Xii Chemistry Paper With Solutions

CLASS -XII
SUBJECT -CHEMISTRY TIME- 1 HOUR
TOPIC- SOLUTION & ELECTRO M.M-60
SECTION A (ONE MARKS EACH)
1. The charge required for the reduction of 1 mol of MnO4– to MnO2 is

(a) 1 F
(b) 3 F
(c) 5 F
(d) 6 F
2. If limiting molar conductivity of Ca2+ and Cl– are 119.0 and 76.3 S cm2 mol-1, then the value of limiting
molar conductivity of CaCl2 will be
(a) 195.3 S cm2 mol-1
(b) 271.6 S cm2 mol-1
(c) 43.3 S cm2 mol-1
(d) 314.3 S cm2 mol-1.
3. The reaction, 3ClO– (aq) → ClO3 (aq) + 2Cl– (aq) is an example of
(a) Oxidation reaction
(b) Reduction reaction
(c) Disproportionation reaction
(d) Decomposition reaction
4. The emf of the cell:
Ni / Ni2+ (1.0 M) // Au3+ (1.0 M) / Au (E° = -0.25 V for Ni2+/Ni; E° = 1.5 V for Au3+/Au) is
(a) 1.25 V
(b) -1.25 V
(c) 1.75 V
(d) 2.0 V
5. The standard emf of a galvanic cell involving cell reaction with n = 2 is formed to be 0.295 V at 25° C.
The equilibrium constant of the reaction would be
(a) 1.0 × 1010
(b) 2.0 × 1011
(c) 4.0 × 1012
(d) 1.0 × 102
[Given F = 96500 (mol-1); R = 8.314 JK-1 mol-1]
6. If E°Fe2+/Fe = -0.441 V and E°Fe2+/Fe2+ = 0.771 V, the standard EMF of the reaction,
Fe + 2Fe3+ → 3Fe2+ will be
(a) 1.212 V
(b) 0.111 V
(C) 0.330 V
(d) 1.653 V
Read the passage given below and answer the following questions :
The potential of each electrode is known as electrode potential. Standard electrode potential is the
potential when concentration of each species taking part in electrode reaction is unity and the reaction
is taking place at 298 K. By convention, the standard ectrode potential of hydrogen (SHE) is 0.0 V. The
electrode potential value for eacfi electrode process is a measure of relative tendency of the active
species in the process to remain in the oxidisedlreduced form. The negative electrode potential means
that the redox couple is stronger reducing agent than H+/H2 couple. A positive electrode potential
means that the redox couple is a weaker reducing agent than the H+/H2 couple. Metals which have
higher positive value of standard reduction potential form the oxides of greater thermal stability.
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In these questions (i-iv), a statement of assertion followed by a statement of reason is given. Choose
the correct answer out of the following choices.
(a) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation
for assertion
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
7. Assertion : An electrochemical cell can be set-up only if the redox reaction is spontaneous.
Reason : A reaction is spontaneous if the free energy change is negative.
8. Assertion : The standard electrode potential of hydrogen is 0.0 V.
Reason : It is by convention.
9. Assertion : The negative value of standard reduction potential means that reduction takes place on
this electrode with reference to hydrogen electrode.
Reason : The standard electrode potential of a half cell has a fixed value.
10. Assertion : The absolute value of electrode potential cannot be determined experimentally.
Reason : The electrode potential values are generally determined with respect to SHE.
SECTION B (TWO MARKS EACH)
11. What is the effect of dilution on conductivity and molar conductivity.

12. Consider the reaction: Cr2O72--+ 14H+ + 6e- -> 2Cr3+ + 7H2O What is the quantity of electricity in
coulombs needed to reduce 1 mol of Cr2O72- ?
13. Given the standard electrode potentials, K+/K=-2. 93 V, Ag+/Ag = 0.80 V, Hg2+/Hg =0.79V, Mg2+/Mg=-
2.37V, Cr3+/Cr=0.74V.
Arrange these metals in their increasing order of reducing power.
14. The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm-1. Calculate its molar conductivity.
15. How much electricity in terms of Faraday is required to produce :
(i) 20·0 g of Ca from molten CaCl2
(ii) 40·0 g of Al from molten Al2O3 ?
16. Calculate the mass percentage of benzene (C6H6) and carbon tetrachloride (CCl4) if 22 g of benzene
is dissolved in 122 g of carbon tetrachloride.
17. A sample of drinking water was found to be severely contaminated with chloroform (CHCl3),
supposed to be a carcinogen. The level of contamination was 15 ppm (by mass).
(i) express this in percent by mass.
(ii) determine the molality of chloroform in the water sample.
18. State Henry’s law and mention some of its important applications.
19. Define azeotrope and its types.
20. Calulate vant hoff factor of K4[Fe(CN)6] when it under goes 100% dissociation.
SECTION C ( THREE MARKS EACH)
21. Give the reaction involved at Anode ,Cathode and net reaction in dry cell (lachlanche cell)
22. Give the product of electrolysis of
a) aq NaCl b) aq Na2SO4 c) aq Ag2SO4.
23. Calculate the standard cell potentials of the galvanic cells in which the following reactions take
place.

Also calculate ∆G° and equilibrium constant for the reaction.
24. Conductivity of 0.00241 M acetic acid is 7.896 x 10-5 S cm-1. Calculate its molar conductivity. If Λm0,
for acetic acid is 390.5 S cm2 mol-1, what is its dissociation constant?
25. Three electrolytic cells A, B, C containing solutions of ZnS04, AgNO3 and CuS04, respectively are
connected in series. A steady current of 1.5 amperes was passed through them until 45 g of silver
deposited at the cathode of call B. How long did the current flow? What mass of copper and zinc
were deposited?
26. Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K 2SO4 in 2 litre of
water at 25°C, assuming that it is completely dissociated.
27. Two elements A and B form compounds having formula AB2 and AB4. When dissolved in 20g of
benzene (C6H6), 1 g of AB2 lowers the freezing point by 2.3 K whereas 1.0 g of AB4 lowers it by 1.3 K.
The molar depression constant for benzene is 5.1 K kg mol-1. Calculate atomic masses of A and B.
28. Define the following terms:
(i) Mole fraction
(ii) Molality
(iii) Molarity
29. Calculate the mass of ascorbic acid (vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to
lower its melting point by 1·5°C. (Kf for CH3COOH) = 3·9 K kg mol-1)
30. Distinguish between ideal and non ideal solution.
ALL THE BEST

Answer key and solution
1- B
2- B
3- C
4- C
5- A
6- A
7- B
8- A
9- D
10- A
11-
>Conductance is define for the no.of ions per ml. On dilution as volume of solution increase. Thus no.of ions per ml
decrease and hence conductivity decreases.
>Molar conductivity is defined for 1 mole of ions. Thus on dilution ions more apart and mobility of ions increase
which leads to increase in molar conductivity of the solution.
12- 6F = 5.79×105 C
13-
The increasing order of reducing power is as follows:
Ag+|Ag<Hg2+|Hg<Cr3+|Cr<Mg2+|Mg<K+|K
Metal with most positive standard electrode potential has the least reducing power.
Metal with most negative standard electrode potential has maximum reducing power.
14

k (Conductivity) =0.0248 Scm−1
C (molarity) =0.20 M
T (temperature) =298 K
Λm=? (molar conductivity)
The formula is Λm=1000×kC
=1000×0.0248 Scm−10.20 mol cm−3
=124 S cm2 mol−1
The molar conductivity is 124 S cm2 mol−1
15-
16
17

18
According to Henry's law, the solubility of a gas in a liquid is directly proportional to the pressure of the gas.
X=Kh×P
X is the mole fraction of gas, Kh is Henry's law constant and P is the partial pressure of the gas.
Important applications of Henry's law:
1) In packing of soda cans: Soda water bottles are always packed under higher pressure to increase the solubility
of CO2 gas.
2) In deep-sea diving: Nitrogen is more soluble than Helium in our blood. In the deep sea, the pressure is higher
than at the surface of the water. When diver tries to come rapidly towards the surface of the water, pressure
decreases and dissolved nitrogen comes back from blood and makes bubbles in veins. Hence, divers use oxygen
diluted with helium.
19
An azeotropic mixture is a mixture of substances that has the same concentration of vapour and fluid
phases. It is basically a mixture that contains two or more liquids. A zeotropic mixture basically has
constant or the same boiling points, and the mixture’s vapour will also have the same composition as the
liquid.
Minimum Boiling Azeotropes or Negative Azeotrope
Azeotropic mixtures with a higher boiling point in their constitutions are maximum boiling azeotropes.
Water boils at 373 K, and hydrochloric acid boil at about 188 K, while azeotropes boil at around 383 K,

which is a boiling point greater than its constituents. Consider, for example, hydrochloric acid consisting
of a weight concentration of approximately twenty per cent and 79 per cent of water.
Examples:
• Separation of water and isobutanol.

• Dehydration of ethanol.
• Separation of cyclohexane and benzene.
Maximum Boiling Azeotropes or Positive Azeotrope

Similarly, an azeotropic mixture that has a boiling point lesser than its constituents is known as a minimum
boiling azeotrope. Consider, for example, ethanol consisting of a weight concentration of approximately
ninety-five per cent and four per cent of water. Water boils at 373 K, and ethanol boils at about 351.5 K,
while azeotropes boil at around 351.15 K, suggesting a boiling point lower than its constituents.
20. i=5
21.
Net reation –
22. product of electrolysis
23.
24

25
26

27

28 (i) Mole fraction
It is the ratio of the number of moles of a particular component to the total number of moles of all the components in
the mixture. It is denoted by symbol χ.
(ii) Molality
It is the number of moles of the solute per kilogram of the solvent. It is the ratio of the number of moles of solute to
the mass of solvent in kg.
(iii) Molarity
It is the number of moles of solute per litre of the solution. It is the ratio of the number of moles of solute to the
volume of solution in litre.
29

30


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CLASS -XII

SUBJECT -CHEMISTRY TIME- 1 HOUR

TOPIC- SOLUTION & ELECTRO M.M-60

SECTION A (ONE MARKS EACH)

1. The charge required for the reduction of 1 mol of MnO4– to MnO2 is

SECTION B (TWO MARKS EACH)

11. What is the effect of dilution on conductivity and molar conductivity.

SECTION C ( THREE MARKS EACH)

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

ALL THE BEST

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

The increasing order of reducing power is as follows:

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2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

Important applications of Henry's law:

Minimum Boiling Azeotropes or Negative Azeotrope

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

• Separation of water and isobutanol.

Maximum Boiling Azeotropes or Positive Azeotrope

22. product of electrolysis

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

2nd FLOOR, ABOVE SBI BANK, KILVANI NAKA, SILVASSA -396230

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