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EXERCISE-I (Conceptual Questions) Build Up Your Understanding

CONCENTRATION TERMS 11. Molarity of 720 g of pure water -
1. 8 g NaOH is dissolved in one litre of solution. Its (1) 40M
molarity is : (2) 4M
(1) 0.8 M (2) 0.4 M (3) 0.2 M (4) 0.1 M
(3) 55.5M
LS0001
(4) Can't be determined
2. If 18 g of glucose is present in 1000 g of solvent,
the solution is said to be : LS0011
(1) 1 molar (2) 0.1 molar 12. Equal weight of NaCl and KCl are dissolved
(3) 0.5 molar (4) 0.1 molal separately in equal volumes of solutions then
LS0002 molarity of the two solutions will be –
3. The molarity of a solution of sodium chloride (1) Equal
(mol wt. = 58.5) in water containing 5.85 g of (2) That of NaCl will be less than that of KCl
sodium chloride in 500 mL of solution is :- (3) That of NaCl will be more than that of KCl

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(1) 0.25 (2) 2.0 (3) 1.0 (4) 0.2 Solution
(4) That of NaCl will be half of that of KCl
LS0003
solution
4. For preparing 0.1 M solution of H2SO4 in one
LS0012
litre, we need H2SO4 :
13. The mole fraction of oxygen in a mixture of 7g
(1) 0.98 g (2) 4.9 g
of nitrogen and 8g of oxygen is :
(3) 49.0 g (4) 9.8 g
8
LS0004 (1) (2) 0.5 (3) 0.25 (4) 1.0
15
5. Mole fraction of glycerine(C3H5(OH)3) in a
LS0013
solution of 36 g of water and 46 g of glycerine
is : 14. In a solution of 7.8 g benzene (C6H6) and 46.0g
(1) 0.46 (2) 0.36 toluene (C6H5CH3), the mole fraction of benzene
is:-
(3) 0.20 (4) 0.40
1 1 1 1
LS0005 (1) (2) (3) (4)
6 5 2 3
6. 1000 g aqueous solution of CaCO3 contains 10
LS0014
g of calcium carbonate, concentration of the
15. An X molal solution of a compound in benzene
solution is :
has mole fraction of solute equal to 0.2. The
(1) 10 ppm (2) 100 ppm value of X is:-
(3) 1000 ppm (4) 10,000 ppm (1) 14 (2) 3.2 (3) 1.4 (4) 2
LS0006 LS0015
7. What is the normality of 1M H3PO4 solution ? 16. A 500 g tooth paste sample has 0.02 g fluoride
(1) 0.5 N (2) 1.0 N concentration. What is the concentration of
(3) 2.0 N (4) 3.0 N fluorine in terms of ppm level:-
(1) 250 (2) 40 (3) 400 (4) 1000
LS0007
LS0017
8. The molarity of 0.2 N Na2CO3 solution will be :
17. The normality of a '20 V' H2O2 solution is
(1) 0.05 M (2) 0.2 M (1) 1.79 (2) 3.58
(3) 0.1 M (4) 0.4 M (3) 60.86 (4) 6.086
LS0008 LS0018
9. Normality of 0.3 M phosphorous acid is:- 18. H2O2 solution used for hair bleaching is sold as a
(1) 0.15 (2) 0.6 solution of approximately 5.0 g H2O2 per 100
(3) 0.9 (4) 0.1 mL of the solution. The molecular mass of H2O2
LS0009 is 34. The molarity of this solution is
10. The molarity of pure water is : approximately:-
(1) 100 M (2) 55.5 M (1) 0.15 M (2) 1.5 M
(3) 50 M (4) 18M (3) 3.0 M (4) 3.4 M
LS0010 LS0019
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19. Normality of 10% (w\V) H2SO4 solution is nearly SOLUBILITY (HENRY'S LAW)
(1) 0.1 (2) 0.2 (3) 0.5 (4) 2 26. Henry's law constant for dissolution of CH4 in
LS0020 5
benzene at 298 K is 2 × 10 mm of Hg. Then
20. What volume of 0.1 N HNO3 solution can be solubility of CH4 in benzene at 298 K (in terms of
prepared from 6.3 g of HNO3 ? mole fraction) under 760 mm of Hg is :
(1) 1 litre (2) 2 litre
(1) 1.2 × 10–5 (2) 3.8 × 10–3
(3) 0.5 litre (4) 5 litre
(3) 4 × 10–7 (4) 1 × 10–2
LS0021
LS0027
21. A molal solution is one that contains one mole of
a solute in 27. Which of the following gas does not obey
(1) 1000 g of the solvent Henry's law ?
(2) one litre of the solution (1) NH3 (2) H2 (3) O2 (4) He
(3) one litre of the solvent LS0028
(4) 22.4 litres of the solution VAPOUR PRESSURE

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(LIQUID-LIQUID MIXTURE)
LS0022
28. 1 mol of heptane (V. P. = 92 mm of Hg) was
22. Which of the following statement is true :-
mixed with 4 mol of octane (V. P. = 31mm of
(a) Molarity is the no. of moles of solute
Hg). The vapour pressure of resulting ideal
dissolved per litre of solvent.
solution is :
(b) The molarity and normality of a solution of
sodium carbonate are same. (1) 46.2 mm of Hg (2) 40.0 mm of Hg
(c) Molality (m) of a solution is defined as the (3) 43.2 mm of Hg (4) 38.4 mm of Hg
number of moles of solute dissolved is 1000 LS0029
gm of solution 29. At 88 °C benzene has a vapour pressure of 900
(d) The ratio of mole fraction of solute and torr and toluene has a vapour pressure of 360
solvent is in the ratio of their respective
torr. What is the mole fraction of benzene in the
moles.
mixture with toluene that will boil at
(1) a & c (2) a & d
88 °C at 1 atm. pressure, (benzene - toluene
(3) b & c (4) Only d
form an ideal solution) :
LS0023
(1) 0.416 (2) 0.588 (3) 0.688 (4) 0.740
23. Two bottles of A and B contain 1M and 1m
LS0030
aqueous solutionof sulphuric acid respectively-
(1) A is more concentrated than B 30. If PA0 and PB0 are 108 and 36 torr respectively.
(2) B is more concentrated than A What will be the mole fraction of A in vapour
(3) Concentration of A = concentration of B phase if B has mole fraction of 0.5 in solution :-
(4) It is not possible to compare the
(1) 0.25 (2) 0.75 (3) 0.60 (4) 0.35
concentration
LS0031
LS0024
24. When 8 gm of aspirin (C9H8O4) is dissolved in 31. What is correct relation between mole fraction in
152 g of acetonitrile (CH3CN) then calculate the vapour phase (YA) of A in terms of XA. If mole
mass percentage of C9H8O4 in CH3CN ? fraction in solution of A is (XA) (If PA0 is vapour
(1) 2.5% (2) 3.5% (3) 15% (4) 5% pressure of A in pure state)
LS0260
XA
25. The molarity of 98% (w/w) H2SO4 (1) (1 − X A )PA0 (2) PA0
1 − XA
(d = 1.8 g mL–1) is :-
(1) 6 M (2) 18 M 1 − XA 0 PA0 X A
(3) PA (4)
(3) 10 M (4) 4 M XA PS
LS0026 LS0032
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IDEAL AND NON-IDEAL SOLUTIONS 39. If P0 and PS are the vapour pressure of solvent
32. Which condition is not satisfied by an ideal and its solution respectively. N1 and N2 are the
solution mole fraction of solvent and solute respectively
(1) ∆Hmixing = 0 then :
(2) ∆Vmixing = 0 P0
(1) PS =
(3) ∆Smixing = 0 N2
(4) Obeyance of Raoult's law (2) P0 – PS = P0N2
LS0033 (3) PS = P0N2
33. Among the following, that does not form an ideal
solution is : (4)
( P0 − PS ) = N1
(1) C6H6 and C6H5CH3 PS ( N1 + N2 )
(2) C2H5Cl and C6H5OH LS0041
(3) C6H5Cl and C6H5Br
(4) C2H5Br and C2H5I 40. One mole of non volatile solute is dissolved in
LS0034 two mole of water. The vapour pressure of the

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34. An azeotropic mixture of two liquids has boiling solution relative to that of water is
point lower than either of them when it :- 2 1 1 3
(1) shows a (+ve) deviation from Raoult's law (1) (2) (3) (4)
3 3 2 2
(2) shows no deviation from Raoult's law
(3) shows (+ve) deviation from Henry's law LS0042
(4) shows (–ve) deviation from Henry's law 41. The vapour pressure of a dilute aqueous solution
LS0035 of Glucose is 750 mm Hg at 373 K. The mole
COLLIGATIVE PROPERTIES fraction of solute is :

35. Which is not a colligative property ? 1 1 1 1

(1) (2) (3) (4)
(1) Osmotic pressure 10 7.6 35 76
(2) Relative lowering in vapour pressure LS0043
(3) Depression in freezing point
42. The vapour pressure of water at room
(4) Refractive index
LS0036 temperature is 23.8 mm of Hg. The vapour
36. The lowering of vapour pressure of a solvent by pressure of an aqueous solution of sucrose with
addition of a non-volatile solute to it, is directly mole fraction 0.1 is equal to :
proportional to : (1) 23.9 mm Hg (2) 24.2 mm Hg
(1) Mole fraction of solute (3) 21.42 mm Hg (4) 31.44 mm Hg
(2) The nature of the solute in the solution
LS0044
(3) The atmospheric pressure
(4) All 43. The vapour pressure of pure A is 10 torr. At the
LS0037 same temperature, when 3 g of B is dissolved in
37. The relative lowering of vapour pressure is equal 20 gm of A, its vapour pressure is reduced to
to the mole fraction of the nonvolatile solute. 9.0 torr. If the molecular mass of A is 200 amu,
This statement was given by : then the molecular mass of B is :
(1) Raoult (2) Henry (3) Joule (4) Dalton
(1) 200 amu (2) 270 amu
LS0038
38. The vapour pressure of a solution having solid as (3) 310 amu (4) 220 amu
solute and liquid as solvent is : LS0268
(1) Directly proportional to mole fraction of the 44. The boiling point of C6H6, CH3OH, C6H5NH2
solvent
and C6H5NO2 are 80°C, 65°C, 184°C and 2120C
(2) Inversely proportional to mole fraction of the
solvent respectively. Which will show highest vapour
(3) Directly proportional to mole fraction of the pressure at room temperature :
solute (1) C6H6 (2) CH3OH
(4) Inversely proportional to mole fraction of the (3) C6H5NH2 (4) C6H5NO2
solute
LS0040 LS0046
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45. If Raoult's law is obeyed, the vapour pressure of 52. An aqueous solution freezes at – 0.186 °C
–1 –1
the solvent in a solution is directly proportional (Kf = 1.86 K kg mol ; Kb = 0.512 K kg mol ).
to : What is the elevation in boiling point ?
(1) Mole fraction of the solvent (1) 0.186 (2) 0.512
(2) Mole fraction of the solute 0.512
(3) (4) 0.0512
(3) Mole fraction of the solvent and solute 1.86
(4) The volume of the solution LS0054
LS0047 53. In the depression of freezing point experiment, it
46. The vapour pressure of a pure liquid 'A' is 70 torr is found that :-
0
at 27 C. It forms an ideal solution with another (1) The vapour pressure of solution is more than
of pure H2O.
liquid B. The mole fraction of B is 0.2 and total
(2) The vapour pressure of solution is less than
vapour pressure of the solution is 84 torr at
0 that of pure solute
27 C. The vapour pressure of pure liquid B at (3) Only solute molecules solidify at of freezing
0
27 C is - point
(1) 14 (2) 56 (3) 140 (4) 70 (4) Only solvent molecules solidify at freezing

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LS0048 point
47. The boiling point of an aqueous solution of a non LS0056
volatile solute is 100.15 °C. What is the freezing 54. Molal depression constant of water is 1.86 K Kg
point of an aqueous solution obtained by diluting mol–1 . 0.02 mole of urea dissolved in 100 g of
the above solution with an equal volume of water will produce a depression in freezing point
water? The values of Kb and Kf for water are of :
0.512 and 1.86 K molality :
–1 (1) 0.186 °C (2) 0.372 °C
(1) –0.544 °C (2) –0.512 °C (3) 1.86 °C (4) 3.72 °C
LS0057
(3) –0.272 °C (4) –1.86 °C
LS0049 55. What would be the freezing point of aqueous
solution containing 18 g of C6H12O6 in 1000 g of
48. The molal elevation constant is the ratio of the
water ? (Kf = 1.86 K molality–1)
elevation in B.P. to : (1) –0.186° C (2) –0.372° C
(1) Molarity (3) –0.54° C (4) –0.72° C
(2) Molality LS0058
(3) Mole fraction of solute 56. A solution of 1.25 g of a non-electrolyte in 20 g
(4) Mole fraction of solvent of water freezes at 271.94 K. If Kf = 1.86K
LS0050 molality–1 and F.pt. of water is 273.15 K then
49 Elevation in boiling point was 0.52 °C when 6 g the molar mass of solute is :
of a compound X was dissolved in 100 g of (1) 207.8 g mol–1 (2) 179.79 g mol
–1

–1 –1
water. Molecular weight of X is : (Kb for water = (3) 209.6 g mol (4) 96.01 g mol
0.52 K mol )
–1 LS0059
(1) 120 (2) 60 (3) 100 (4) 342 57. If a thin slice of sugar beet is placed in
LS0051 concentrated solution of NaCl then
(1) Sugar beet will lose water from its cells
50. An aqueous solution containing 1g of urea boils
(2) Sugar beet will absorb water from solution
at 100.25 °C. The aqueous solution containing (3) Sugar beet will neither absorb nor lose water
3g of glucose in the same volume will boil at - (4) Sugar beet will dissolve in solution
(1) 100.75 °C (2) 100.5 °C LS0060
(3) 100 °C (4) 100.25 °C 58. In osmosis phenomenon net flow of :
LS0052 (1) Solvent molecules occurs from higher
51. Pure benzene freezes at 5.45 °C at a certain concentration to lower concentration
place but a 0.374 m solution of (2) Solvent molecules occurs from lower
tetrachloroethane in benzene freezes at 3.55 °C. concentration to higher concentration
The Kf for benzene is- (3) Solute molecules occurs from higher
(1) 5.08 K Kg mol
–1
(2) 508 K Kg mol
–1 concentratioin to lower concentration
–1 (4) Solute molecules occurs from lower
(3) 0.508 K Kg mol (4) 50.8 °C Kg mol–1
concentration to higher concentration
LS0053
LS0061
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59. At constant temperature, the osmotic pressure of 65. If density of 2 molal sucrose solution is
a solution is : 1.4 g mL–1 at 25°C, find osmotic pressure.
(1) Directly proportional to the concentration (1) 4.06 atm (2) 2 atm
(2) Inversely proportional to the concentration (3) 40.7 atm (4) 3.4 atm
(3) Directly proportional to the square of LS0069
concentration 66. If total concentration of dissolved particles inside
(4) Directly proportional to the square root of red blood cells is 0.3 M (approximate) and the
concentration membrane surrounding the cell is
LS0062 semipermeable. Find osmotic pressure inside the
60. Which inorganic compounds can act as cell
semipermeable membrane ? (1) 7.34 atm (2) 1.78 atm
(1) Calcium sulphate (3) 2.34 atm (4) 0.74 atm
LS0070
(2) Barium oxalate
(3) Nickel phosphate 67. Equal volume of 0.1 M urea and 0.1 M glucose
(4) Copper ferrocyanide are mixed. The mixture will have :-
(1) Lower osmotic pressure

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LS0063
(2) Same osmotic pressure
61. If 0.1 M solution of glucose and 0.1 M urea
(3) Higher osmotic pressure
solution are placed on two sides of a
(4) None of these
semipermeable membrane to equal heights, then
LS0071
it will be correct to say that :
68. Osmotic pressure of a solution (density is
(1) There will be no net movement across the –1
1g mL ) containing 3 g of glucose (molecular
membrane 0
weight = 180) in 60 g of water at 15 C is :
(2) Glucose will flow towards urea solution
(1) 0.34 atm (2) 0.65 atm
(3) Urea will flow towards glucose solution
(3) 6.25 atm (4) 5.57 atm
(4) Water will flow from urea solution towards
LS0072
glucose solution.
69.
0
Osmotic pressure of a sugar solution at 24 C is
LS0064
2.5 atm. The concentration of the solution in
62. If mole fraction of the solvent in solution
mole per litre is :
decreases then : (1) 10.25 (2) 1.025
(1) Vapour pressure of solution increases (3) 1025 (4) 0.1025
(2) B. P. decreases LS0073
(3) Osmotic pressure increases
70. A solution containing 8.6 g urea in one litre was
(4) All are correct
found to be isotonic with 0.5% (wt./vol) solution
LS0066 of an organic non volatile solute. The molecular
63. The osmotic pressure of a solution increases if : weight of organic solute is :
(1) Temperature is lowered (1) 348.9 (2) 34.89 (3) 3489 (4) 861.2
(2) Volume is increased LS0075
(3) Number of solute molecules is increased 71. If 6.84% (w/V) solution of cane-sugar
(4) None (mol. wt. 342) is isotonic with 1.52% (w/V)
LS0067 solution of thiocarbamide, then the molecular
64. Which of the following solutions at the same weight of thiocarbamide is :
temperature will be isotonic : (1) 152 (2) 76
(1) 3.42 g of cane sugar in one litre water and (3) 60 (4) 180
0.18 g of glucose in one litre water. LS0076
(2) 3.42 g of cane sugar in one litre water and 72. A solution containing 500 g of a protein per litre
0.18 g of glucose in 0.1 litre water. is isotonic with a solution containing 3.42 g of
(3) 3.42 g of cane sugar in one litre water and sucrose per litre. The molecular mass of protein
0.585g of NaCl in one litre water. is
(4) 3.42 g of cane sugar in one litre water and (1) 5 (2) 146
1.17 g of NaCl in one litre water. (3) 34200 (4) 50000
LS0068 LS0250
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73. ___(A)____ injection are dissolved in water 81. The ratio of the value of any colligative property
containing salts at particular ___(B)____ for KCl solution to that for sugar solution is
concentrations that matches ___(C)____ nearly ......................... time :
concentration. Here A, B and C refer to : (1) 1 (2) 0.5
(1) Intravenous, ionic, blood plasma (3) 2 (4) 2.5
(2) Intravenous, blood plasma, ionic LS0086

(3) Blood plasma, intravenous, ionic
(4) Blood plasma, ionic, intravenous
LS0077
ABNORMAL COLLIGATIVE PROPERTIES
74. Equimolal solutions of A and B show depression
in freezing point in the ratio of 2 : 1. If a remains
in normal state in solution, B will be in .........
82. The lowering of vapour pressure of 0.1M
aqueous solutions of NaCl, CuSO4 and K2SO4
are :
(1) All equal
(2) In the ratio of 1 : 1 : 1.5
(3) In the ratio of 3 : 2 : 1
(4) In the ratio of 1.5 : 1 : 2.5
LS0087
83. The freezing point of 1 molal NaCl solution

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state in solution :
assuming NaCl to be 100% dissociated in water
(1) Normal (2) Associated
is:
(3) Hydrolysed (4) Dissociated
(Kf = 1.86 K Molality–1)
LS0079
(1) –1.86 °C (2) –3.72 °C
75. Vant Hoff factor is :
(3) +1.86 °C (4) + 3.72 °C
(1) Less than one in case of dissociation
(2) More than one in case of association LS0088
(3) Always less than one 84. The molal elevation constant of water is 0.51.
(4) Less than one in case of association The boiling point of 0.1 molal aqueous NaCl
LS0080 solution is nearly :
76. The vant Hoff factor (i) for a dilute solution of (1) 100.05 °C (2) 100.1 °C
K3[Fe(CN)6] is : (3) 100.2° C (4) 101.0° C
(1) 10 (2) 4 (3) 5 (4) 0.25 LS0089
LS0081 85. Phenol associates in benzene as
77. The experimental molecular weight of an 1
C6H5OH  (C6H5OH)2
electrolyte will always be less than its calculated 2
value because the value of vant Hoff factor, 'i' is : If degree of association of phenol is 40%,
(1) Less than 1 (2) Greater than 1 Van't Hoff factor i is :-
(3) One (4) Zero (1) 1 (2) 0.8
LS0082 (3) 1.4 (4) 0.6
78. The vant Hoff factor (i) for a dilute aqueous LS0092
solution of Glucose is : 86. The values of observed and calculated molecular
(1) Zero (2) 1.0 (3) 1.5 (4) 2.0 weight of calcium nitrate are respectively 65.6
LS0083 and 164. The degree of dissociation of calcium
79. Osmotic pressure of 0.585% w/v NaCl solution nitrate will be :
at 27°C is . (1) 25% (2) 50%
(1) 2.49 atm (2) 4.92 atm (3) 75% (4) 60%
(3) 1.2 atm (4) 3.8 atm LS0093
LS0084 87. A 0.004M solution of Na2SO4 is isotonic with a
80 The substance A when dissolved in solvent B 0.010M solution of glucose at the 25°C
shows the molecular mass corresponding to A3. temperature. The degree of dissociation of
The vant Hoff's factor will be - Na2SO4 is
1 (1) 25% (2) 50%
(1) 1 (2) 2 (3) 3 (4)
3 (3) 75% (4) 85%
LS0085 LS0094
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88. A 5.8% (wt./vol.) NaCl solution will exert an 95. Two solutions of KNO3 and CH3COOH are
osmotic pressure closest to which one of the prepared separately. Molarity of both is 0.1M
following : and osmotic pressures are P1 and P2 respectively.
(1) 5.8% (wt./vol) sucrose solution The correct relationship between the osmotic
(2) 5.8% (wt./vol) glucose solution pressures is
(3) 2 M sucrose solution
(1) P2 > P1 (2) P1 = P2
(4) 1 M glucose solution
LS0095 P1 P2
(3) P1 > P2 (4) =
P1 + P2 P1 + P2
89. Which salt shows maximum osmotic pressure in
its 1M solution : LS0103
(1) AgNO3 (2) Na2SO4 96. The correct relationship between the boiling
(3) (NH4)3PO4 (4) MgCl2
points of dilute solutions of AlCl3(T1) and
LS0096
CaCl2(T2), having the same molar concentration
90. Which solution will exert highest osmotic is :
pressure?

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(1) T1 = T2 (2) T1 > T2
(1) 1M glucose solution (2) 1M urea solution
(3) T2 = T1 (4) T2 > T1
(3) 1M Alum solution (4) 1M NaCl solution
LS0097 LS0104
91. Which is the correct relation between osmotic 97. Which of the following 0.1 M aqueous solutions
pressure of 0.1M NaCl solution and 0.1M will have the lowest freezing point :
Na2SO4 solution ? (1) Potassium Sulphate (2) Sodium Chloride
(1) The osmotic pressure of Na2SO4 is less than (3) Urea (4) Glucose
NaCl solution
LS0105
(2) The osmotic pressure Na2SO4 is more than
NaCl solution 98. Which aqueous solution has minimum freezing
(3) Both have same osmotic pressure point?
(4) None of the above (1) 0.01 M NaCl (2) 0.005 M C2H5OH
LS0098 (3) 0.005 M MgI2 (4) 0.005 M MgSO4
92. The following solutions have equal LS0106
concentrations. Which one will show minimum 99. If α is the degree of dissociation of K4[Fe(CN)6],
osmotic pressure?
then abnormal mass of complex in the solution
(1) BaCl2 (2) AgNO3
will be :-
(3) Na2SO4 (4) (NH4)3PO4
LS0100 (1) Mnormal (1+2α)–1 (2) Mnormal (1+3α)–1

93. The osmotic pressure of equimolar solutions of (3) Mnormal (1+α)–1 (4) Mnormal (1+4α)–1
BaCl2, NaCl, and glucose will be in the order : LS0107
(1) Glucose > NaCl > BaCl2 100. Which solution will have least vapour pressure :
(2) BaCl2 > NaCl > Glucose (1) 0.1 M BaCl2 (2) 0.1 M urea
(3) NaCl > BaCl2 > Glucose (3) 0.1 M Na2SO4 (4) 0.1 M Na3PO4
(4) NaCl > Glucose > BaCl2 LS0108
LS0101 101. Which has maximum freezing point :
94. Which one of the following pairs of solutions will (1) 1 M of NaCl solution
be expected to be isotonic under the same (2) 1 M of KCl solution
(3) 1 M of CaCl2 solution
temperature ?
(4) 1 M of urea solution
(1) 0.1M urea and 0.1 M NaCl LS0109
(2) 0.1M urea and 0.2 M MgCl2 102. The freezing point of 1% w/w aqueous solution
(3) 0.1M NaCl and 0.1M Na2SO4 of calcium nitrate will be :
0
(1) 0 C (2) Above 00C
(4) 0.1M Ca(NO3)2 and 0.1M Na2SO4 0
(3) 1 C (4) Below 00C
LS0102 LS0110
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103. The following aqueous solution in the correct 107. The molecular weight of benzoic acid in benzene
order of decreasing freezing point is -
(1) 0.2M BaCl2, 0.2M KCl, 0.1M Na2SO4 as determined by depression in freezing point
(2) 0.2M KCl, 0.1M Na2SO4, 0.2M BaCl2 method corresponds to :
(3) 0.1M Na2SO4, 0.2M KCl, 0.2M BaCl2 (1) Ionisation of benzoic acid
(4) 0.1M Na2SO4, 0.2M BaCl2, 0.2M KCl
(2) Dimerization of benzoic acid
LS0111
(3) Trimerization of benzoic acid
104. Which of the following solutions will have highest
(4) Solvation of benzoic acid
boiling point ? LS0115
(1) 1% w/w Glucose in water
(2) 1% w/w NaCl in water 108. What would be the osmotic pressure of 0.1 M
(3) 1% w/w Ca3(PO4)2 in water K2SO4 solution (90% dissociated) at 27°C :-
(4) 1% w/w Urea in water (1) 6.89 atm (2) 0.689 atm
LS0112
(3) 0.344 atm (4) 3.4 atm
105. The freezing point of equimolal aqueous solution
will be highest for : LS0116
(1) urea (2) Ca(NO3)2 109. Which one has same Van't Hoff factor i as that

®
(3) Al(NO3)3 (4) NaCl of Hg2Cl2 :-
LS0113
(1) NaCl (2) Na2SO4
106. When mercuric Iodide is added to the aqueous
solution of potassium iodide ? (3) Al(NO3)3 (4) Al2(SO4)3
(1) The boiling point does not change LS0117
(2) Freezing point is raised
(3) The freezing point is lowered
(4) Freezing point does not change
LS0114

EXERCISE-I (Conceptual Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 4 4 4 3 4 4 3 2 2 3 3 2 1 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 2 2 2 4 1 1 4 1 4 2 2 1 3 4 2
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 4 3 2 1 4 1 1 1 2 1 4 3 2 2 1
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 3 3 2 2 4 1 4 4 2 1 4 1 2 1 4
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans. 1 3 3 2 3 1 2 3 4 2 2 4 1 2 4
Que. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. 2 2 2 2 4 3 2 2 2 2 3 3 3 3 3
Que. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. 2 2 2 4 3 2 1 1 4 4 4 4 3 2 1
Que. 106 107 108 109
Ans. 2 2 1 2
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115

EXERCISE-II (Previous Year Questions) AIPMT/NEET

AIPMT 2014 NEET-I 2016
1. Of the following 0.10m aqueous solutions, which 6. Which of the following statement about the
one will exhibit the largest freezing point composition of the vapour over an ideal a 1 : 1
depression? molar mixture of benzene and toluene is correct?
Assume that the temperature is constant at
(1) KCl (2) C6H12O6
(25°C).
(3) Al2(SO4)3 (4) K2SO4 (Given : Vapour Pressure Data at 25°C,
LS0138 benzene = 12.8 kPa, Toluene = 3.85 kPa)

AIPMT 2015 (1) The vapour will contain a higher percentage

of benzene
2. The boiling point of 0.2 mol kg–1 solution of X in
(2) The vapour will contain a higher percentage
water is greater than equimolal solution of Y in of toluene
water. Which one of the following statements is
(3) The vapour will contain equal amounts of

®
true in this case? benezene and toluene
(1) Molecular mass of X is greater than the (4) Not enough information is given to make a
molecular mass of Y. predication
(2) Molecular mass of X is less than the molecular LS0146
mass of Y. 7. At 100°C the vapour pressure of a solution of
(3) Y is undergoing dissociation in water while X 6.5g of a solute in 100 g water is 732 mm. If
–1
undergoes no change. Kb = 0.52 °C m , the boiling point of this
solution will be :-
(4) X is undergoing dissociation in water while Y
undergoes no change. (1) 101°C (2) 100°C (3) 102°C (4) 103°C
LS0147
LS0140
8. Consider the following liquid-vapour equilibrium.
3. Which one is not equal to zero for an ideal
solution:- Liquid  Vapour

(1) ∆Smix Which of the following relations is correct ?

(2) ∆Vmix d n G ∆H v d n P −∆H v
(1) = (2) =
(3) ∆P = Pobserved - PRaoult dT2 RT2 dT RT

(4) ∆Hmix d n P −∆H v d n P ∆H v

(3) = (4) =
dT2 T2 dT RT2
LS0141
LS0148
4. Which one of the following electrolytes has the
same value of van't Hoff's factor (i) as that of the NEET-II 2016
Al2(SO4)3 (if all are 100% ionised) ? 9. The van't Hoff factor (i) for a dilute aqueous
(1) K3[Fe(CN)6] (2) Al(NO3)3 solution of the strong electrolyte barium
hydroxide is
(3) K4[Fe(CN)6] (4) K2SO4
(1) 2 (2) 3 (3) 0 (4) 1
LS0142
LS0149
Re-AIPMT 2015 10. Which one of the following is incorrect for ideal
5. What is the mole fraction of the solute in a solution ?
1.00 m aqueous solution ? (1) ∆P = Pobs – Pcalculated by Raoult's law = 0
(1) 0.0354 (2) 0.0177 (2) ∆Gmix = 0
(3) 0.177 (4) 1.770 (3) ∆Hmix = 0
LS0143 (4) ∆Umix = 0
LS0150
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NEET(UG) 2017 17. The mixture which shows positive deviation from
11. If molality of a dilute solution is doubled, the Raoult's law is :-
value of molal depression constant (Kf) will be :- (1) Chloroethane + Bromoethane
(1) halved (2) Ethanol + Acetone
(2) tripled (3) Benzene + Toluene
(4) Acetone + Chloroform
(3) unchanged
LS0252
(4) doubled
LS0155 NEET (UG) 2020 (COVID-19)
12. Which of the following is dependent on temperature? 18. If 8g of a non-electrolyte solute is dissolved in
(1) Molarity 114 g of n-octane to reduce its vapour pressure
(2) Mole fraction to 80%, the molar mass (in g mol–1) of the
(3) Weight percentage solute is
[Given that molar mass of n-octane is 114 g
(4) Molality
mol–1]
LS0156 (1) 40 (2) 60 (3) 80 (4) 20

®
NEET(UG) 2019 LS0253
13. For an ideal solution, the correct option is :- 19. Isotonic solutions have same
(1) ∆mix S = 0 at constant T and P (1) vapour pressure
(2) freezing temperature
(2) ∆mix V ≠ 0 at constant T and P (3) osmotic pressure
(3) ∆mix H = 0 at constant T and P (4) boiling temperature
(4) ∆mix G = 0 at constant T and P LS0254
LS0238 NEET (UG) 2021
NEET(UG)(Odisha) 2019 20. The following solutions were prepared by
14. Which of the following statements is correct dissolving 10 g of glucose (C6H12O6) in 250 ml
regarding a solution of two compounds A and B of water (P1), 10 g of urea (CH4N2O) in 250 ml
exhibiting positive deviation from ideal of water (P2) and 10 g of sucrose (C12H22O11) in
behaviour? 250 ml of water (P3). The right option for the
(1) Intermolecular attractive forces between A-A decreasing order of osmotic pressure of these
and B-B are stronger than those between solutions is :
A-B. (1) P2 > P1 > P3 (2) P1 > P2 > P3
(2) ∆mix H = 0 at constant T and P (3) P2 > P3 > P1 (4) P3 > P1 > P2
(3) ∆mix V = 0 at constant T and P LS0255
(4) Intermolecular attractive forces between A-A 21. The correct option for the value of vapour
and B-B are equal to those between A-B. pressure of a solution at 45°C with benzene to
LS0239 octane in molar ratio 3 : 2 is :
15. The density of 2 M aqueous solution of NaOH is [At 45°C vapour pressure of benzene is 280 mm
1.28 g/cm3. The molality of the solution is Hg and that of octane is 420 mm Hg.
[Given that molecular mass of NaOH = 40 g mol–1] Assume Ideal gas]
(1) 1.20 m (2) 1.56 m (1) 160 mm of Hg (2) 168 mm of Hg
(3) 336 mm of Hg (4) 350 mm of Hg
(3) 1.67 m (4) 1.32 m
LS0256
LS0240
NEET (UG) 2020 NEET (UG) 2022

16. The freezing point depression constant (Kf) of 22. In one molal solution that contains 0.5 mole of a
–1 solute, there is
benzene is 5.12 K kg mol . The freezing point
depression for the solution of molality 0.078 m (1) 500 g of solvent
containing a non-electrolyte solute in benzene is (2) 100 mL of solvent
(rounded off upto two decimal places) : (3) 1000 g of solvent
(1) 0.60 K (2) 0.20 K (3) 0.80 K (4) 0.40 K (4) 500 mL of solvent
LS0251 LS0257
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NEET (UG) 2022 (OVERSEAS) NEET (UG) 2023 (Manipur)

23. One mole of sugar is dissolved in three moles of 25. The density of 1 M solution of a compound 'X' is
1.25 g mL . The correct option for the molality
–1
water at 298 K. The relative lowering of vapour
of solution is (Molar mass of compound X = 85
pressure is
g) :
(1) 0.20 (2) 0.50
(1) 0.705 m
(3) 0.33 (4) 0.25 (2) 1.208 m
LS0258 (3) 1.165 m
(4) 0.858 m
Re-NEET (UG) 2022
LS0261
24. KH value for some gases at the same temperature
'T' are given :
gas KH/k bar

®
Ar 40.3
CO2 1.67
HCHO 1.83 × 10–5
CH4 0.413
where KH is Henry's Law constant in water. The
order of their solubility in water is :
(1) Ar < CO2 < CH4 < HCHO
(2) Ar < CH4 < CO2 < HCHO
(3) HCHO < CO2 < CH4 < Ar
(4) HCHO < CH4 < CO2 < Ar
LS0259

EXERCISE-II (Previous Year Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 3 4 1 3 2 1 1 4 2 2 3 1 3 1 3
Que. 16 17 18 19 20 21 22 23 24 25
Ans. 4 2 1 3 1 3 1 4 1 4
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EXERCISE-III (Analytical Questions) Master Your Understanding

1. A 0.0020 m aqueous solution of an ionic 6. 200 mL of an aqueous solution of a protein

compound [Co(NH3)5(NO2)]Cl freezes at contain its 1.26 g. The Osmotic pressure of this
– 0.00732°C. Number of moles of ions which
solution at 300 K is found to be 2.57 × 10–3 bar.
1mol of ionic compound produces on being
The molar mass of protein will be :-
dissolved in water will be
(Kf = 1.86°C m–1) :- (R = 0.083 L bar mol–1 K–1)

(1) 1 (2) 2 (3) 3 (4) 4 (1) 61038 g mol–1 (2) 51022 g mol–1
LS0124 (3) 122044 g mol–1 (4) 31011 g mol–1
2. An aqueous solution of KI is 1.00 molal. Which LS0131
change will cause increase in vapour pressure of 7. pA and pB are the vapour pressure of pure liquid
the solution ?
components, A and B, respectively of an ideal
(1) Addition of water

®
binary solution. If xA represents the mole
(2) Addition of NaCl fraction of component A, the total pressure of
(3) Addition of Na2SO4 the solution will be.
(4) Addition of 100 molal KI (1) pB + xA (pB – pA)
LS0125
(2) pB + xA (pA – pB)
-1
3. A solution of sucrose (molar mass = 342 g mol ) (3) pA + xA (pB – pA)
has been prepared by dissolving 68.5 g of
(4) pA + xA (pA – pB)
sucrose in 1000 g of water. The freezing point
of the solution obtained will be :- LS0132
(Kf for water = 1.86 K kg mol–1) 8. Which of the following compounds can be used
(1) –0.570°C as antifreeze in automobile radiators ?
(2) –0.372°C (1) Nitrophenol (2) Ethyl alcohol
(3) –0.520°C (3) Methyl alcohol (4) Glycol
(4) +0.372°C LS0133
LS0126
9. Vapour pressure of chloroform (CHCl3) and
4. The freezing point depression constant for water
–1
dichloromethane (CH2Cl2) at 25°C are
is –1.86°C m . If 5 g Na2SO4 is dissolved in
200 mmHg and 415 mmHg respectively.
45.0 g H2O, the freezing point is changed by
Vapour pressure of the solution obtained by
–3.82°C. Calculate the Van't Hoff factor for
Na2SO4 mixing 25.5 g of CHCl3 and 40g of CH2Cl2 at
(1) 2.05 (2) 2.63 the same temperature will be: (Molecular mass of

(3) 3.11 (4) 0.381 CHCl3 = 119.5 u and molecular mass of

CH2Cl2 = 85 u)
LS0128
(1) 347.9 mmHg (2) 280.5 mmHg
5. The Van't Hoff factor i for a compound which
undergoes dissociation in one solvent and (3) 173.9 mmHg (4) 615 mmHg
association in other solvent is respectively : LS0134
(1) Less than one and greater than one
10. 6.02 × 1020 molecules of urea are present in
(2) Less than one and less than one
100mL of its solution. The concentration of
(3) Greater than one and less than one solution is :-
(4) Greater than one and greater than one (1) 0.1 M (2) 0.02 M
LS0129 (3) 0.01 M (4) 0.001M
LS0135
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11. Which of the following solutions has the highest 18. Which of the following plots does not represent
normality :- the behaviour of an ideal binary liquid solution :-
(1) 8 g of KOH per litre (1) Plot of PA versus XA (mole fraction of A in
(2) 1 N phosphoric acid liquid phase) is linear
(3) 6 g of NaOH per 100 mL
(2) Plot of PB versus XB is linear
(4) 0.5 M H2SO4
(3) Plot of ptotal versus XA (or XB) is linear
LS0165
12. An aqueous solution of glucose is 10% w/v. The (4) Plot of ptotal versus XA is non linear
volume in which 2 mole of it is dissolved will be:- LS0175
(1) 18 litre (2) 3.6 litre 19. The vapour pressure of two pure liquids (A) and
(3) 0.9 litre (4) 1.8 litre (B) are 100 and 80 torr respectively. The total
LS0166 pressure of the solution obtained by mixing 2
13. The mole fraction of the solute in one molal mol of (A) and 3 mol of (B) would be

®
aqueous solution is :- (1) 20 torr (2) 36 torr
(1) 0.027 (2) 0.036
(3) 88 torr (4) 180 torr
(3) 0.018 (4) 0.009
LS0168 LS0176
14. –1
What will be density (in g mL ) of 3.60 molar 20. For a solution of two liquids A and B, it was
sulphuric acid having 29% by mass. proved that P = XA (PA0 – PB0) + PB0. The solution
–1
(Molar mass = 98 g mol ) is:–
(1) 1.88 (2) 1.22
(1) Ideal
(3) 1.45 (4) 1.64
(2) Non ideal
LS0170
15. The molality of a urea solution in which 0.0100g (3) Both (1) and (2)
of urea. [(NH2)2CO] is added to 0.3000 dm3 of (4) None of the above
water at STP is :- LS0177
(1) 0.555 m
21. Mole fraction of A vapours above solution in
(2) 5.55 × 10–4 m
mixture of A and B (XA = 0.4) will be :-
(3) 33.3 m
(4) 3.33 × 10–2 m (PA° = 100mm, PB° = 200mm)
LS0171 (1) 0.4 (2) 0.8
16. The concentration of a solution of H2O2 is (3) 0.25 (4) None
6.8%(w/V) then the volume concentration of the
LS0178
solution is:-
(1) 22.4 (2) 11.2 (3) 20 (4) 5 22. The vapour pressure of pure benzene and
LS0172 toluene are 160 and 60 torr respectively. The
17. The vapour pressure of two liquids ‘P’ and ‘Q’ mole fraction of toluene in vapour phase in
are 80 and 60 torr, respectively. The total contact with equimolar solution of benzene and
vapour pressure of solution obtained by mixing toluene is:
3 mole of P and 2 mol of Q would be :- (1) 0.50 (2) 0.6
(1) 68 torr (2) 140 torr (3) 0.27 (4) 0.73
(3) 72 torr (4) 20 torr
LS0179
LS0174
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23. A solution has a 1 : 4 mole ratio of pentane to 29. The vapour pressure of a solution of 5 g of non
hexane. The vapour pressures of the pure electrolyte in 100 g. of water at a particular
hydrocarbons at 20°C are 440 mm Hg for –2
temperature is 2985 Nm . The vapour pressure
pentane and 120 mm Hg for hexane. The mole –2
of pure water at that temperature is 3000 Nm .
fraction of pentane in the vapour phase would The molecular weight of the solute is :-
be :-
(1) 180 (2) 90 (3) 270 (4) 200
(1) 0.200 (2) 0.478 (3) 0.549 (4) 0.786
LS0190
LS0181
30. The vapour pressure of a pure liquid solvent (X)
24. A mixture of ethyl alcohol and propyl alcohol has
is decreased to 0.60 atm. from 0.80 atm on
a vapour pressure of 290 mm at 300 K. The
vapour pressure of propyl alcohol is 200 mm. If addition of a non volatile substance (Y). The mole
the mole fraction of ethyl alcohol is 0.6, its fraction of (Y) in the solution is:-
vapour pressure (in mm) at the same temperature (1) 0.20 (2) 0.25 (3) 0.5 (4) 0.75
will be

®
LS0192
(1) 300 (2) 700 (3) 360 (4) 350
LS0182 31. 18 g of glucose (C6H12O6) is added to 178.2 g of
water. The vapour pressure of this aqueous
25. A mixture of liquid showing positive deviation in
Raoult's law is :- solution at 100 °C is :

(1) (CH3)2 CO + C2H5OH (1) 759.00 torr (2) 7.60 torr

(2) (CH3)2CO + CHCl3 (3) 76.00 torr (4) 752.40 torr
(3) (C2H5)2O + CHCl3
LS0193
(4) (CH3)2CO + C6H5NH2
32. Water is added to the solution such that the mole
LS0183
fraction of water in the solution becomes 0.9.
26. Azeotropic mixture are :
The boiling point of the solution is
(1) Mixture of two solids
(1) 354.7 K (2) 375.5 K
(2) Those which boil at different temperatures
(3) Those which can be fractionally distilled (3) 376.2 K (4) 380.4 K
(4) Constant boiling mixtures LS0194
LS0185 33. Glucose is added to 1 litre water to such an
27. An azeotropic mixture of two liquids boil at a ∆Tf 1
lower temperature than either of them when extent that becomes equal to , the
Kf 1000
(1) It is saturated
wt. of glucose added is :-
(2) It does not deviate from Raoult's law
(1) 180 g (2) 18 g
(3) It shows negative deviation from Raoult's law
(4) It shows positive deviation from Raoult's law (3) 1.8 g (4) 0.18 g
LS0186 LS0195
28. The azeotropic mixture of water (B.P 100.15 C) 0
34. A solution of urea boils at 100.18°C at the
and HCl (B.P. –850C) boils at 108.50C. When atomospheric pressure. If Kf and Kb for water are
this mixture is distilled, it is possible to obtain : –1
1.86 and 0.512K kg mol respectively, the
(1) Pure HCl
above solution will freeze at :-
(2) Pure water
(1) –6.54°C (2) –0.654°C
(3) Pure water as well as HCl
(4) Neither HCl nor H2O in their pure states (3) 6.54°C (4) 0.654°C
LS0187 LS0196
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35. Kf for water is 1.86 K kg mol . If your –1
41. The Vant Hoff factor for 0.1 M Ba(NO3)2 solution
automobile radiator holds 1.0 kg of water, how is 2.74 . The degree of dissociation is :-
many grams of ethylene glycol (C2H6O2) must (1) 91.3% (2) 87%
you add to get the freezing point of the solution (3) 100% (4) 74%
lowered to –2.8°C ? LS0206
(1) 27 g (2) 72 g (3) 93 g (4) 39 g
42. Arrange the following aqueous solutions in the
LS0198
order of their increasing boiling points :-
36. Osmosis of A into solution B will not take place –4
(i) 10 M NaCl (ii) 10–4 M Urea
if:- –3
(iii) 10 M MgCl2 (iv) 10–2 M NaCl
(1) A is hypertonic
(1) (i) < (ii) < (iv) < (iii)
(2) A is hypotonic
(2) (ii)<(i)=(iii)<(iv)
(3) A is isotonic
(4) Either 1 or 3 may correct (3) (ii)<(i)<(iii)<(iv)

®
LS0199 (4) (iv)<(iii)<(i)=(ii)
LS0207
37. The average osmotic pressure of human blood is
7.8 bar at 37°C. What is the concentration of an 43. Among 0.1M solutions of urea,Na3PO4 and
aqueous NaCl solution that could be used in the Al2(SO4)3:-
blood stream (a) The vapour pressure and freezing point are
(1) 0.16 mol L–1 (2) 0.32 mol L–1 the lowest for urea
(3) 0.60 mol L–1 (4) 0.45 mol L–1 (b) The vapour pressure and freezing point are
LS0201 the highest for urea
38. A 5.25% solution of a substance is isotonic with (c) The elevation in boiling point is the highest
a 1.5% solution of urea (molar mass=60g mol )
–1 for Al2(SO4)3
in the same solvent. If the densities of both the (d) The depression in freezing point is the
solutions are assumed to be equal to 1.0 gcm ,
–3 highest for Al2(SO4)3
molar mass of the substance will be. (1) Only a (2) b & c both
(1) 115.0 g mol
–1
(2) 105.0 g mol
–1 (3) b, c and d (4) a, b, c and d
(3) 210.0 g mol –1
(4) 90.0 g mol –1 LS0209

LS0203 44. When equimolar aqueous solutions of glucose,

39. A 5% (w/V) solution of cane sugar (molar mass sodium chloride and barium nitrate are compared
342) is isotonic with 1% (w/V) of a solution of an the vapour pressure of the solutions will be in the
unknown solute. The molar mass of unknown following order :-
–1
solute in g mol is :- (1) Glucose > NaCl > Ba(NO3)2
(1) 136.2 (2) 171.2 (3) 68.4 (4) 34.2 (2) Glucose = NaCl = Ba(NO3)2
LS0204 (3) Ba(NO3)2 > NaCl > Glucose
40. The degree of dissociation (α) of a weak (4) NaCl > Ba(NO3)2 > Glucose
electrolyte, AxBy is related to Vant Hoff factor LS0210
(i) by the expression :-
45. A 0.2 molal aqueous solution of a weak acid
x + y −1 x + y +1 (HX) is 20% ionised. The elevation in boiling
(1) α = (2) α =
i −1 i −1 point of this solution is (given Kb = 0.52°C kg
i −1 i −1 mol–1 for H2O)
(3) α = (4) α =
(x + y − 1) x + y +1 (1) 0.81 (2) 0.125 (3) 0.48 (4) 1.3
LS0205 LS0212
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46. The substance when dissolved in water would 52. Which of the two processes occur at the same
decrease the vapour pressure of water to the rate in order to achieve this equilibrium ?
greatest extent is :-
 Solution
Solute + Solvent 
(1) 0.1 M KCl (2) 0.1 M urea
(3) 0.1 M BaCl2 (4) 0.1 M NaCl (1) Saturation, unsaturation
LS0213 (2) Saturation, crystallization
(3) Crystallization, dissolution
47. The molar mass of NaCl determined by the
osmotic pressure method will be :– (4) Unsaturation, crystallization
(1) Higher than the theoretical value LS0241
(2) Lower than the theoretical value 53. What happens to the solubility of substance with
(3) The same as the theoretical value the rise in temperature, if the dissolution process
(4) None of these is endothermic ?
LS0214
(1) Increases
48.
3
A solution containing 10g per dm of urea

®
–1 (2) Decreases
(molecular mass = 60g mol ) is isotonic with a
5% solution of a nonvolatile solute. The (3) Increases or decreases depend on nature of
molecular mass of this nonvolatile solute is : substance
(1) 250g mol
–1
(2) 300g mol–1 (4) No effect of temperature on solubility
(3) 350g mol–1 (4) 200g mol–1 LS0242
LS0118
54. In the graph given below, what does the slope of
49. 1.00g of a non-electrolyte solute (molar mass the line represent ?
–1
250g mol ) was dissolved in 51.2g of benzene. If
Partial pressure

the freezing point depression constant, Kf of

of HCl (Torr)

–1
benzene is 5.12 K kg mol , the freezing point of
benzene will be lowered by :
(1) 0.4 K (2) 0.3 K (3) 0.5 K (4) 0.2 K
LS0119 Mole fraction of HCl in
50. During osmosis, flow of water through a its solution in cyclohexane

semipermeable membrane is : (1) Partial pressure of the gas in vapour phase (p)
(1) from both sides of semipermeable membrane (2) Mole fraction of gas in the solution (x)
with equal flow rates
(3) Henry's law constant (KH)
(2) from both sides of semipermeable membrane
(4) All of the above
with unequal flow rates
LS0243
(3) from solution having lower concentration
only 55. ∆Tb and ∆Tf for ethanoic acid in benzene will
(4) from solution having higher concentration be___ (i)___ of normal value (neither association
only nor dissocation) and molar mass of solute
LS0121 (Ethanoic acid) ____(ii)____ of normal value.
Here, (i) and (ii) refer to :
51. 0.5 molal aqueous solution of a weak acid (HX) is
(1) (i) Half ; (ii) half
20% ionised. If Kf for water is1.86 K kg mol–1,
(2) (i) Twice ; (ii) half
the lowering in freezing point of the solution is :
(1) –0.56 K (2) –1.12 K (3) (i) Half ; (ii) twice

(3) 0.56 K (4) 1.12 K (4) (i) Twice ; (ii) twice

LS0244
LS0123
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56. Which of the following units is useful in relating 61. Out of the following concentration terms :-
concentration of solution with its vapour (a) mass% (b) ppm (c) mole fraction
pressure? (d) molality (e) molarity
(1) Mole fraction (2) Mass percentage Those which are independents on temperature
is:-
(3) Parts per million (4) Molality
(1) a, b, d & e
LS0245
(2) b, e
57. Different gases have different KH values at the (3) a, b, c & d
same temperature. Their solubilities will be in the (4) a, c & d
order. LS0263
Gas KH/kbar 62. Given below are two statements:
He 114.97 Statement I : Solutions which obey Raoult's
H2 69.16 law over entire range of concentration are
N2 76.48

®
known as ideal solutions.
O2 34.86 Statement II : For an ideal mixture of
(1) O2 > H2 > N2 > He (2) He > N2 > H2 > O2 components ∆Hmix = 0, ∆Vmix = 0.
(3) He > H2 > N2 > O2 (4) O2 > H2 > He > N2 In the light of the above statements, choose the
LS0247 correct answer from the options given below:
58 Calculate the mass of urea (NH2CONH2) required (1) Both Statement I and Statement II are
to prepare 2.06 kg of 0.5 molal aqueous correct.
solution? (2) Statement I is correct and Statement II is
incorrect.
(1) 90 g (2) 120 g (3) 60 g (4) 45 g
(3) Statement I is incorrect and Statement II is
LS0248
correct.
59. Vapour pressure of pure water at 298 K is (4) Both Statement I and Statement II are
25 mm of Hg. 60 g of urea (NH2CONH2) is incorrect.
dissolved in 882 g of water. Calculate the vapour LS0264
pressure of water for this solution and its relative 63. Given below are two statements:
lowering? Statement I : For KCl, NaCl and MgSO4, Vant
(1) 22mm ; 0.02 (2) 24.5 mm ; 0.02 hoff factor (i) approaches two as solution
(3) 20mm ; 0.01 (4) 27mm ; 0.01 becomes very dilute.
LS0249 Statement II : The value of 'i' gets close to four
60. In the match of Column I with Column II :- for CsI3.
Column-I Column-II In the light of the above statements, choose the
(A) Pgas = KHxgas (P) Raoult's law correct answer from the options given below:
(B) P1 = P°x1 (Q) Henry's law (1) Both Statement I and Statement II are
(C) Ptotal = P1+ P2 (R) Dalton's law
d ∆H v correct.
(D) ln P = + (S) Clasius clayperon (2) Statement I is correct and Statement II is
dt RT2
equation incorrect.
The correct one is :- (3) Statement I is incorrect and Statement II is
(1) (A-P), (B-Q), (C-R), (D-S) correct.
(2) (A-Q), (B-P), (C-R), (D-S)
(3) (A-Q), (B-R), (C-P), (D-S) (4) Both Statement I and Statement II are
(4) (A-P), (B-S), (C-Q), (D-R) incorrect.
LS0262 LS0265

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64. Given below are two statements : one is labelled as
Assertion (A) and the other is labelled as Reason
(R) :
Assertion (A) :- The extent to which a solute is
dissociated or associated can be expressed by
Van't hoff factor 'i'.
Reason (R) :- Van't hoff factor can be zero.
In the light of the above statements, choose the
correct answer from the options given below :
(1) Both (A) and (R) are true and (R) is the
correct explanation of (A).
(2) Both (A) and (R) are true and (R) is NOT the
correct explanation of (A).
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65. Given below are two statements : one is labelled as
Assertion (A) and the other is labelled as Reason
(R) :
Assertion (A) :- Ethanoic acid (acetic acid)
dimerise in benzene.
Reason (R) :- It happens due to hydrogen
bonding.
In the light of the above statements, choose the
correct answer from the options given below :
(1) Both (A) and (R) are true and (R) is the
correct explanation of (A).
(2) Both (A) and (R) are true and (R) is NOT the
correct explanation of (A).

®
(3) (A) is true but (R) is false. (3) (A) is true but (R) is false.
(4) (A) is false but (R) is true. (4) (A) is false but (R) is true.
LS0266 LS0267

EXERCISE-III (Analytical Questions) ANSWER KEY

Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans. 2 1 2 2 3 1 2 4 1 3 3 2 3 2 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 1 3 4 3 1 3 3 2 4 1 4 4 4 1 2
Que. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans. 4 3 4 2 3 4 1 3 3 3 2 3 3 1 2
Que. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 3 2 2 1 2 4 3 1 3 3 1 1 3 2 2
Que. 61 62 63 64 65
Ans. 3 1 2 3 1
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