1

GYANA VIKASH ACADEMY

Haloalkanes and Haloarenes DPP-07

Br 4. CH3–CH–CH2 CH3MgCl
Cl Product
Mg/THF
1. P , Product P is: O
 Product is?
MgBr (1) CH3–CH–CH2OH
MgCl
(1) (2) CH3
(2) CH3–CH–CH2–CH3
Br
OH
MgCl (3) CH3 –CH–CH2
(3) (4) CH3
(4) HO–CH2–CH2–CH2–CH2–OH
Cl
|
t − BuO− 5. Elimination reaction generally occurs with the
2. CH 3 − CH − CH − CH 3 ⎯⎯⎯⎯  →
Major product is:
formation of
|
CH 3 (1) One sigma bond
(1) CH3 − C = CH − CH3 (2) one pi bond
| (3) one sigma and one pi bond
CH3 (4) None of the above
(2) CH3 − CH − CH = CH 2
| 6. Which of the following reaction is an elimination
CH3 reaction?
(3) CH 2 = C − CH 2 − CH3 (1) CH3 — CH2 — CH 2 — OH ⎯⎯⎯ PCl5
→
|
CH3 CH3 — CH2 — CH2 — Cl
OH CH3 — CH — CH3
| (2) CH3 — CH = CH 2 ⎯⎯⎯
HCl
→ |
(4) CH 3 − CH − CH − CH 3 Cl
| (3) CH3 — CH — CH 3 ⎯⎯⎯⎯
Alc.KOH
→ CH3 — CH = CH2
CH3 |
Cl
MgCl Cl CH3 — C — OCH3
CH3 — C — OH ⎯⎯⎯⎯ →
CH3OH
(4) ||
|| O
3. + P O
7. The reaction:
RX+2Na+RX ⎯⎯⎯⎯ Dry ether
→ R − R + 2NaX is called:
(1) (2)
(1) Sandmeyer's reaction
(2) Fittig reaction
(3) (4) (3) Wurtz reaction
(4) Williamson's synthesis
 2

8. The reaction given below is known as 10. C6H5COOH + CH3MgI → possible products
C6H5I + 2Na + ICH3 → C6H5 − CH3 + 2NaI (1) C6H5COOMgI
(2) CH4
(1) Wurtz reaction
(3) Both (1) and (2)
(2) Fittig reaction (4) C6 H5 — C — CH3
(3) Wurtz-Fittig reaction ||
(4) Ullmann reaction O

9. Major product of the reaction given below is 11. (CH3)3CMgCI on reaction with D2O, produces
(1) (CH3)3CD (2) (CH3)3COD
(3) (CD3)3CD (4) (CD3)3COD
alc. KOH

(1)

(2)

(3)

(4)