Professional Documents
Culture Documents
7 (1) 7+final+doi
7 (1) 7+final+doi
Sri Widyastuti1, Yitno Utomo2, Annisa Firdayanti1, Rhenny Ratnawati1*, Umi Sholikah3
1
Department of Environmental Engineering, Universitas PGRI Adi Buana Surabaya, Dukuh Menanggal XII
Surabaya, 60234, West Java, Indonesia
2
Department of Industrial Engineering, Universitas PGRI Adi Buana Surabaya, Dukuh Menanggal XII Surabaya
60234, West Java, Indonesia
3
Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-Hiroshima, Japan
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 89
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
1. INTRODUCTION
Currently, people have used plastic for all types of packaging. The advantages of plastic are
waterproof, strong enough, transparent, lightweight, and relatively cheap. However, plastic has
the disadvantage that it is difficult to decompose. When plastic is dumped into the environment,
it becomes inorganic waste that is dangerous and causes environmental pollution (Nuriyah et al.,
2018; Fachrul et al., 2021; Sugito et al., 2021). Data from Jambeck et al., (2015) states that
Indonesia is the second largest producer of plastic waste after China with 187.2 million tons.
Meanwhile, Rahadi et al., (2020) concluded that of the 6.3 billion tons of plastic waste in the
world so far only 9% can be processed through the recycling process, the rest is still accumulated
in the environment.
Plastic waste that is scattered, burned, or thrown away takes a long time to decompose and
can turn into toxic chemicals (Purwanegara et al., 2023). These chemicals will be dissolved in the
environment and then absorbed by plants and cause disease in humans (Thahir et al., 2021;
Kuntaryo et al., 2023). One of the efforts to overcome this problem is to develop bioplastics.
Bioplastics are plastics that are easily degraded naturally by microbial activity and naturally do
not leave toxic residues that can return to nature. It happens because the raw material for
bioplastics is starch which contains carbohydrates, the main components of which are amylose
and amylopectin (Nuriyah et al., 2018).
Starch is a natural polymer. The use of starch to produce biodegradable materials is because
it is environmentally friendly, easily degraded, available in large quantities, and affordable (Melani
et al., 2017). The use of starch in the production of bioplastics can improve biodegradable
properties. Starch as the main ingredient of bioplastics still has shortcomings, so it is necessary
to add additives to improve its properties (Widyastuti et al., 2021). There are weaknesses in the
manufacture of starch-based bioplastics such as low mechanical properties (tensile strength,
strain, and young's modulus) and hydrophilicity.
The disadvantages of production bioplastics can be overcome by mixing starch and other
biofilm-forming materials such as glycerol and sorbitol (Maneking et al., 2020). The addition of
glycerol plays a role as a contributor to the elastic properties of the plastic film, the addition of
higher glycerol will increase the elongation value when the plastic breaks (Nurrahmi et al., 2020).
Research conducted by Suryanto et al., (2016) explains that glycerol plays an important role in
the manufacture of bioplastics because glycerol can reduce the hardness of bioplastics caused by
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 90
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
2. RESEARCH METHODOLOGY
2.1 Materials
Tapioca starch waste produced from tapioca flour factory UD. HH in Kediri, East Java, Indonesia.
Rice waste came from a village in the Balongbendo area. Other materials needed include distilled
water, glycerol, 96% ethanol, and acetate solvent pH 7. The tools used in this study were a baking
sheet, blender, digital scale, 250 mL beaker glass, water bath, stirrer, 100 mL measuring cup,
container, 200 mesh size filter, and oven.
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 91
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
At the beginning of the manufacture was drying rice waste under the hot sun to a moisture
content of 70%. Next, the dried rice waste was mashed with a blender and sieved through a 200
mesh sieve. Then, the researchers put materials such as tapioca starch waste and rice waste into
a 250 mL glass beaker according to variations as presented in Table 1.
Load of break
Tensile strength (MPa) = (Original width)(Original thickness) (1)
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 92
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
The final length of the test object − the initial length of the test object
Elongation (%) = The initial length of the test object
× 100% (2)
c. Biodegradation Test
This test method was to prepare a 2×6 cm sample and then weighed it. Then, the researchers
buried the sample for 1 week. After that, the researchers dried the sample and weighed the
constant weight. Calculations are conducted using the formula:
e. Bioplastics Standard
Indonesia national standards for bioplastics are presented in Table 2.
This research produces bioplastics in the form of sheets with a smooth surface, chewy and sticky
texture, easy to fold, and easy to tear. The results of bioplastics from variations in tapioca starch
waste and rice waste can be seen in Figure 1.
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 93
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
Figure 1 Variations in tapioca starch waste and rice waste, A) 100% rice waste bioplastic;
B) 100% tapioca starch waste bioplastic; C) Bioplastic tapioca starch and rice waste (30% :
70%); D) Bioplastic tapioca starch and rice waste (50% : 50%); E) Bioplastic tapioca starch
and rice waste (70% : 30%)
The results of the tensile strength test on bioplastics can be seen in Figure 2. The results of
the analysis of the tensile strength test data show that the addition of glycerol and the use of
organic waste raw materials such as rice waste affects the tensile strength test results . The results
of the analysis of the five bioplastic samples when compared with SNI 7188.7:2016 for the easily
biodegradable bioplastic category, still do not meet the quality standard, which is at least
13.7 MPa. Changes in tensile strength that occur in bioplastics are related to the interaction
between rice waste, tapioca starch waste, and glycerol, that the higher the glycerol
concentration, the lower the tensile strength value (Kurniawati et al., 2022). This study used 10
mL of glycerol for the manufacture of bioplastics.
The tensile strength of bioplastic which is only made from rice waste raw material has the
highest yield when compared to other compositions. It is due to the addition of amylose from
rice waste which makes the bioplastic polymer network denser (Haryanto dan Saputri, 2017). The
diagram shows that as the composition of rice waste decreases, the tensile strength produced
decreases. Arini et al., (2017) stated that the more starch used, the smaller the tensile strength
value and it is following the results of research that has been conducted.
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 94
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
4
Tensile Strength Value (MPa) 3,45
3,5
3
2,5 2,11 2 2
2 1,6
1,5
1
0,5
0
N 100 P 100 P30N70 P50N50 P70N30
Sample
Research by Saputra et al., (2015) using a starch concentration of 90% resulted in a tensile
strength value of 5.43 MPa. While this study used a starch concentration of 100%. The
concentration used for starch in this study was higher than that of Saputra et al., (2015) resulting
in a low plastic tensile strength value. Moreover, research by Aini et al., (2018) which uses rice
waste raw materials and varied additions of chitosan produces the best tensile strength value of
58.1 MPa with 50% chitosan concentration. While this study did not use chitosan as additional
material in the manufacture of bioplastics. The increase in the value of the tensile strength of
bioplastics because the number of hydrogen bonds in the plastic increases with the increase in
the percentage of chitosan. The more hydrogen bonds that occur, the stronger the plastic film
and the less likely it is to break.
The results of the elongation at break test on bioplastics can be seen in Figure 3. The results
of the data analysis of the elongation test at the break when compared with SNI 7188.7:2016 for
the bioplastic category that is easily decomposed, the first sample, 100% rice waste, has met the
quality standard, which is a maximum of 5%. Starch is one of the polysaccharides as the main
ingredient in the manufacture of bioplastics and also plays a role in binding polymer
bonds.Research by Arini et al., (2017) explains that the more starch added, the lower the
elongation. It is following the results of existing research, it can be seen in the diagram that the
higher the amount of starch, the lower the elongation value. Rahim dan Musta (2019) explained
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 95
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
that a decrease in the mechanical properties of bioplastics such as elongation at break occurs
because the more starch added, the lower the surface interaction between the two polymers.
14 13
Elongation at Break Value (%)
12
9,7
10
7,7
8
6 5,2
3,8
4
2
0
N100 P100 P30N70 P50N50 P70N30
Sample
Moreover, research by Herawati dan Yustinah (2021) stated that the more amount of rice
waste used, the higher the elongation value or plastic flexibility. It is not following the results of
this research which can be seen in the diagram that the use of 100% rice waste mass gets the
lowest elongation at break. The research by Selpiana et al., (2015) who made bioplastics from
aking rice (dry wasted rice) flour and the use of varied chitosan states that the more chitosan
added, the elongation will decrease. The decrease in elongation is the result of the presence of
additives added to chitosan. Furthermore, chitosan will shorten the distance between the
stretched biopolymers and reduce the intermolecular forces between the chains.
The results of the biodegradation test on bioplastics can be seen in Figure 3. The results of the
analysis of the biodegradation test data when compared with SNI 7188.7:2016 for the easily
biodegradable bioplastic category, the five samples have met the specified quality standard,
which is at least 30%. Research by Dai et al., (2010) states that the type of plasticizer such as
glycerol added to the starch solution can affect the characteristics of the bioplastic produced.
Research by Haryanto dan Saputri (2017) states that the most important property of bioplastics
is decomposition.
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 96
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
120
100
Biodegradation Value (%)
100 87 84
80 70
60 47
40
20
0
N100 P100 P30N70 P50N50 P70N30
Sample
The research of Nafilah dan Sedyadi (2019) explained that the humidity of the test media will
affect the degradation process because it can facilitate the consumption of bioplastics by
microorganisms. According to Situmorang et al., (2019), the functional groups O-H (hydroxyl
ester), C=O (carbonyl), and C-O (carboxyl) contained in bioplastics will facilitate the degradation
process. The group above has water-loving (hydrophilic) properties that allow water molecules
to attract microbes from the environment to penetrate the plastic matrix. This study proves it in
the N100 sample which is a 100% composition rice waste that has a high water absorption ability
because in only 7 (seven) days it can get 100% results.
Moreover, a study by Martina et al., (2016) which uses aking rice as the basic ingredient in
the manufacture of bioplastics states that bioplastics with higher mass compositions produce
high biodegradability as well. It is following the results of this study, which is the biodegradation
test of 100% composition of rice waste sample with the use of 30 grams of the mass showed the
highest biodegradation results. The use mass of one of the materials must be higher to optimally
degrade bioplastics. According to Nur et al., (2020), the factors that affect the biodegradability of
plastics are hydrophobicity, manufacturing process, morphology, additives, polymer structure,
and molecular weight of the materials used.
The FTIR (Fourier Transform Infra Red Spectrophotometry) test at the Testing Service Unit of the
Faculty of Pharmacy, Airlangga University, Surabaya, obtained the results of bioplastic testing that
referred to the quality standard value of SNI 7188.7:2016 for the bioplastic category.According
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 97
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
to Harsojuwono et al., (2016), the absorption peak at a wave number of 3200-3500 cm-1 indicates
an O-H (hydroxyl) group bonded to hydrogen. Meanwhile, wave numbers 2850-2970 indicate
alkanes (C-H), wave numbers 2750-2850 indicate aldehydes (C-H), spectrum 2500-2700 indicate
hydrogen bonds of carboxylic acids, and 2100-2260 indicate the presence of alkynes (C≡C). Wave
numbers 2000-2300 cm-1 indicate the ester functional group and 1650-2000 cm-1 indicate the
presence of simple aromatic compounds. Wave numbers 1000-1300 cm-1 indicate the presence
of carboxyl (C-O). Wave numbers 675-995 cm-1 indicate the presence of an alkene functional
group (C=C). Moreover, below 700 cm-1 indicates other hydrocarbon compounds such as -(CH2)n.
a. N100 Sample
The results of the N100 sample bioplastic FTIR test are presented in Figure 4.
Samples with a 100% composition of rice waste raw materials having the O-H (hydroxyl)
functional group will bind to hydrogen at a wave number of 3278.21 cm-1. The C-H functional
group of the alkane compound was indicated at 2933.32 cm-1 as an antimicrobial agent. C≡C
triple bonds (alkynes) and ester compounds were identified at 2136.79 cm-1. Simple aromatic
compounds exist in the wave number of 1642.10 cm-1. The C-O (carboxyl) functional group
was indicated at the numbers of 1239.64 cm-1, 1210.93 cm-1, 1150.05 cm-1, 1105.87 cm-1,
1078.97 cm-1, and 1018.90 cm-1. C=C double bonds (alkenes) were identified at 850.41 cm -1
and 924,88 cm-1. Wave number 643.84 cm-1 is a hydrocarbon compound-(CH2)n.
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 98
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
b. P100 Sample
The results of the P100 sample bioplastic FTIR test are presented in Figure 5.
Samples with 100% tapioca starch waste as raw material have O-H (hydroxyl)
functional groups bonded to hydrogen at wave numbers 3480.88 cm-1, 3449.44 cm-1, and
3358.17 cm-1. The C-H functional groups of alkane compounds were indicated at 2952.68 cm-
1
, 2916.17 cm-1, and 2873.26 cm-1 as antimicrobial agents. The C-H functional group
(aldehyde) was found at numbers 2772.12 cm-1 and 2838.45 cm-1. C≡C triple bonds (alkynes)
and ester compounds were identified at numbers 2073.38 cm -1, 2163.85 cm-1, and 2257.09
cm-1. The C-O (carboxyl) functional groups were identified at 1300.20 cm-1, 1255.00 cm-1,
1217.17 cm-1, 1163.31 cm-1, 1103.67 cm-1, and 1044.71 cm-1. C=C double bonds (alkenes)
were identified at the numbers 972.66 cm-1, 940.38 cm-1, 898.71 cm-1, 841.11 cm-1, 808.17
cm-1, and 698.14 cm-1. Wave numbers 626.62 cm-1 and 648.23 cm-1are included in the
hydrocarbon compound -(CH2)n.
c. P30N70 Sample
The results of the P30N70 bioplastic sample FTIR test are presented in Figure 6. The raw
material sample of tapioca starch waste with rice waste in a ratio of 30%:70% had an O-H
(hydroxyl) functional group that will bind to hydrogen at a wave number of 3288.06 cm-1. The
C-H functional group of alkane compounds was indicated at 2929.18 cm-1 as an antimicrobial
Doi: https://doi.org/10.25105/urbanenvirotech.v7i1.18775 99
Bioplastic from Tapioca Strach Waste and Rice Waste
Widyastuti, Firdayanti, Utomo, Ratnawati
p-ISSN 2579-9150; e-ISSN 2579-9207, Volume 7, Number 1, page 89-105, April 2024
Accredited SINTA 2 byMinistry of Research, Technology, and
Higher Education of The Republic of Indonesia No. 230/E/KPT/2022 on December 30th, 2022
from October 1st, 2022 to September 30th, 2027
agent. C≡C triple bonds (alkynes) and ester compounds were identified at numbers 2138.22
cm-1 and 2367.71cm-1. The C-O (carboxyl) functional group was identified at the numbers
1243.86 cm-1, 1211.09 cm-1, 1149.33 cm-1, 1105.34 cm-1, 1078.59 cm-1 and 1016.45 cm-1. C=C
double bonds (alkenes) were indicated at the numbers 926.99 cm-1, 851.61 cm-1, and 755.54
cm-1. Wave number 647.78 cm-1 is a hydrocarbon compound -(CH2)n.
d. P50N50 Sample.
The results of the P50N50 bioplastic sample FTIR test are presented in Figure 7.
The raw material sample of tapioca starch waste with rice waste in a ratio of 50%:50% has an
O-H (hydroxyl) functional group that will bind to hydrogen at a wave number of 3289.93 cm -1.
The C-H functional group of the alkane compound was indicated at 2934.44 cm-1 as an
antimicrobial agent. C≡C triple bonds (alkynes) and ester compounds were identified at
numbers 2103.94 cm-1 and 2140.99 cm-1. Simple aromatic compounds were identified at
1888.92 cm-1 and 1974.64 cm-1. The C-O (carboxyl) functional group was identified at the
numbers 1242.14 cm-1, 1211.05 cm-1, 1150.34 cm-1, 1106.02 cm-1, 1078.61 cm-1, and 1015.29
cm-1. C=C double bonds (alkenes) were identified at 852.54 cm-1 and 924.75 cm-1.
e. P70N30 Sample
The results of the FTIR test for bioplastic sample P70N30 are presented in Figure 8. The raw
material sample of tapioca starch waste with rice waste in a ratio of 70%:30% has an O-H
(hydroxyl) functional group that will bind to hydrogen at a wave number of 3287.63 cm-1. The
C-H functional groups of alkane compounds were indicated at numbers 2889.80 cm -1 and
2931.35 cm-1 as antimicrobial agents. C≡C triple bonds (alkynes) and ester compounds were
identified at 2141.31 cm-1. Simple aromatic compounds were identified at 1899.50 cm-1 and
1952.78 cm-1. The C-O (carboxyl) functional group was identified at the numbers 1242.82
cm1, 1209.40 cm-1, 1149.73 cm-1, 1105.57 cm-1, 1078.95 cm-1, and 1016.56 cm-1. The C=C
double bond (alkene) is found at the numbers 755.02 cm-1, 925.96 cm-1, and 850.10 cm-1.
The results above explain that the functional groups in bioplastics can combine with other
compounds to form branch bonds and cross-links, therefore, enabling the creation of strong
polymers. The strength of a chemical bond depends on the number of molecular bonds and
the type of bond. The more molecular bonds that occur, the stronger the resulting material
(Situmorang et al., 2019). Because the functional groups contained in the bioplastic film are
bound to the functional groups of their constituent components, the resulting bioplastic still
has the properties of its constituent components such as ease to decompose, plastic, and the
presence of antibacterial properties (Kurniawati et al., 2022). The FTIR results show that there
are no new functional groups, which means that there is no chemical change so the process
of bioplastics productionis physical mixing. This result makes bioplastics still have hydrophilic
properties like their constituent properties (Zaroh dan Widyastuti, 2019).
4. CONCLUSION
The quality of bioplastics produced from the composition of 100% rice waste raw materials has
the highest tensile strength test results of 3.45 MPa. The elongation test value at break is 3.8%
which has met the SNI for bioplastics and the biodegradation test of 100% has also met the SNI
for bioplastics. The resulting bioplastics contain functional groups O-H (hydroxyl) bonded to
hydrogen, C-H (alkanes), C≡C (alkynes), esters, simple aromatic compounds, C-O (carboxyl), C=C
(alkenes), and hydrocarbons -(CH2)n.
5. ACKNOWLEDGMENT
The authors gratefully acknowledge the Research and Public Service of the Universitas PGRI Adi
Buana for the Adi Buana Research Grant, contract No. 104.1/LPPM/VII/2021. We also thank Ms.
Nurmasyta Sylviana Priyonofor her scientific contribution.
REFERENCES
Aini, A. N., Riyati, N., Restiandika, F., & Lestari, R. A. S. 2018. Rice Waste Biodegradable Plastic.
Prosiding SNTK Eco-SMART. 1(1): 203-211.
Arini, D., Ulum, M. S., & Kasman. 2017. Manufacture and Testing of Mechanical Properties on
Durian Seed Flour Based Biodegradable Plastics. Natural Science: Journal of Science and
Technology. 6(3): 276-283.
Bahari, D. D., & Cahyonugroho, O. H. 2018. Potential of Rice Flour and Leaf Waste as Alternative
Biodegradable Plastic Materials. Jurnal Envirotek. 10(2): 50-54.
Dai, H., Chang, P. R., Geng, F., Yu, J., & Ma, X. 2010. Preparation and Properties of Starch Based
Film using N, N-bis (2-hydroxyethyl) Formamide as a New Plasticizer. Carbohydrate Polymers.
79(2): 306-311.
Fachrul, M.F., Fulazzaky, M.A, Rinanti, A., Muda, K., Tazkiaturrizki, T., Sunaryo, T. 2024.
Mass Transfer Kinetics of Polyethylene Degradation by Bacterial-Fungal Consortium.
Cleaner Waste Systems. Volume 7, April 2024, 100136.
Doi: https://doi.org/10.1016/j.clwas.2024.100136.
Harsojuwono, B. A., Arnata, I. W., & Mulyani, S. 2016. The Profile Surface and Functional Groups
of Biodegradable Plastics which Made from Cassava Modified Starch. Scientific Journal of
Food Technology. 3(2): 97-103.
Haryanto, & Saputri, A. E. 2017. Development of Bioplastics from Tapioca Starch and White
Glutinous Rice Flour. Techno. 17(2): 104-110.
Herawati, R., & Yustinah. 2021. The Comparative Effect of Aking Rice Flour and Banana Peel Flour
in Production of Biodegradable Plastics. Jurnal Konversi. 10(2): 1-6.
Jambeck, J. R., Geyer, R., Wilcox, C., Siegler, T. R., Perryman, M., Andrady, A., Narayan, R., & Law,
K. L. 2015. Plastic Waste Inputs from Land into the Ocean. Science. 347(6223): 768-771.
Kuntaryo, A. M., Pramiati Purwaningrum, Tazkiaturrizki, Astari Minarti, & Fitrio Ashardiono. 2023.
The Recycling Potential of Solid Waste in Jatinegara Sub-District, East Jakarta. Indonesian
Journal of Urban and Environmental Technology. 6(1): 100-113.
Doi: https://doi.org/10.25105/urbanenvirotech.v6i1.14793.
Kurniawati, C. T., Sutrisno, J., Walujo, D. A., & Sembodo, B. P. 2022. Utilization of Sweet Corn Cob
Waste (Zea Mays L. Saccharata) as Bioplastic Material with the Addition of ZnO and Glycerol.
Jurnal Teknik WAKTU. 20(01): 54-64.
Maneking, E., Sangian, H. F., & Tongkukuta, S. H. J. 2020. Production and Characterization of
Bioplastics Based on Biomass with Glycerol Plasticizer. Jurnal MIPA. 9(1): 23-27.
Martina, S. P., Masturi, & Yulianti, I. 2016. Analysis of Biodegradable Plastic Made from Aking Rice.
Jurnal Ilmu Pendidikan Fisika. 1(1): 9-12.
Melani, A., Herawati, N., & Kurniawan, A. F. 2017. Bioplastics of Taro Bulbs through the Melt
Intercalation Process (Study of the Effect of Filler Type, Filler Concentration and Type of
Plasticiezer). Distilasi. 2(2): 53-67.
Nafilah, I., & Sedyadi, E. 2019. Effect of Addition of Sorbitol and Glycerol on Cassava Starch
Bioplastic Degradation in Soil and Compost Media. Jurnal Kridatama Sains dan Teknologi.
1(1): 38-47.
Nur, R. A., Nazir, N., & Taib, G. 2020. Bioplastic Characteristics of Durian Seed Starch and Cassava
Starch Using MCC (Microcrystalline Cellulose) Filler from Cocoa Peel. Gema Agro. 25(01):
1-10. Doi: https://doi.org/http://dx.doi.org/10.22225/ga.25.1.1713.01-10.
Nuriyah, L., Saroja, G., Ghufron, M., Razanata, A., & Rosid, N. F. 2018. Tensile Strength and
Elongation Characteristics of Bioplastics Made from Cilembu Sweet Potatoes Starch with
Various Types of Plasticizers. NATURAL B. 4(4): 177-182.
Nurrahmi, S., Nuraisyah, S., & Hernawati. 2020. Effect of Addition of Starch and Glycerol
Plasticizer on Mechanical Properties of Biodegradable Plastics. Jurnal Fisika dan Terapannya.
7(2): 128-138. Doi: https://doi.org/10.24252/jft.v7i2.18267.
Purwanegara, M. S., Pinandhika, A. A. N. T., Sun, Y., & Athalia, R. 2023. Analyzing the Factors That
Affect the Amount of Plastic Waste. Indonesian Journal of Urban and Environmental
Technology. 6(2): 229-257. Doi: https://doi.org/10.25105/urbanenvirotech.v6i2.16654.
Rahim, A., & Musta, R. 2019. The Effect of Adding Tapioca Flour to Cassava Starch (Manihot
Esculenta) on the Production of Biodegradable Plastics and Their Characterization.
Indonesian Journal of Chemical Analysis. 02(02): 66-73.
Saputra, A., Lutfi, M., & Masruroh, E. 2015. Study of Manufacturing and Mechanical
Characteristics of Biodegradable Plastic Based on Sweet Potatoes (Amorphophallus
Campanulatus). Journal of Agricultural and Biosystems Engineering. 3(1): 1-6.
Selpiana, Riansya, J. F., & Yordan, K. 2015. Production of Biodegradable Plastic from Aking Rice
Flour. Seminar Nasional Added Value of Energy Resources Avoer VII Proceeding. 7: 130-138.
Situmorang, F. U., Hartiati, A., & Harsojuwono, B. A. 2019. Effect of Concentration of Taro Potato
Starch (Colocasia Esculenta) and Type of Plasticizer on Bioplastic Characteristics. Journal of
Agroindustrial Engineering and Management. 7(3): 457-467.
Sugito, Ratnawati, R., & Afiafani, H. 2021. Hybrid Anaerobic Baffled Reactor for
Removal of BOD and Phosphate Concentration in Domestic Wastewater.
Indonesian Journal of Urban and Environmental Technology. 5(1): 14-27.
Doi: https://doi.org/10.25105/urbanenvirotech.v5i1.10571.
Suryanto, H., Hutomo, P. T., Wanjaya, R., Puspitasari, P., & Sukarni. 2016. The Stucture of
Bioplastic from Cassava Starch with Nanoclay Reinforcement. Proceedings of the
International Mechanical Engineering and Engineering Education Conferences.
1778(030027): 1-5. Doi: https://doi.org/10.1063/1.4965761.
Thahir, R., Fadhilah, N., Nurdiyanti, Magfirah, N., & Anisa. 2021. Caring for the Environment from
Pollution of Plastic Waste in the Lembanna Area. Jurnal Abdidas. 2(4): 969-974.
Widyastuti, S., Ratnawati, R., & Priyono, N. S. 2021. Production of Bioplastics from Organic Waste
with Tapioca Flour and Glycerol. Journal of Natural Resources and Environmental
Management. 11(4): 677-684.
Zaroh, P. F., & Widyastuti, S. 2019. Utilization of Tapioca Dregs as Raw Material for Biodegradable
Plastics. Jurnal Wahana. 71(2): 15-22.