CHEMISTRY-XII

1
CH#09 (P.S#01) BY:- SIR. HARESH KUMAR
1. Which of the following alcohol is known as wood spirit:
(a) Methanol (b) Ethyl alcohol (c) Propyl alcohol (d) None of these
2. Alcohol react with H – X to give:
(a) Aldehyde (b) Alkyl halide (c) Ketone (d) Alkanes
3. A positively charge ion in which an oxygen atom is bonded to three atom or group of atoms is called
_____ ion.
(a) Carbonium (b) Carbanion (c) Oxonium (d) Both a & b
4. Ketone are produced by the oxidation of ______ alcohol.
(a) 1° (b) 2° (c) 3° (d) None of these
5. William on synthesis is used to prepare __________?
(a) Acetone (b)Ethyl acetate (c) Ether (d) Bakelite
6. The chemical reaction C12H22O11 + H2O →4CO2 + 4C2H5OH is an example of:
(a) Esterification (b) Fermentation (c) Saponification (d) None of these
7. __________ also known as carbolic acid:
(a) Phenol (b) Benzene (c) Naphthol (d) None of these
8. 1 –Naphthol contain _______ C – atom:
(a) 10 (b) 12 (c) 14 (d) N.O.T
9. Ethanol can be converted into ethanoic acid by the process of:
(a) Oxidation (b) Reduction (c) Redox reaction (d) None of these
10. Which of the following compounds is 3° Alkyl halide?
(a) CH3Cl (b) CHCl3 (c) (CH3)3C Cl (d) N.O.T
𝐊𝐎𝐇 𝐇𝟐 𝐎/𝐇+
11. Identify A & B in the following reaction sequence CH3CH2CH2Cl→ A → B:
(a) Propene, Isopyl alcohol (b) Isopropyl alcohol, Acetylene
(c) Isopropyl Bromide, Alkane (d) None of these
12. CH3I.Mg is react with CO2and then hydrolysis ________ is final product:
(a) Formic acid (b) Acetaldehyde (c) Acetic acid (d) None of these
13. Ethyl alcohol react with an excess of concentrated H2SO4 to form:
(a) Ethylene (b) Di ethyl ether (c) Ethyl chloride (d) None of these
14. Which of the following is not a functional group contain oxygen:
(a) Alcohol (b) Aldehyde (c) Ketone (d) Halides
15. Fermentation process to manufacture ethyl alcohol is:
(a) Aerobic process (b) Polymerization process
(c) Anaerobic process (d) Catalytic anaerobic process
16. Methanol reacts with NaOH to produce Metanal and salt of carboxylic acid this reaction is called:
(a) Al Dol condensation (b) Tollen’sreaction
(c) Cannizaro reaction (d) None of these
17. What is formalin?
(a) 60%Formaldehyde (b) 40% Formaldehyde (c) 12% Formaldehyde (d) None of these
18. The carbonyl C atom in aldehyde and ketone is:
(a) sp3 (b) sp2 (c) sp (d) All of these
19. In oxidation of Aldehydes in presence of H2SO4, the number of carbon atom in the product side acid is:
(a) Become Half (b) Become double (c) Remains same (d) Both a & c
20. Ethyl alcohol react with ‘Na’ metal _______ is form.
(a) Sodium ethoxide (b) Di ethyl ether (c) Aldehyde (d) Ketone
21. Dry distillation of calcium acetate _______ form.
(a) Form aldehyde (b) Acetaldehyed (c) Acetone (d) None of these
22. Which of the following does not have COOH group:
(a) Benzoic acid (b) Acetone (c) Acetic acid (d) None of these

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CHEMISTRY-XII
1
CH#09 (P.S#01) BY:- SIR. HARESH KUMAR
23. Those reagent or group which have excessive electron are called:
(a) Nucleophile (b) Electrophile (c) Substrate (d) None of these
24. Cyanohydrins is formed by:
(a) Methanalreact with HCN (b) Ketone react with HCN
(c) Alcohol react with HCN (d) None of these
25. The formation of cyanhydrin from a Methanal is an example of:
(a) Electrophillic reaction (b) Nucleophillic addition reaction
(c) Nucleophillic substitution reaction (d) None of these
26. The reaction CH3 – CH2Cl + OH →CH2 = CH2 + H2O + Cl –is an example of:
(a) Dehydration (b) β–elimination (c) Hydrolysis (d) None of these
27. When ethanol is _______________ to form acetaldehyde.
(a) Oxidation (b) Reduction (c) Redox reaction (d) Rearrangement
28. The function of Glacial acetic acid is:
(a) Cool the media (b) Hot the media (c) Both a & b (d) None of these
29. The elimination reaction of primary alkyl halide is:
(a) 1st step (b) 2nd step (c) Photochemical reaction (d) None of these
30. Ethyl acohol react with H – I to form:
(a) Ethane (b) Ethylene (c) Alkyl halide (d) None of these
31. Which of the following compound is prepared from water gas?
(a) Methanol (b) Ethanol (c) 1 –Isopropyl (d) 2 – Butanol
32. According to IUPAC system di-isopropyl ketone is called:
(a) Propanone (b) 2, 2 dimethyl propanol
(c) 3 – methyl – 2 – butanone (d) 2, 4 – dimethyl – 3 – pentanone
33. Which of the following is Williamson reaction:
(a) CH3 – CH2 – Cl + KOH (b) CH3 – CH2 – Cl + CH3 – CH2 - ONa
(c) CH3 – CH2 – Cl + NaOH (d) None of these
34. The reaction of methanal with (NH2 – OH) Hydroxalamineto produce oxime is:
(a) Nucleophillic substitution reaction (b) Electrophillic substitution reaction
(c) Nucleophillic addition reaction (d) Electrophillic addition reaction
35. Which of the following conversion does not involve in oxidation:
(a) Propanol to Propanal (b) Propanal to Propanonicacid
(c) Sec: propyl alcohol to acetone (d) Propanal to alcohol
36. Which one reduced when aldehyde react Tollenreagent:
(a) CU+2 (b) Ag+ (c) N (d) Cu2O
37. Which of the following metal can replace Hydrogen from acids to form ‘Salts’?
(a) Na (b) Cu (c) Au (d) Pt
38. Aldehyde may be distinguished from ketone by the use of:
(a) Concentrated H2SO4 (b) Pyrogallol (c) Grignard’s reagent (d) Fehling solution
39. Which statement about aldehyde and ketone is correct?
(a) Cyclic aldehyde exists (b) Cyclic ketone exists
(c)Both a & b (d) Neither cyclic aldehyde & ketone exists
40. The structural difference between hemiacetal and acetal is replacement of:
(a) OH group with OR (b) H atom with OR group
(c) H – atom with OH group (d) None of these
41. A hemiacetal is compound in which:
(a) OH, OR are attached with same carbon (b) OH –, R are attached with same carbon
–
(c)Two OH are attached with same carbon (d) None of these
42. Diastase, Surcrase, Zymase are used in the preparation of:
(a) Acetone (b) Acetic acid (c) Ethyl acetate (d) Ethyl alcohol

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CHEMISTRY-XII
1
CH#09 (P.S#01) BY:- SIR. HARESH KUMAR
43. Mixture of 85% C2H5OH, 4% CH3OH, 11% H2O is called:
(a) Wood spirit (b) Methylated spirit (c) Absolute alcohol (d) Rectifed spirit
44. General formula of Ketone is:
(a) CnH2nO (b) CnH2n+2 (c) CnH2nO2 (d) CnH2n-2O
45. Pyroligneous acid contains:
(a) Methanol (b) Acetone (c) Acetic acid (d) A.O.T
46. Reaction of phenol with conc: HNO3 from:
(a) Benzoic acid (b) Picric acid (c) Acetic acid (d) Amino acid
47. The weakest among the following is:
(a) CH3COOH (b) Cl2CHCOOH (c) ClCH2COOH (d) Cl3CCOOH
48. The reagent which does not give acid chloride on treating with a carboxylic acid is:
(a) H2SO4 (b) P2O5 (c) CH3COONa (d) CH3COOH
49. Acetic anhydride is obtained from acetyl chloride by the reaction of:
(a) PCl5 (b) Cl2 (c) SOCl2 (d) PCl3
50. Aldol condensation involving CH3CHO + CH3CHO gives the product:
(a) CH3CH (OH) CH2CHO (b) CH3COCH2CH3
(c) CH3 – CH = CH2 (d) None of these
51. Aldol condensation will not take place in:
(a) HCHO (b) CH3CH2CHO (c) CH3CHO (d) CH3CH2CH2CHO
52. Acetaldehyde reacts with:
(a) Electrophiles only (b) Nucleophiles only (c) Both (d) Free radicals only
53. Glycerol is used in the manufacture of:
(a) Points (b) Dynamite (c) Soft drinks (d) Dynamite
54. Which of the following gives negative iodo form test?
(a) C2H5OH (b) CH3 – CH2 – CH2 – OH
CH 3 − CH − CH 3 OH
(c) | (d) |
OH C6 H 5 − CH − CH 3
55. Acetals are:
(a) Ketones (b) Diethers (c) Aldehyde (d) Hydroxy aldehyde
56. In esterification, the reactivity of alcohols is:
(a) 1°> 2°> 3° (b) 3°> 2°> 1° (c) Same in all cases (d) N.O.T
57. Electrophillic substitution reaction on phenol takes place at:
(a) p-position (b) m-position (c) o-position (d) o and para position
58. The B.P of glycerol is more than propanol because of:
(a) Hydrogen bonding (b) Resonance
(c) Hyberdization (d) All of these
59. The alcohol which easily react with conc: HCl is:
(a) CH3 – CH(OH) – CH2 – CH3 (b) (CH3)3 C – OH
(c) (CH3)2 – CH2OH (d) CH3 – CH2 – CH2 – CH2 – OH
60. Which compounds has the highest boiling point:
(a) Acetone (b) Diethyl ether (c) Ethanol (d) Methanol
61. Which of these methods can be used to prepare alcohols?
(I) Hydrolysis of cyanides (II) Hydrolysis of olefins
(III) Reduction of carboxyl compounds
(a) I, II and III (b) I and II (c) II and III (d) I and III

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Cell: 0331-2677132, 0333-2757592