Ex 2

Page # 12 Solutions Slot – 1 (Chemistry)
EXERCISE – II MULTIPLE CORRECT (OBJECTIVE QUESTIONS)
1. R – X + Mg Ether RMgX CH3–OH

R–H+
n-butane
(i) CH3–CH2–CH2–CH2–X (n butyl halide)
(ii) CH3–CH2– CH–CH3 (sec. butyl halide)
X
Ans. A,B
Ether
2. H3C – CH2 – CH MgI + HC CH H3C – CH2 – CH2 – CH3
CH3 +
HC CMgI
Ans. B, D
Et
3. (A) EtMgX + H – C – H
H3 O
H–C–H Et – CH2– OH
O O Mgx
(B) MeMgX + (CH2)2O Me–CH2–CH2–OMgX
CH2 – CH2
H3O
O
Me–CH2–CH2–OH
H
(C) EtMgX + 1/2 O2 Et – OMgX EtOH
Me
(D) MeMgX + CH3–CHO CH3–CH CH3–CH–Me
OMgX OH
Ans. A,B
4. A,B,CD
(A) Mgx+O2 OH
RMgx OMgx
+
O H
(B)
OH
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Solutions Slot – 1 (Chemistry) Page # 13
CH3–C–CH3 + C2H5MgBr OMgBr
O H
(C)
OH
Cl
CH3–C–Cl + C2H5MgBr CH3–C–C2H5
(D)
O O MgBr
CH3 CH3
H CH3MgBr
CH3–C–C2H5 CH3–C–C2H5 CH3–C–C2H5
OH OMgBr O
5. (A) CH3–CH2–C–CH2–CH3+ MgBr CH3–CH2–C–CH2–CH3

O OMgBr
H3O
CH3–CH2–C–CH2–CH3
OH
Et
(B)
Ph–C–OEt + EtMgBr Ph – C – OEt
O OMgBr
Et
H3O EtMgBr Ph – C – Et
Ph – C – Et
OMgBr O
Et
Ph – C – Et
OH
(C)
Et
Ph – C – Et + EtMgBr Ph – C – Et
O OMgBr
H3O
Et
Ph – C – Et
OH
Ans. ABC
6. (A) CH3
CH3 – C – CH3 + CH3MgBr CH3 – C – CH3
O oMgBr
CH3
CH3 – C – CH3
OH
(B)
CH3
CH3 – CH2– CHO + CH3MgBr CH3–CH2 – C – H
oMgBr
H
R/S
*
CH3 –CH2– CH – CH3
OH
(C)
CH3 – CHO + C2H5 MgI CH 3–CH–C 2H 5

OMgI
R/S
*
CH3 – CH – C2H5
OH
Ans. (B,C)
7. (i)
Br MgBr H
(i) Mg, ether
N N N
MgBr
H H
Acidic Hydrogen
O O O O
(ii) (i) Mg, ether
(ii) Ph–C–H
Br Ph–CH
O
(iii) H3O OH
(iii)
MgBr
O
CH3–C–CH3
CH3–C–CH3
H3O
O MgBr
H 3O
CH3 CH3
OH
(iv)
O O
(i) CH3–CH2 MgBr
OH (ii) H3 O OMgBr
+CH3–CH3
Ans. (A,B,D)
OH ONa
8.
* *
+ NaHCO3 + H2CO3
NO2 NO2 *
H2O+CO2
Mg/ether *
CH 2=CH—Br CH 2=CHMgBr + C=O
O
*
CH2=CH—C—OMgBr
O
H3 O
*
CH 2=CH—C—OH
O
Ans A,B,C,
(i) et2O H2CrO 4

9. X+y Alcohal ketone
Acetone
O
(i) oMgBr
CH3
MgBr + H—C—CH
CH3
O
H3O
(x) (y)
OH
(Alcohal)
H
(ii) MgBr +
O
oMgx OH
Alcohal
Ans. A,B,D
(i) Mg/ether
C N No Rxn
10. (A) (ii) H3O
Cl MgCl COOH
(B) (i) Mg/ether CO2
F F
Mg/ether
(c)
Cl Mgcl
+ CH3—C CH CH 3MgBr CH4+CH3—C C MgBr

(d)
O
CH3
C C OMgBr
CH3 C C OH
Ans. B,D
11. These comp react with G.R. and gives alkane which have more acidic Hydrogen
O O
(i) CH3—CH2—NO 2 (ii) CH3 CH2 CH3

Nitro ethane Acetyl Acetone
Ans. A,B
O
MgBr (excess) + H—C—Cl CH
12. (A)
OH
2º alcohal
Ph CH3
(B) PhMgBr+CH3—C—Cl CH3—C—Cl Ph—C
(excess) O OMgBr O PhMgBr
Ph
ph—C—CH 3
OMgBr
Ph
ph—C—CH3
OH
O O
(C)
CH3 MgBr (excess) + CH3—C—O—C—CH3
CH3 O
CH3—C—O—C—CH3 CH3—C—CH3
O Mgx O
CH3Mgx
CH3 CH3
H
CH3—C—CH3 CH3—C—CH3
OH OMgx
CH3
(D) CH 3 MgBr+Cl—C—OEt CH 3—C—CH 3

O OH
Ans. B,C,D
OH
Carbonyl compd. (x) + G.R. (y) Me ph

13.
Et
(i) Et—C—Ph + MeMgBr (ii) Me—C—Ph + Et MgBr

O O
(iii) Me—C—et + Ph MgBr

O
Ans. A,B,C
14. C,D
O OMgBr
2 CH3 MgBr
C2H5O–C–OC2H5 CH 3–C–OC2H 5
OC2H 5
CH3–C–OC2H5
O
CH3 MgBr
CH3
CH3–C–OC2H5
O OMgBr
15. (A) CH3—C—C—CH3 Show NAR with G.R

O O
(B) CH3—C—CH2—C—CH3 Acidic H react with G.R and give Alkane
O O
(C) CH 3—C—CH 2—CH 2—C—CH 3 show NAR with G.R
O O
O
(D) This is acidic H react with G.R. and given alkane
H
O H
Ans. B,D
16. Cl2 Mg
ph—CH3 Ph—CH2—Cl ether Ph—CH2MgCl
hv
CH3—CHO
NH 4Cl
CH2 CH2 CH2

MgBr
O
H MgBr
–C
3
CH
CH3 CH 2
CH—CH3 Tautomerism CH—CH 3
OH
OH
CH3 CH 2
Tautomerism
CH 3CHO
CH—CH3 CH—CH3
OH OH
Ans. A,B,C
17. A,B
HO OEt I MgO OEt

CH3MgI
+CH4
P1
CH3MgI
NH4Cl
IMgO CH3
MgI
O P2 O
18. C,D
(i) CH3 O NH2

1 CH 3MgBr CH3–O–NH MgBr+CH4
CH 3MgBr
CH 3 O Mg Br + CH 3NH MgBr
H H
CH 3–OH CH 3—NH 2
19. B,C
O O MgBr O MgBr
(i) CH 3 MgBr
CH3 CH 3
H/H2O
HO OH
CH3 CH3
Geometrical
Isomers
both comp having pos and show geometrical Isomer

20. A,C,D
O BrMgO Ph HO Ph
(i) PhMgBr NH4Cl

(ii) NH4Cl
BrMgO HO Ph (G.I./ Diastereomer)

Ph

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Page # 12 Solutions Slot – 1 (Chemistry)

EXERCISE – II MULTIPLE CORRECT (OBJECTIVE QUESTIONS)

1. R – X + Mg Ether RMgX CH3–OH

(B) MeMgX + (CH2)2O Me–CH2–CH2–OMgX

CH3–C–CH3 + C2H5MgBr OMgBr

5. (A) CH3–CH2–C–CH2–CH3+ MgBr CH3–CH2–C–CH2–CH3

CH3 – CHO + C2H5 MgI CH 3–CH–C 2H 5

(i) CH3–CH2 MgBr

(i) et2O H2CrO 4

(B) (i) Mg/ether CO2

+ CH3—C CH CH 3MgBr CH4+CH3—C C MgBr

(i) CH3—CH2—NO 2 (ii) CH3 CH2 CH3

(D) CH 3 MgBr+Cl—C—OEt CH 3—C—CH 3

Carbonyl compd. (x) + G.R. (y) Me ph

(i) Et—C—Ph + MeMgBr (ii) Me—C—Ph + Et MgBr

(iii) Me—C—et + Ph MgBr

15. (A) CH3—C—C—CH3 Show NAR with G.R

(B) CH3—C—CH2—C—CH3 Acidic H react with G.R and give Alkane

CH2 CH2 CH2

HO OEt I MgO OEt

(i) CH3 O NH2

both comp having pos and show geometrical Isomer

(i) PhMgBr NH4Cl

BrMgO HO Ph (G.I./ Diastereomer)

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