cheieaaoh Miata nansee Sov, | Ono arses Maren Bhavan. Marne Morne Mar, NSieaerihe 1s RD Serene a ‘Yaa Pate (7), Mme!” 400 69. na BR een Second Preliminary Examination January 2024 CHEMISTRY Std. 10 Marks:80 Time:2 hrs Date:12/01/2024 Answers to this Paper must be writterdpn the paper provided separately. You will not be allowed to write This time is to be spe The time given at the head of this answers. Question 1 Choose the estions from the given options. {15} (Do not cop cc answers only) (i) Sodium hydroge@Btxbonate when addRjto acetic acid evolves a gas. Which of the following zi Sock ee ccd 4 cag connie (B) It extinguishes a burning Cayoort4 whys, Skee (C) It dissolves in a solution of cdg soda. (D) It has a pungent odour 5 @)AandB AOT (b)A, Band C (@)B,CandD (@)Aand D (ii) Assertion (A). Volumes of gases are converted to standard temperature and pressure conditions and compared, Reason(RR): Changes in any volume changes the temperature and pressure, (@) Both assertion and reason are true, and reason is the correct explanation of assertion(b) Both assertion and reason are rue, bul reason is not the correct explanation of assertion. (©) Assertion is tre but reason is false. (4) Assertion is false, but reason is tru. (Gli) IFS moles each of NaOH Ht ‘sCOsand ‘heaviest and lightest in mass? (At. wt: Na=23, Heaviest MgCOs CaCO i: ‘NaOH (iv) 20 em*of ethyne are reacted with 500. 2Calh2 + 502 4C0; +2120 Calculate the total volume of gas remaining. ‘measured at room temperature and pressure. (a) 400 ce (0) $20ce (0) 450ce (@) 490ce () Sulphyffe (a) it has two () it yields nascent (©)it displaces more vol @ it forms acid salts, I's concentrated gen ions. (vi) A salt solution when ‘and the gas formed on Potassium iodide (@) Sodium nitrate (b) Potassium nitrate (©) Calcium nitrate (@) Ammonium nitrate (vil) Which one of the chloride (@) Catto ) CHa (©) Croke Cathe(iti) solution contains two cation Positive for that anion? (2) tums starch iodide paper blue black (b) bums with a greenish yellow fame (©) tums potassium iodide paper brown (€) tums Nesser’s reagent brown (ix) The reactions of four different oxides P, Prreacts with Hydrochl Q reacts with both Hy R does not r S reat B.S ae ge ric cd bt not wth Sod RR srochloc and Sau hyo with both Hyer and So with Sodium hydro Which ow shows the corey but not with hy pe of oxide? T basic [acid neutral @ [Rr Q oP. S fy {Q a @ Is P (x) The diagram shows, us Concentrated aquecus: cram poorer (oaty1 O)iads (Genly2 (@)2anss (xi) The substance which will NOT react with liquor ammonia’ (@) Rock salt (b) Blue vitrio! (©Slaked lime (@ Green vitriol 's namely Barium and silver, but one anion, which test will be nes, at which electrode(xi) These reactions occur in the air during a thunderstorm, N: +0: 2NO 2NO +0: 9 2NO; NO +0} NO; + 0: Which row shows what happens tothe reactant molecules iGEM Sede FeRetne? tao. NO Oy oxidised oxidised oxidised oxidised oxidised reduced reduced | reduced reduced | reduced |_| (xiii) Which of the following is correct with referen (@) Na>Mg>Cl>Ar () NaC1>Na>Mg (@) Ar Myo + 4 jc mixture other than the ore of Aluminium. ice of *X*. (b) Name *X" and ¥” (©) Name the compounds in the ele (@) Write a reaction that may take place’ (€) Write the reaction at Z. wart the underlined word, rewrite the false 1s) (iii) State whether the statement is true or statement (a) When an atom of an element loses or gains electrons it undergoes ionization. (>) An element X placed to the right of element B, will be a better reducing agent. () The hydrolysis of Calcium earbide results in formation of Ethylene, (4) Gay Lussac's law explains the relationship between the volume of a gas and the number oof moles at constant conditions of temperature and pressure, (c) Sulphur produces its own acid on treatment with Cane. Sulphuric acid 5 ~~(Gv) (@) Draw the structural formula of following organic compounds: a 1) Carbon compound containing two carbons whose general formula IS Cylfix0 2) Position isomer of Dimethyl acetylene 3) 2,2-dimethyl_ butan-I-oie acid (b) Draw an electron dot diagram for formation of the anion formed on splitting of water molecule, a (¥)_ Observe the setup for preparation of ammonia angfanswer the questions that follow: S| Cauchy Ng Gree ‘with a balance chemical equation. fon of Ammonia from *X? and alkali ‘Question 3 ( Write balanced chemical reactions forthe following: bI (8) Formation of insoluble sulphate of a divalent amphoteric metal using two salt solutions (©) Formation of Carbon dioxide from Ethanol (©) Reaction of the sulphide of bivalent metal with a monobasic acid + 4c casts(li) Write the IUPAC names of the following compound: @ ad A, acenendiciren 2 ou chy os Cagceon t NASY + o fe CA3¢ oN ate i \ (iit) Observe the schematic diagram and answer the qutgjons that fo A main eee ick time cHsCOOH => * + NaxCOs (@) Which of the compounds willie 2 higher pH, P or R? Justify your answer. Question 4 (i) Students of grade 10 were given the f0 appropriate method to prepare the given} ate, Calcium chloride, Tron, Nitric acid, dilute Hydrochloric acid, Copper, dilute Sulphuric acid, Calcium, Copper (II) oxide, (mention the method used) White balanced chemical equations for the preparation of the salts, mention the method used. [3] (@) Ferric chloride (&) Blue vitriol (©) Calcium carbonatear (it) Give reasons for the following {a) Bauxite ore is concentrated by a chemical method 1) The reactivity of halogens decreases down the group llows large amount of current to pass through i (©) Dilute Hydrochloric acid (i) Due to its affinity for water, pure anhydrous sulphur not exist innature. (4) uric acid, but itis used in production of Voleanic activity can result in the production of various chemicals and thus is prepared industri (a) Name the process. prepare the acid, Explain why? (@) Write a balanced che furic acid of desired concentration, Question 5 is evolved which turns acid no such gas is evolved by salt *Q Step 2) On adding ammonium hydroxide to the solution of (Qa pale blue was formed cide to form a deep inky blue solution, Step 3) On adding freshly prepared. ate solution and cone, Sulphuric acid to solution of “Q’ a brown ring was observed atthe junction ofthe two liquids. which dissolves in excess Based on the inform: given, answer the following questions: - 8 (@) Identify the anion present in *P” and *Q?. (b) Write a, ical reaction for addition of Ammonium hydroxide solution to solution of Q’ «© ‘if salt *Q? is thermally decomposed.(@) Wate a balanced chemical reaction taking place in step IP (©) What will you observe if 2 Ca oryNd, +0, Oxygen just sufficient to roast 9.7; ort ethetle (i) Cateulate: