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IJE - Volume 29 - Issue 10 - Pages 1469-1477
IJE - Volume 29 - Issue 10 - Pages 1469-1477
IJE - Volume 29 - Issue 10 - Pages 1469-1477
PAPER INFO A B S T R A C T
Paper history: The two-fluid flow is produced by the combined effects of electroosmotic force in a conducting liquid
Received 29 May 2016 and pressure gradient force in a non-conducting liquid. The Poisson-Boltzmann and Navier-Stokes
Received in revised form 17 July 2016 equations are solved analytically; and the effects of governing parameters are examined. Poiseuille
Accepted 25 August 2016
number increases with increasing the parameters involved. In the absence of pressure gradient, the two
fluids demonstrate plug-like velocity profiles. The results reveal that the two-fluid electroosmotic
Keywords: pumping flow rate is feasible for a relatively small interface zeta potential; or large wall zeta potential
Electroosmosis and electrokinetic radius. For particular values of the governing parameters, the flow rate approaches a
Pressure-gradient specific value as the electrokinetic radius tends to infinity. A back flow (a negative value of the
Two-fluid stratified Flow resultant flow rate) occurs for sufficiently small values of the wall zeta potential or sufficiently large
Exact Solution values of the interface zeta potential (even in the case of pressure-assisted flow). Zero-value flow rates
may also be attained.
doi: 10.5829/idosi.ije.2016.29.10a.18
NOMENCLATURE
dp dz pressure gradient [Pa/m]
e electron charge [C] z axial coordinate [m]
E axial electrical field strength [V/m] Z Dimensionless wall zeta potential
f friction factor Z0 dimensionless interface zeta potential
I x modified Bessel function of the first kind of order Valence of ionic species
K x modified Bessel function of the second kind of order Greek symbols
kB Boltzmann constant [J/K] liquid dynamic viscosity [kg/m.s]
Please cite this article as: A. Jabari Moghadam, Two-fluid Electrokinetic Flow in a Circular Microchannel, International Journal of Engineering
(IJE), TRANSACTIONS A: Basics Vol. 29, No. 10, (October 2016) 1469-1477
A. Jabari Moghadam / IJE TRANSACTIONS A: Basics Vol. 29, No. 10, (October 2016) 1469-1477 1470
kPa, respectively; but depends largely on geometrical as is a non-conducting liquid and the outer fluid is a
well as electrical properties. In order to drive low EO conducting liquid. Electric double layers form at the
mobility liquids and also avoid the aforementioned wall as well as at the liquid-liquid interface, which are
problems, Brask et al. [26] and Watanabe et al. [25], in contact with the high EO mobility liquid. The zeta
independently, proposed the idea of using high EO potential at the wall and at the interface are and 0 ,
mobility liquids as driving mechanism to drag another respectively. The electroosmosis body force (applied on
fluid. The flow of two immiscible fluids was modeled the liquid 1) and the pressure-gradient body force
by Ngoma and Erchiqui [27] in a parallel-plate (applied on the liquid 2) are along the z-direction.
microchannel; and the effects of pressure gradient and
electroosmosis were studied. Gao et al. [28] studied 2. 1. Potential Field The electric potential
two-fluid EOF in a rectangular microchannel, and distribution for a symmetric electrolyte due to the
examine the effects of various variables on the flow presence of EDL is determined by the Poisson-
field. Analytic solutions of transient electroosmotic and Boltzmann equation [34, 35]:
pressure-driven flow of two-layer fluids was obtained
by Su et al. [29] and Gao et al. [30] in slit and d 2 1 d 2en 0 e
sinh (1)
rectangular microchannels, respectively. Stiles et al. dr 2 r dr k BT
[31] proposed a simple method to focus the sample
stream by using either a single suction pump or where, , , e , n0 , , k B , and T are the electrical
capillary pumping effect. The focused stream width was potential, the valence, the electron charge, the bulk ion
controlled by varying the relative resistances of the side concentration, the electric permittivity of the electrolyte,
and inlet channel flows. Fu at al. [32] presented the Boltzmann constant, and the absolute temperature,
experimental and numerical results electrokinetic flow respectively. The boundary conditions are:
injection. By applying different voltages at different
parts of the channel, the sample fluid can be directed r (2a)
into a specific outlet channel. An analytical model was
presented by Afonso at al. [33] to describe a two-fluid r 0 0 (2b)
electroosmotic flow of Newtonian and viscoelastic
fluids in a planar microchannel. Introducing the following dimensionless variables:
While the previous studies consider the flow in
r e
microtubes under various conditions, there is a distinct R , (3)
lack of discussion on the hydrodynamic behavior of the k BT
combined electroosmotic and pressure-driven flow in and under the Debye-Huckel approximation
e k BT , we write Equation (1) in dimensionless
circular microchannels. This paper presents an analytic
solution of two-fluid EOF in a circular microchannel
which is driven by electroosmosis and pressure gradient form as follows:
effects; the surface charge at the liquid-liquid interface
d 2 1 d
is also taken into account. This EOF pump consists of 2 (4)
two immiscible liquids: a high EO mobility or dR 2 R dR
conducting liquid near the channel wall and a low EO in which, is the electrokinetic radius (the length
mobility or non-conducting liquid around the channel scale ratio); is the Debye-Huckel parameter defined
centerline. The liquid-liquid interface has excess surface as:
charge density. The applied external electric field
12
interacts with net charges within the double layers (at 22e 2 n 0
the wall and at the interface) and creates an (5)
electroosmotic body force on the bulk conducting k BT
liquid; a pressure gradient may also be applied across
the non-conducting liquid. The non-conducting liquid is
delivered by the applied pressure gradient force as well
as the interfacial viscous force of the conducting liquid
driven by electroosmosis. The resultant body force
drives the two-liquid field whose characteristics depend
on the relative intensity of each body force.
The boundary conditions (2) in dimensionless form are: where, L is the distance between the two electrodes,
R 1 Z (6a) is the body force ratio, U PD and U HS are the pressure-
driven and Helmholtz-Smoluchowski reference
R R0 Z 0 (6b) velocities, respectively, expressed by:
It is noted that 0 R 0 1 . Solution of (4) subjected to 2 dp k BTE z
U PD ; U HS (14)
(6) is: 42 dz e 1
K 0 R Z 0 I 0 x Z I 0 R 0 I 0 R Z 0 K 0 Z K 0 R 0
R (7) Then, Equations (8)-(10) become:
K 0 R0 I 0 K 0 I 0 R0
d 2V 1 1 dV 1
It should be noted that the electric potential for 2 0 (15)
dR 2 R dR
0 R R 0 is zero; while it is specified by Equation (7)
d 2V 2 1 dV 2
for R 0 R 1 . 4 0 (16)
dR 2 R dR
satisfied. They are the continuities of velocity and shear One the flow field is determined, the Poiseuille number
stress which are represented as: Po , the non-dimensional volumetric flow rate Q ,
V z 1 V z 2 and the liquid-2 flow rate ratio q can be obtained by
V z 1 V z 2 s (10) the following formula:
1 r E
z ei
r at r 0
2
Po f .Re 2W R 1 (21)
in which, the interface charge density, , is calculated s
ei
1 R0
from:
Q Q1 Q 2 RV dR RV dR
R0
1
0
2 (22)
eis r 0 in dimensionless form eis R R0 (11) q Q2 Q (23)
r R
HS
Re 1U HS 1 and
(7) evaluated at R R 0 : rz
U V1 R . The above quantities
1 HS
reference quantities:
V z1 Vz2 Z R 02 R4
V1
U HS
, V2
U HS
Q 21 Z 0 0 1 221
2 2 4
(13) Nume .
(25)
Ez L U PD
E ,
U HS K 0 R0 I 0 K 0 I 0 R0
1473 A. Jabari Moghadam / IJE TRANSACTIONS A: Basics Vol. 29, No. 10, (October 2016) 1469-1477
Nume . R 0 K 1 R 0 Z I 0 R 0 Z 0 I 0
R 0 I 1 R 0 Z K 0 R 0 Z 0 K 0
(26)
I 1 Z 0 K 0 Z K 0 R 0
K 1 Z 0 I 0 Z I 0 R 0
q
R 02
4Q
2 Z Z 0 R 02 1 421 ln R 0 (27)
(a)
(e) (f)
Figure 6. Variations of volumetric flow rate with (a) (b)
Z (c) Z 0 (d) R0 (e) 21 and (f)
Interestingly, in this case, there are two values of R 0 At some special values of Z and Z 0 where Q 0 , the
which produce the same flow rate (Figure 6d). Figures q curves demonstrate singularities due to diminishing
6e and 6f show that increasing 21 and cause the flow the denominator of Equation (23).
rate to increase. Higher 21 means relatively lower
viscosity and so higher velocity of liquid 1; higher
means relatively higher velocity of liquid 2. 4. CONCLUSIONS
Effects of parameters involved in liquid-2 flow rate
ratio are illustrated in Figure 7. The non-conducting Analytic solutions of linear Poisson-Boltzmann and
liquid is slightly affected by and Z . Figure 7c shows Navier-Stokes equations are obtained in a circular
that Z 0 has descending influence on q , because the microchannel, considering the electroosmosis-driven
force and the pressure-driven force as body forces in a
interface free charges induce a resistance to the flow and conducting and non-conducting incompressible fluids,
cause a smaller flow rate of the non-conducting liquid. respectively. The flow behavior depends on the
For some special value of Z 0 , q will be zero; and coupling effect between the two liquids. The external
beyond that particular Z 0 , a reversing flow will be electric intensity interacts with the free charges at the
observed. As shown in Figure 7d, the proportion of non- liquid-liquid interface to generate a surface force. Upon
conducting liquid is obviously increased with increasing the application of the electric field, the flow is activated
in regions close to the channel wall and the interface.
R 0 . When 21 increases, the relative importance of
The results of the current research are summarized
non-conducting liquid viscosity increases (or below:
conducting liquid viscosity decreases); as liquids 1 and I. Larger values of electrokinetic radius
2 are driven by electroosmosis and pressure-gradient, correspond to smaller values of Debye length
respectively, the combined effect is to enhance the and higher velocity gradients near the wall; this
liquid-2 flow rate slightly (Figure 7e). Liquid 2 is leads to larger electroosmotic forces.
directly influenced by , and its flow rate increases II. The interaction between the interface free
with increasing the body force ratio. charges and the external electric field produces
The volumetric flow rate may be negative for a force acting in the opposite direction to the
sufficiently small values of Z or sufficiently large electroosmotic body force in the EDL.
values of Z 0 (Figure 8). III. A steeper velocity gradient is observed in the
conducting liquid for higher viscosity ratio.
IV. An increase in the body force ratio results in
increasing the flow velocity, and also curving
the non-conducting fluid velocity profile and
inclining the conducting fluid velocity profile.
V. When body force ratio is zero, both liquids
attain plug-like velocity profiles.
(a) (b)
(a) (b)
(c) (d)
(c) (d)
(e) (f) Figure 8. Variations of volumetric flow rate with (a) Z and
Figure 7. Variations of the liquid-2 flow rate ratio with (a) (b) Z 0 , and variations of the liquid-2 flow rate ratio with (c) Z
(b) Z (c) Z 0 (d) R0 (e) 21 and (f) and (d) Z 0
A. Jabari Moghadam / IJE TRANSACTIONS A: Basics Vol. 29, No. 10, (October 2016) 1469-1477 1476
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A. Jabari Moghadam
Paper history:
Received 29 May 2016 . بٍيسیلٍی اثز تزکیبی ویزيی الکتزياسمًتیک در مایع رساوا ي گزادیان فشار در مایع وارساوا ایجاد میشًد،ٍجزیان ديسیال
Received in revised form 17 July 2016
Accepted 25 August 2016 عذد.استًکس بٍ صًرت تحلیلی حل میشًوذ؛ ي اثز پارامتزَای حاکم بزرسی میگزدد-بًلتشمه ي وايیز-معادلٍَای پًاسًن
- پزيفیلَای تًپی شکل را بٍ ومایش می،در غیاب گزادیان فشار، دي سیال. سیاد میشًد،پًاسی با افشایش پارامتزَای درگیز
Keywords:
Electroosmosis یا، بٍ اسای پتاوسیل ستای وسبتا کًچک مزس دي سیال،ٍ اس وتایج آشکار میشًد کٍ دبی پمپاص الکتزياسمًتیک ديسیال.گذاروذ
Pressure-gradient
Two-fluid stratified Flow
بزای مقادیز بخصًصی اس. امکانپذیز ي قابل دستزسی است،مقادیز بشرگ پتاوسیل ستای دیًار ي شعاع الکتزيسیىتیک بشرگ
Exact Solution بٍ اسای مقادیز بٍ قذر کافی کًچک. دبی بٍ یک مقذار خاص میرسذ، با میل شعاع الکتزيسیىتیک بٍ بیىُایت،پارامتزَای حاکم
جزیان بزگشتی (مقذار مىفی بزآیىذ دبی) رخ میدَذ (حتا،پتاوسیل ستای دیًار یا مقادیز بٍ قذر کافی بشرگ پتاوسیل ستای مزس
. دبیَای صفز ویش ممکه است بٍ دست آیذ.)در حالت جزیان یاری شًوذٌ تًسط فشار
doi: 10.5829/idosi.ije.2016.29.10a.18