ANURADHA ENGINEERING COLLEGE, CHIKHLI

Department of Chemical Engineering

Subject: CET II Semester: IV
Unit Test: II Subject code: 4CH02
Time: - 1:30 Hr. Max. Marks:-30

Q.no. Question Marks CO Level

Q. 1 (a) Discuss the term elevation of boiling point (ΔTb). Prove that elvation of boiling point is a colligative property. 7 C3 L3
Q.1 (b) Explain that the freezing point depression is a colligative property 8 C3 L2

OR
Q. 2 (a) State Gibbs-phase rule and explain the meaning of the term and symbol used. 8 C3 L3
Q. 2 (b) Calculate the mass of methyl alcohol which when dissolved in 100 g of water, would just prevent the formation of ice at 7 C4 L3
-10°C. (Kf of water is 1.86 K molal-1)Explain the working of plate column
Q. 3 (a) Define the chemical potential. Explain the effect of temperature and pressure on chemical potential. 8 C2 L2
Q. 3 (b) Derive an equation for β for a Vander Waals gas 7 C2 L3

OR
Q. 4 (a) Define the term fugacity. Derive the expression for the calculation of fugacity of gas. 8 C2 L3
Q. 4 (b) Calculate the molal freezing point depression constant for benzene if its heat of fusion at 5°C is 9.83 kJ mol -1.Derive an 7 C4 L3
expression of molar mass flux in steady state diffusion of component ‘A’ through non diffusing component ‘B’