6.

(D)
SECTION-A
1. (B) d 100
Sol. [SO3] = 100 gram / min = mole /
dt 80
Sol. x A + yB  z C
min = 1.25 mole/min.
–d –d –d –1 d –d 1 d
[A] = [B] = 1.5 [SO2] = [O2] = [SO3]
dt dt dt 2 dt dt 2 dt

 [C]
–d 1.25 1.25
[O2] = mole/min = × 32
–1 – d –1 – d 1 dt 2 2
 [A] = [B] =
3 dt 3 dt 2 gram/min = 20 gram/min
–d
[C] 7. (B)
dt Sol. R k [A]a [B]b

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x=3 y=3 z=2 1
acc. to data, a=2, b=
2
1
2. (B) 2A + B  Product
2
1 d[c] 1 d[D] 1 d[A] d[B] 1 d[A] d[B]
Sol. =– = = – =
2 dt 3 dt 4 dt dt 4 dt dt

B & Dwill be same side and A & C will be 8. (D)

LA
same state ratio of stoichiometric 1 1 1 13
Sol. Overall order = + + = .
coefficient 2 3 4 12
B:D: A : C = 1 : 3 : 4 : 2.
9. (B)
Sol. Rate of reaction is independent of
3. (B) concentration of reactant for zero order
1 d[B] reaction.
1 d[A]
Sol. 3A  2B, =
2 dt 2 dt
10. (D)
Sol. R = K [A] [B]
4. (D) Order wrt. A = 1 & above wr.t B = 1
A

K depends an temperature
Sol. A + 2B 
 3C + D
R = K [A] [B]
–d[A] –1 d[B] 1 d[c]  d[D]
= = = 11. (C)
dt 2 dt 3 dt dt
Sol. A + B  Products
R = k [A]2 [B]3
B

5. (A) R' = R.22 [A]2 23 [B]3 = 25 R = 32R

CLASSES BY ANKUR SIR 7983744732

12. (C) 20. (B)
Sol. Unit of k is L mol–1 sec–1 60
Sol. t1/2 = 10 No. of Half life = =6
so order is 2. 10
CO C C 
13. (B) half life Ct = n
= O6 =  O 
(2) (2)  64 
2.303 C
Sol. t= log O  t
K Ct
21. (C)
2.303 Sol. It is properties of Ist order Rxn and other
= [log CO – log Ct ]
K all are properties of IInd order.
K t
= log CO – log Ct  Ct
2.303 22. (B)
Sol. A+BC
– K R = k [A]m[B]n
=   t + log CO
 2.303  compere exp. (A) & (B)
n
– K 0.1  1 
So slope =  = m=3

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
 2.303  0.8  2 
compere exp. (B) & (D)
n
14. (C) 0.8  1 
= n=0 so. R =
Sol. According to graph given it would be zero 0.8  2 
order reaction so rate independent of time. K[A]
3

15. (A) 23. (C)

1 dx
LA
Sol. N2O5  2NO2 + O2 2
Sol. = K[A]
2 dt
R = K [N2O5]
–4 –1 –1
R = 6.2 × 10 S × 1.25 mole L dx
–4 –1 –1
= 7.75 × 10 mole L S

16. (B)
Sol. Equal amount of Rxn completed in equal
time property as zero order Rxn, and unit dx
–1 –1
log = 2log[A] + logk
as Rate constant mole Litre sec dt

17. (C) compare with y = mx + c graph obtained

A

Sol. Unit of rate constant is (time)–1. Hence first

order reaction. 24. (D)
Time required to change concentration 1
Sol. A (s)  2 B (g) + C (g)
ln2
M to 0.25 M = 2 × t1/2 = 2 × = 20 min. 1  P  P0 
k K = ln    P0 = 0
t  P  Pt 
B

18. (A) Pt = 150 P = 225

Sol. A + B   product 1  225 
ln  
1
r = K [A] [B]
2 20  225 – 150 
r1 = K [1]1 [1]2 = 1 × 10–2 (K = 1 × 1  225 
 ln   = 0.05 ln 3
10–2) 20  75 
2
 1  1 1 1  225  1  225 
r1 = K     = 1 × 10–2 × = 1.25 × ln   = ln  
2 2  8 20  75  20  225  P40 
10–3 2
 225  225
  75  = 225  P
19. (B)   40

Sol. Reaction is zero order (unit of k) 225 1

=
[B] = 2 × moles of A reacted 75  75 225 – P40
–1
[B] = 2 × kt = 0.2 mol lit .  P40 = 200

CLASSES BY ANKUR SIR 7983744732

25. (A) 33. (B)
Sol. 2 A (g)  3 B (g) + C (g) 1  a 
Sol. k= ln  
t=0 P0 0 t ax
0 V  a
3 x
t = 3 hour (P0 – x) Vt  x
2
 a   V 
x ax = V V 
2     t 
 
(P0 + x) = 2 P0 34. (A)
x = P0
Reaction is completed in limited time so 106
Sol. log k = 15.0 –
reaction is zero order reaction. T
compair this relation with log k =
26. (B) E
log A –
Sol. A  2 B + C 2.303RT
t=0 P0 0 0 we find A = 1015. E = 1.9 ×

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P0 104 KJ
t=t (PO – x) 2x x 35. (B)
P0 + 2x = 176 Slow  C + D
Sol. A + B 
0 2 P0 P0 3
fast
A + C  E
P0 = 270 P0 = 90
2 x = 176 – 90 = 86 R = k [A] [B] (slow step rate is determining
x = 43 step)
SECTION-B
Pressure of A after 10 minute = 90 – 43 =
LA
36. (C)
47
Sol. Since (A) is the intermediate reactive
27. (B) species whose concentration is
determined from equilibrium step.
Sol. NH4NO2 (aq)  N2 (g) + 2H2O ()
Slow step is :
2.303  V – VO 
K= log     A + B2   AB + B (slow)
t  V – Vt  r = k[A][B2]
2.303 From equilibrium step
 V0 = 0  K = log
20 A2 A + A (fast)
 70 – 0  [A]2
 70 – 40  keq =
  [A 2 ]
A

2.303  70   [A] = (keq[A2])

1/2
= log    K
20  30  Substitute the value of [A] in equation (i),
2.303 7 r = k.keq 1/2[A2]1/2[B2]
= log .
1200 3 1 3
Thus, order of reaction = + 1 = =1.5
2 2
28. (A)
B

Sol. Rate increases as temperature increases. 37. (D)


1 d[Br ] 1 d[Br2 ] d[Br2 ] 3
Sol. – = + or =–
29. (B) 5 dt 3 dt dt 5

d[Br ]
30. (B) dt
Sol. K = A × e– Ea/RT
= A × e– Ea/RT
= A = 6.0 ×
1014 s–1. 38. (B)
Sol. 2N2O5 
 4NO2 + O2
31. (D)  d[N2 O5 ]
– = k . [N2O5]
dt
32. (A) –4 –5 –1
1.02  10 = 3.4  10 s  [N2O5]
Sol. H = Eaf - Eab 1.02  104
[N2O5] = =3
– 20 = 60 – Eab so Eab = 80 . 3.4  10 5
3

CLASSES BY ANKUR SIR 7983744732

39. (B) 46. (B)
Sol. Unit of K is mole L–1 Sec–1 Sol. 2A + B  products
x y
So order is 0. r = K[A] [B]
0.3 = K[A] [B]y
x
….(A)
40. (B) 2.4 = K[2A]x [2B]y ….(B)
Sol. As given, it is an elementary reaction. (2)
 8 = 2x × 2y
(1)
41. (D)
Or, 8 = 2x+y  x + y = 3
x=1 y=2
1 a  2.303 a
Sol. K= ln = log
t  a  x 
 t ax 47. (A)
2.303 1 2.303 4 Sol. (A) For a first order reaction,
K = log = log =
20 0.25 20 1 2.303 a
K log , where a is initial
0.0693 min–1 t ax
concentration, and x is the amount reacted

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42. (C) in time t. For half-life x  a / 2 , t  t1 / 2
Sol. K = Ae– E/RT 2.303 a
K log
K aa/2
43. (B) 2.303 0.693
–E1 /RT –E 2 / RT
t1 / 2  log 2  .
Sol. K1 = A 1e and K2 = A 2 e K K
K1 A
= 1 = e(E2 –E1 ) / RT ; A1 and A2 are not 48. (B)
K2 A2
Sol. (B) For a zero order reaction,
LA
given. t1 / 2  [ A0 ] / 2 K .

44. (A)
49. (B)
Sol. Half life is not depend upon initial
Sol. (B) According to Arrhenius equation,
concentration.  Ea / RT
K  Ae when Ea  0, K  A .
45. (B)
(A) 4 (B*) 3 50. (B)
(C) 2 (D) 1 Sol. (B) Molecularity of a reaction can be
Sol. M   N defined only for an elementary reaction
x because complex reaction does not take
r = K [M]
A

place in one single step and it is almost

as [M] is doubled, rate increases by a
impossible for all the total molecules of the
factor of 8.
x reactants to be in a state of encounter
i.e. 8 r = K [2M]
x simultaneously.
  8 = (B)
x=3
B

CLASSES BY ANKUR SIR 7983744732