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Lakshya JEE (2024)


Electrochemistry DPP-09

1. The desired amount of charge for obtaining one 8. 3 Faradays of electricity was passed an aqueous
mole of Al from Al+3 solution of iron (II) bromide. The mass of iron metal
(1) 3 × 96500 C (2) 96500 C (atomic mass 56) deposited at the cathode is
96500 96500 (1) 56 g (2) 84 g
(3) C (4) C
3 2 (3) 112 g (4) 168 g

2. When electricity is passed through the solution of 9. A current of 9.65 ampere is passed through the
AlCl3, 13.5 g of Al are deposited. The number of aqueous solution of NaCl using suitable electrodes
Faraday must be for 1000 sec. The amount of NaOH formed during
(1) 0.50 (2) 1.00 electrolysis is
(3) 1.50 (4) 2.00 (1) 2.0 g (2) 4.0 g
(3) 6.0 g (4) 8.0 g
3. One Faraday of electricity when passed through a
10. A current of 2.6 ampere is passed through CuSO4
solution of copper sulphate deposits
solution for 6 minute 20 seconds. The amount of Cu
(1) 1 mole of Cu (2) 1 gm atom of Cu
deposited is
(3) 1 molecule of Cu (4) 1 gm equiv. of Cu
(At wt. of Cu = 63.5, Faraday = 96500 C)
(1) 6.35 g (2) 0.635 g
4. The density of Cu is 8.94 g/cm3 the quantity of
(3) 0.325 g (4) 3.175 g
electricity needed to plate an area 10 cm × 10 cm to
a thickness of 10–2 cm using CuSO4 solution would
11. 3 Faradays of electricity are passed through molten
be
Al2O3, aqueous solution of CuSO4 and molten NaCl
(1) 13586 C (2) 27172 C
taken in three different electrolytic cells. The
(3) 40758 C (4) 20348 C
amount of Al, Cu and Na deposited at the cathodes
will be in the ratio
5. What current strength in ampere will be required to
(1) 1 mole : 2 mole : 3 mole
liberate 10 g of chlorine from sodium chloride (2) 1 mole : 1.5 mole : 3 mole
solution in one hour? (3) 3 mole : 2 mole : 1 mole
(1) 7.55 ampere (2) 7.15 ampere (4) 1 mole : 1.5 mole : 2 mole
(3) 7.50 ampere (4) 7.45 ampere
12. 2.5F of electricity are passed through a CuSO4
6. A certain current liberated 0.50 gm of hydrogen in 2 solution. The number of gram-equivalent of Cu
hours. How many grams of copper can be liberated deposited on cathode is
by the same current flowing for the same time in a (1) zero (2) 1.25
copper sulphate solution. (3) 2.5 (4) 5.0
(1) 12.7 gm (2) 15.9 gm
(3) 31.8 gm (4) 63.5 gm 13. An electric current of 100 amperes is passed through
a molten liquid of sodium chloride for 5 hours.
7. One Faraday of electricity will liberate one mole of Calculate the volume of chlorine gas liberated at the
metal from solution of electrode at NTP.
(1) AuCl3 (2) CuSO4 (1) 210.5 L (2) 200 L
(3) BaCl2 (4) KCl (3) 211 L (4) 208.91 L
2

14. A current of strength 2.5 amp was passed through 16. If 0.5 amp current is passed through acidified silver
CuSO4 solution for 6 minutes 26 seconds. The nitrate solution for 10 minutes. The mass of silver
amount of copper deposited is (Atomic weight of deposited on cathode is : (Eq. mass of silver nitrate
Cu = 63.5) = 108 )
(1 faraday = 96500 coulomb) (1) 0.235 g
(1) 0.3175 g (2) 3.175 g (2) 0.336 g
(3) 0.635 g (4) 6.35 g (3) 0.536 g
(4) 0.636 g
15. Electrolysis of water with 1 Faraday electricity gives
(1) 1 mole of oxygen
(2) 1 gram equivalent of oxygen
(3) 1 molecule of oxygen
(4) 1 atom of oxygen
3

Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (1) 9. (2)
2. (3) 10. (3)
3. (4) 11. (2)
4. (2) 12. (3)
5. (1) 13. (4)
6. (2) 14. (1)
7. (4) 15. (2)
8. (2) 16. (2)

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