Sec: JR.IIT_*CO SC(MODEL-A) WAT-19 Date: 13.11.

22
Time: 3HRS 2021_P1 Max. Marks: 180
KEY SHEET
PHYSICS
1 C 2 B 3 A 4 C 5 5000
6 0 7 20 8 15 9 7 10 6
11 ACD 12 AD 13 ABC 14 BCD 15 BC
16 BC 17 5 18 3 19 9

CHEMISTRY
20 C 21 A 22 C 23 B 24 2.8

25 16.8 26 4 27 10 28 3 29 5

30 BC 31 BC 32 BD 33 BCD 34 BC

35 BD 36 6 37 5 38 5

MATHEMATICS
39 C 40 D 41 A 42 B 43 7
3.14
44 2.33 45 15 46 1.25 47 to 48 6.40
3.15
49 ABCD 50 ABCD 51 AC 52 ABD 53 ABCD
54 AB 55 1 56 4 57 99
Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
SOLUTIONS
PHYSICS
1. Conceptual
2. T cos   mg
mg
or T 
cos 

TL
If L is the original length of the wire, the increases in length is l 
AY
l T mg
 Strain   
L AY AY cos 
3. FB  mg  water   mg  container 

H
 W  A  A  g   W hAg  C W HAg
2
 AH   AH 
hA       C AH 
 2   2 
H HA
h   0.5  C 
2 A
H
This shows that h  if C  0.5
2
4. By torricelli’s Law

Ve  2gH

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
Thrust force on the tank
dm dx
 FTh  Vr .  Ve .A
dt dt
 Ve .AVe  AVe 2

FTh AVe2
So, a Tank  
m m
A2gH g
 
  NA2H  N
5. y  0, u  0 C3  0
y  2cm, u  2m / sec
2  C1 4  104  C 2 2  102
du
 2C1 y  2
dy
du
F  A
dy
at y = 2cm, F = 2N
2  102  1  2  2  102 C1  C 2 
4 104 C1  102 C2  2
4 104 C1  2  102 C2  2
On solving C2  0 & C1  5000
du
6.  2C1 y  C2
dy
du
at y = 0,  C2  0
dy
7 to 8: Let tension in steel rod be T1 and in bras rod be T2 , then T1  2T2  5000
Extension in both steel and brass rods will be same: ls  lb
T1l1 T2 l2 T  30 T  20
  1 11  2 11
AY1 AY2 2 10 110
4T
T1  2
3
From (i) and (ii), T1  2000 N
T2  1500 N
T 2000
Stress is steel wire: S  1  4  2  107 N / m 2  20MPa
A 10
T 1500
Stress in brass wire: S2  2  4  1.5  107 N / m 2  15MPa
A 10
9 and 10: Apply Bernoulli’s theorem.
11. Conceptual
12. Conceptual
14. Viscous force  mg sin   Fnet  0 
V t ag sin 
a 2  a 3g sin    
t v

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
15.

At any distance ‘x’ from edge left there be a cross section for which FBD is given
A

F
For complete rod: mg  F  a  ......  i 
m
 mx 
For portion BC: m BC a  T  T    a;
 L 
 mx  F F Fx
T   x  stres 
 L M L Al
Fx
dl stress LA Fx
(C)   
dx Y Y LAY
l
l
Fx F
 l   dx  
0
LAY L 2AY
1 2
1 F A 3
1 F2 L F2 L
(D) Energy stored   x 2
dxA  2
  
0
2 L2 A 2 Y L2 A 2 Y  3  6AY
17. For minimum velocity at orifice
2h
  v min    1  v min  5m / s
g
This will give us minimum height for this velocity
1
 2gh min  5  h min  m  0.25 m
4
v1  2gh & v 2  dh / dt

By equation of continuity av1  Av 2

 dh 
0.25
 a 2gh  A     
dh
t a 2g
 dt
 
 dt  0.81 h 0 A
 t  125sec   5         5
3 3

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
r d  P
2

18. v

2
v  r    d  1 
 P   P  2 . 
v Q  rQ  1  d  2 
 2  2  8  0.8 
2

     = 3
 1  3  8  1.6 
1
19. u  F L
2
3 FL0
For this case L 
4 AY

CHEMISTRY
20. F2  cold & dil. NaOH  NaF  OF2  H 2O
Cl

21. marked C-atoms are 30

Br

22. CH 3  NH  C  H

O
N-methylmethanamide
O

23. CH 2  C  C  O  C2 H 5
3 2 1

CH 3
Ethyl 2-methylpropenoate
24 & 25.
4 Li  O2  2 Li2O, 6 Li  N2  2 Li3 N
‘x’ mole (A) ‘4x’ mole (B)
Total moles of Li reacted = 4 x  6  4 x  28 x
nLi2O produced = 2 x, nLi3N produced = 8x
Li2O  H 2O  2 LiOH
(C)
LiN  3H 2O  3LiOH  NH 3
(D)
nNH 3
produced = nLi N  8 x
3

nLi  4.9 10

3
700
 700  28 x  700  x 
7 28
8  700
nNH  8x   200, mNH3  200  14  2800 g
3
28
 2.8 kg

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
nLiOH produced (total) = nLi reacted = 700
mLiOH produced = 700  24 g 16,800 g 16.8 kg
4
26&27. 2 :
1 3 2,2,3,3-Tetramethylbutane

No. of C-atoms in parent chain = 4

Sum of locants = 2+2+3+3+ = 10

28&29. C6 H 8 BrCl : DU  2
Cl

: 5-Bromo-3-chlorocyclohex-1-ene

Br
NH 2

30. : Aniline

N N Heterocyclic
OH Homocyclic

H
Pyridine Pyrrole
: Phenol

31. A) : 3-methylhexane

B) : 2-methylpentane

C) : 3-ethylpentane

D) : 2-methylpentane
32. tert –Butyl > Isopropyl
Dimethylethyl > Methylethyl
(Letters considered in alphabetical order are underlined)
33.
Group Suffix
CONH 2 amide or carboxamide
COCl oylchloride or carbonyl
chloride
COOR oate or carboxylate
CN nitrile or carbonitrile

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
34. CO2  2 NaOH  Na2CO3  H 2O
2 NO2  2 NaOH  NaNO2  NaNO3  H 2O
2ClO2  2 NaOH  NaClO2  NaClO3  H 2O
SO2  2 NaOH  Na2 SO3  H 2O

35. : Phenylethanoic acid, 2

COOH

COOH : 2-Methylbenzoic acid, 6

O C  H : Phenylmethanoate, 1

O
CH 3  NH  C  CH 2CH 3 : N-Methylpropanamide, 3

O
CHO
1
6 2
OH
36. IUPAC name : 3- (1,2-Dihydroxypropyl)cyclohexanecarbaldehyde
5 3 2
4 1
OH
Cl

37. : 2-chlorocyclohex-2-en-1-ol

OH
38. Suffix “oate” is used for
a , b, d , f , h
MATHS
    1   -1  1 
39. x  cosec  tan 1  cos  cot 1       x  cosec  tan   
  
 1 a      2a 
2 2
   
 x  3  a2
    1   1  1 
y  sec  cot 1  sin  tan 1       y  sec  cot   
    1 a
2
     2a
2

   
y  3  a2
x  y
4n
40. tan 1 4
n  2n 2  2
1
  n  12   n  12 
 tan  
 1   n  12  n  12 
 

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
 tan 1  n  1  tan 1  n  1
2 2

x 1 x 1
41.  x   0,1  0;  0 and  1
1  x2 x3 1-x 2 x 3
 x 1 

 1  x 2 x3 
x 1 1 1  1  3
 tan 1  tan    tan 1
     tan   
1  x2 x3  1 
x 1
 3   x  4
 1 x x 2

 x  1 not possible 
42. 0  x2  x  1  1 and 0  x2  x  1
 x = {– 1, 0}
 1  x2  1  x2   1
Now k  tan 
1
   cos 1 x
 1  x2  1  x2  4 2
 
3
6k  3cos 1 x 
2
For x = –1
1 1 3
L.H.S  2sin 1  cos 0 
2
 x = –1 is a solution
1 1 3
for x = 0 L.H.S  2sin 1  cos 0 
2
 x = 0 is a solution
 sum of the solution = –1
  x 
43. f x   cos 1  1
  tan x
4  1 x 
2


 f  x    cot 1 x  tan 1 x
4
3
  2 tan 1 x  x  0
4
 sgn  f  x    1  f  x   0
3 3
  2 tan 1 x  0  tan 1 x   x  2 1
4 8
 Possible positive inegral values of x are 1,2
2
 n  n

  ai    ai 9  5
2

a1  1 and a 2  2   i1  i 1
 7
  a ia j
1i j n
2

44. P  x   x  4kx  3k
2 2

Px  0 x   a1,a 2  i.e.x  1,2 

P 1  0 and P  2   0

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
1  4k  3k  0 and 4  8k  3k  0
2 2

 3k  1 k  1  0  3k  2 k  2   0

1  2 
k   ,1 ........1 k   ,2 ..... 2 
3  3 
2 
 Intersection of equations 1 and  2  is k   ,1
3 
2
  and   1
3
4
2     1  2.33
3
45. f   x   f  x  x  R
 f  x  is symmetrical about y-axis  even function 
f  x    x 2  4  4
2

 x 4  8x 2  12
f x  k
x 4  8x 2  12  k  0
Put x 2  t,
2
 8t
t 
12  k 0 .... i 
g t 

For four distnict real roots.

Both roots of the equation  i  must be distnct and positive
1 D  0  64  4 12  k   0  16  12  k  0  k  4
b 8
 2   0   4  0
2a 2.1
 3 g  0   0  12  k  0  k  12
 Number of integral values of k is 15.
n  8r  n
 8r 
46. lim  tan  1
  lim  tan 1  4  .... ii 
 f r  5   r  8r  17 
n  n  2
r 1 r 1

 2 
1   r  2    r  2  
n 2

 lim  tan
n 
r 1  1   r 2  4 2 
 

 
n
 lim  tan 1  r  2   tan 1  r  2 
2 2

n 
r 1

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
 lim  tan 3  tan 1 1 2 1
n 

  tan 1
 n  1
2
 tan 1 n 2  tan 1  n  1  tan 1  n  2   tan 1 12  tan 1 12  tan 1 2 2
2 2

 8r 
n
     3 
 lim  tan 1    4      0   tan 1 4     tan 1 4 
 f r  5  2 4   2 
n  4
r 1

ab
a  3,b  2,   4   1.25

n
1  2r 1
47.  tan
lim  
2 r 1 
n r 1  1 2 
n  2r  2r 1 
S = lim  tan 1 
n r 1  1  2r.2r 1 
 
S = tan 1 2  tan 1 1
  
S=  
2 4 4
 4S    3.14
48. cos ec 1 5  cos ec 1 65  cos ec 1  325  ...
= cot 1 2  cot 1 8  cot 1 18  ...

cot 1  2r 2 
n
= lim
n

r 1
n
 2 
= lim
n
 tan 1  4r 2 
r 1
n
 
n
 2r  1   2r  1 
 tan
2
lim tan 1    lim
1
 
 1  4r  1  n   1  4r  1 
n r 1 2 2
r 1
n
 lim  tan 1  2r  1  tan 1  2r  1
n 
r 1

= tan 1   tan 1 1   a  1,b  4
4
8
HM   1.6  4  HM   6.40
5
49. cos 1 x  a,sin 1 y  b
 2 
a  b  0,   
2

 4
 k  0,1,2
 K2  2
a a 
 4  16
2
 K  2, x  cos , y  1
4

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Narayana IIT Academy 13-11-22_JR.IIT_*COSC(MODEL-A)_WAT-19_Key&Sol’s
 1 1
 3cos x  2 ,  1  x  
2


cos 1  4x 3  3x   2  3cos 1 x,   x 
1 1
50.
 2 2
 1 1
 3cos x,  x 1
2
A) a  2 and b  3
 a  b  2  3  
B) a  2,b  3
  2    2   2  
sin 1  sin       sin 1  sin         
  3   3   3  3
C) a  0,b  3
 cos y  1
lim b 1 cos y  lim  
y a y 0
 b  3
D) a  2,b  3
a
 1 and 2b  6
2
51. Conceptual
52.
y  cos 1cos x y | x 2  a |, a  0 y | x 2  a |, a  0


yx
y  x

0  2 0

For a  0, there is always a solution. For a  0, the solution exists for all a  [b, 0] where b is the
number when y = |x2 – b| touches y = cos–1 cos x.
1  1 
So, y1 = y2 and y1  y2  x = x2 – b and 1 = 2x  b =  . So finally a    ,   .
4  4 
 
53. sin 1  cos 1 x  tan 1 x  cot 1 x   sin 1   cos 1 x 
2 
  
For domain  1   cos 1 x  1  1   cos 1 x  1 
2 2 2
1
But 0  cos x   so no solution.
 
Similarly for cos 1  tan 1 x  cot 1 x  sin 1 x   cos1   sin 1 x 
2 
  
1   sin 1 x  1    1  sin 1 x  1 
2 2 2
 
  sin 1 x  1   1  x   cos1
2 2

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sin 1
 cos x   1  cos x  1  0  cos x  1  cos1  x  1
1 1 1

cos 1  sin x   1  sin x  1   sin1  x  sin1

1 1

 2
Tr  tan 1 
r
 
2 r 52  1
r
  r
2 r 52  1  2  
  2r 
    5   
54.
2r
1 5 2r
r r
 5 1 52  1  1  52  1

1 2r 1 2r 1
 tan  tan
 r
52  1

 
5  1
2r

Vr Vr 1

 tan 1 S   Tr   V1  V2    V2  V3   ..........
rt

1
tan 1 S  V1  V  V1  0  tan 1  
 12 
144S  12
10
1  3  10   3r  2    3r  1 
56.  tan  2  
 tan 1
 
r 1  9r  3r  1  r 1  1   3r  2  3r  1 
10
  tan 1  3r  2   tan 1  3r  1
r 1

 tan 1 32  tan 1 2
 13 
 cot 1    m  13,n  6
6
2m  n 32
  4
8 8
57. f  n   n

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