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Xii Stud Iit - FTM-02 - 08.05.2023 - QP
Xii Stud Iit - FTM-02 - 08.05.2023 - QP
Xii Stud Iit - FTM-02 - 08.05.2023 - QP
CHEMISTRY
+Ve –Ve No. of Total
Section Question Type
Marks Marks Qs. marks
Sec – I
(Q.N : 31 – 50)
Questions with Single Correct Choice 4 –1 20 80
Sec–II Questions with Integer
4 –1 10 20
(Q.N : 51 – 60) Answer Type (+ / – Number)
Total 30 100
MATHEMATICS
+Ve –Ve No. of Total
Section Question Type
Marks Marks Qs. marks
Sec–I
(Q.N : 61 – 80)
Questions with Single Correct Choice 4 –1 20 80
Sec–II Questions with Integer
4 –1 10 20
(Q.N : 81 – 90) Answer Type (+ / – Number)
Total 30 100
TG ~ @bohring_bot
XII_STU_IC_IIT_ FTM–02 EX. DT: 08-05-2023
Exam Syllabus
Electric flux, Gauss's law and its applications to find field due to infinitely long uniformly charged straight wire,
uniformly charged infinite plane sheet and uniformly charged thin spherical shell.
Electric potential and its calculation for a point charge and system of charges; Equipotential surfaces, Electrical
potential energy of a system of two point charges in an electrostatic field. Potential of various charge configurations,
PHYSICS
Electric charges: Conservation of charge, Coulomb's law forces between two point charges, forces between multiple
charges; superposition principle Electric field: Electric field due to a point charge, lectric field lines, Electric field Due
to continuous charge distribution. (Linear, Area, Volume)
Vapour pressure of solution, Factors affecting vapour pressure, Raoult's law for non-volatile and volatile solutes, ideal
and non-ideal solutions, Azeotropic mixture
Elevation in boiling point, Depression in freezing point, Osmotic pressur, van't Hoff factor and abnormal molecular
CHEMISTRY mass
Elements of symmetry in cube : (i) Centre of symmetry, (ii) Plane of symmetry, (iii) Axis of symmetry, Close packed
structures : (i) 1-D close packing, (ii) 2-D close packing, (iii) 3-D close packing, (AAA… type packing). Voids, types of
crystal and deffects
MATRICES Adjoint and Inverse of a matrix, Solution of equations- Using Inverse and Cramer’s rule
RELATION AND FUNCTION Relation : Definition, Total number of relations, Composition & inverse of relations,
Types of relation, Reflexive, Symmetric, Transitive, Equivalence, Introduction of Function and Domain
MATHEMATICS
DETERMINATS: Determinants of matrix of order one, two, three, Properties of Determinants, Properties of
Determinant Continued. Applications of Determinants- Area, Minor and Cofactors, Products of determinants,
differentiation of a determinant, Limit of Determinant. MATRICES: Matrix as an array, Types of matrices, equality of
matrices, Operation on Matrices, Product of matrices and its properties., matrix polynomial, Determinant of a square
matrix and its properties, Trace of a matrix, Transpose of a matrix ; Symmetric and Skew Symmetric matrix.-
Rough Work
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XII_STU_IC_IIT_ FTM–02 EX. DT: 08-05-2023
PHYSICS Max. Marks: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
1. A uniformly charged ring of radius 3a and total charge q is placed in xy-plane centred at origin. A
point charge q is moving towards the ring along the z-axis and has speed v at z = 4a. The
minimum value of v such that it crosses the origin is:
1/2 1/2
2 4 q2 2 4 q2
(A) (B)
m 15 4 0 a m 5 4 0 a
1/2 1/2
2 2 q2 2 1 q2
(C) (D)
m 15 4 0 a m 15 4 0 a
2. The given graph shows variation (with distance r from centre) of:
Rough Work
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A 2 r / a
3. Charge is distributed within a sphere of radius R with a volume charge density p r e
r2
where A and a are constants. If Q is the total charge of this charge distribution, the radius R is:
𝑄 𝑎 1
(A) 𝑎 𝑙𝑛 (1 − 2𝜋𝑎𝐴) (B) 2 𝑙𝑛 ( 𝑄 )
1−
2𝜋𝑎𝐴
1 𝑎 𝑄
(C) 𝑎 𝑙𝑛 ( 𝑄 ) (D) 2 𝑙𝑛 (1 − 2𝜋𝑎𝐴)
1−
2𝜋𝑎𝐴
4. A, B, C are three points on a circle of radius 1 cm. These points form the corners of an equilateral
triangle. A charge 2C is placed at the centre of the circle. The work done in carrying a charge of
0.1 μC from A to B is
(A) 0 (B) 18 × 1011J
(C) 1.8 × 1011J (D) 54 × 1011J
5. An electron of mass 'M' kg and charge 'e' coulomb travels from rest through a potential difference
of 'V' volt. The final velocity of the electron is (in m/s)
2eV 2MV
(A) (B)
M e
2eV 2MV
(C) (D)
M e
6. Figure shows equi-potential surfaces for a two charges system. At which of the labelled points will
an electron have the highest potential energy?
Rough Work
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7. Two semicircular rings lying in the same plane of uniform linear charge density have radii r and
2r. They are joined using two straight uniformly charged wires of linear charge density and
length r as shown in the figure. The magnitude of electric field at common centre of semicircular
rings is
1 3 1 3
(A) (B)
4 0 2r 4 0 2r
1 2 1
(C) (D)
4 0 r 4 0 r
8. Charges q, 2q, 3q and 4q are placed at the comers A, B, C and D of a square as shown in the
following figure. The direction of electric field at the centre of the square is along
(A) AB (B) CB
(C) BD (D) AC
9. Two concentric rings, one of radius R and total charge +Q and the second of radius 2R and total
charge 8Q lie in x-y plane (i.e., z = 0 plane). The common centre of rings lies, at origin and the
common axis coincides with z-axis. The charge is uniformly distributed on both rings. At what
distance from origin is the net electric field on z-axis zero?
Rough Work
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R R
(A) (B)
2 2
R
(C) (D) 2R
2 2
10. An infinitely long wire is kept along z-axis from z = – to z = + , having uniform linear charge
10
density nC/m. The electric field at point (6 cm, 8 cm, 10 cm) will be
9
(A) 120 i 160 i 200 k V/m
(B) 200 k V/m
11. A point charge q is placed at origin. Let E A , EB and Ec be the electric field at three points A (1,
2, 3), B (1, 1, –1) and C (2, 2, 2) due to charge q. Then select the correct alternative.
→ →
[i] EA EB [ii] |𝐸𝐵 | = 4 |𝐸𝑐 |
Rough Work
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12. Two identical point charges are placed at a separation of . P is a point on the line joining the
charges, at a distance x from any one charge. The field at P is E. E is plotted against x for values of
x from close to zero to slightly less than .Which of the following best represents the resulting
curve?
(A) (B)
(C) (D)
13. Two identical positive charges are fixed on the y-axis, at equal distances from the origin O.A
particle with a negative charge starts on the x-axis at a large distance from O, moves
along the + x-axis, passes through O and moves far away from O. Its acceleration 'a' is taken as
positive along its direction of motion. The particle’s acceleration 'a' is plotted against its x-
coordinate. Which of the following best represents the plot?
(A) (B)
(C) (D)
14. Two point charges –q and +q/2 are situated at the origin and at the point (a, 0, 0) respectively. The
point along the x-axis where the electric field vanishes is
Rough Work
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a
(A) x (B) x 2 a
2
2a 2a
(C) x (D) x
2 1 2 1
15. Statement (A): Negative charges always move from a higher potential to lower potential point
Statement (B): Electric potential is vector.
(a) A is true but B is false (b) B is true but A is false
(c) Both A and B false (d) Both A and R are true
16. In a uniform electric field, the potential is 10 V at the origin of coordinates, and 8V at each of the
point (1, 0, 0), (0, 1, 0) and (0, 0, 1). The potential at the point (1, 1, 1) will be
(A) 0 (B) 4 V
(C) 8 V (D) 10 V
17. In a regular polygon of n sides, each corner is at a distance r from the centre. Identical charges are
placed at (n – 1) corners. At the centre, the intensity is E and the potential is V. The ratio V/E in
magnitude
(A) r n (B) r (n – 1)
(C) (n – 1) / r (D) r (n – 1) / n
18. The equation of an equipotential line in an electric field is y = 2x, then the electric field strength
vector (1, 2) may be
(A) 4 i 3 j (B) 4 i 8 j
(C) 8 i 4 j (D) 8 i 4 j
19. A uniform electric field having strength 8 i 4 j is existing in x-y plane as shown in figure. Find
the potential difference between origin O & A (d, d, 0)
Rough Work
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(C) 2k 3 (D) 4k 3
SECTION-II
(Integer Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer is in the
decimals, have to Answer any 5 only out of 10 questions and question will be evaluated according to
the following marking scheme:
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
21. The electric field in a region is given by E = (Ax+B) i , where E is in NC–1 and x is in meters. The
values of constants are A = 20 SI unit and B = 10 SI unit. If the potential at x = 1 is V 1 and that at
x = -5 is V2, V1 – V2 (in Volt) is:
22. An infinite number of point charges, each carrying 1C charge, are placed along the y-axis at y = 1
m, 2m, 4m, 8m_______.
The total force on a 1 C point charge, placed at the origin, is. x ×103 N.
The value of x, to the nearest integer, is:
1
[4𝜋𝜀 = 9 × 109 𝑁𝑚2 /𝐶 2 ]
0
Rough Work
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23. Two identical conducting spheres with negligible volume have 2.1 nC and -0.1 nC charges,
respectively. They are brought into contact and then separated by a distance of 0.5 m. The
electrostatic force acting between the spheres P×10-9N. Find out value of P.
1
Given : 4 0 9 109 SI unit
24. Two identical conducting spheres A and B, carry equal charge. They are separated by a distance
much larger than their diameter, and the force between them is F. A third identical conducting
phere, C, is uncharged. Sphere C is first touched to A, then to B, and then removed. As a result,
𝑥𝐹
the force between A and B would be equal to . Find out value of x.
8
25. A charge 3 coulomb experiences a force 3000 N when placed in a uniform electric field. The
potential difference in volt between two points separated by a distance of 1 cm along the field lines
is:
26. A certain charge Q is divided into two parts q and (Q-q). Q is divided such that q and (Q-q) placed
at a certain distance apart experience maximum electrostatic repulsion? Then Q = xq. Find out
value of x.
27. Three charges each 20μC are placed at the corners of an equilateral triangle of side 0.4m. The
potential energy of the system is __________J.
28. Three charges + Q. q, + Q are placed respectively, at origin, d/2 and d from the origin, on the x-
axis. If the net force experienced by +Q, placed at x=0, is zero, then value of q is
–Q/x. Find out value of x.
A point charge 50 C is located in the X-Y plane at the point of position vector r0 2 i 3 j . The
29.
electric field at the point of position vector r 8 i 5 j is Px100 V/m. Find out value of P.
30. Infinite charges of magnitude q each are lying at x =1, 2, 4, 8... meter on X-axis. The value of
intensity of electric field at point x = 0 due to these charges will be 𝑃 × 109 q N/C. Find out value
of P.
Rough Work
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XII_STU_IC_IIT_ FTM–02 EX. DT: 08-05-2023
CHEMISTRY Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
31. What would be the molality of 40% (mass/mass) aqueous solution of H 2SO4 ?
A) 1.48 B) 1.51
C) 1.35 D) 6.8
32. Liquids A and B form an ideal solution in the entire composition range. At 350 K, the vapour
pressures of pure A and pure B are 760 Torr and 1200 Torr, respectively. The composition of B in
vapour in equilibrium with a solution containing 60 mole percent of A at this temperature is
A) 0.51 B) 0.6
C) 0.4 D) 0.55
33. Which one of the following statements regarding Henry’s law is/are correct?
A) Different gases have different KH (Henry’s law constant) values at the same temperature.
B) Higher the value of KH at a given pressure, higher is the solubility of the gas in the liquids.
36. An azeotropic solution of two liquids has boiling point higher than either of them when it
Rough Work
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A) shows negative deviation from Raoult’s law
B) shows no deviation from Raoult’s law
C) shows positive deviation from Raoult’s law
D) is saturated
37. Mixture(s) showing negative deviation from Raoult’s law at 35°C is -
A) carbon tetrachloride + methanol B) Chloroform + acetone
C) benzene + toluene D) CCl4+SiCl4.
38. A solution is prepared by dissolving 1.2 g of urea (molar mass = 60 g mol-1) 2.925 gm NaCl (Mass
58.5) and 1.8 g of glucose (molar mass = 180 g mol-1) in 100 mL of water at 27°C. The osmotic
pressure of the solution is (R = 0.08206 L atm K-1 mol-1)
A) 39.8 B) 19.7
C) 32 D) 20
39. 1 g of a non-volatile, non-electrolyte solute is dissolved in 100 g of two different solvents A and B,
whose ebulliosocopic constants are in the ratio of 1 : 5. The ratio of the elevation in their boiling
Tb A
points, is,
Tb B
A) 5 : 1 B) 10 : 1
C) 1 : 5 D) 1 : 0.2
40. Molal depression constant for a solvent is 2.0 K kg mol-1. The depression in the freezing point of
the solvent for 0.03 mol kg-1 solution of K2SO4 is (Assume complete dissociation of the electrolyte)
A) 0.18K B) 0.36K
C) 0.12K D) 0.24K
41. A 0.001 molal solution of [Pt(NH3)4Cl4] in water had a freezing point depression of 0.0054OC. If Kf
of water is 1.80 the correct formula is
A) [Pt(NH3)4Cl3]Cl B) [Pt(NH3)4Cl2]Cl2
C) [Pt(NH3)4Cl]Cl3 D) [Pt(NH3)4Cl4]
42. Freezing point of a 10 % aqueous solution of X is equal to freezing point of 15% aqueous solution
of Y. If molecular weight of X is A, then molecular weight of Y is
Rough Work
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27 17
A) A B) A
17 27
90 3
C) A D) A
85 2
43. AB2 is 90% ionised in aqueous solution. The value of its van’t Hoff factor (i) is
A) 1.6 B) 2.8
C) 2.2 D) 2.0
44. A unit cell in which atoms are present on the corners and on two opposite faces is.
A) Face centre B) Body centered
C) End centered D) Simple cubic
45. A solution contain 31 g of C2 H6O2 in 200 g of water is cooled upto -5.5º C. If K f for water is 1.86
K kg mol-1, then amount of water (in g) separated as ice is
A) 31 B) 48.6
C) 64.2 D) 38.7
46. The freezing point of benzene decreases by 0.38°C when 0.2 g of benzoic acid is added to 20 g of
benzene. If benzoic acid associates to form a dimer in benzene, percentage association of Benzoic
acid in benzene will be ( K f for benzene = 5.12 K kg mol-1)
A) 13% B) 17%
C) 20% D) 18%
47. The freezing point (in °C) of solution containing 39 g of Al(OH)3 (mol. wt. 78) in 1000 g of water
(Kf = 1.86 K kg mol-1) is
A) 0.5 B) 1.5
C) 2.8 D) 3.72
48. Which of the following crystal is represented by a b c & 90 ?
A) Orthorhombic B) Monoclinic
C) Triclinic D) Tetrogonal
49. A solid has a structure in which A atoms are located at the cube corners of the unit cell, B atoms are
located at the cube edges of unit cell and the C atoms at the body centre. Formula of the compound
Rough Work
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A) CAB3 B) C2 AB3
C) CA3B D) C2 A 3B
50. In a cubic close packed structure of mixed oxides, the lattice is made up of oxide ions, one eighth of
tetrahedral voids are occupied by divalent (X2+) ions, while one-half of the octahedral voids are
occupied by trivalent ions (Y3+), then the formula of the oxide is
A) XY2 O 4 B) X 2 YO4
C) X 4 Y5O10 D) X5 Y4 O10
SECTION-II
(Integer Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer is in the
decimals, Have to Answer any 5 only out of 10 questions and question will be evaluated according to
the following marking scheme:
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
51. In a ccp type structure, if half of the face-centred atoms are removed, then percentage void in unit
cell is approximately
52. CsCl crystallises in a cubic cell that has a Cl- at each corner and Cs+ at the centre of the unit cell. If
radius of Cs+ is 1.69 Å and rCl =1.81 Å, what is the edge length of unit cell?
53. The vapour pressure of a solution having 2.0 g of solute X (gram atomic mass = 32 g mol-1) in 100 g
of CS2 (vapour pressure = 854 torr) is 848.9 torr. The atomicity formula of the solute is.
54. What would be the osmotic pressure at 25°C of an aqueous solution containing 1.95 g of sucrose
(C12H22O11) present in 150 ml of solution?(Upto 2 decimal)
55. A solution containing 8.6 g L-1 of urea is isotonic with a 5% (w/v) solution of unknown solute. The
molar mass of the solute will be
56. An aqueous solution freezes at -0.36°C. Kf, and Kb for water are 1.8 and 0.52 K kg mol-1
respectively then value of boiling point of solution at 1 atm pressure is (inoC)
57. van't Hoff factor for acetic acid in aqueous medium at infinite dilution is
58. Boiling point of 0.01 M AB2, which is 10% dissociated in aqueous medium (Kb (H2O) = 0.52) as
A+2 and B- is (in kelvin) (upto 3 decimal)
Rough Work
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59. Substance A tetramerises in water to the extent of 80%. A solution of 2.5 g of A in 100 g of water
lowers the freezing point by 0.3°C. The molar mass of A is (Kf for water = 1.86 K kg mol-1)
60. If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapour pressure to
80%, the molar mass (in g mol-¹) of the solute is [Given that molar mass of n-octane is 114 g mol-1]
Rough Work
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67. Let M and N be two 3 3 nonsingular skew-symmetric matrices such that MN NM. If P T denotes
the transpose of P, then M2 N2 MT N MN
1 1 T
is equal to
72. Let a relation R on the set N of natural numbers be defined as x, y x 2 4xy 3y 2 0x, y N.
The relation R is
(A) reflexive (B) symmetric (C) transitive (D) an equivalence relation
73. Let R be the real line. Consider the following subsets of the plane R R
S x, y : y x 1 and 0 x 2
T x, y : x y is an integer
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(A) T is an equivalence relation on R but S is not
(B) Neither S nor T are equivalence relations on R
(C) Both S and T are equivalence relations on R
(D) S is an equivalence relation on R but T is not
74. If R be a relation defined as aRb iff | a b | 0, then the relation is
(A) reflexive (B) symmetric
(C) transitive (D) symmetric and transitive
75. R is a relation from 11,12,13 to 8,10,12 defined by y x 3 . Then, R 1 is
(A) 8,11 , 10,13 (B) 11,18 , 13,10 (C) 10,13 , 8,11 (D) None of these
76. On the set N of all natural numbers define the relation R by aRb if and only if the GCD of a and b
is 2, then R is
(A) reflexive, but not symmetric (B) symmetric only
(C) reflexive, symmetric and transitive (D) not reflexive, not symmetric and not transitive
77. Let W denotes the words in the English dictionary. Define the relation R by
R = { x, y W W : the words x and y have at least one letter in common}. Then, R is
(A) reflexive, symmetric and not transitive (B) reflexive, symmetric and transitive
(C) reflexive, not symmetric and transitive (D) not reflexive, symmetric and transitive
78. Let R be a relation on the set of integers given by aRb a 2k. b for some integer k. Then, R is
(A) an equivalence relation (B) reflexive but not symmetric
(C) reflexive and transitive but not symmetric (D) reflexive and symmetric but not transitive
79. The domain of the function f x log2 log3 log4 x is
e 1
(A) x 0 (B) x (C) x 1 (D) x 1 e
e
SECTION-II
(Integer Value Answer Type)
Rough Work
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XII_STU_IC_IIT_ FTM–02 EX. DT: 08-05-2023
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer is in the
decimals, Have to Answer any 5 only out of 10 questions and question will be evaluated according to
the following marking scheme:
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
4 0 0
| adj adjA |
81. Let A be a square matrix such A adj.A 0 4 0 , then ___________ .
| adjA |
0 0 4
82. If A and B are square matrices of the same order such that |A| = |B| = 1 and A(adj A + adj B) = B,
then the value of |A + B| is (where |M| = det M) _________.
1 0 0
83. Let P 4 1 0 and I be the identity matrix of order 3. If Q qij is a matrix such that
16 4 1
q 31 q 32
P50 Q I, then equals
q 21
84. How many 3 3 matrices M with entries from 0,1, 2 are there, for which the sum of the diagonal
entries of M T M is 5I ?
Let A and B be two 3 3 matrices such that AB = I and | A | , then | adj Badj 2A | is equal to
1
85.
8
86. The trace of a square matrix is defined to be the sum of its diagonal entries. If A is a 2 2 matrix such that
the trace of A is 3 and the trace of A 3 is -18, then the value of the determinant of A is __________.
87. If the system of linear equations,
x y z 6, x 2y 3z 10 and 3x 2y z has more than two solutions, then two solutions, then
2 is equal to ……………….
88. For a real number , if the system
1 2 x 1
1 y 1
2 1 z 1
det A 1 0, is
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90. If A 1, 2,3 , the number of reflexive relation in A is
*****
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