Professional Documents
Culture Documents
Mechanical Properties of 9Cr-1W Reduced Activation Ferritic Martensitic Steel Weldment Prepared by Electron Beam Welding Process
Mechanical Properties of 9Cr-1W Reduced Activation Ferritic Martensitic Steel Weldment Prepared by Electron Beam Welding Process
Mechanical Properties of 9Cr-1W Reduced Activation Ferritic Martensitic Steel Weldment Prepared by Electron Beam Welding Process
net/publication/264198285
CITATIONS READS
20 310
9 authors, including:
All content following this page was uploaded by G M S K Chaitanya on 11 January 2018.
h i g h l i g h t s
• Width of HAZ is smaller in the 9Cr–1W RAFM weldment prepared by EB process compared to that reported for TIG weldments in literature.
• Weld joint is stronger than that of the base metal.
• Toughness of weld metal prepared by EB welding process is comparable to that (in PWHT condition) prepared by TIG process.
• DBTT of as-welded 9Cr–1W RAFM weldment prepared by EB process is comparable to that reported for TIG weld metal in PWHT condition.
a r t i c l e i n f o a b s t r a c t
Article history: Microstructure and mechanical properties of the weldments prepared from 9Cr–1W reduced activation
Received 24 August 2013 ferritic martensitic (RAFM) steel using electron beam welding (EBW) process were studied. Microstruc-
Received in revised form 26 June 2014 ture consists of tempered lath martensite where precipitates decorating the boundaries in post weld heat
Accepted 4 July 2014
treated (PWHT) condition. Lath and precipitate sizes were found to be finer in the weld metal than in
Available online 24 July 2014
base metal. Accordingly, hardness of the weld metal was found to be higher than the base metal. Ten-
sile strength of the cross weldment specimen was 684 MPa, which was comparable with the base metal
Keywords:
tensile strength of 670 MPa. On the other hand, DBTT of 9Cr–1W weld metal in as-welded condition is
Electron beam welding
9Cr–1W RAFM steel
similar to that reported for TIG weld metal in PWHT condition.
Martensite © 2014 Elsevier B.V. All rights reserved.
Toughness and DBTT
1. Introduction specific RAFM steel has been developed at Indira Gandhi Cen-
ter for Atomic Research (IGCAR) [2]. The chemical composition of
Reduced activation ferritic martensitic (RAFM) steel is chosen 9Cr–1Mo–0.06Nb–0.2V–0.05N has been modified by substitution
as a structural material for test blanket modules (TBMs) to be of highly radioactive (induced) elements like Mo by W and Nb by
tested in ITER, for first wall and tritium breeding blanket appli- Ta to produce RAFM steel [2,3]. Physical and mechanical properties
cations in DEMO reactor. RAFM steels are chosen for their good of this steel are similar to that of Eurofer 97 [3].
irradiation resistance, thermo-physical and thermo-mechanical Joining and inspection technologies are very important for the
properties [1]. At present, all partner countries are collaborat- fabrication of TBM because of its complex design which is similar to
ing to achieve sustainable fusion reaction at ITER, France. Each a box structure with a maze of channels and irregular subcompo-
collaborating partner country in this program is working toward nents, thereby giving numerous joint configurations with limited
the development of its own indigenous structural material and accessibility for welding. Welding procedure qualification using
associated fabrication technologies for the TBMs [2–4]. Indian this steel for different fusion welding processes is in progress at
IGCAR in collaboration with other partner organizations. In weld
joints of high-Cr ferritic steels, heat affected zones (HAZs) are
∗ Corresponding author. Tel.: +91 44 27480118; fax: +91 44 27480118. known to be the weakest link in the structure [5,6]. Owing to the
E-mail addresses: chitta@igcar.gov.in, chittachaitri@gmail.com (C.R. Das). complicated design of the TBM, fusion welding processes, such as
http://dx.doi.org/10.1016/j.fusengdes.2014.07.001
0920-3796/© 2014 Elsevier B.V. All rights reserved.
C.R. Das et al. / Fusion Engineering and Design 89 (2014) 2672–2678 2673
tungsten inert gas (TIG), narrow gap TIG (NG-TIG), electron beam parameters that provide full penetration welds in 12 mm thick
(EB) and laser and laser-MIG hybrid welding are considered for fab- plate. The welding parameters used for EBW process are: Gun volt-
rication. EB, laser and laser hybrid welding are advanced joining age: 55 kV, welding speed: 1 m min−1 and electron beam current:
processes wherein the width of HAZs is significantly lower than 135 mA. Weldments were subsequently examined by radiographic
the width of HAZs formed in manual metal arc (MMA) or TIG weld- and ultrasonic inspection techniques. These weld joints were sub-
ments. Lower width of the HAZ enhances creep rupture life of jected to PWHT at 750 ◦ C for 90 min in a furnace at a heating rate of
the weldment [7]. Therefore, it is very important to understand 100 ◦ C h−1 . A few set of specimen blanks were subjected to PWHT
the microstructure and mechanical properties of the weldments of for 2 h at 740, 750 and 760 ◦ C. Face bend test specimens of size
9Cr–1W RAFM steel prepared by the above mentioned advanced 180 mm × 30 mm × 10 mm were fabricated from the as-welded
joining processes. This manuscript discusses the microstructural and post weld heat treated weldments and they were subjected to
and mechanical properties of 9Cr–1W RAFM steel weldments made three point face bend tests in a custom made bend test machine.
by electron beam welding. It may be noted that Indian specific For metallographic observation, cross weld specimens of size
RAFM steel contains 1.4 wt.% W and initial development was initi- 10 mm × 10 mm × 2 mm were prepared using conventional metal-
ated with 1 wt.% W, and present results are based on research work lographic route. For optical and scanning electron microscopic
carried out on 1 wt.% W RAFM steel. observations, the mirror polished specimens were etched using Vil-
lella’s reagent (1 g picric acid and 5 ml hydrochloric acid in 100 ml
2. Experimental ethanol). For comparison of weld metal microstructure, between
EB and gas tungsten arc welding (GTAW) process, weld pad was
9Cr–1W RAFM steel plates of 200 mm × 120 mm × 12 mm were prepared by 1.0 wt.% RAFM steel filler wire using 9Cr–1W RAFM
used for preparation of weld pads using EB welding process in steel plate of size 300 mm × 125 mm × 12 mm. Pre-heat tempera-
vacuum condition (1 × 10−3 mbar). A few autogenous weld beads ture, interpass temperature and heat input were 300 ◦ C, 250 ◦ C and
were made on a 9Cr–1W RAFM steel plates, to optimize the welding 1.2 kJ mm−1 respectively used for GTAW process. X-ray diffraction
Table 1
Chemical composition (in wt%) of RAFM steel used.
Element Cr C Mn V W Ta N B Ti Nb Mo
RAFMS 9.07 0.093 0.56 0.22 1.01 0.06 0.02 0.0005 <0.005 0.001 0.002
Element Ni Cu Al Si Co O P S As + Sn + Sb + Zr
RAFMS 0.005 <0.001 0.004 0.09 0.002 0.0046 0.002 0.002 <0.03
Fig. 1. Three-point bend test of 9Cr–1W RAFMS weldment in (a) as-welded and (b) PWHT conditions.
2674 C.R. Das et al. / Fusion Engineering and Design 89 (2014) 2672–2678
Fig. 3. (a) Low magnification image of RAFM weldment and low magnification secondary electron image of (b) CGHAZ (c) FGHAZ, and (d) ICHAZ.
also comparable with that of the base metal (350 MPa for YS and 4. Discussion
365 MPa for UTS). All cross-weld specimens failed in the base metal
far away from the weld interface. Photographs of the cross-weld Microstructure and mechanical properties of weld metal are
tensile tested specimens are shown in Fig. 7. These results clearly presented in the preceding sections. The influence of micro-
show that the weld metal is stronger than the base metal and structural changes on mechanical properties of the weldment is
this is also in agreement with higher hardness of the weld metal discussed in the succeeding section. From the macrographs (Fig. 3)
than that of the base metal. It may be noted that no filler wire and hardness distribution (Fig. 6a), it is estimated that the width
was used for joining this material. Therefore, the volume of weld of the HAZ is 0.5 mm. Commonly, HAZ width in the weldment
metal as compared to the base metal in the gauge is considerably varies between 1.5 and 3.5 mm when the weldments are prepared
less. Hence, the tensile properties of the weldment are influenced using MMA or TIG welding processes [9]. Lower width of HAZs in
marginally by high strength of weld metal. the weldment prepared by EB process as compared to those pre-
pared by other arc welding processes has been reported in literature
3.5. Impact toughness [5,6,10], and it is attributed to the high electron density and instan-
taneous decay of electron energy. In the case of metal–electron
Room temperature Charpy-V notch impact toughness of the interaction, the energetic electron hits the metallic surface caus-
weld metal in as-welded condition is found to be 190 J. Similarly, ing ejection of the valence electron or replacement of core electron
room temperature toughness of the weld metal after PWHT at dif- if the energy is sufficient. In this process, the electron instanta-
ferent temperatures is shown in Fig. 8. It shows that the toughness neously loses its energy during its interaction with material. The
value increased marginally to 191–210 J from the as-welded value time period of electronic decay is several orders less in magnitude
of 190 J after PWHT which was done at different temperatures. as compared to the heat transport properties of the material. As a
These values are similar to that obtained for the base metal (225 J). result, less volume of the metal gets affected in the case of EB pro-
Fractographs of tested specimens (as-welded and one PWHT con- cess compared to large volume of metal in the case of MMA process
dition) are shown in Fig. 9. Fig. 9a shows the presence of shallow and thereby, resulting in development of finer HAZ width.
dimple facets on the fracture surface of the as-welded specimen High hardness in the as-welded weld metal is due to the for-
whereas Fig. 9b shows the presence of numerous finer dimple facets mation of lath martensite after cooling to room temperature. This
on the fracture surface of PWHT specimen. Variations in toughness high hardness of the weld metal reduced from 400 HV0.5 in as-
of the EB weld metal (in the as-welded condition) with temperature welded condition to 264–294 HV0.5 after PWHT at 740–760 ◦ C.
is plotted along with published data on GTAW weld metal of RAFM During PWHT, carbon and other alloying elements diffused out
steel (PWHT at 750 ◦ C/2 h) in Fig. 10 [8]. From this figure it is clearly from the martensite lattice and bring down the c/a ratio resulting
evident that the DBTT of EB weld metal in as-welded condition is in decrease in the lattice strain [10]. As a result, lattice distortion
similar to that of TIG weld metal in PWHT condition. Here it may be decreases and consequently the hardness of the material decreases
mentioned that Srinivasan et al. performed Charpy-V impact test of too. On the other hand, further decrease in hardness of the base
weld metal after completion of PWHT at 750 ◦ C for 2 h. Considering metal after PWHT from that of the as-received condition suggests
68 J criteria, ductile brittle transition temperature estimated from adequate tempering of the base metal has not taken place in the
their test was reported to be −81 ◦ C [8]. Under similar criteria, the as-received condition. Hence, during PWHT, lath martensite con-
DBTT for EB weld metal is found to be −80 ◦ C. tinues to temper resulting in the coarsening of precipitates and
2676 C.R. Das et al. / Fusion Engineering and Design 89 (2014) 2672–2678
Fig. 5. XRD profile for as-welded and PWHT weld metal prepared using EB welding
process.
Fig. 6. Variation of the hardness (a) across the weld metal and (b) from root to cap.
C.R. Das et al. / Fusion Engineering and Design 89 (2014) 2672–2678 2677
Fig. 7. Cross weld tensile tested specimen in (a) As-welded and (b) PWHT condition.
tensile testing. It was shown that both yield and tensile strengths of During tensile loading, load was supported by the base metal
weldment are comparable to those of the base metal even though instead of the weld metal and HAZ due to their smaller dimensions
a slight reduction in the hardness of the base metal after PWHT is and as a result, failure location shifted toward the base metal. Albert
noted. This clearly shows that the weld metal is stronger than that of et al. [7] also reported similar observation regarding the shifting
the base metal. Width of the HAZ in the EB weldment is too narrow of failure location in the unaffected base metal far away from the
to affect the overall tensile properties of the weldment. Constraint weld interface in laser weldments under high stress condition at
effect of adjacent zones with higher hardness than this zone could high temperature. Rodrigues et al. [17] reported that the hardness
prevent its deformation during tensile testing. The observation of of the soft zone was lower compared to the base material in the
failure locations in cross-weld specimens clearly revealed that the weldment made using conventional fusion welding process. These
failure location was outside the HAZ in the base metal. In this con- authors also reported that with increase in width of soft zone, i.e.
text, one can conclude that the tensile properties of EB weldment width of the HAZ, the tensile strength of the soft zone decreases
would be better than that of weldments prepared using other pro- [18]. It may be noted that such observations were not noted in
cess. In fact, in literature, it has been noticed that the cross-weld the present investigation. Stability of microstructure in the HAZs
specimen of 9Cr steels fails in the unaffected base metal, outside the of EB weldment as compared to other weldments prepared by high
HAZ [13]. But, the formation of soft zone [14] in the HAZ of dissimi- heat input process, like SMA (submerged arc), FCA (flux-core arc)
lar weldment of 9Cr steel with 2.25Cr steel attributed to the failure and TIG welding process results in less variation in the hardness
in the weakest region of the HAZ [15]. Comparable strength of the which improves the creep life of the weldments. But substructures
base metal and cross-weld specimen is due to the matching com- develop in the ICHAZ or FGHAZ. In this direction, Albert et al. [7]
position of the weld metal, in addition to smaller volume of weld reported the improvement in creep rupture life for the ferritic steel
metal and HAZ comparable to that of the unaffected base metal in weldment prepared using EB process compared to TIG welding
the gauge length of the specimen. Though hardness in the HAZ of process at higher stress levels.
the fine and inter-critical heat affected zones is reduced marginally Good toughness in weld metal in as-welded and PWHT con-
[5,6,9], its contribution in reducing the overall strength of the cross- ditions is discussed as follows. The size of lath martensite and
weld specimen was minimal. In fact, more softening of base metal precipitates formed in the weld metal prepared by EB process is
and lesser softening of the weld metal could be the reason for com- finer than those reported in the weldment prepared by TIG process
parable strength of base metal and weldment. Observation of cross- [18]. In order to compare the precipitate size, high magnifica-
weld tensile tested fracture specimens (Fig. 7) revealed that the tion image, at 20,000×, was taken from TIG weld metal, EB weld
entire strain was accumulated in the fracture location. Das et al. [13] metal and 9Cr–1W RAFMS base metal. The measurement shows
reported the failure of the cross-weld specimen outside the HAZ in that the precipitate size is 137 ± 30 and 210 ± 75 nm in EB and
the unaffected base metal junction made of modified 9Cr–1Mo steel TIG weld metals, respectively. On the other hand, the precipitate
weldment and similar results are reported by many authors [16]. size is 161 ± 67 nm in RAFMS base metal studied in this investiga-
tion. It clearly suggests that the size of precipitate is bigger for TIG
weld metal as compared to the 9Cr–1W RAFMS base metal but it is
smaller for EB weld metal than that of the base metal. This is prob-
ably due to the high cooling rate experienced in the EB weld metal
after EB welding. These are clearly evident from the Figs. 2 and 4b.
During PWHT, annihilation of dislocations and precipitates form.
Annihilation of dislocations reduces internal strain and this is con-
firmed by the reduction in the width of {1 1 0} peak in XRD of the
weld metal subjected to PWHT from that of the as-welded condi-
tion. As a result marginal increase in toughness value is observed
after PWHT.
It is worth noting that W promotes retention of delta ferrite in
9Cr steel at room temperature, but this phase was not observed in
the present study as W content was 1 wt.%. Recently, Albert et al.
[19] reported retention of delta ferrite in 9Cr–1.4W RAFMS weld
metal prepared with EB welding process. Presence of delta ferrite
Fig. 8. Toughness of weld metal subjected to PWHT at 740, 750 and 760 ◦ C for 2 h is reported to increase the DBTT of 9Cr–1.4W RAFM steel close to
along with base metal toughness. the room temperature. These authors also showed that the DBTT
2678 C.R. Das et al. / Fusion Engineering and Design 89 (2014) 2672–2678
Fig. 9. Fractograph of Charpy impact specimen in (a) as welded and (b) PWHT condition (750 ◦ C).
References
[1] B. Van der Schaaf, D.S. Gelles, S. Jitsukawa, A. Kimura, R.L. Klueh, A. Moeslang,
et al., J. Nucl. Mater. 283–287 (2000) 52–59.
[2] B. Raj, T. Jayakumar, J. Nucl. Mater. 417 (1–3) (2011) 72–76.
[3] B. Van Der Schaar, F. Tavassoli, C. Fazio, E. Rigal, E. Diegele, R. Lindau, et al.,
Fusion Eng. Des. 69 (2003) 197–203.
[4] H. Tanigawa, T. Hirose, K. Shiba, R. Kasada, E. Wakai, H. Serizawa, et al., Fusion
Fig. 10. Variation in Charpy-V impact toughness vs. test temperature. Eng. Des. 83 (2008) 1471–1476.
[5] T. Kojima, K. Hayashi, Y. Kajita, ISIJ Int. 35 (1995) 1284–1290.
[6] V. Gaffard, A.F. Gourgues-Lorenzon, J. Besson, ISIJ Int. 45 (2005) 1915–1924.
does not change with increase in PWHT duration to 4 h at 750 ◦ C. [7] S.K. Albert, M. Tabuchi, H. Hongo, T. Watanabe, K. Kubo, M. Matsui, Sci. Technol.
Therefore, present result clearly demonstrate that lower DBTT is Weld. Join. 10 (2) (2005) 149–157.
[8] G. Srinivasan, B. Arivazhagan, S.K. Albert, A.K. Bhaduri, Fusion Eng. Des. 86
achievable if W content in 9Cr steel is 1 wt.%. Marginal variations in (2011) 446–451.
toughness values after PWHT at different temperatures suggest that [9] Z. Jiang, L. Ren, J. Huang, X. Ju, H. Wu, Q. Huang, et al., Fusion Eng. Des. 85 (2010)
the microstructure of weld metal is more stable within the temper- 1903–1908.
[10] M. Tamura, Y. Haruguchi, M. Yamashita, Y. Nagaoka, K. Ohinata, K. Ohnishi,
ature range investigated. Comparable DBTT values of as-welded EB et al., ISIJ Int. 46 (2006) 1693–1702.
weld metal and that of TIG weld metal (Fig. 10), which was tested [11] F. Abe, Mater. Sci. Eng. A 387–389 (2004) 565–569.
after 750 ◦ C/2 h PWHT suggests EB weld metal is tougher even in [12] H. Morito, T. Yoshida, X. Maki, Huang, Mater. Sci. Eng. A 438–440 (2006)
237–240.
the as-welded condition which is attributed to the fineness of the
[13] C.R. Das, S.K. Albert, A.K. Bhaduri, G. Srinivasan, B.S. Murty, Mater. Sci. Eng. A
microstructural features for EB weld metal. 477 (1–2) (2008) 185–192.
[14] S.K. Albert, T.P.S. Gill, A.K. Tiyagi, S.L. Mannan, S.D. Kulkarni, P. Rodriguez, Weld.
J. 76 (3) (1997) 135–142.
5. Conclusions
[15] S.K. Albert, G. Srinivasan, T.P.S. Gill, Proceedings of the National Welding Sem-
inar, IIW, Bangalore, 1997, pp. 222–232.
1. Sound weld joints were prepared with RAFM steel using EBW [16] B. Shanmugarajan, G. Padmanabham, H. Kumar, S.K. Albert, A.K. Bhaduri, Sci.
Technol. Weld. Join. 6 (2011) 528–534.
process.
[17] D.M. Rodrigues, L.F. Menezes, A. Loureiro, J.V. Fernandes, Int. J. Plasticity 20
2. Hardness of the weld metal decreased from ∼400 HV0.5 in as- (2004) 1–18.
welded conditions to 264–294 HV0.5 on PWHT at 740–760 ◦ C [18] S.K. Albert, M. Matsui, H. Hongo, T. Watanabe, K. Kubo, M. Tabuchi, Int. J. Press.
and variation of hardness across the weld joint after PWHT is Vessel Piping 81 (2004) 221–234.
[19] S.K. Albert, C.R. Das, S. Sam, P. Mastaniah, M. Patil, A.K. Bhaduri, et al., Fusion
found to be less than those reported for arc welds. Eng. Des. (2014), http://dx.doi.org/10.1016//j.fusengdes.2014.04.063 (in press).
3. Width of HAZ is smaller in the RAFM weldment prepared by
EB process compared to those reported for TIG weldments in
literature.