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Solutions to JEE Main - 3 | JEE-2023 (Gen 1 & 2)

PHYSICS
SECTION-1
1.(B) For stone to hit the bird again
horizontal speed of stone = horizontal speed of bird
4
u cos37  4  u  4  u  5 m/s
5
2.(A) F.B.D at hill top
mg  N  mar
mv 2
mg  0 
R
mv 2
mg  … (1)
R
F.B.D at valley bottom
N  mg  mar
m(2v )2
N  mg 
R
4mv 2
N  mg  … (2)
R
From (1) and (2)
N  mg  4mg  N  5mg
 N  5  60  10  3000 Newton

3.(C) For total acceleration of particle to become perpendicular to velocity vector, at should be 0

at  R  0 | Also   4  2t
(4  2t ) R  0
t  2sec
dv
Also, at  (4  2t ) R ;  (4  2t ) R
dt
dv  (4  2t ) Rdt
Integrating both sides
v 2

 dv  R  (4  2t )dt
0 0

v  R[4t  t 2 ]02
v  R (8  4) | also R  2
 24; v  8 m/s

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4.(B) For ball A

u 2A sin 2
R | Given   37
g

u 2A  2sin 37 cos37

R
g

24 u 2A
R … (1)
25 g
For ball B

u B2 sin 2
R |   45
g

u B2 sin 90

g

u B2
R … (2)
g
(1)  (2)

24 u 2A uA 5 5 6
1 ;  
25 u B2 uB 2 6 12

5.(D) Ball during the throw

From vertical direction, time of flight (T) will be

1
S  ut  at 2
2
1 2u
O  uT  ( g )T 2 ; T
2 g

Displacement in horizontal direction

1 1
S  ut  at 2  a xT 2
2 2
Also, boy should have same displacement to catch the ball
1
vbT  axT 2 | vb is speed of boy
2
1 1 a x  2u a x u
vb  axT ; vb  
2 2 g g

2  30
Putting values vb   6 m/s
10

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6.(A) From graph given,

Horizontal component of initial speed (u x )  40 m/s
(as minimum speed is at top point of projectile)
Initial speed (u )  50 m/s (at t  0)
u x  u cos 
40  50cos     37
Vertical component u y  u sin 37
u y  30 m/s
Speed in vertical direction after 80 m displacement downward
v 2y  u 2y  2 g (80)

 (30) 2  20  80  2500 ; v y  50 m/s

Final velocity before hitting ground

vy 5 5
tan    ;   tan 1
ux 4 4

7.(C) In relative frame of monkey

Bullet will appear to come straight as relative acceleration is 0.

400 4
Time to hit (t )   sec
500 5
In ground frame, monkey will move downward by S (acceleration g downward)
2
1 1 1 1 4
s  ut  at 2  0  t  (  g )t 2   gt 2    10     3.2m
2 2 2 2 5
Height from ground h  10  3.2  6.8m

u2 u2
8.(B) On earth, Rmax   40  ; u 2  40 g
g g
On moon, for maximum height u should be vertically upwards
g
v 2  u 2  2as | a
6
g 6u 2 3  40 g
0  u 2  2   H max ; H max    120m
6 2g g

20  8 12
9.(D) a   2 m/s 2
1 2  3 6
20  N  3a
 N  20  6  14 Newton

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10.(D) To pass through original position acceleration

should be antiparallel to initial velocity
u y ay
tan   
u x ax
3 b
 ; b  9 3
4 12 3

11.(A) At top most point ball’s speed v will be v  u cos 

v2 v2
Radius of curvature ( R )  
a g
u 2 cos 2  100 16
R    6.4 m
g 10 25

12.(C) Solving for projectile

Range = velocity along horizontal × time of flight
10  v  0.5
v  20 m/s

mv 2 0.5  (20)2
Fcentripetal    500 N
R 0.4

13.(D)

F.B.D of mass m
Fnet  ma
mg  N  mg
N 0
14.(B) Maximum value of friction
from ground  1 (ma  mb ) g 1  0.6
 0.6(3  5)10  48 N
Maximum value of friction between
blocks   2 ma g  0.2  3  10  2  0.2
6N
F.B.D. of block A

Fnet  3  a  6  3a  a  2 m /s 2
F.B.D. of block B

Fnet  5  2  Fext  48  6  5  2
Fext  54  10  64 N

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15.(A) Consider system of 20 blocks

M  20  5  100 kg
F.B.D
F  Mg  Ma
1500  1000  100a
500  100a  a  5 m/s 2 (upwards)
Now, consider 18th, 19th and 20th block together
T  mg  ma
T  150  15(5)
T  150  75  225 N

16.(B) Along y
2u sin 
Time of flight of ball (T ) 
g cos 
Along x
Ball will have only relative velocity of u cos  w.r.t block
Separation in time T  u cos   T
u cos   2u sin 

g cos 
 108 m

17.(C) For case I, using system’s approach

m2 g  mg  m1 g  ( m1  m2  m) a
(m2  m  m1 ) g g

(m1  m2  m) 4
 m2  m1  3  1
    4m2  4m1  12  m1  m2  3
 m1  m2  3  4
3m2  5m1  9 … (1)
Similarly, for Case II
(m1  m  m2 ) g  (m1  m2  m)a
(m1  m  m2 ) g
g
(m1  m2  m) 8
8m1  8m2  24  m1  m2  3
7 m1  9m2  21 … (2)
From (1) and (2)
m2  7 and m1  6
m2 7

m1 6

18.(D) P  Pf  Pi  5  5  5(10)  25  50  75Ns

P 75
Favg    750 N
t 0.1

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19.(A) Fnet  ma
f r  manet

mg  m at 2  ar2
2
2 2  v2 
 g  at2  
R
 
2
 400 
(0.8  10) 2  at2   
 100 
at2  64  16  48
at  4 3 m/s 2

20.(B) In elevator’s frame

(relative acceleration of all will be 0 w.r.t elevator)

In t  0.2sec
Vertical distance covered by A( y A )  0.2  5  1 m (upward)
Vertical distance covered by B ( y B )  0.2  5sin 53  0.8 m (downward)
Height of elevator  y A  y B  1  0.8  1.8
Height of boy  yB  0.8
height of boy 0.8 4
 
height of elevator 1.8 9

SECTION-2
2
u sin 2
21.(3) R  80 3
g
800 3 3
sin 2  2
   30 or 60° (complementary angles)
(40) 2
2
2u sin   t   sin 60  2
Also T ; Thus  1     3
g  t2   sin 30 
a1  a2
22.(4) ap 
2
0  a2
2
2
 a2  4 m/s 2

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23.(5) On m2
T  m2 g
On m1
3
Perpendicular to incline N  m1 g cos53  m1 g
5
Parallel to incline m1 g sin 53  T  N
4 3 4 0.6  3
m1 g  m2 g   m1 g ; m1  m2  m1
5 5 5 5
2.2m1
 2.2 ; m1  5 kg
5
24.(5) Apply Fnet  ma (on monkey)
T  mg  ma … (1)
As 4T can be at max 300 N
Tmax can be 75 N
Thus from (1)
Tmax  mg
amax 
m
75  50

5
 5 m/s 2

25.(4) From equilibrium situation spring force ( Fs )  mg

Fs  36 N

At the instant string is cut T becomes zero, but spring force remains same
Fs  mg  ma
36  60  6a  6a  96
a  16 m/s 2
x 2  16  x  4

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Chemistry

SECTION-1
1.(C) SO32 , SO 42 and NH 4 3
are sp hybridised.
Θ  Θ
2.(B) N3 : NNN

I3 :

C2 H 2 : HC  CH

3.(B) Energy of MO in O 2

1s  1s   2s  2s   2p z  2px  2py

4.(D) In F2 molecule, energy of 2pz is less than 2px and  2py .

5.(C) KCN has ionic linkage between K  and CN  .

It has covalent linkage between C and N i.e. C  N 

6.(C)

7.(B) (a) Correct order  Ca 2   K   Cl   S 2  (Ionization energy).

For isoelectronic species (I.E.  Zeff . )
(b) Correct order  C  N  F  O (2nd I.E.).
Second electron removal from O requires more energy as it acquires stable 2s 2 2p3
configuration after removal of one electron.
(c) Correct order  B  Al  Ga  In  Tl
(d) Correct order  Na   Li   Mg 2  Al3  Be 2 (Ionic radius)
Ionic radius depends on Z eff and number of shells.

8.(D) In Na  , 11 proton are attracting 10 electrons.

Increasing order of size  Na   F  O 2  N 3

9.(B) Li < Be < B < C (first ionisation energy)

(i) Bond angle of NH3  107
PH3  AsH 3
(ii) On moving left to right in a period ionisation energy increases. Li < Be < B < C but the
ionisation potential of Be is higher than that of B because Be has fulfilled configuration.
(iii) Metallic character increases hence the basic character of oxide increases.
(iv) In a group from top to the bottom, the number of the shell increases hence radius increases.

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10.(C) Atomic number of (B)  Z and is a noble gas

Atomic number of (A)  Z  1 (i.e., is a Halogen)
Atomic number (C)  Z  1 (i.e., is a alkali metal)
Atomic number of (D)  Z  2 (i.e., alkaline earth metal)
Hence, element (A) must be a Halogen, so has highest electron affinity among the given species. (C)
is an alkali metal and (D) is an alkaline earth metal.

11.(D)  Cal  4.8  1010 e.s.u  108 cm  4.8  10 18 esu cm  4.8 D
experimental 1.2
Hence % ionic character   100   100  25%
calculated 4.8

12.(B) SF6 has 12, 90° Bond Angles.

13.(A)   n(n  2)  2.84  n2

Electronic configuration of Ni 2  1s 2 2s 2 2p 6 3s 2 3p6 3d8 having two unpaired electrons

Electronic configuration of Ti3  1s 2 2s2 2p6 3s 2 3p6 3d1 only one unpaired electrons
Electronic configuration of Cr 2  1s 2 2s 2 2p6 3s 2 3p6 3d 4 having four unpaired electrons
Electronic configuration of Co 2  1s 2 2s 2 2p 6 3s 2 3p6 3d 7 having three unpaired electrons

x 8x
14.(B) Change in kinetic energy is x  
9 9
For Bohr model of atom
The kinetic energy in a state is equal to half of the potential energy in magnitude.
8x 16x
 Potential energy = 2 Kinetic energy  2  
9 9
nh h
15.(A) 
2 
n2
n2 22
r  a0   a0   2a 0
z 2
n  2r    r   2a 0

16.(B)   0  eV0 …… (1)

  work function
0  threshold energy
h  h 0  eV0
h h0
V0   …… (2)
e e
  frequency
 0  threshold frequency
Comparing equation (2) with straight line equation :
y  mx  c
h
Slope of  0 vs  curve 
e

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17.(C) The maximum probability of finding electron in the d xy orbital lies at the angle of 45° from the x-axis and y-
axis.

hC
18.(A) E  NA 

6  1023  6.6  1034  3  108
240  103     4.95  107 m

 2a 
19.(D) Radial nodes for 2s orbital is at distance  0 
 Z 
 2a 0  2
For (A) 
Z  is least Z  3 for Li
 
 2a 0  
For (B) 
Z  is intermediate Z  2 for He
 
 2a 0 
For (C)   is maximum Z  1 for H
 Z 
A  Li 2  , B  He , C  H
20.(A) For polar molecule dipole moment,  depends upon geometry. Symmetrical molecule is non-polar even
through it contains polar bonds. Bond dipole moment of C  H and C  Cl bond reinforce on one another.
In CH3Cl the resultant C  H and C  Cl dipoles oppose the resultant of two C  Cl dipoles, while in
CH 2 Cl2 the resultant of C  H dipoles add to resultant of two C  Cl. In case of CH3Cl the resultant of two
C  H dipoles add to the resultant of C  H and C  Cl dipoles. Thus dipole moment of CH3Cl is highest
among the given compound. CCl 4 becomes symmetrical and its reduces to zero.

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SECTION-2
21.(3) Number of orbitals in 1 period = 1. Maximum number of elements  1  3  3
st

12 mg
22.(1)  0.5  103 moles
24g
Energy per atom  7.646  15.035  22.68eV
22.68  96.48  21.88  10 2 kJ / mol
E (needed) 21.88  102  0.5  103
10.94  10 1  1.094 kJ / mol

23.(8) Mg  1s 2 2s 2 2p6 3s 2

Total 8e

24.(3) CaC2  Ca 2  C22

C 22   C  C 

25.(2) O 2 and CsO 2 are paramagnetic.

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Mathematics

SECTION-1

(cot )( sin )

1.(A)  (sin  )(sin  )  (  cos )(  cos )
(cos  )
1  sin 2   cos 2   0

x sin t
2.(C) xy  2sin t cos t 
y cos t
x 2  2sin 2 t y 2  2cos 2 t
x2  y2  2

3.(B) 
x2  x  1  0 . . .  ,  2 
z  3 3  3i
z 6

4.(A) zz 0
5  4i sin  5  4i sin  30
   0  30  16 sin 2   0  sin 2   (Not possible)
3  2i sin  3  2i sin  16

2sin 2 x  1 cos x (1  2sin x)

5.(B) 
cos x 1  sin x
2sin 2 x  2sin 3 x  1  sin x  cos 2 x  2sin x cos 2 x
cos x(1  sin x)
2sin 2 x  2sin 3 x  1  sin x  cos 2 x  2sin x  2sin 3 x
cos x(1  sin x)
sin 2 x  sin x
 tan x
cos x(1  sin x)

sin 69º  sin 21º 2sin 24º cos 45º

6.(D)   2
sin 90ºsin 24º sin 24º
  
i 15 i   15
7.(C) z e 3 e  3  ei 5  e i 5   cos 5  i sin 5    cos 5  i sin 5   2i sin 5  0

8.(B) 64  x  iy   212  ei  312

 212  e4 i  212
 y  0 , x  64
2 2
 1 1  2 2
     4   16
2
9.(C)    ;
 cos 60º sin 30º   1 1 

1 sin 50º
10.(C) 
cos10º cos10º cos 40º
cos 40º  sin 50º
0
cos10º cos 40º

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11.(C) z 2  z    0 . . . .(i)
2
 z  2  z
z
2
 z  z    0
4 2
 2
    0   z 2  2 z  4  0 . . . .(ii)
z z
From (i) and (ii)
 1  2 2
    4
 2 4
1  3i
12.(D) x 2  x  1  0  x   ,   2
2
30 90
  2
13.(C) | z1  z2 |max  13  9  4  26

z  z 
14.(B)   | z |2  z   z   2  (| z |2  z   z   2 )  | z |2   2    2
z  z 

15.(C) 49sin  cos   24  7 cos 2   24  7sin 2   242 cos  sin 

2sin  cos 
(7 2  242 )  24  7(cos 2)
2
(7 2  242 )sin 2  2  24  7cos 2
2
7 4  (24) 4  2  7 2  (24) 2  22  242  7 2
Max value 
2
7 2  242 625
Max value  
2 2

16.(D) 4sin  cos   2cos   2 3 sin   3  0

2cos (2sin   1)  3(2sin   1)  0
1 3
sin   , cos  
2 2
 5 11 17 
, , Sum 
6 6 6 6

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17.(B) sin 8  sin 2  sin16  sin 2

1
sin 8  0 cos8 
2
    5 
  0, , , , 
 8 4 24 24 

A B  A B
18.(A)   45º  tan     1
2 2 2 2
A B
tan  tan
 2 2 1
A B
1  tan tan
2 2
A B A B
 1  tan  tan  tan tan  2
2 2 2 2
 A  B
  1  tan 1  tan   2
 2  2

19.(D) x 2  y 2  x  iy  5  5i
y 5

 x2  5  5  x  x 2  5  25  x 2  10 x  x  2
z 3

20.(B) z  
 ( z  z 2  2)(2  z  z 2 )  (  2  2)(2    2 )
2
 2    2
2
 2i 3  7

SECTION-2

21.(9) 2cos10º  sin(90º 10º )  sin(1080º 80º )  sin(10800º 800º )

2cos10º  cos10º  sin 80º  sin 800º
3cos10º  cos10º  cos10º  cos10º

22.(9) f ( x)  11  8sin x  2  2sin 2 x

f ( x)  2sin 2 x  8sin x  9
f ( x)  2(sin x  2)2  1
( f ( x )) max  19, ( f ( x )) min  3
M  8 19  8 27
  9
m 3 3
sin 6 cos5
23.(1) cos 0  cos 2  cos 4  cos 6  cos8  cos10 
sin 
n  6, m  5
6  5 1

Solutions | Page 14 JEE Main-3 | JEE 2023 (Gen 1 & 2)

 Vidyamandir Classes: Innovating For Your Success

1
24.(2) Let (1) 5  1, ,  2 , 3 ,  4
1     2  3   4  0
1     2  3   4 and  5  1
1
   4 and   1

1
Now 4log 4  4   4  4log 4 2 4  4log 4 2  4  4  log 4 2  4  log 2 2  2
2
25.(5) Note that   1
i are possible value of z1
i are possible value of z2
(i  1, 2, 3)
3 i
 
2 2

i
e 6


i
2  e 3


i
3  e 2


2i
4  e 3

5
i
5  e 6

2  5 7  4
So, z1Oz2 can be  , , , ,
3 6 6 3

Solutions | Page 15 JEE Main-3 | JEE 2023 (Gen 1 & 2)