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3. The carbon-carbon sigma bond in ethane is formed by overlap of which two orbitals?

A. 2p-2p
B. sp-sp
2 2
C. sp -sp
3 3
D. sp -sp

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.07
Subtopic: Hybridization
Topic: Molecular Shape

2-2
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
4.What is the IUPAC name of the following compound?

A. 4,4-dimethylpentane
B.1-tert-butylpropane
C.2,2-dimethylpentane
D. 1,1,1-trimethylbutane

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-3
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
5.The correct IUPAC name of the following compound is

A. 2-ethyl-3,5-dimethylheptane.
B.6-ethyl-5,5-dimethylheptane.
C.3,4,4-trimethyloctane.
D. 5,5,6-trimethyloctane.
Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

6.The common name of the following group is

A. n-butyl
B. sec-butyl
C. isobutyl
D. tert-butyl

Bloom's Level: 1. Remember


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.16
Subtopic: Alkyl groups
Topic: Alkanes (Acyclic and Cyclic)

2-4
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
7. Which one of the following is 2,2,5-trimethylhexane?

A. (CH3)2CHCH2C(CH3)3

B. (CH3)2CHCH2CH2C(CH3)3
C. CH3CH2CH(CH3)C(CH3)3
D. (CH3)2CHCH2CH2CH2C(CH3)3
Accessibility: Keyboard Navigation
Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

8.The correct IUPAC name of the following is

A. 2,4,7-trimethylnonane.
B. 7-ethyl-2,4-dimethyloctane.
C. 3,6,8-trimethylnonane.
D. 2-ethyl-5,7-dimethyloctane.

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-5
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
9.What is the IUPAC name of the following?

A. 5,6-diethylhexane
B. 5-ethyl-6-methylheptane
C. 2,3-diethylhexane
D. 4-ethyl-3-methylheptane
Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

10.What is the IUPAC name of the following?

A. 1-ethyl-4.4-dimethylcyclopentane
B.1-ethyl-3,3-dimethylcyclopentane
C.3-ethyl-1,1-dimethylcyclopentane
D. 4-ethyl-1,1-dimethylcyclopentane

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.18
Subtopic: IUPAC Nomenclature of cycloalkanes
Topic: Alkanes (Acyclic and Cyclic)

2-6
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
11. Cyclohexane is composed of

A. methine groups.
B.methylene groups.
C.methyl groups.
D. both methine and methylene groups.
Accessibility: Keyboard Navigation
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.11
Subtopic: IUPAC Nomenclature of cycloalkanes
Topic: Alkanes (Acyclic and Cyclic)

12. All the carbons in cyclopentane are

A. primary carbons.
B.secondary carbons.
C.tertiary carbons.
D. quaternary carbons.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.16
Subtopic: IUPAC Nomenclature of cycloalkanes
Topic: Alkanes (Acyclic and Cyclic)

2-7
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
13.The correct name of the following compound is

A. (1-methylpropyl)cyclohexane.
B.(2-methylpropyl)cyclohexane.
C.(2,2-dimethylethyl)cyclohexane.
D. (2,2-dimethylpropyl)cyclohexane.

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.18
Subtopic: IUPAC Nomenclature of cycloalkanes
Topic: Alkanes (Acyclic and Cyclic)

2-8
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
14.The correct IUPAC name of the following compound is

A. (1-methylhexyl)cyclopentane.
B.(1-pentylethyl)cyclopentane.
C.2-cyclopentylheptane.
D. 1-cyclopentyl-2-heptane.

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.18
Subtopic: IUPAC Nomenclature of cycloalkanes
Topic: Alkanes (Acyclic and Cyclic)

15.The C-C sigma bond in acetylene is formed by the overlap of which two orbitals?

A. 2p-2p
B. sp-sp
2 2
C. sp -sp
3 3
D. sp -sp

Bloom's Level: 2. Understand


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.09
Subtopic: Hybridization
Topic: Molecular Shape

2-9
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
° °
16.The boiling point of isobutane (-10.2 C) is lower than n-butane (-0.4 C) because
isobutane has

A. weaker intermolecular van der Waals forces.


B. stronger intermolecular van der Waals forces.
C. weaker dipole-dipole attractive forces.
D. stronger dipole-dipole attractive forces.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.21
Subtopic: Intermolecular forces
Topic: Functional Groups

17. Which of the following describes an atom or group of atoms that has similar
chemical properties when it occurs in different compounds?
A. hydrocarbon
B.functional group
C.paraffin
D. isomer

Accessibility: Keyboard Navigation


Bloom's Level: 1. Remember
Chapter: 02
Difficulty: Easy
Gradable: automatic
Section: 02.19
Subtopic: C-Z functional groups (Z = N, O, S, halogen)
Subtopic: Hydrocarbons
Topic: Functional Groups

2-10
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
18.Arrange the following isomeric alkanes in order of increasing boiling point.

I. n-heptane

II. 2,3-dimethylpentane

III. 2,2,3-trimethylbutane

A. I < II < III


B. II < III < I
C. III < I < II
D. III < II < I
Accessibility: Keyboard Navigation
Bloom's Level: 4. Analyze
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.21
Subtopic: Intermolecular forces
Topic: Functional Groups

19. The oxidation states of carbon range from

A. 0 to +2.
B. 0 to +4.
C. -4 to 0.
D. -4 to +4.

Accessibility: Keyboard Navigation


Bloom's Level: 1. Remember
Chapter: 02
Difficulty: Easy
Gradable: automatic
Section: 02.23
Subtopic: Acyclic vs cyclic
Topic: Alkanes (Acyclic and Cyclic)

2-11
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
20.Which of the following has(have) a higher oxidation state of carbon than the carbon in
formaldehyde, H2C=O?
I. CH3OH

II. HCO2H

III. H2CO3

A. I
B. III
C. II and III
D. I, II, and III
Accessibility: Keyboard Navigation
Bloom's Level: 4. Analyze
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.23
Subtopic: Acyclic vs cyclic
Topic: Alkanes (Acyclic and Cyclic)

21. The tert-butyl group can also be called

A. 1,1-dimethylpropyl.
B.1,1-dimethylethyl.
C.2,2-dimethylpropyl.
D. 2,2-dimethylethyl.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.16
Subtopic: Alkyl groups
Topic: Alkanes (Acyclic and Cyclic)

2-12
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
22.Carbon atoms 1, 2, and 3 in the following structure are classified, respectively, as

A. tertiary, primary, secondary.


B. quaternary, secondary, secondary.
C. quaternary, primary, tertiary.
D. quaternary, secondary, tertiary.

Bloom's Level: 2. Understand


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.16
Subtopic: Alkyl groups
Topic: Alkanes (Acyclic and Cyclic)

23. Identify the isomer of C6H14 that only has primary and tertiary carbons.

A. hexane
B. 2,2-dimethylbutane
C. 3-methylpentane
D. 2,3-dimethylbutane

Accessibility: Keyboard Navigation


Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Hard
Gradable: automatic
Section: 02.16
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-13
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
24.Why can heats of combustion of constitutional isomers of hydrocarbons be used to
measure their stabilities?
I. Combustion of constitutional isomers gives different final states.

II. Combustion of constitutional isomers gives the same final states.

III. Constitutional isomers of hydrocarbons have the same potential energies.

IV. Constitutional isomers of hydrocarbons have different potential energies.

A. only I
B. only II
C. I and III
D. II and IV
Accessibility: Keyboard Navigation
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.22
Subtopic: Reactions of alkanes
Topic: Alkanes (Acyclic and Cyclic)

°
25.The heats of combustion (-∆H ) of heptane and 3,3-dimethypentane are 4,817 and 4,809

kJ/mol, respectively. Which statement is true?

A. Heptane is 8 kJ/mol more stable then 3,3-dimethylpentane.


B. 3,3-Dimethylpentane is 8 kJ/mol more stable than heptane.
C. Stabilities cannot be compared since they are not isomers.
D. Stabilities cannot be compared since they give different combustion products.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.22
Subtopic: Reactions of alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-14
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
26.The reaction of acetylene with hydrogen gas is shown below. Which statements are true
concerning the reaction?

I. Acetylene is oxidized to ethane.

II. Acetylene is reduced to ethane.

III. Carbon changes oxidation state from -1 to -3.

IV. Hydrogen (from H2) changes oxidation state from 0 to +1.

A. I and III
B. II and IV
C. I, III, and IV
D. II, III, and IV
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.23
Subtopic: Reactions of alkanes
Topic: Alkanes (Acyclic and Cyclic)

27. How many methine groups are there in isopropylcyclopentane?

A. one
B. two
C. three
D. four

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.11
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-15
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
28. What is the total number of constitutional isomers with the formula C5H12?

A. two
B. three
C. four
D. five
Accessibility: Keyboard Navigation
Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.13
Subtopic: Constitutional isomers
Topic: Drawing Organic Molecules

29.What is the IUPAC name of the following?

A. 6-isopropyl-3-methylnonane
B. 2-ethyl-5-isopropyloctane
C. 6-propyl-3-methylnonane
D. 2-ethyl-5-propyloctane

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-16
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
30. How many moles of O2 gas would be consumed in the complete combustion of
0.100 mole of C5H12?
A. 0.100 mole O2
B. 0.400 mole O2
C. 0.800 mole O2
D. 1.60 mole O2
Accessibility: Keyboard Navigation
Bloom's Level: 4. Analyze
Chapter: 02
Difficulty: Hard
Gradable: automatic
Section: 02.22
Subtopic: Reactions of alkanes
Topic: Alkanes (Acyclic and Cyclic)

31.The systematic name of the following group is

A. 5-ethyl-2-methylpentyl.
B.1-ethyl-4-methylpentyl.
C.6-methyl-3-heptyl.
D. 2-methyl-5-heptyl.

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.16
Subtopic: Alkyl groups
Topic: Alkanes (Acyclic and Cyclic)

2-17
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
32.What is the relationship between the two structures below?

A. identical structures
B. resonance forms
C. constitutional isomers
D. different compounds with different compositions

Bloom's Level: 2. Understand


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.11
Subtopic: Constitutional isomers
Topic: Drawing Organic Molecules

2-18
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
33.What is the IUPAC name of the following structure?

A. 3-propylpentane
B. 3-ethylhexane
C. 2-ethylheptane
D. 4-ethylpentane

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.17
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)

2-19
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
34.Which of the following are constitutional isomers?

I. 2,3,3-dimethylhexane

II. 2,2-diethylpentane

III. 3-ethyl-2-methylheptane

A. I and II
B. I and III
C. II and III
D. they are all constitutional isomers

Accessibility: Keyboard Navigation


Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.11
Subtopic: Constitutional isomers
Subtopic: IUPAC Nomenclature of acyclic alkanes
Topic: Alkanes (Acyclic and Cyclic)
Topic: Drawing Organic Molecules

35.What is the estimated C-C-C bond angle in the following model?

o
A. 90
o
B. 109.5
o
C. 120
o
D. 180
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.08
Subtopic: Hybridization
Topic: Molecular Shape

2-20
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
36.What are the hybridizations of carbon atoms 2, 3, and 4 shown in the model below?

2 2
A. sp, sp , sp
2 3
B. sp, sp , sp2
C. sp, sp, sp
3
D. sp, sp, sp
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.09
Subtopic: Hybridization
Topic: Molecular Shape

2-21
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
37.Arrange the following hydrocarbons in order of increasing boiling point.

I. pentane

II. 2,2-dimethylpropane

III. 2-methylbutane

A. I < II < III


B. I < III < II
C. II < I < III
D. II < III < I
Accessibility: Keyboard Navigation
Bloom's Level: 4. Analyze
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.21
Subtopic: Intermolecular forces
Topic: Functional Groups

38. The 1,1-dimethylethyl group, -C(CH3)3, can also be called

A. butyl.
B. isobutyl.
C. sec-butyl.
D. tert-butyl.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.16
Subtopic: Alkyl groups
Topic: Alkanes (Acyclic and Cyclic)

2-22
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
39.What is the relationship between the following two structures?

A. identical structures
B. resonance forms
C. constitutional isomers
D. different compounds with different compositions
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Easy
Gradable: automatic
Section: 02.11
Subtopic: Skeletal/bond-line structures
Topic: Drawing Organic Molecules
3
40. The sp orbitals of carbon in CH4 are formed from the

A. three 2p orbitals.
B. 2s and two of the 2p orbitals.
C. 2s and one of the 2p orbitals.
D. 2s and the three 2p orbitals.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.06
Subtopic: Hybridization
Topic: Molecular Shape

2-23
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
3
41. The geometry of sp hybrid orbitals can be described as pointing towards the corners
of a
A. triangle.
B. square.
C. tetrahedron.
D. square pyramid.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.06
Subtopic: Hybridization
Topic: Molecular Shape

42. What is the Cl-C-Cl bond angle in CCl4?

o
A. 60
o
B. 90
o
C. 109.5
o
D. 120
Accessibility: Keyboard Navigation
Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.08
Subtopic: Hybridization
Topic: Molecular Shape

43. Which of the following has the lowest boiling point?

A. pentane
B. 2,2-dimethylpropane
C. 2-methylbutane
D. hexane

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.21
Subtopic: Intermolecular forces
Topic: Functional Groups

2-24
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
44.The shortest and longest carbon-carbon bonds, respectively, in this molecule are:

A. II and III
B. IV and III
C. I and IV
D. IV and I
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.08
Subtopic: Bond properties
Subtopic: Types of bonds
Topic: Structure and Bonding

45. How many isomers of C6H14 are possible?

A. four
B. five
C. six
D. seven

Accessibility: Keyboard Navigation


Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.15
Subtopic: Constitutional isomers
Topic: Drawing Organic Molecules

2-25
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
46.Which of the molecules below is NOT an isomer of formula C6H14?

A. A
B. B
C. C
D. D

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Easy
Gradable: automatic
Section: 02.18
Subtopic: Constitutional isomers
Subtopic: Skeletal/bond-line structures
Topic: Drawing Organic Molecules

47. Which of the following statements is not true concerning hydrocarbons?

A. Hydrocarbons are compounds that carbon, hydrogen, and oxygen atoms.


B. Alkanes, alkenes, and alkynes are examples of aliphatic hydrocarbons.
C. Aromatic hydrocarbons are also referred to as arenes.
D. Hydrocarbons may contain sigma bonds and/or pi bonds.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Easy
Gradable: automatic
Section: 02.01
Subtopic: Alkanes
Subtopic: Alkenes
Subtopic: Alkynes
Subtopic: Arenes (Aromatics)
Subtopic: Hydrocarbons
Topic: Functional Groups

2-26
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
48. How many isomers of C4H9Cl are possible?

A. two
B. three
C. four
D. five

Accessibility: Keyboard Navigation


Bloom's Level: 3. Apply
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.11
Subtopic: Constitutional isomers
Topic: Drawing Organic Molecules

49. The smallest straight-chain alkane that is liquid at room temperature and
atmospheric pressure is
A. propane.
B. butane.
C. pentane.
D. hexane.

Accessibility: Keyboard Navigation


Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.21
Subtopic: Intermolecular forces
Topic: Functional Groups

2-27
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
50.The lowest-boiling isomer of C7H16 would be

A. A.
B. B.
C. C.
D. D.
Bloom's Level: 2. Understand
Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.21
Subtopic: Intermolecular forces
Topic: Functional Groups

51.The C-C-C bond angle in propyne, shown below, is

A. 90°.
B. 109.5°.
C. 120°.
D. 180°.

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.09
Subtopic: Hybridization
Topic: Molecular Shape

2-28
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
52.The hybridization of carbon atoms 1, 2, and 3 in the following are respectively,

2
A. sp, sp, and sp .

3
B.sp, sp, and sp .
2 2 3
C.sp , sp , and sp .

2 3 3
D. sp , sp , and sp .

Bloom's Level: 3. Apply


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.08
Subtopic: Hybridization
Topic: Molecular Shape

53.How many pi bonds are present in the following structure?

A. one
B. two
C. three
D. four

Bloom's Level: 2. Understand


Chapter: 02
Difficulty: Easy
Gradable: automatic
Section: 02.09
Subtopic: Hybridization
Topic: Molecular Shape

2-29
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
54.The carbon-carbon single bond in the following is formed by the overlap of which two
orbitals?

A. sp-sp
2
B. sp -sp
2 2
C. sp -sp
2 3
D. sp -sp

Bloom's Level: 2. Understand


Chapter: 02
Difficulty: Medium
Gradable: automatic
Section: 02.09
Subtopic: Hybridization
Topic: Molecular Shape

2-30
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Category # of Questions
Accessibility: Keyboard Navigation 29
Bloom's Level: 1. Remember 5
Bloom's Level: 2. Understand 25
Bloom's Level: 3. Apply 20
Bloom's Level: 4. Analyze 4
Chapter: 02 54
Difficulty: Easy 8
Difficulty: Hard 2
Difficulty: Medium 44
Gradable: automatic 54
Section: 02.01 1
Section: 02.05 1
Section: 02.06 2
Section: 02.07 1
Section: 02.08 4
Section: 02.09 5
Section: 02.11 6
Section: 02.13 1
Section: 02.15 1
Section: 02.16 7
Section: 02.17 7
Section: 02.18 5
Section: 02.19 1
Section: 02.21 6
Section: 02.22 3
Section: 02.23 3
Subtopic: Acyclic vs cyclic 4
Subtopic: Alkanes 3
Subtopic: Alkenes 1
Subtopic: Alkyl groups 5
Subtopic: Alkynes 1
Subtopic: Arenes (Aromatics) 1
Subtopic: Bond properties 1

2-31
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the
prior written consent of
McGraw-Hill Education.
Subtopic: C-Z functional groups (Z = N, O, S, halogen) 1
Subtopic: Constitutional isomers 6
Subtopic: Hybridization 11

2-32
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the
prior written consent of
McGraw-Hill Education.
Subtopic: Hydrocarbons 4
Subtopic: Intermolecular forces 6
Subtopic: IUPAC Nomenclature of acyclic alkanes 10
Subtopic: IUPAC Nomenclature of cycloalkanes 5
Subtopic: Reactions of alkanes 4
Subtopic: Skeletal/bond-line structures 2
Subtopic: Types of bonds 1
Topic: Alkanes (Acyclic and Cyclic) 28
Topic: Drawing Organic Molecules 7
Topic: Functional Groups 10
Topic: Molecular Shape 11
Topic: Structure and Bonding 1

2-33
Copyright © 2016 McGraw-Hill Education. All rights reserved. No reproduction or distribution
without the prior written consent of
McGraw-Hill Education.
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