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Chapter 4 Notes
Chapter 4 Notes
Chapter 4 Notes
Fourth Edition
David Klein
Chapter 4
• Isomers
o different structures, same molecular formula
• Constitutional Isomers
o different connectivity of atoms
C5H12 3
C6H14 5
C7H16 9
C8H18 18
C9H20 35
C10H22 75
(a) Rotating only the C3-C4 bond, identify the lowest energy
conformation.
(b) Rotating only the C3-C4 bond, identify the highest energy
conformation.
• Also, if a ring was flat, then all the C—C bonds would be in
eclipsing rotamers... causing considerable torsional strain.
• The equatorial groups are drawn off the ring and they run
parallel to the lines in the chair