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Full Download PDF of Test Bank For Organic Chemistry, 6th Edition: Brown All Chapter
Full Download PDF of Test Bank For Organic Chemistry, 6th Edition: Brown All Chapter
Edition: Brown
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Question Which of the following species has an atom that has an unfilled valence shell of electrons?
Answer molecular hydrogen, H2
-
hydroxide anion, HO
boron trifluoride, BF3
water, H2O
Question Which of the following species has an atom that has an unfilled valence shell of electrons?
Answer molecular bromine, Br2
-
fluoride anion, F
ammonia, NH3
aluminum trichloride, AlCl3
PCl3
(CH 3) 2CHOH
CH3CH 2CH 2OH
CO2
HCºCH
Cl
2
Question What is the approximate value of the H-C-H bond angles in methane, CH4?
Answer 90°
109°
120°
180°
Question Which of the following bonds has the smallest dipole moment?
Answer C-N
C-O
C-F
O-H
Question Which of the following bonds has the smallest dipole moment?
Answer Li-Cl
C-H
O-H
H-Cl
Answer 1
2
3
4
Answer 1
2
3
4
HCºCH
Cl
2
Question Which of the following best represents the shape of the 2s atomic orbital of carbon?
6 of 14
Answer 1
2
3
4
Question Which of the following best represents the shape of a 2p atomic orbital of carbon?
Answer 1
2
3
4
Answer 1
2
3
4
Answer 1
2
3
4
Question Which atomic orbitals overlap to form the C=O bond of acetone, (CH3)2C=O?
Answer 3 2
C 2sp + O 2sp
2
C 2sp + O 2p
2 2
C 2sp + O 2sp
3
C 2sp + O 2sp
Question Which atomic orbitals overlap to form the C-O bond of dimethyl ether, (CH3)2O?
Answer 3 2
C 2sp + O 2sp
2
C 2sp + O 2p
2 2
C 2sp + O 2sp
3 3
C 2sp + O 2sp
Question What is the approximate value of the length of the C=C bond in ethane, CH2=CH2?
Answer 121 pm
134 pm
142 pm
154 pm
Question What is the approximate value of the length of the CºC bond in ethyne, HCºCH?
Answer 121 pm
134 pm
142 pm
154 pm
Question Which of the following statements is not true regarding resonance structures?
Answer All resonance structures must have the same number of electrons
Each atom in all of the resonance structures must have a complete shell of valence electrons
All resonance structures must have the same arrangement of atoms
All resonance structures must be valid Lewis structures
Question Which of the following statements is not true regarding resonance structures?
Answer Each resonance structure is in rapid equilibrium with all of the other structures
The resonance structures may have different energies
All resonance structures must have the same arrangement of atoms
All resonance structures must have the same number of electrons
Question Which of the following statements is not true about the acetate anion, CH CO -?
3 2
Answer The oxygen atoms bear the same amount of charge
The two carbon-oxygen bonds are the same length
The carbon atom bears the negative charge
It is basic
Question Rank the following in order of decreasing importance as a contributing resonance structure to the molecular structure of acetone,
CH3COCH3 (more important > less important)
Answer 1>2>3
1>3>2
2>1>3
3>1>2
Answer 1
2
3
4
Answer 4
5
6
7
Question How many electrons are there in the valence shell of the oxygen atom of water?
Answer 2
4
6
8
Question How many electrons are there in the valence shell of the nitrogen atom of ammonia?
Answer 4
5
6
8
Question Which atomic orbitals overlap to form the carbon-hydrogen sbonding molecular orbitals of ethane, CH3CH3?
Answer C2p + H1s
C2sp + H1s
2
C2sp + H1s
C2sp3 + H1s
Question Which atomic orbitals overlap to form the carbon-hydrogen sbonding molecular orbitals of ethene, H2 C=CH 2?
Answer C2p + H1s
C2sp + H1s
2
C2sp + H1s
3
C2sp + H1s
Question Which atomic orbitals overlap to form the carbon-carbon sand p bonding molecular orbitals of ethene, H2C=CH 2?
Answer 3 3
C2sp + C2sp , and C2p + C2p
2 2 2 2
C2sp + C2sp , and C2sp + C2sp
2 2
C2sp + C2sp , and C2p + C2p
3 3 2 2
C2sp + C2sp , and C2sp + C2sp
Question Which atomic orbitals overlap to form the carbon-hydrogen sbonding molecular orbitals of ethyne, HCºCH?
Answer C2p + H1s
C2sp + H1s
2
C2sp + H1s
3
C2sp + H1s
Question Which atomic orbitals overlap to form the carbon-carbon smolecular bonding orbital of ethyne, HCºCH?
Answer C2p + C2p
C2sp + C2sp
2 2
C2sp + C2sp
C2sp3 + C2sp3
Answer 1
2
3
4
Answer 1
2
3
4
Answer 1
2
3
4
Answer 1
2
3
4
Answer 1
2
3
4
Answer 1
2
3
4
Answer 1
2
3
4
Question Which of the following shows curved arrows that correctly accounts for the differences between the two structures?
Answer 1
2
3
4
1.methane, CH4
2.methyl carbocation, CH +
3
3.methyl carbanion, CH -
3
4.methyl radical, CH ×
3
Answer only 1 and 2
only 1 and 3
only 1 and 4
only 2 and 3
Question Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in water (H2O) and which contain the lone
pair of electrons. Label each orbital with its hybridization.
Answer
Question Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in ammonia (NH3 ) and which contain the
lone pair of electons. Label each orbital with its hybridization.
Answer
Question Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in ethene (ethylene, H2C=CH 2). Label
3
each bond (e.g., C–H s bond) and indicate which atomic orbitals contribute to this bond (e.g., C 2sp + H 1s).
Answer
Question Provide a neatly drawn figure to show the atomic orbitals that overlap to form each of the bonds in ethyne (acetylene, HCºCH). Label each
3
bond (e.g., C–H s bond) and indicate which atomic orbitals contribute to this bond (e.g., C 2sp + H 1s).
Answer
Add Question Here
Question Draw bond-line structures of all of the alkanes that have the formula C5H12.
Answer
Question Draw bond-line structures of all of the alcohols that have the formula C4 H10 O.
Answer
Question Draw bond-line structures of all of the aldehydes that have the formula C5H10O.
Answer
Question Draw bond-line structures of all of the ketones that have the formula C5H10 O.
Answer
Question Draw bond-line structures of all of the primary (1°) alcohols that have the formula C5H12O.
Answer
Question Draw bond-line structures of all of the tertiary (3°) alcohols that have the formula C6H14 O.
Answer
Question Draw bond-line structures of all of the secondary (2°) amines that have the formula C4 H9N.
Answer
Question Draw bond-line structures of all of the tertiary (3°) amines that have the formula C5H11 N.
Answer
2
Question Circle all of the sp hybridized atoms in the following molecular structure.
Answer
Add Question Here
Question Circle all of the sp hybridized atoms in the following molecular structure.
13 of 14
Answer
Answer
Add Question Here
Answer
Add Question Here
Answer C H N O
14 18 2 5
Question Circle and name the functional groups in the following molecule.
Answer
Add Question Here
Question Circle and name the functional groups in the following molecule.
Answer
Siitä on nyt aikaa, kun tuo tapahtui. Mutta yhä vieläkin muistelen
eräänlaisella kaiholla henkivakuutustoimintaani. Siinä oli tuntuvasti
kiertävän trubaduurin tunnelmaa. Jokainen talo oli kuin lukittu
ritarilinna, josta edeltäpäin ei tiennyt, aukenisiko se vai ei. Sai joka
kerta virittää harppunsa eri tavalla, riippuen siitä, minkälaisten
ihmisten kanssa kulloinkin joutui tekemisiin. Toiset pitivät polskista ja
iloisista rallituksista t.s. heille piti aatteestakin puhua kuin leikkiä
laskien. Toiset taas ottivat asian verisen vakavasti. Heille piti asia
esittää saarnaäänellä ja joka kerta kun »kuolema» mainittiin, piti
hiljentää ääntä ja kuiskailla salaperäisesti, — aivan kuin olisi
viikatemies jo odottanut oviverhojen takana, valmiina ryhtymään
virkaansa heti, kun asiamies Aadam Kuuskoski oli saanut paperit
reilaan.
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