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ADARSH MATRIC HIGHER SECONDARY SCHOOL -

VANIYAMBADI.
FULL PORTION EXAM 2022
CLASS: XII CHEMISTRY
MARKS: 70
PART – I
Choose the correct answers: 15x1=15
1. Adsorption of a gas on solid metal surface is spontaneous and exothermic, then
a) increases b) S increases c) G increases d) V decreases
2. When one of the following ores is best concentrated by froth-flotation method?
a) Magnetite b) Haematite c) Galena d) Cassiterite

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3. Match the following

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(A) V2O5 (i) High density poly ethylene
(B) Ziegler- Natta (ii) PAN
(C) Peroxide (iii) NH3
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(D) Finely divided Fe (iv) H2SO4
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A B C D
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a) (iv) (i) (ii) (iii)

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b) (i) (ii) (iv) (iii)

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c) (ii) (iii) (iv) (i)

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d) (iii) (iv) (ii) (i)

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4. – D (+) Glucose and - D (+) Glucose are

a) Epimers b) Anomers c) Enantiomers d) Conformational isomers

5. pH of a saturated solution of Ca(OH)2 is 9. The solubility product (Ksp) of Ca(OH)2

a) 0.5 x10-15 b) 0.25 x10-10 c) 0.125 x10-15 d) 0.5x10-10
6. Which one of the sollowing will react with phenol to give Salicyclaldehyde after
hydrolysis
a) Dichloromethane b) Trichloroethane c) Trichloromethane d) CO2

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7. Benzaldehyde in the presence of Pyridine condenses with malanic acid gives

a) Benzoin b) Cinnamic acid c) Cinnamaldehyde d) Benzyl alcohol
8. During electrolysis os molten sodium chloride, the time required to produce 0.1 mole of
chlorine gas using a current of 3A is
a) 55 minutes b) 107.2 minutes c) 220 minutes d) 330 minutes
9. Which of the following is not sp2 hybridised?
a) Graphite b) Graphene c) Fullerene d) Dry ice
10. Which one of the following reduces tollens reagent
a) formic acid b) acetic acid c) benzophenone d) none of these
11. The fraction of ototal volume occupied by the atoms in a Body Centered Cubic is

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a) b) c) d)

12. The magnetic moment of Mn2+ ion is

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a) 4.89 BM b) 5.92 BM c) 8.95 BM d) 2.80 BM
13. After 2 hours, a radioactive substance becomes (1/6)th of original amount. Then the half
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Life (in min) is
a) 60 minutes b) 120 minutes c) 30 minutes d) 15 minutes
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14. Most easily liquefiable gas is

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a) Ar b) Ne c) He d) Kr
15. A complex in which the oxidation number of the metal is Zero is
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a) K4[Fe(CN)6] b) [Fe (CN)3 (NH3)3] c) [Fe (CO)5] d) both (b) and (c)
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PART –II
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Answer any 6 questions. Q.No: 24 is compulsory: 6x2=12

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16. How will you identify borate radical?

17. Why transition elements form complex compounds?
18. Calculate the number of atoms in a FCC unit cell.
19. What is Buffer solution? Give one example.
20. Define equivalent conductance.
21. State Faraday’s second law of electrolysis.
22. Write a note on Catalytic Poison.
23. What are the different types of RNA which are found in cell?

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24. From the following reaction, Identify A and B.

PART - III

Answer any 6 questions. Q.No: 33 is compulsory: 6x3=18

25. Explain Schottky defect.

26. Give the three uses of helium.

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27. Based on the VB theory, explain why [Ni (CN)4]2- is paramagnetic.

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28. Give the uses of Silicones.

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29. State Kohlrausch law. How is it useful to determine the molar conductivity of weak

electrolyte at infinite dilution.

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30. How are the following conversions effected?
(i) glycerol Acrolein
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(ii) Phenol Phenolphthalein

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31. Write a short notes on

(i) Kolbe’s electrolytic decarboxylation
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(ii) HVZ reaction

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32. Give any three difference between DNA and RNA.

33. Solution metal crystallizes in bcc structure with the edge length of the unit cell
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4.3 x 10-8 cm. Calculate the radius of sodium atom.

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PART –IV

Answer all the questions: 5x5=25

34. a) Explain zone refining process with an example. (OR)
b) i) What are inter halogen compounds?
ii) Write any three uses of Helium.

35. a) i) Calculate the number of unpaired electrons in Ti2+, Mn2+ and calculate the spin
only magnetic moments.
ii) Compare Lanthanoids and Actinoids. (OR)

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b) Write the postulates of Werner’s theory.

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36. a) i) What are the differences between order and molecularity of a reaction?
ii) Derive integrated rate law for a zero order reaction A Product (OR)

b) Derive Henderson - Hasselbalch equation.

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37. a) How will you convert benzaldehyde into the following compounds?
(i) Cinnaldehyde
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(ii) Benzal aniline

(iii) Malachite green dye
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(OR)
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b) Write a short notes on

i) Kolbe’s (or) Kolbe’s schmit reaction
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ii) Schotten Baumann reaction

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iii) Hydroboration
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38. a) Explain intermediate compound formation theory of catalysis with an example

(OR)
b) Explain the Reduction of Nitro benzene in Acid, Neutral and alkaline media.

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