1

Manzil
Thermodynamics
Aa dekhein zara

TIME 50 MIN.
MAXIMUM MARKS 200
MARKING SCHEME +4/–1

1. Which is an irreversible process? (B) E = q + w for every thermodynamic

(A) Mixing two gases by diffusion system at rest in the absence of
(B) Evaporation of water at 373 K and 1 external field
atm pressure (C) q = 0 for every cyclic process
(C) Solidification of water at 273 K and 1 (D) E = 0 for every cyclic process
atm pressure
(D) All of these 5. Reversible melting of solid benzene at 1
atm and normal melting point correspond
2. E = 0 for which process to
(A) Cyclic process (A) q > 0 (B) w < 0
(B) Isobaric expansion process (C)  E> 0 (D) All of these
(C) Isochoric process
(D) Adiabatic process 6. A system is provided 50 J of heat and
work done on the system is 10 J. The
3. If x and y are arbitrary extensive variable, change in internal energy during the
then process is
(A) (x + y) is an intensive variable (A) 40 J (B) 60 J
x (C) 80 J (D) 50 J
(B) is intensive variable
y
(C) (x – y is intensive variable 7. The incorrect statement among following
(D) (x × y) is intensive variable is
(A) When a substance is in its
4. Out of the following the correct statement thermodynamics standard state, the
is substance must be at 25ºC
(A) w is a state function (B) Heat capacity at constant pressure is
an extensive property
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(C) Reversible process can be reversed at (C) There is no exchange of mass and
any point in the process by making energy with the surroundings
infinitesimal change (D) There is exchange of mass with the
(D) Molar internal energy is an intensive surroundings
property
15. Universe is considered as
8. A system absorbs 600 J of heat and does (A) Close system
work equivalent to 300 J on its (B) Open system
surroundings. The change in internal (C) Isolated system
energy is (D) None of these
(A) 200 J (B) 300 J
(C) 400 J (D) 600 J 16. Five moles of an ideal gas expand
isothermally and reversibly from a
9. Which of the following is an extensive pressure of 10 atm to 2 atm at 300 K.
property? What is the largest mass (approx.) which
(A) Temperature (B) Pressure can be lifted through a height of 1 m in
 Mass  this expansion?
(C)   (D) Enthalpy (A) 20.48 g (B) 204.8g
 Volume 
(C) 20.48 kg (D) 2048 kg
10. Which among the following is not state
17. Two moles of an ideal monoatomic gases
function?
are allowed to expand adiabatically and
(A) Internal energy
reversibly from 300 K and 200 K. the
(B) Free energy
work done in the system is (CV = 12.5
(C) Enthalpy
J/K/mole).
(D) Work
(A) –12.5 kJ (B) –2.5 kJ
(C) –625 kJ (D) 500 kJ
11. Which of the following is an intensive
property?
18. If a certain mass of gas is made to
(A) Volume (B) Free energy
undergo separately adiabatic and
(C) Entropy (D) Pressure
isothermal expansions to the same
pressure, starting from the same initial
12. The first law of thermodynamics is
conditions of temperature and pressure,
represented by the equation
then as compared to that of isothermal
(A) E = Q + W (B) E = Q – W expansion, in the case of adiabatic
(C) E = Q (D) Q = W – E expansion, the final
(A) Volume and temperature will be
13. The net internal energy change in higher
reversible cyclic process is (B) Volume and temperature will be
3 lower
(A) RT
2 (C) Temperature will be lower but the
(B) Zero final volume will be higher
(C) Greater than zero \ (D) Volume will be lower but the final
(D) Less than zero temperature will be higher

14. An isolated system is that system in which
(A) There is no exchange of energy with
the surroundings
(B) There is exchange of mass and
energy with the surroundings
19. If separate samples of argon, methane,
nitrogen and carbon dioxide, all at the
same initial temperature and pressure and
expanded adiabatically reversibly to
double their original volumes, then which

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one of these gases will have high 5 7

temperature as final temperature? (A) (B)
3 5
(A) Nitrogen (B) Argon 9 9
(C) Methane (D) Carbon dioxide (C) (D)
7 11
20. Out of the following incorrect statement/s
is/are 27. 16 gm of O2 expand at constant pressure
(A) CV is independent of T for a perfect and 273.15 K to occupy double its
gas original volume. The work done during
(B) A process in which final temperature the process will be
equals initial temperature must be an (A) w = –260 cal
isothermal process (B) w = –180 cal
(C) w = –130 cal
(C) T = 0 for every adiabatic process in
(D) w = –273.15 cal
a closed system
(D) All of these
28. One mole of ideal gas is allowed to
expand reversibly and adiabatically from
21. Reversible cooling of perfect gas at
a temperature of 27ºC. If the work done
constant volume takes place then which
during the process is 3kJ. The final
among the following is incorrect?
temperature will be equal to
(A) q < 0 (B) w = 0
(Cv = 20 JK–1)
(C) E < 0 (D) H > 0
(A) 150 K (B) 100 K
(C) 26.85 K (D) 295 K
22. Adiabatic expansion of ideal gas into
vacuum correspond to
29. The work done on the system when one
(A) w = 0
mole of an ideal gas at 500 K is
(B) E = 0 compressed isothermally and reversibly to
(C) H = 0 1
(D) All of these th of its original volume (R = 2 cal)
10
23. Reversible heating of perfect gas at (A) 500 kcal (B) 15.1 kcal
constant P is not correctly explained by (C) 25.03 kcal (D) 2.303 kcal
(A) q > 0 (B) w < 0
30. Adiabatic process involves
(C) E > 0 (D) H > 0
(A) q = 0 (B) W = 0
24. The temperature of 1 mole of a gas is (C) E = 0 (D) V = 0
increased by 1ºC at constant pressure. The
work done is 31. What is correct for adiabatic expansion of
(A) R (B) 2R  Cp 
ideal gas   = ?
R  Cv 
(C) (D) 3R
2 (A) PV = constant
(B) TV = constant
25. Heat capacity of H2O at its boiling point is P
(A) 3 cal mol–1 K–1 (C) = constant
(B) 5 cal mol–1 K–1 T
(C) 7 cal mol–1 K–1 (D) PV–1 = constant
(D) Infinite
32. Molar heat capacity of water in
26. For monoatomic ideal gas, the exact value equilibrium with ice at constant pressure
of the ratio of Cp,m and Cv,m is is
(A) Zero

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(B) Infinity volume of 1 litre to 10 litre. The E for

(C) 40.45 kJ K–1 mol–1 the process is: (R = 2 Cal K–1 mol–1)
(D) 75.48 JK–1 mol–1 (A) 163.7 Cal (B) 1381.1 Cal
(C) 9 L-atm (D) Zero
33. Which of the following is an open
system? 39. In an adiabatic process which of the
(A) Animals and plants following is true?
(B) A fridge (A) q = +w
(C) A solar cooker (B) –E = –w
(D) None of these (C) PV = 0
(D) q = E
34. One mole of gas occupying 3 litre volume
is expanded against a constant external 40. In an isochoric process, the increase in
pressure of one atm to a volume of 15 internal energy is:
litre. The work done by the system is: (A) Equal to the heat absorbed
(A) –1.215 × 103J (B) Equal to the heat evolved
(B) + 12.15 × 103J (C) Equal to the work done
(C) + 121.5 × 103J (D) Equal to zero
(D) + 1.215 × 103J
41. When a solid melts, there is:
35. The work done during the expansion of a (A) No increase in enthalpy
gas from a volume of 4dm3 to 6 dm3 (B) Increase in enthalpy
against a constant external pressure of 3 (C) Decrease in enthalpy
atm is: (D) Anything can happen
(A) –608 J
(B) + 304 J 42. For the reaction N2(g) + 3H2(g) →
(C) –304 J 2NH3(g) which of the following is valid?
(D) –6 J (A) H = E (B) H < E
(C) H > E (D) None of these
36. The work done during the expansion of a
gas from a volume of 14 dm3 to 16 dm3
43. Heat exchanged in a chemical reaction at
against a constant external pressure of 2
constant pressure is called:
atm is:
(A) Internal energy (B) Enthalpy
(A) –405.2 J (B) +304 J
(C) Entropy (D) Free energy
(C) –304 J (D) –6 J
44. Latent heat of vaporization of a liquid at
37. A system absorb 300 Cal of heat with the
500 K and 1 atm pressure is 10.0 kCal
result of that, the volume of the system
mol–1. What will be the change in internal
becomes double of its initial volume and
energy of 3 mol of liquid at same
temperature changes from 273K to 546K.
temperature and pressure?
The work done by the system on the
(A) 13.0 kCal (B) –13.0 kCal
surroundings is 200.0 Cal, then calculate
(C) 27.0 kCal (D) –27.0 kCal
E.
(A) 273 kCal
45. What is the value of ng if we consider the
(B) 500 Cal
combustion of 1 mol of liquid ethanol if
(C) 100 Cal
reactants and products are at 298 K:
(D) –500 Cal
(A) –1 (B) –2
(C) +1 (D) +2
38. One mole of an ideal gas at 300 K is
46. If a reaction involves only solids and
expanded isothermally from an initial
liquids, which of the following is true?

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(A) H < E 49. Calculate w for the isothermal reversible

(B) H = E of 1 mol of an ideal gas from an initial
(C) H > E pressure of 1.0 bar to a final pressure of
(D) H = E + RTng 0.1 bar at a constant temperature of 273
K:
47. The value of H – E for the following (A) –5227.2J (B) +5227.2J
reaction at 27ºC will be, 2NH3(g) → N2(g) (C) –2257 J (D) +2257 J
+ 3H2(g):
(A) 8.314 × 273 × (–2) J 50. When 229 J of energy is supplied as heat
(B) 8.314 × 300 × (–2) J at constant pressure to 3 mol Ar(g), the
(C) 8.314 × 27 (+2) J temperature of the sample is increased by
(D) 8.314 × 300 (+2) J 2.55K. Calculate the molar heat capacity
at constant volume:
48. At constant temperature for the reaction (A) 30 kJ K–1 mol–1
(B) 30 J K–1 mol–1
C3Hg(g) + 5O2(g) → 3CO2(g) + 4H2O ( ) ,
(C) 21.7 J K–1mol–1
E – H is: (D) 21.7 kJ K–1 mol–1
(A) +RT (B) –3RT
(C) +3RT (D) –RT

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ANSWER KEY

1 (A) 14 (B) 27 (D) 40 (A)

2 (A) 15 (C) 28 (A) 41 (B)
3 (B) 16 (A) 29 (D) 42 (B)
4 (D) 17 (B) 30 (A) 43 (B)
5 (D) 18 (B) 31 (A) 44 (C)
6 (B) 19 (C) 32 (B) 45 (A)
7 (A) 20 (D) 33 (A) 46 (B)
8 (B) 21 (D) 34 (A) 47 (D)
9 (D) 22 (D) 35 (A) 48 (C)
10 (D) 23 (B) 36 (A) 49 (A)
11 (D) 24 (A) 37 (C) 50 (C)
12 (A) 25 (D) 38 (D)
13 (B) 26 (A) 39 (B)

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