Revision Test for Electrochemistry [50marks]

1) W22QP41Q3

(Ion (Sn2+/Sn4+) concentration) 1 mol dm–3 AND 298 K (25 °C)

• both half-cells have Pt or C electrode

• Sn2+ / Sn4+ AND H+ solutions

• feasible gas delivery system

• H2 label

• V/voltmeter AND correct circuit AND salt bridge touching solution

• salt bridge labelled

 no (reaction) AND

both Eo values (Sn2+ / Sn) –0.14 and (Cl2 / Cl – ) +1.36 [1]

Ecell is –1.5 V / Ecell is negative

OR Eo of Sn4+ / Sn2+ is more negative/smaller than Eo of Cl2 / Cl – [1]

Sn2+→Sn4+ and VO2+→V3+ [1] Sn2++ 2VO2+ + 4H+ → Sn4+ + 2V3+ +2H2O [1]

moles of Sn = 2.95 / 118.7 = 0.0249 moles

moles of Al (is 2 / 3 moles of Sn) = 0.0166 moles [1]

mass of Al = 0.0166 27 = 0.447 / 0.448 g to 3sf [1]

2) S22QP42Q5

number of Cu2+ formed = 0.35 / 63.5 = 5.51 10–3

Q =I t = 0.60 30 60 = 1080 C

number of electrons = 1080 / 1.6 10-19 = 6.75 1021 ecf

number of Cu2+ ions = 6.75 1021 / 2 = 3.375 1021 ecf

number of Cu2+ ions per mole ( L) = 3.375 1021 / 5.51 10-3 = 6.12 1023 ecf min 2sf

all five points for four marks

ALLOW valid alternate calculations of L

Avogadro constant, L = .............................. [4]

[Total: 8]
3) S22QP41Q3c

voltage / EMF / potential difference when a half-cell is connected to a

(standard) hydrogen electrode under standard conditions

ions move (from the salt bridge) to maintain charge balance /

complete the circuit

SHE labelled negative AND arrow in the external circuit moving away from this electrode
[10marks]
4) W21QP41Q1

[5marks]
5) M20QP42Q2b

[5marks]
6) M20QP42Q3

voltage of an electrode / half-cell •

compared / connected to (S)HE / hydrogen half-cell / electrode •

under standard conditions / 1 mol dm–3, 1 atm, 298 K

[4]
[3]
[11 marks]