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JEE Cheat Sheet Series

(Practice Sheet)
Atomic Structure
CHEMISTRY

Single Correct Type Questions 6. In order to increase the kinetic energy of ejected
1. The cathode rays experiment demonstrated that photoelectrons, there should be an increase in
(1) -particles are the nuclei of He atoms. (1) intensity of radiation.
(2) the e/m ratio for the particles of the cathode rays (2) wavelength of radiation.
varies gas to gas. (3) frequency of radiation.
(3) cathode rays are streams of negatively charged (4) both wavelength and intensity of radiation.
particles.
(4) the mass of an atom is essentially all contained in 7. The force of attraction on electron by the nucleus
its very small nucleus. is directly proportional to
n3 Z3
(1) (2)
2. Radiations of frequency, () are incident on a Z4 n4
photosensitive metal. The maximum kinetic energy
n4 Z2
of photoelectrons is E. When the frequency of the (3) (4)
Z2 n4
incident radiations is doubled, then what is the
maximum kinetic energy of the photoelectrons?
8. The angular momentum of electron revolving
(1) 2E (2) E/2
around the nucleus of H–atom is directly
(3) E + hv (4) E – hv
proportional to
(1) r (2) r1/2
3. The eyes of a certain member of the reptile family
(3) r–1/2 (4) r–1
pass a single visual single to the brain when the
visual receptors are stuck by photons of
9. What is the angular speed of an electron revolving
wavelength 662.6 nm. If a total energy of 3.0 ×
in the third orbit of He+ ion?
10–14 J is required to trap the signal, what is the
(1) 6.12 × 1015s−1 (2) 1.63 × 10–16 s
minimum number of photons that must strike the
(3) 1.92 × 1016 s–1 (4) 1.95 × 1015s–1
receptor?
(1) 1.0 × 105 (2) 1.0 × 106
10. For which transition in H-atom, the amount of
(3) 1000 (4) 1
energy released will be maximum?
(1) n = 4 to n = 2 (2) n = 5 to n = 2
4. A green bulb and a red bulb are emitting the
(3) n = 2 to n = 1 (4) n = 7 to n = 2
radiations with equal power. The correct relation
between numbers of photons emitted by the bulbs
11. The ratio of potential energy of electron in the third
per second is
orbit of Li2+ ion to the kinetic energy of electron in
(1) ng = nr (2) ng < nr
the fourth orbit of He+ ion should be
(3) ng > nr (4) unpredictable
(1) 8 : 1 (2) –8 : 1
(3) –16 : 1 (4) 1 : 1
5. The threshold wavelength for ejection of electrons
from a metal is 330 nm. The work function for the
12. The potential energy of electron revolving in the
photoelectric emission from the metal is (h = 6.6 ×
ground state of H atom is
10–34 J-s)
(1) –13.6 eV (2) –6.8 eV
(1) 1.2 × 10–18 J
(3) –27.2 eV (4) Zero
(2) 6.0 × 10–19 J
(3) 1.2 × 10–10 J
(4) 6.0 × 10–12 J
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13. The amount of energy released when an electron 20. The mass of a particle is 10–10 g and its diameter is
jumps from the seventh excited state to the first 10−4 cm. If its speed is 10–6 cm/s with 0.0001%
excited state in He+ ion is uncertainty in measurement, the minimum
(1) 13.32 eV (2) 53.28 eV uncertainty in its position is
(3) 12.75 eV (4) 26.08 eV (1) 5.28 × 10–8 m (2) 5.28 × 10–7 m
(3) 5.28 × 10–6 m (4) 5.28 × 10–9 m
14. The energy difference will be minimum for which
of the following energy levels of H-atom? 21. Uncertainty in the position of an electron (mass =
(1) n = 2 and n = 3 (2) n = 3 and n = 4 9.1 × 10−31 kg) moving with a velocity 300 m/s
(3) n = 1 and n = 2 (4) n = 1 and n = 4 accurate up to 0.001% will be
(1) 5.76 × 10−3 m
15. How much energy is needed for an electron (2) 1.92 × 10−2 m
revolving in the second orbit of He+ ion in order to (3) 3.84 × 10−3 m
double its angular momentum? (4) 19.2 × 10−4 m
(1) 40.8 eV (2) 2.55 eV 22. Which of the following set of quantum numbers is
(3) 10.2 eV (4) 12.09 eV permissible?
(1) 4, 1, +2, +1/2
16. An electron revolving around H-nucleus in the (2) 4, 2, –1, +1/2
ground state absorbs 10.2 eV energy. Its angular (3) 4, 0, 0, 1
momentum increases by (4) 4, 4, +2, –1/2
h h
(1) (2)
2  23. Number of orbitals represented by n = 3, l = 2 and
2h h m = +2 is
(3) (4)
 4 (1) 1 (2) 2
(3) 3 (4) 4
17. What is the frequency of the second line of the
Paschen series in the spectrum of He+ ion? 24. The correct set of four quantum numbers for the
64R.C 64R valence electron of rubidium (Z = 37) is
(1) (2) (1) 5, 0, 0, +1/2
225 225
(2) 5, 1, 0, +1/2
225 225C
(3) (4) (3) 5, 1, 1, +1/2
64R 64R
(4) 6, 0, 0, +1/2

18. What is the wave number of the radiation of lowest

Integer Type Questions
frequency in the Lyman series of the spectrum of
25. The quantum number n corresponding to the
Li2+ ion?
excited state of He+ ion if on transition to the
4 27R
(1) (2) ground state that ion emits two photons in
27R 4 succession with wavelengths 108.5 and 30.4 nm is
27RC 4C
(3) (4)
4 27R 26. The atomic number of hydrogen-like ion has the
wavelength difference between the first line of
19. Wave number of the first line in the Balmer series Balmer and Lyman series equal to 59.3 nm.
of Be3+ is 2.5 × 105 cm−1. Wave number of the
second line of the Paschen series of Li2+ is 27. The Schrodinger wave equation for hydrogen atom
(1) 7.2 × 104 cm–1 3/2 r
1 1  r0  – a0
0

(2) 7.2 × 105 cm−1 is 2s =    2 –  e , where a0 is

(3) 7.2 × 10−4 cm−1 4 2  a 0   a0 
(4) 1.8 × 104 cm−1 Bohr’s radius. If the radial node is 2s be at r0, then
r
the value of 0 is
a0

28. x moles of photon would contain sufficient energy 29.
to raise the temperature of 245 g of water from
19.5°C to 99.5 °C? The specific heat of water is 4.2
J/oC-g and frequency of light radiation used is 2.45
× 1010 per second. (6.626 × 5.04 = 33.6, NA = 6 ×
x 30.
1023), then find .
100
3
A proton and an electron, both at rest initially,
combines to form a hydrogen atom in the ground
state. A single photon is emitted in this process.
The wavelength (in nm) of emitted photon is
In the hydrogen spectrum, the longest wavelength
in the Lyman series is 120 nm and the shortest
wavelength in the Balmer series is 360 nm. From
this data, the longest wavelength (in nm) of light
that could ionize hydrogen atom is
 ANSWER KEY

1. (3) 16. (1)

2. (3) 17. (1)
3. (1) 18. (2)
4. (2) 19. (1)
5. (2) 20. (1)
6. (3) 21. (2)
7. (2) 22. (2)
8. (2) 23. (1)
9. (1) 24. (1)
10. (3) 25. (5)
11. (2) 26. (3)
12. (3) 27. (2)
13. (3) 28. (84)
14. (2) 29. (91)
15. (3) 30. (90)

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