NEET

UTHAAN NEET 2024

Practice Sheet
Chemistry
Chemical Equilibrium

Q1 In a chemical equilibrium A + B ⇌ C + D when The equilibrium constant ‘K’ for the following
one mole of each of the two reactants are dissociation H3 PO4 ⇌ 3H
+
+ PO
3−
4
is:
mixed, 0.6 mole each of the products are (A) K1/K2K3 (B) K1K2K3
formed. The equilibrium constant calculated is (C) K2/K1K3 (D) K1 + K2 + K3
(A) 1 (B) 0.30
Q6 For the equilibrium.
(C) 2.25 (D) 4/9
2NO(g) + Cl2(g) ⇌ 2
­ NOCl(g)
Q2 1 mole of H2 and 2 mole of I2 are taken initially in Kp is related to Kc by the reaction:
a 2 L vessel. The number of moles H2 at (A) Kp = Kc (RT) (B) Kp = Kc (RT)2
equilibrium is 0.2. Then, the number of moles of (C) Kp =
Kc
(D) Kp =
Kc

2
RT
(RT)
I2 and HI at equilibrium are:
(A) 1.2, 1.6 (B) 1.8, 1.0 Q7 PCl5, PCl3, and Cl2 are at equilibrium at 500 K in
(C) 0.4, 2.4 (D) 0.8, 2.0 a closed container and their concentrations are
0.8 × 10–3 mol L–1, 1.2 × 10–3 mol L–1 and 1.2 × 10–3
Q3 Kc for the reaction N2 + 3H2 ⇌ 2NH3 is K then
mol L–1, respectively. The value of Kc for the
the value of Kc for the reaction 2NH3 ⇌ N2 + 3H2
reaction PCl5(g) ⇌ PCl3(g) + Cl2(g) will be:
will be
(A) 1.8 × 103 mol L–1
(A) K (B) 2K
(B) 1.8 × 10–3 L/mol
(C) 1/K (D) K2
(C) 1.8 × 10–3 mol-1 L
Q4 For the reaction, N2(g) + O2(g) ⇌ 2NO(g) the (D) 0.55 × 104 mol/ L
equilibrium constant is K1. The equilibrium
Q8 Calculate Kc for the reversible process given
constant is K2 for the reaction 2NO(g) + O2(g) ⇌
below. If Kp = 167 and T = 800°C
2NO2(g). What is “K” for the reaction?
1
CaCO3(s) ⇌ CaO(s) + CO2(g)
NO2 (g) ⇌ N 2 (g) + O2 (g)
2 (A) 1.95 (B) 1.85
(A) 1

( K1 K2 ) (C) 1.89 (D) 1.60

(B) 1

(2 K1 K2 )
Q9 What is the unit of Kp for the reaction?
(C) 1

(4 K1 K2 )
CS2(g) + 4H2(g) ⇌ CH4(g) + 2H2S(g)
(D)
1

[
1
]
2
(A) atm (B) atm-2
( K1 K2 )

(C) atm2 (D) atm-1

Q5 Consider the equilibrium reactions:
K1
Q10 2HI(g) ⇌ H2(g) + I2(g)
+ −
H3 PO4 ⇌ H + H2 PO
4 The equilibrium constant of the above reaction
K2

H2 PO
−
⇌ H
+
+ HPO
2− is 6.4 at 300 K. If 0.25 mole each of H2 and I2 are
4 4

K3 added to the system, the equilibrium constant

2− + 3−
HPO ⇌ H + PO
4 4 will be:

Android App | iOS App | PW Website

 NEET

(A) 0.8 (B) 3.2

(C) 1.6 (D) 6.4
PCl5(g) ⇌ PCl3(g) +
(B) (ii) Kp < Kc
Q11 An increase in pressure would favour the Cl2(g)
forward reaction
(A) N2(g) + O2(g) ⇌ 2NO(g)
(B) 2SO2(g) + O2(g) ⇌ 2SO3(g)
2SO3(g) ⇌ 2SO2(g) + Kp not
(C) PCl5(g) ⇌ PCl3(g) + Cl2(g) (C) (iii)
O2(g) defined
(D) H2(g) + I2(g) ⇌ 2HI(g)

Q12 Assertion (A): For the reaction, N2 + O2 ⇌ 2NO,

an increase in pressure at equilibrium does not
affect the reaction.
Reason (R): Σ Moles of gaseous product – Σ
CH3COOC2H5(l) +
moles of gaseous reactant = 0.
H2O(l) ⇌ CH3COOH(l) +
(A) Both Assertion (A) and Reason (R) are the
(D) C2H5OH(l) (iv) Kp > Kc
true, and Reason (R) is a correct explanation
(assume temperature =
of Assertion (A).
25°C)
(B) Both Assertion (A) and Reason (R) are the
true, but Reason (R) is not a correct
explanation of Assertion (A).
(C) Assertion (A) is true, and Reason (R) is false.
(A) (A) → (ii); (B) → (i), (iv); (C) → (i),
(D) Assertion (A) is false, and Reason (R) is true.
(iv); (D) → (iii)

Q13 High temperature and high pressure (as per Le (B) (A) → (i), (iv); (B) → (ii); (C) → (i),

Chatelier’s principle) favour (iv); (D) → (iii)

(A) N2 + 2H2 ⇌ 2NH3, ΔH = –Q1 (C) (A) → (i), (iv); (B) → (iii); (C) → (i);

(B) CaCO 3 ⇌ CaO + CO2 , ΔH = +Q2 (D) → (i), (iv)

(C) 3O2 ⇌ 2O3 , ΔH = +Q3 (D) (A) → (iii); (B) → (i), (iv); (C) → (ii);

(D) N2 + O2 ⇌ 2 NO, ΔH = +Q4 (D) → (i), (iv)

Q14 For the homogeneous reaction Q16 The reaction favored at low pressure is:
4NH3(g) + 5O2(g) ⇌ 4NO(g) + 6H2O(g) (A) H2 ( g) + I2 ( g) ⇌ 2 HI(g)

the equilibrium constant Kc has the unit of (B) PCl5 ( g) ⇌ PCl3 ( g) + Cl 2 ( g)

(A) (Conc) –1 (C) N2 ( g) + O2 ( g) ⇌ 2 NO(g)

(B) Conc (D) N2 ( g) + 3H2 ( g) ⇌ 2 NH3 ( g)

+10
(C) (Conc)
Q17 In the reaction,
(D) it is dimensionless
2SO2(g) + O2(g) ⇌ 2SO3(g) + X cal, most
Q15 Match the Column-I with Column-II. favourable conditions of temperature and
pressure for greater yield of SO3 are
Column-I Column-II (A) Low temperature and low pressure
(B) High temperature and low pressure
(C) High temperature and high pressure
(A) N2(g) + 3H2(g) ⇌2NH3(g) (i) Δ ng > 0
(D) Low temperature and high pressure

Android App | iOS App | PW Website

 NEET

Q18 For the reaction, is constant in temperature range between T1

H2(g) + I2(g) ⇌ ­2HI(g), the standard free energy and T2, it is readily observed that
is greater than zero. The equilibrium constant (K) (A) Kp > K′P
would be: (B) Kp < K′p
(A) K = 0 (B) K > 1 (C) Kp = K′P
(C) K =1 (D) K <1 (D) Kp =
1
′
Kp

Q19 Which one of the following conditions will favour

Q24 For the reversible reaction,
maximum formation of the product in the
N2(g) +3H2(g) ⇌ 2NH3(g) + Heat. The equilibrium
reaction,
shifts in forward direction:
A2(g) + B2(g) ⇌ X2(g) ΔrH = -H kJ
(A) By decreasing the pressure
(A) Low temperature and high pressure
(B) By decreasing the concentrations of N2(g)
(B) Low temperature and low pressure and H2(g)
(C) High temperature and low pressure
(C) By increasing pressure and decreasing
(D) High temperature and high pressure temperature

Q20 A 20 litre container at 400 K contains CO2(g) at (D) By increasing the concentration of NH3(g)
pressure 0.4 atm and an excess of SrO (neglect
Q25 KMnO4 can be prepared from K2MnO4 as per
the volume of solid SrO). The volume of the
the reaction:
containers is now decreased by moving the 2− −
3 MnO + 2H2 O ⇌ 2 MnO + MnO2
4 4
movable piston fitted in the container. The −
+ 4 OH
maximum volume of the container, when The reaction can go to completion by removing
pressure of CO2 attains its maximum value, will OH– ions by adding:
be: (A) HCl (B) KOH
(Given that: SrCO3(s) ⇌ SrO(s) + CO2(g) Kp = 1.6 (C) CO2 (D) SO2
atm)
(A) 2 litre (B) 5 litre
(C) 10 litre (D) 4 litre

Q21 Consider the nitration of benzene using mixed

conc. H2SO4 and HNO3. If a larger amount of
KHSO4 is added to the mixture, the rate of
nitration will be:
(A) Doubled (B) Increase
(C) Decrease (D) Unchanged

Q22 Which of the following statements is correct for

a reversible process in a state of equilibrium?
(A) ΔGº = –2.303 RT log K
(B) ΔGº = 2.303 RT log K
(C) ΔG = –2.303 RT log K
(D) ΔG = 2.303 RT log K

Q23 For a given exothermic reaction, Kp and K´p are

the equilibrium constants at temperature T1 and
T2, respectively. Assuming that heat of reaction

Android App | iOS App | PW Website

 NEET

Answer Key
Q1 (C) Q14 (B)

Q2 (A) Q15 (A)

Q3 (C) Q16 (B)

Q4 (D) Q17 (D)

Q5 (B) Q18 (D)

Q6 (C) Q19 (A)

Q7 (A) Q20 (B)

Q8 (C) Q21 (C)

Q9 (B) Q22 (A)

Q10 (D) Q23 (A)

Q11 (B) Q24 (C)

Q12 (A) Q25 (C)

Q13 (C)

Android App | iOS App | PW Website

 NEET

Hints & Solutions

Q1 Text Solution:

Q5 Text Solution:

Q2 Text Solution:
At equilibrium,
[H2 ] = 1 − α = 0. 2

α = 0. 8

[I 2 ] = 2 − α = 1. 2

[HI] = 2α = 1. 6

Q3 Text Solution:

Q6 Text Solution:
Δng
K p = K c (RT )

& Δng = np(g) − nR(g)

Kc
⇒ Kp =
RT

Q7 Text Solution:

Q4 Text Solution:

Android App | iOS App | PW Website

 NEET

Q8 Text Solution:
Q15 Text Solution:

Q16 Text Solution:

Q9 Text Solution:
Q17 Text Solution:
The given reaction favour the formation of SO3
if temperature is lowered and pressure is
increased.

Q18 Text Solution:

Q10 Text Solution:
The value of equilibrium constant remains
unchanged even on changing the Q19 Text Solution:
concentration of the reaction system. Low temperature and high pressure will favour
the forward reaction as the reaction is
Q11 Text Solution:
exothermic and gaseous number of mole
decreases.

Q12 Text Solution: Q20 Text Solution:

Q13 Text Solution:

Q14 Text Solution:

Q21 Text Solution:
If a large amount KHSO4 is added then conc. of
-
HSO4 ions increases and the reaction will be

Android App | iOS App | PW Website

 NEET

shifted in backward direction hence the rate of Q24 Text Solution:

nitration will be slower. The given reaction is exothermic and gaseous
number of moles decreases and hence at low
Q22 Text Solution:
temperature and high pressure favour the
forward reaction.

Q25 Text Solution:

Q23 Text Solution: To disturb the equilibrium in the forward
For an exothermic reaction, if temperature is direction, the hydroxide ions are needed to be
increased the equilibrium constant decreases. removed and that can be done by adding
carbon dioxide.

Android App | iOS App | PW Website