Professional Documents
Culture Documents
Atom and Radioactivity
Atom and Radioactivity
Atom
Matter is composed of tiny particles, called molecules,
which are continuously in motion. These molecules
themselves comprise of groups of atoms.
Atom is the smallest unit of matter that has the characteristic properties of a chemical element.
Evidence for the structure of the atom was discovered by Ernest Rutherford in the
beginning of the 20th century from the study of α-particle scattering
The experimental setup consists of alpha particles fired at thin gold foil and a detector on
the other side to detect how many particles deflected at different angles
α-particles are the nucleus of a helium atom and are positively charged
Example:
In an α-particle scattering experiment, a student set up the apparatus below to determine
the number n of α-particle incident per unit time on a detector held at various angles θ.
Which of the following graphs best represents the variation of n with θ from 0 to 90°?
ANSWER: A
The Rutherford scattering experience directed parallel beams of α-particles at gold foil
The observations were:
o Most of the α-particles went straight through the foil
o The largest value of n will therefore be at small angles
o Some of the α-particles were deflected through small angles
o n drops quickly with increasing angle of deflection θ
These observations fit with graph A
Atoms are mostly empty space. The nucleus contains 99.95% of the atom’s mass but only
a tenth-billionth part of its volume. Practically all the mass of an atom is the mass of its
nucleus.
A proton, a constituent of every atomic nucleus, is a stable sub-atomic particle that has a unit-
positive electric charge (i.e. 1.60 x 10-19 C) and a rest mass of 1.67 x 10-27 kg.
A neutron, a constituent of every atomic nucleus except ordinary hydrogen, is a stable sub-
atomic particle that has no electric charge and a rest mass of 1.67 x 10-27 kg.
Protons and neutrons are in the nucleus and are called nucleons.
Do you know?
The proton and the neutrons are made of much smaller particles, called quarks. You might ask:
are they themselves made by even smaller particles? Physicists are proposing that everything in
the Universe might be made up of tiny, vibrating closed strings. For more you learn about the
string theory.(in next Level)
Electrons
The space surrounding the nucleus is occupied by the electrons, moving so rapidly that we can
think of them as being everywhere at once. (Note: This is not very accurate, but it will suffice for
now.)
An electron is not part of the atomic nucleus, but orbits the nucleus. It carries a unit-negative
electric charge (i.e. -1.60 x 10-19 C). An electron is nearly mass-less. It has a rest mass of 9.11 x
10-31 kg. The rest mass of a proton is 1836 times the rest mass of an electron.
In a neutral atom, the number of electrons is the same as the number of protons. Circulating
electrons are held in orbit by the influence of protons’ positive charge.
Atoms of different chemical element have a different numbers of protons in their nuclei, and
therefore different numbers of electrons in the orbit. Chemical elements are characterized and
identified by their atomic numbers and have unique chemical properties.
The proton (or atomic) number is the number of protons present in the nucleus of the
atom.
The atom is electrically neutral. Hence, the atom has the same number of protons as its
number of electrons.
The nucleon (or mass) number is the number of nucleons (sum of protons and neutrons)
present in the nucleus of the atom.
Since the mass of an atom is concentrated at its nucleus, the nucleon (or mass) number is
thus an approximate measure of the mass of the atom.
The number of neutrons present in the nucleus of the atom (the neutron number, N) may
be deduced by subtracting the proton number (Z) from its nucleon number (A).
Nucleon number (A) = neutron number (N) + proton number (Z)
Relative Charge
Nuclear Charge
Nuclide
Nuclide, also called nuclear species, species of atom as characterized by the number of protons,
the number of neutrons, and the energy state of the nucleus.
A nuclide is characterized by the mass number (A) and the atomic number (Z).
A
Z X, where
X = symbol of the element
A = nucleon number (AKA mass number)
Z = proton number (AKA atomic number)
Each species of atom has its own name and chemical symbol. Most symbols are based on either
English or Latin names. The symbol will have a capital letter and may be followed by a small
cap letter.
Radioactivity
Isotopes of an atom can be stable or unstable (radio-isotopes). A nucleus is unstable IF it
contains too many neutrons and/or protons. The unstable nuclei will try to become more stable
by ejecting particles. The process of ejecting the particles is called radioactivity.
Radioactive emission of particles from the nucleus of mass is in the form of alpha particles or
beta particles, sometimes accompanied by the emission of energy in the form of gamma rays.
Radioactive decay is a random and spontaneous process in which an unstable nucleus will
disintegrate into a more stable configuration by the emission of alpha-particles (helium nuclei),
beta-particles (electrons) and/or gamma radiation (short-wavelength electromagnetic waves).
Do you know?
Henri Becquerel (1896) accidentally discovered that a double salt of uranium and potassium give
off sub-atomic particles and/or radiation energies, when it is exposed to a photographic plate.
Soon thereafter it was found that all uranium compounds and the metal itself were similarly
radioactive.
Background radiation is the radiation that is present all around in the environment. Radon
gas is given off from some types of rock
Every second of the day there is some radiation emanating from natural sources such as:
o Rocks
o Cosmic rays from space
o Foods
Although most background radiation is natural, a small amount of it comes from artificial
sources, such as medical procedures (including X-rays)
Levels of background radiation can vary significantly from place to place
Background radiation can come from natural sources on Earth or space and man-made
sources
Natural Sources
Man-Made Sources
Medical sources
o In medicine, radiation is utilised all the time
o Uses include X-rays, CT scans, radioactive tracers, and radiation therapy
Nuclear waste
o While nuclear waste itself does not contribute much to background radiation, it
can be dangerous for the people handling it
Nuclear fallout from nuclear weapons
o Fallout is the residue radioactive material that is thrown into the air after a nuclear
explosion, such as the bomb that exploded at Hiroshima
o While the amount of fallout in the environment is presently very low, it would
increase significantly in areas where nuclear weapons are tested
Nuclear accidents
o Accidents such as that in Chernobyl contributed a large dose of radiation into the
environment
o While these accidents are now extremely rare, they can be catastrophic and render
areas devastated for centuries
Radiation Detectors
Count rate is the number of decays per second recorded by a detector and recorded by
the counter
o It is measured in counts/s or counts/min
The count rate decreases the further the detector is from the source
o This is because the radiation becomes more spread out the further away it is from
the source
Photographic detectors
When a radioactive substance is placed near a photographic film coated with silver halide, the
latter will produce a similar effect as seen with exposure to visible light. After the exposure is
completed, this latent record of the accumulated exposure can be made visible through a
chemical development process.
These free electrons will then accelerate towards the fine wire anode placed along the axis of the
cylindrical cathode. These accelerated electrons will cause further ionization of the argon atoms
The positively charged ions will be attracted towards the cathode. The collection of the electrons
and the argon ions at the electrodes produces a current pulse. This current pulse is then amplified
and fed to a ratemeter.
If asked to name a device for detecting radiation, the Geiger-Müller tube is a good example
to give. You can also refer to it as a GM tube, a GM detector, GM counter, Geiger counter
etc. (The examiners will allow some level of misspelling, providing it is readable). Don’t,
however, refer to it as a ‘radiation detector’ as this is too vague and may simply restate
what was asked for in the question.
The diffusion cloud chamber is the device for making visible the paths of ionizing emissions.
When emissions from the radioactive substances are placed in the chamber, the emissions will
cause ionization along its paths. The ionized air molecules will attract the vapour molecules and
become too heavy to stay in suspension and thus, condense into tiny liquid droplets along the
paths of the emissions.
Since it is independent of external conditions and the breakdown within the nucleus is
completely random, i.e., occurrence of radioactive emission is random over space and time.
But, it is noticed that with many repeated observations of the random process, the average of its
radioactive emissions does follow some statistical laws. You can calculate approximately how
much of a “basket” of radioactive materials will decay in X time.
Carbon-12 is stable, whereas carbon-14 is unstable. This is because carbon-14 has two
extra neutrons
Some isotopes are unstable because of their large size or because they have too many or
too few neutrons
As the radiation moves away from the nucleus, it takes some energy with it
o This reduces the overall energy of the nucleus
o This makes the nucleus more stable
The process of emitting radiation is called radioactive decay
Sir Malik sirmalikphysics2020@gmail.com
More Information Contact us
The Name of Success
0333- 6877764
M.Phil Physics, M.Sc Physics, M.Sc Maths, MIT
0345-2124028
Radioactive decay is a random process
o This means it is not possible to know exactly when a particular nucleus will decay
It cannot be predicted when a particular unstable nucleus will decay
The terms unstable, random and decay have very particular meanings in this topic.
Remember to use them correctly when answering questions!
Alpha Particles
Beta Particles
Gamma Rays
α, β and γ radiation can be identified by the emission from a nucleus by recalling their:
o Nature (what type of particle or radiation they are)
o Their relative ionising effects (how easily they ionise other atoms)
o Their relative penetrating abilities (how far can they travel before they are stopped
completely)
The properties of Alpha, Beta and Gamma are given in this table, and then described in
more detail below
Ionisation
Ion is a charged atom, formed by losing or gaining electrons. All three kinds of emissions are
capable of creating ions.
α-particles knock electrons out of nearby atoms, thus ionizing the atoms. The α-particles
are much heavier than the electrons and can simply dislodge them from the atoms, thus
they have the most powerful ionization ability.
β-particles are less strongly ionising than α-particles, but more than γ-rays. It is less likely
for a lighter β-particles to dislodge an electron.
γ-rays are the least ionising of the nuclear radiation as it is uncharged.
Alpha is by far the most ionising form of radiation
Alpha particles leave a dense trail of ions behind them, affecting virtually every
atom they meet
Because of this they quickly lose their energy and so have a short range
Their short range makes them relatively harmless if handled carefully, but they
have the potential to be extremely dangerous if the alpha emitter enters the body
Beta particles are moderately ionising
Sir Malik sirmalikphysics2020@gmail.com
More Information Contact us
The Name of Success
0333- 6877764
M.Phil Physics, M.Sc Physics, M.Sc Maths, MIT
0345-2124028
The particles create a less dense trail of ions than alpha, and consequently have a
longer range
They tend to be more dangerous than alpha because they are able to travel further
and penetrate the skin, and yet are still ionising enough to cause significant
damage
Gamma is the least ionising form of radiation (although it is still dangerous)
Because Gamma rays don’t produce as many ions as alpha or beta, they are more
penetrating and have a greater range
This can make them hazardous in large amounts
The ionising effects depend on the kinetic energy and charge of the type of radiation
The higher the kinetic energy of the radiation, the more ionising it is
o This means alpha particle is still the most ionising because it has the greatest mass
o However, a beta particle is very light (it is an electron) but travels at high speeds,
therefore, it has a lot of kinetic energy and is still moderately ionising
o Gamma radiation has virtually no mass so is weakly ionising
Similarly, alpha and beta particles are deflected by magnetic fields whilst they are
moving
They are deflected in opposite directions due to their opposite charges
Remembering the properties of alpha, beta and gamma radiation really helps with
deducing how much ionising power they have. E.g. An alpha particle is a helium nucleus
which contains two protons and two neutrons. It therefore has a charge of +2 since each
proton has a charge of +1 and a neutron has no charge.
Kinetic energy is defined by the equation mv2 therefore it depends on the mass m of the
particle and its velocity v.
It is important to note that because of their opposite charges, alpha and beta particles will
deflect in opposite directions. You do not need to know which direction alpha and beta
particles are deflected in a magnetic field (this is covered at A-level) but you should know
that they are deflected, whilst gamma is not because they are charged and they deflect in
opposite directions.
The most stable nuclei have roughly the same number of protons to neutrons
o If there were too many protons, then the repulsive force caused by them all having
the same positive charge which cause the nucleus to repel when it becomes very
large
Therefore, if a nucleus has an imbalance of protons or neutrons, it is more likely to decay
into small nuclei until it gets to a stable nucleus with roughly the same number of each
Therefore, Isotopes of an element may be radioactive due to:
o An excess of neutrons in the nucleus
o The nucleus being too heavy
An example of these are the isotope of hydrogen–1
Hydrogen Isotopes
If an nucleus is too heavy, this means it has too many protons and neutrons
Sir Malik sirmalikphysics2020@gmail.com
More Information Contact us
The Name of Success
0333- 6877764
M.Phil Physics, M.Sc Physics, M.Sc Maths, MIT
0345-2124028
o The forces in the nucleus will be weaker in keeping the protons and neutrons
together
o This can also cause the nucleus to decay
An example of this is Uranium–238 which is used in nuclear fission
o This nucleus has 238 protons and neutrons
The decay of Uranium–238 gradually reduces the mass number of the element which it
decays into
o This is done through alpha (α) or beta (β) decay
A nucleus decays to increase its stability by reducing the number of excess neutrons
Alpha Decay
Alpha decay usually happens in large unstable nuclei, causing the overall mass and charge
of the nucleus to decrease
γ-rays are usually emitted at the same time as α-particles and β-particles. With some nuclides, the
emission of α-particles and β-particles from a nucleus leaves the electrons and neutrons in an
excited arrangement with more energy than normal.
These protons and neutrons rearrange themselves to become more stable and release the excess
energy as a photon of gamma radiation.
Half-Life Basics
The number of radioactive atoms in a substance decreases exponentially over time. Therefore
every radioactive element has a characteristic time called half-life. After that time, the number of
radioactive nuclei in the sample would have decreased to half the number originally present.
The half-life of a sample of a radioactive isotope is defined as the time taken for half the original
unstable radioactive nuclei to decay.
Different radioactive elements decay at different rates and hence different half-life.
Uranium-238 has a half-life of over 400 million years. Strontium-90 has a half-life of 28
years and the half-life of oxygen-18 is less than 0.01 s.
where
Note: You can apply logarithm to the above equation if you need to find the number of half-life
(when you are given both final and initial number of elements)
The time taken for half the nuclei of that isotope in any sample to decay
In other words, the time it takes for the activity of a sample to fall to half its original level
The graph shows how the activity of a radioactive sample changes over time. Each time the
original activity halves, another half-life has passed
The time it takes for the activity of the sample to decrease from 100 % to 50 % is the
half-life
o It is the same length of time as it would take to decrease from 50 % activity to 25
% activity
o The half-life is constant for a particular isotope
Uses of Radiation
Smoke Detectors
In the diagram on the right, alpha particles are stopped by the smoke, preventing the flow
of current and triggering the alarm
Archaeological dating
The atmosphere contains a small proportion of radioactive carbon-14 which is absorbed
by living plants and trees as a result of photosynthesis.
The half-life of carbon-14 is 5568 years so there is negligible disintegration over the life
time of most plants.
However, once the plant has died, no further carbon-14 is taken in so the proportion of
carbon-14 in the plant starts to decrease as the radioactive carbon decays.
After one half-life of 5568 years, the proportion of carbon-14 remaining is down to 50%
of its initial value.
Since activity is proportional to the number of carbon-14 atoms remaining, measuring the
activity enables the age (time since death) of the dead sample to be calculated.
To do this, the measured activity is compared with the activity of the same mass of living
wood. Then using the value of half-life of carbon-14, the age can be determined.