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Selecting The Right Material For 3D Printing
Selecting The Right Material For 3D Printing
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 2
Selecting the Right Material for 3D Printing
Material Selection
However, the material suppliers rarely publish material Generally, one or two material properties
specifications that document the change in properties distinguish an additive material from all others.
from one axis to another, as the data behind these For example, if seeking the average tensile
specifications can vary greatly by material, process and strength of polyamide (PA) 11, a stereolithography
even type of machine photopolymer maybe be a better option than a
selective laser sintering PA. Conversely, if the heat
By designing for the 3D printing process and adjusting deflection temperature (HDT) of an ABS is needed,
the build orientation, anisotropism or inadequate the best option would be a sintered nylon.
material properties can be overcome. To do this,
leverage the experiences from past projects or that of Recognizing that a few properties will separate
a qualified service organization to fill in the data gaps one material from the others, the recommended
that exist because of the limited material properties approach for selecting a material for 3D printing
data. When performance is critical, also consider is to first define what mechanical or thermal
independent lab testing of additive materials. properties are critical. Then review the material
options to find a fit. With the options narrowed,
While success is dependent on material properties, they review other remaining properties to determine if
are not the only considerations. Each additive material the material will be acceptable for the project.
and build process will also dictate characteristics such
as maximum part size, dimensional accuracy, feature Since 3D printing is unique, a goal of finding a
resolution, surface finish, production time and part perfect match to a cast, molded or machined
cost. So it is advised to select a suitable material and material is ill-advised. Instead, investigate the
then evaluate its ability to meet expectations and material options to find the material that satisfies
requirements related to time, cost and quality. the most critical requirements.
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 3
Selecting the Right Material for 3D Printing
the grain structures, which can change with the DMLS 130 ksi
Cobalt Chrome
laser parameters, post-build heat treatment and hot
DMLS
isostatic pressing. However, the results are not widely Inconel 718
180 ksi
available. Ultimately, this difference will become an DMLS
advantage when grain structure can be manipulated 129 ksi
Titanium
to offer varying mechanical properties in a part. DMLS
190 ksi
SS 17-4
Chart 1
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 4
Selecting the Right Material for 3D Printing
elongation at break is significantly lower (1% vs. 11%) when Wrought Metal 10%
Ti 23
compared to the average for 3000 series aluminums.
Wrought Metal 5 – 7%
17-4 Machined
DMLS titanium (Ti-64 ELI) is most commonly used for Wrought Metal 56%
aerospace and defense applications due to its strength- 316 Machined
to-weight ratio, temperature resistance and acid/
corrosion resistance. It is also used in medical applications. 0% 20% 40% 60% 80% 100%
Versus Ti grade 23 annealed, the mechanical properties
PERCENT
are nearly identical with a tensile strength of 130 ksi,
elongation at break of 10% and hardness of 36 HRC.
Chart 2
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 5
Selecting the Right Material for 3D Printing
Cobalt chrome (CoCr) is one of two DMLS superalloys that DIRECT METAL LASER SINTERING
tend to be used for specialty applications in aerospace and HARDNESS
medical. CoCr has an exceptional EB (20%), and it is creep and
corrosion resistant. Versus ASTM F-75 CoCr (dependent on MATERIAL
heat treating), DMLS CoCr offers moderate material properties DMLS
(DMLS vs. F-75): tensile strength of 130 ksi vs. 95-140 ksi, EB 25 HRC
Cobalt Chrome
of 20% vs. 8-20%, yield strength of 75 ksi vs. 65-81 ksi, and DMLS
35.5 HRC
Inconel 718
hardness of 25 HRC vs. 25-35 HRC. Of all DMLS metals, CoCr DMLS
has the best biocompatibility — which requires additional 39 HRC
Titanium
biocompatibility processing outside of Proto Labs — making DMLS
40 – 47 HRC
SS 17-4
it ideal for medical applications such as dental implants. Wrought Metal
IN718
36 HRC
40 60 80 100 120
Chart 3
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 6
Selecting the Right Material for 3D Printing
Selective Laser Sintering Generally, SLS PAs, when compared to the average values of
their injection-molded counterparts, have similar HDT values
DuraForm HST Composite is a fiber-filled PA that is similar
to a 25% mineral-filled PA 12. The fiber content in HST
SLS uses thermoplastic powders, predominantly polyamide but lower values for the mechanical properties. The exception significantly increases strength, stiffness and HDT. Compared
(PA), to make functional parts that have greater toughness is the fiber-filled DuraForm HST composite, which exceeds to other SLS and SL options (excluding ceramic-filled
and higher impact strength than parts produced through a mineral-filled PA 12 in all areas except tensile strength. In materials), HST has the highest tensile strength, flexural
SL, as well as high HDTs (351°F to 370°F). The tradeoffs a few instances, SLS PAs report properties that document modulus and impact strength, and it maintains an elevated
are that SLS lacks the surface finish and fine feature details the degree of anisotropism. For a visual comparison of SLS HDT. This makes HST a great choice for functional applications
available with SL. material properties, see Chart 4 for heat deflection, Chart 5 where temperatures exceeding 300°F may be present. The
for elongation at break and Chart 6 for tensile strength. material is somewhat brittle, however, with an EB of 4.5%.
Also consider that like injection-molded fiber-filled materials,
there is a significant delta in the Z-axis values.
DEGREES° IN FAHRENHEIT
Chart 4
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 7
Selecting the Right Material for 3D Printing
0 10 20 30 40 50
Charts 5 & 6
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 8
Selecting the Right Material for 3D Printing
Stereolithography
SL uses photopolymers, thermoset resins cured with STEREOLITHOGRAPHY
ultraviolet (UV) light. It offers the broadest material
MATERIAL HEAT DEFLECTION
selection with a large range of tensile strengths,
tensile and flexural moduli, and EBs. Note that the Accura 5530 131° – 482°
impact strengths and HDTs are generally much lower
than those of common injection-molded plastics. Accura 60 118° – 131°
The range of materials also offers options for color and
Somos Nano Tool 185° – 437°
opacity. Combined with good surface finish and high
feature resolution, SL can produce parts that mimic PC (Molded) 250° – 280°
injection molding in terms of performance and appearance.
RenShape 7820 125°
The photopolymers are hygroscopic and UV sensitive,
MicroFine Green 122° – 138°
which may alter the dimensions and performance
of the part over time. Exposure to moisture and UV Somos Watershed 115° – 130°
light will alter the appearance, size and mechanical
properties. For a visual comparison of SL material ABS (Molded) 185° – 215°
properties, see Chart 7 for heat deflection, Chart 8 for
Accura Xtreme White 108° – 117°
elongation at break and Chart 9 for tensile strength.
Somos 9120 126° – 142°
Accura Xtreme White 200 is a widely used SL material.
In terms of flexibility and strength, it falls between PP (Molded) 124° – 203°
polypropylene and ABS, which makes it a good choice for
SLArmor
snap fits, master patterns and demanding applications. 10% Metal Volume
122° – 516°
Xtreme is a durable SL material; it has a very high SLArmor 122° – 516°
impact strength (1.2 ft.-lb./in.) and a high EB (20%) 20% Metal Volume
Chart 7
MOLDED MATERIAL COMPARISON KEY
POLYCARBONATE ABS POLYPROPYLENE METAL
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 9
Selecting the Right Material for 3D Printing
PERCENT
Chart 8
MOLDED MATERIAL COMPARISON KEY
POLYCARBONATE ABS POLYPROPYLENE METAL
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 10
Selecting the Right Material for 3D Printing
0 10 20 30 40 50
Chart 9
MOLDED MATERIAL COMPARISON KEY
POLYCARBONATE ABS POLYPROPYLENE METAL
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 11
Selecting the Right Material for 3D Printing
Accura SL 5530 provides a strong, stiff part with high MicroFine Green is custom formulated at Proto Labs Proto Labs offers another proprietary material, SLArmor,
temperature resistance. Furthermore, a thermal post-cure to deliver the highest level of detail — 0.002 in. combining nickel plating with Somos NanoTool parts
option can increase HDT from 131°F to 482°F. 5530 has features are possible —and tightest tolerance available to offer an alternative to die-cast aluminum. The
the highest tensile and flexural moduli (545 ksi and 527 from any SL material. The material is used to make plating increases NanoTool’s tensile strength to 14.5
ksi, respectively) of all the unfilled SL materials and the small parts, generally less than 1 in. by 1in. by 1in. ksi to 29 ksi, depending on the percentage of metal
second highest tensile strength (8.9 ksi). However, the post- volume. HDT is drastically increased over NanoTool
cure does make 5530 less durable, resulting in an impact In terms of mechanical properties, MicroFine with a range of 122°F up to 516°F, and when
strength of only 0.4 ft.-lb./in. and an EB of 2.9%. Without Green falls in the mid-range of SL materials for compared to die-cast aluminum, the HDT is greater
the thermal post-cure, 5530 retains its tensile strength tensile strength and modulus (6.5 ksi and 305 ksi, than 500°F with a tensile strength of 43.5 ksi.
and becomes more flexible. Also, EB increases by 50%. respectively) and on the low end for impact strength
and EB (0.46 ft.-lb./in. and 6% respectively).
When compared to injection-molded thermoplastics, a
10% glass-filled polycarbonate is the closest match. With MicroFine Green has a stiffness (329 ksi vs. 333
the thermal post-cure, 5530 has similar tensile strength ksi) and tensile strengths (6.5 ksi vs. 6.0 ksi) similar
and flexural modulus (compared to the average values) to injection-molded ABS, however, MicroFine does
with 66% higher HDT. However, impact strength and EB are have a lower HDT than ABS of 138°F vs. 215°F.
much lower for 5530 (81% and 72% lower, respectively).
Conclusion
Spanning metals, thermoplastics and thermosets, 3D printing provides many different
materials that can simulate, if not replace, those that are processed through conventional
means. While an exact match is not possible, since the fundamental processes are
different, the material breadth means that there is a strong likelihood that the important
material characteristics are satisfied.
The key to success is being open to, and cognizant of, the differences. With the support
of an informed, qualified 3D printing resource that can fill in the data gaps, this mindset
opens the door to leveraging the unique advantages that 3D printing technology can offer.
>>Sources:
matweb.com, ulprospector.com, vendor datasheets and protolabs.com.
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 12
Selecting the Right Material for 3D Printing
Aluminum
LIGHTWEIGHT
Titanium Ti-6-4
Cobalt Chrome Inconel
TS: 896 MPa TS: 1,240 MPa
Aluminum
TEMPERATURE Elongation: 20% Elongation: 12%
Inconel 718
RESISTANCE Hardness: 25 HRC Hardness: 35.5 HRC
Titanium Ti-6-4
STRENGTH-TO-WEIGHT Aluminum
RATIO Cobalt Chrome
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 13
Selecting the Right Material for 3D Printing
Somos NanoTool
Huntsman RenShape 7820 SLArmor Somos 9120 TEMPERATURE
ALM PA 650
Similar to: ABS Similar to: Die-cast Aluminum Similar to: PP RESISTANCE
PA 615-GS
HD: 122°F HD: 122-516°F HD: 126-142°F
EB: 8-18% EB: 0.9-1% EB: 15-25%
TS: 36-51 MPa TS: 100-200 MPa TS: 30-32 MPa
Accura 5530
HIGH RESOLUTION MicroFine Green
Somos 9120
© Proto Labs 1999–2016 Proto Labs, Inc., 5540 Pioneer Creek Dr., Maple Plain, MN 55359 USA | 877.479.3680 14