(a2 )  f '(a1 )  f '( a3 )
 2.2aa2  2aa1  2aa3  2a2  a1  a3  a1 , a2 , a3 are in AP.
 f '(a1 ), f '(a2 ), f '(a3 ) are in AP.

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5!
12.(D) Total number formed by using given 5 digits 
2!
For number greater than 40000, digit 2 cannot come at first place. Hence, numbers formed in which 2 is
4!
at the first place 
2!
5! 4!
Hence, total numbers formed greater than 40000    60  12  48
2! 2!
dV
13.(A) Given,  100 cm3 / min
dt
d 4 3 2 dr 300  dr  300
  r   100   3r       1cm / min
dt  3  dt 4  ( r  5)
dt 4  3  25
14.(B) Let a and b the intercepts made by the straight line on the axes. Then, according to question
ab 2 2
ab   1
2 a b
x y
On comparing with   1, we get  x  2, y2
a b
Hence, straight lines passes through the point (2, 2).
b2 3 1
15.(A) Eccentricity of ellipse  1  2
 1 
a 4 2

b2 b2
 Eccentricity of hyperbola = 2  1 2  4 1  192  b 2
64 64
16.(D) Given, x3  6 x  9  0
 ( x  3)( x2  3x  3)  0  x  3 or x2  3 x  3  0
Now, Discriminant, D  9  4  3  3 imaginary
Hence, real roots of the given equation is –3.
17.(D) Total number of cards = 52
13 1
Probability of getting spade  
52 4
1 3 3 3 9
Probability of not getting spade  1    Required probability   
4 4 4 4 16
x  2 y 1 z  2
18.(A) Given line is    k (say)
3 4 12
Any point on the lines is (3k  2, 4k  1, 12k  2)
This point lies on the plane x y z 5
 3k  2  (4k  1)  12k  2  5  11k  0  k  0
 Intersection point (2,  1, 2).
 Distance, between points (2,  1, 2) and (1,  5,  10)

 (1  2)2  (5  1)2  (10  2)2  9  16  144  13


 sin 4 x
19.(D) Let I 2 0 sin 4 x  cos4 xdx

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/ 2 sin 4 x
4 0 sin 4 x  cos 4 x
dx …..(i)

/ 2 cos4 x
 I 4 0
sin 4 x  cos4 x
dx …..(ii)

On adding equations (i) and (ii), we get


/ 2
2I  4 0 1  dx  2  I 

3 1 1  5 5 5 
20.(D) B  adj ( A)   6 2 3 , Therefore, adj ( B)   0 10 15

 4 3 2 10 5 0 
5 5 5  1 1 1 
Now, | adj B |   0 10 15  625 and | C | 125 | A | 125 0 2 3  625

10 5 0   2 5 0 
| adj ( B ) | 625
  1
|C | 625
NUMERICAL VALUE TYPE

6 2 3 18  10  6 22
21.(22) Projection  12  (1)  [5  0]  [1  3]   
7 7 7 7 7
 7  22
22.(120) (1  x  x2  x3 )6  (1  x)6 (1  x2 )6

  6
C0 6 C1 x 6 C2 x 2 6 C3 x3 6 C4 x 4 6 C5 x5 6 C6 x 6 
  6
C0 6 C1 x 2 6 C2 x 4 6 C3 x6 6 C4 x8 6 C5 x10 6 C6 x12 
 Coefficient of x14 in (1  x  x2  x3 )6

 6C2  6C6  6C4  6C5  6C6  6C4  15  90  15  120


dy 1 x2
23.(2) Given,  (1  x)(1  y)  dy  (1  x) dx  log(1  y )  x  c
dx 1 y 2
(1 x ) 2
1 ( x 2  2 x  1)
At y(1)  0  c  log(1  y )   y e 2 1
2 2
Required answer = 2

24.(0) Let f ( x)  3  x  x2
Now, D  12  4(3)  11  0
Here, coefficient of x2  0  f ( x)  0
Thus, LHS of the given equation is always positive whereas the RHS is always less than zero.
Hence, the given equation has no solution.
25.(4) Let angle between b and c is .
15
Given, b  c  15  b c sin   15  sin  
4

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15 1
 cos   1  sin 2   1  
16 4
b  2c   a
2 2 2
 (b  2 c)  2 ( a)2  b  4 c  4b  c   2 a

 16  4 1  4(| b | | c | cos )  2  12
 20  4   2    4  || 4
2 64
26.(1) Here z 2  z  z  5
………(i)
z

 z2  z  z 2  z ( z 2  z is purely real number)


  z  z   z  z  1  0
 1
 z  z as z  z  1 is not possible  x 
 2
 zx
64
 Equation (i), given as x 2  x  x 
2
5
0
x
 x  2
 only one solution

e x / a  eb / x
b
27.(0) I  dx
a
x
b y
x b e y  ea
a
 ab 
Put      2  dy
a y b
ab  y 
y
eb / x  e x / a
b
 dx    2I  0  I  0
a
x
28.(8) y 2  ax
y x2

 x  2 2  ax  0
x2  x  4  a   4  0
D0
a8

29.(5) PS  ePM  a  (5,  ) , then b  5


30.(6) sin x  sin y  sin( x  y) Y

 x y x y
 sin   sin sin  0
 2  2 2
X
 x  y  2h1 , x  2h2  or y  2h3  , h1 , h2 , h3  Z

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1 1  1 1
Only six solutions are possible  1,0  , 0  1 , ,  ,  , 
2 2  2 2

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