Q- 1: Two liquids A and B have vapour pressure in the ratio PoA : PoB = 1 : 3 at a

certain temperature. Assume A and B form an ideal solution and the ratio of
mole fractions of A to B in the vapour phase is 4 : 3. Then the mole fraction of B
in the solution at the same temperature is:

(a)

(b)

(c)

(d)

Q- 2: A graph of vapour pressure and temperature for three different liquids X,

Y, and Z is shown below
The following inferences are made
(A) X has higher intermolecular interactions compared to Y.
(B) X has lower intermolecular interactions compared to Y
(C) Z has lower intermolecular interactions compared to Y. The correct
inferences is/are

(a) (B)
(b) (C)
(c) (A) and (C)
(d) (A)
Q- 3: One mole of a solute A is dissolved in a given volume of a solvent. The
association of the solute take place as follows:
nA ⇌ An
If ∝ is the degree of association of A, the van’t Hoff factor i is expressed as:
(a) i = 1 - ∝

(b)

(c)

(d) i = 1

Q- 4: The freezing point of equimolal aqueous solutions will be highest for:

(a) C6H5NH3Cl

(b) Ca(NO3)2

(c) La(NO3)2

(d) C6H12O6

Q- 5: One molal solution of a carboxylic acid in benzene shows the elevation

of boiling point of 1.518 K. The degree of association for dimerization of the
acid in benzene is (Kb for benzene = 2.53 K kg mol-1):
(a) 60%
(b) 70%
(c) 75%
(d) 80%

Q- 6: In a solvent 50% of an acid HA dimerizes and the rest dissociates. The

van’t Hoff factor of the acid is ______ × 10–2. (Round off to the Nearest
Integer)
Q- 7: FeCl3 on reaction with K4[Fe(CN)6] in aq. solution gives blue colour. These
are separated by a semipermeable membrane PQ as shown. Due to osmosis
there is-

(a) blue colour formation in side X

(b) blue colour formation in side Y
(c) blue colour formation in both of the sides X and Y
(d) no blue colour formation

Q- 8: The cryoscopic constant of water is 1.86 K kg mol-1.A 0.01 molal acetic

acid solution produces a depression of 0.0194°C in the freezing point. The
degree of dissociation of acetic acid is:
(a) Zero
(b) 0.043
(c) 0.43
(d) 1

Q- 9: According to Henry’s law, the solubility of a gas in a given volume of

liquid increases with increase in:
(a) temperature
(b) pressure
(c) Both (a) and (b)
(d) None of these
Q- 10: Molar solubility of helium, nitrogen and oxygen are plotted against
partial pressure of the gas at constant temperature. Henry’s law constant for
these gases will lie in follow sequence

(a) O2 > N2 > He

(b) O2 < N2 < He
(c) O2 = N2 = He
(d) O2 > N2 < He

Q- 11: At 25oC, the vapour pressure of pure liquid A(mol. Wt = 40) is 100 torr,
while that of pure liquid B is 40 torr, (mol. Wt. =80). The vapour pressure at
25oC of a solution containing 20 g of each A and B is:
(a) 80 torr
(b) 59.8 torr
(c) 68 torr
(d) 48 torr

Q- 12: Benzene and naphthalene form an ideal solution at room temperature.

For this process, the incorrect statement is :
(a) ΔG is positive
(b) ΔSsystem is positive
(c) ΔSsurroundings = 0
(d) ΔH = 0
Q- 13: Total vapour pressure of mixture of 1 mol X (POx = 150 torr) and 2 mol Y
(POy = 300 torr) is 240 torr. In this case:
(a) there is a negative deviation from Raoult’s law
(b) there is a positive deviation from Raoult’s law
(c) there is no deviation from Raoult’s law
(d) can not be decided

Q- 14: At room temperature, a dilute solution of urea is prepared by dissolving

0.60 g of urea in 360 g of water. If the vapour pressure of pure water at this
temperature is 35 mm Hg, lowering of vapour pressure will be: (molar mass of
urea = 60 g mol-1)
(a) 0.027 mmHg
(b) 0.028 mmHg
(c) 0.017 mmHg
(d) 0.031 mmHg

Q- 15: 6.0 g of urea (molecular mass = 60) was dissolved in 9.9 moles of
water. If the vapour pressure of pure water is P°, the vapour pressure of
solution is:
(a) 0.10 PO
(b) 1.10 PO
(c) 0.90 PO
(d) 0.99 PO

Q- 16: The unit of ebullioscopic constant is

(a) K kg mol-1 or K(molality)-1
(b) mol kg-1 K-1 or K-1(molality)
(c) kg mol-1 K-1 or K-1(molality)-1
(d) K mol kg-1 or K(molality)
Q- 17: When 1 mole of a solute is dissolved in 1 kg of H2O, boiling point of
solution was found to be 100.5°C. Kb for H2O is:
(a) 0.5
(b) 100
(c) 100.5
(d) 95.5

Q- 18: Chloroform, CHCl3, boils at 61.7°C. If the Kb for chloroform is

3.63°C/molal, what is the boiling point of a solution of 15.0 kg of CHCl3 and
0.616 kg of acenaphthylene, C12H10?
(a) 61.9
(b) 62.0
(c) 52.2
(d) 62.67

Q- 19: Bromoform has a normal freezing point of 7.734°C and

Kf = 14.4°C/m. A solution of 2.60g of an unknown substance in 100 g of
bromoform freezes at 5.43°C. What is the molecular mass of the unknown
substance?
(a) 16.25
(b) 162.5
(c) 100
(d) none of these
Q- 20: A solution containing 4 g of polyvinyl chloride in 1 litre of dioxane was
found to have an osmotic pressure of 6 × 10-4 atm at 300 K. The molecular
mass of polymer is.
(a) 3 × 103
(b) 6.4 × 102
(c) 5 × 104
(d) 1.6 × 105

Q- 21 : A 5% solution of cane sugar (molar mass 342 is isotonic with 1% of a

solution of an unknown solute. The molar mass of unknown solute in g/mol is
(a) 34.2
(b) 136.2
(c) 171.2
(d) 68.4

Q- 22: Which one of the following 0.06 M aqueous solutions has lowest
freezing point?
(a) Kl
(b) Al2(SO4)3
(c) C6H12O6
(d) K2SO4

Q- 23: The relationship between osmotic pressures (π1, π2 and π3) at a definite
temperature when 1 g glucose, 1 g urea and 1 g sucrose are dissolved in 1 litre
of water is (assume i = 1 for all):
(a) π1 > π2 > π3
(b) π3 > π1 > π2
(c) π2 > π1 > π3
(d) π2 > π3 > π1
Q- 24: If sodium sulphate is considered to be completely dissociated into
cations and anions in aqueous solution, the change in freezing point of water
(Tf ), when 0.01 mol of sodium sulphate is dissolved in 1 kg of water, is (Kf = 1.86
K kg mol–1)
(a) 0.0186 K
(b) 0.0372 K
(c) 0.0558 K
(d) 0.0744 K

Q- 25: K2HgI4 is 40% ionised in aqueous solution. The value of its van’t Hoff
factor (i) is
(a) 1.6
(b) 2.0
(c) 2.2
(d) 1.8
 Answer Key
1 2 3 4 5 6 7 8 9 10 11 12 13

(a) (a) (c) (d) (d) (125) (d) (b) (b) (b) (a) (a) (a)

14 15 16 17 18 19 20 21 22 23 24 25

(c) (d) (a) (a) (d) (b) (d) (d) (b) (c) (c) (d)
 Solutions
Solution-1:

Solution-2:
Vapour pressure of a liquid at a given temperature is inversely proportional to
intermolecular force of attraction.

Solution-3:
Solution-4:
Depression in freezing point, ΔTf = iKf m.
The value of van’t Hoff factor (i) is minimum for the glucose, which
is a non-electrolyte.
Hence, aqueous solution of glucose has highest freezing point.

Solution-5:

Solution-6:
Let initially one mole HA is taken

Solution-7:
Semipermeable membrane allows the solvent particles only to pass through
it.
Solution-8:

Solution-9:

Solution-10:
Solution-11:

Solution-12:

Solution-13:
Solution-14:

Solution-15:

Solution-16:

Solution-17:
Solution-18:

Solution-19:

Solution-20:
Solution-21:

Solution-22:

Solution-23:
Solution-24:

Solution-25: